a CHEMIsTRy 4. 27°C HUH Ee Ae a sett HO} sree AS TAH earns (A) 8.314 kJ (B) 2.494 kJ (C) 24.945 (D) 8.3149 2. Prafefard 8 aa-a ate ate te firge arftifeen ait exter 2 7 (A) CH,(g) + H,0(g) 220K , CO(g) + 3H,(9) eu (B) 2C(s) + O2(g) + 4N,(9) _1273K |, 5¢0(g) + 4N,(9) (C) C(s) + H,0(9) —1270K , CO(g) + H2(9) (0) co(g) + H,0(g) 2B CO,(g) + H2(9) 3. cafes eregtanrea ar zeta Fe fa gre ae fara Hee e ? 1 The work done, in dissolving one mole of zinc in an aqueous HCI in open beaker at 27°C is (A) 8.314 kd (B) 2.494 kJ (C) 24.945 (D) 8.314 ‘The equation that represents the wate gas shift reaction is (A) CH,(g) + H,0(9) art CO(g) + 3H,(9) (B) 2C(s) + O,(g) + 4N2(9) —1273K_, 20019) + 4N2(9) (C) C(s) + H,0(9) _1270K CO(g) + H2(9) (0) CO(g) + H,0(g) 3K, Cat coga)+ Hie “NS . Thesynthesis of ‘aromatic hydrocarbor can not be done by the process (A) Fittig reaction (B) Wurtz-Fittig reaction (C) Wurtz reaction (D) Friedal-Craft alkylation7. Prafefad i : waits 8? ea (A) reef aire (B) settee are (C) Bfratte ary (D) Streeter strat 8, fel fR vonftas ty smsit At sete artes sat (A) 1.15 (8) 1.16 (C) 1.30 (D) 1.67 9. St vai a Pattee arctan A gars 8 (A) Sem (B) ohm cm (c) Sm (D) ohm" mrt 10. Preferftaa & fara aif ang A fer waa sara @ ? (A) (AglI®, [CoF,]*, [Co(NCS),]?° (B) [AgF,)°, [Col,]°°, [Pa(NCS),]°° (C) [Co(CN)gFI, [Co(NCS),P°, [Pd(SCN),]°? (0) [Co(NH,).FI?®, (oF, [Co(SCN), °° ~ . Which one of the followin g has the highest melting point ? (A) Tartaric acid (B) Aminoacetic acid (C) Succinic acid (D) Oxalic acid Ratio of molar heat capacities of diatomic gas molecules is (A) 1.15 (B) 1.16 (C) 1.30 (D) 1.67 The unit of specific conductance in SI system is (a) Som (8) ohm cm (Cc) Sm (0) ohm=1 mrt ‘Among the following complexes most stable species are (A) [AgLJ®, (CoFe}*°, [Co(NCS),}°° (8) [AGF>I°, [Colg]®, [Pa(NCS),P° (C) [Co(CN)gFI®, [Co(NCS),)°, [Pd(SCN),}°° (0) [Co(NH)gFF®, (CoFI®, [Co(SCN), °°11, dia FH ete wtf A, TeTeCT, TA, TTS cen ones TAFE mee (A) Aerts > creer > Fa (@) WR > einfta > BEF (©) Te > wa > TTS (0) PRR > vrata 5 a . aa Swen A sofeae at aa oration Ar safeeate thd & aera Al fe a mathe? (A) CH,- O aaa’ (8) CH,-O-claaa® (C) CH,-O- Om? (D) CH, - O- CH, aT? , Tegra oy pager eregTat % X stesHt Saffire Heh oitearsa Az | XT ame (a) 4 (B) 2 C3 (0) 1 _ Rraferfiaa ta ate As,S, HATES F fere aaa aftr Gener err TET ? (A) POF (B) Ais (Cc) SOF (D) Nat 11, \ i . three heterocyclic compounds, for 'Mple, furan, pyrrole and thiophene, e order of aromaticity is (A) Thiophene > pyrrole > furan (B) Pyrrole > thiophene > furan (C) Pyrrole > furan > thiophene (D) Furan > pyrrole > thiophene Why presence of oxygen decreases the rate of chlorination of methane in the presence of sunlight ? (A) CH, - Ois formed (B) CH,-0-Clis formed (C) CHg- 0 - Ois formed (D) CH, - 0 -CH, is formed The glucose molecule reacts with X molecules of phenyl hydrazine to yield cosazone. The value of X is (A) 4 (8) 2 (c)3 (0) 1 Which one of the following will have the highest coagulating power for As,S3 colloid ? (A) POS (B) AIs* (Cc) SOP (D) Na* PG-02/Aif 2 a FF aA arn H, SeTEOT, er, RT ey eres HAT ammae (a) aris > ayaet > FRA (@ Re > ere > FT (6) rate > gra > ae (0) ARH > rete > ee ayer A sofeata a ori Fase ah 3 ate Mh FH AA? (A) CH, - O aaa® (8) CH,-0-clawar® (C) CH,-0- Ommm® (0) CH, -O- CH, 71 ® cep Frage reg Xx I ativan ace ters 2ar® | X71 me (A) 4 (8) 2 ©3 (D) 1 J frefettan a FIG As,S., FTES 3 fer ore Hera ere eae TAIT? (A) POY (8) Als 1% (©) SOF (D) Nat % . The glucose m Int i i‘ three heterocyclic compounds, for ft imple, furan, pyrtole and thiophene, le Order of aromaticity is (A) Thiophene > pyrrole > furan (B) Pyrrole > thiophene > furan (C) Pyrrole > furan > thiophene (D) Furan > pyrrole > thiophene . Why presence of oxygen decreases the rate of chlorination of methane in the presence of sunlight ? (A) CH, - Ois formed (8) CH, - 0 Clis formed (C) CH,-0- Ois formed (D) CH, - 0 -CH, is formed jolecule reacts with x molecules of pheny! hydrazine to yield osazone. The value of X is (a) 4 (8) 2 (c) 3 (1 Which ‘one of the following will have ‘the highest coagulating power for AS2S3 colloid ? (a) PO (B) AY (c) SOF (0) Nat15. (Re Cl] & aa (A) a Re wer wea dy aan (8) a Re mea an aad (©) a Re ney te au te (2) 3 Re & teq an dy aan ® 16. HSAB fatgia & sigan fevfatad 4a AIT GT ARR ? (A) (AQF,I° (B) [Ca(NH,),J2® (C) (Colg]3® (0) {Agl,I° 47. aifirar an a deez fara Haat ft & fee ara e (A) sie sififipaet (8) warren sftfeat (C) are 2 safer ftir (0) wht siftiiearet 18, Prafeftaad a fra are A eres sp3d?@ ? (A) [IFJ? (B) (Ici (©) [BrFA}° (0) (Cl! osolsho possess ee bond between two Re ©) © “Triple bond between two Re ‘Quediuple bond between twop, pouble bond between two Re i) igh complex amongst the followiy ig stable according to HSAB principle) ak (a) (Ags (@) (Ga(NH,) 12° (©) (Cols (0) [Aalel® +S The collision theory of reaction rate y valid for (A) Complex reactions (8) Parallel reactions (C) Simple bimolecular reactions (D) All the reactions Which ion possess spd? hybridisation 7 ay SEE oe 1 (8) [Ici Je (C) [BrF Ie (0) (lel Bs 19. a19. The outcome of Camot's theorem is the concept of the following (A) Enthalpy (B) Internal energy (C) Free energy (©) Entropy 20. Surface area of an adsorbent is calculated by using following equation (A) Freundlich equation (B) Langmuir equation (C) B.E.T. equation (D) McBain equation 21. Among the chlorides of alkaline earths given below, the lowest melting point as per Fajan’s rules will be ge by (A) CaCl, (®) BaCl, ‘© (C) MgCl, oO (D) SiCl, @ Who first used phenyl for the synthesis of a peptide ¥ (A) Frederic Sanger a ae ‘ (8) Max Bergmann (C) Leonidas Zervas (0) Fehr Edmangad airs Waa Te ‘COOH COOH 23. COOH ‘COOH (0) oa, freee 3 Pra fr 3 srt et atia @ ? (a) #4 (©) Sat (©) Ha (0) #4 25, woomrefacht ar ere Fare arena @ (A) Rrarae (8) arate (C) waren nt (0) arate wea PG-02/A 23, The most strong acid is cooH o ©) cooH OH (8) COOH HO, OH (C) ‘COOH cH, (0) 24, Which of the following compounds has a cylindrical symmetry ? (A) Ethane (B) Ethyne (C) Methane (D) Ethene 25. First law of thermodynamics is based on (A) Theory (B) Derivation (C) Quantum mechanics (D) Experimental factsig 26. 27. 28. 29. 4pCl; + 4NHy 7 satiate ae are 2 ? (A) (PNCI,), + SHCI (8) (PNCI,), + 12HCI (©) (PNCI,), + 12HC1 (0) (PNCI,), + 9HCI fat scha Reet Al arama a Fae Fae are faa A TAA (A) Stefi ete (8) fran ais (Cc) Tefen ore (©) afar artes shi 1,808 faatta BO,2° eae gat a yet ats (A) frega—aeitsht ser (B) Beeash sey (C) faarenita wa & eat agi area & (0) syed ea FRA TT yy HT eH eB 26, 27. 28. 29. 4PCl, + 4NH, > 2 The aforementioned reaction yields (A) (PNCI,). + SHCI (B) (PNCI,), + 12HCI (C) (PNCI,), + 12HCI (0) (PNCI,), + 9HCI Concentrations of following aqueous solutions are equal. Select the solution with highest B.P. (A) Potassium sulfate (8) Potassium chloride (C) Potassium phosphate (0) Urea In orthoboric acid, H,BO,, the trigonal BO,°° units are bonded together through (A) Electrovalent bond (B) Covalent bond (C) Hydrogen bonds into two dimensional sheet (0) Coordinate bonds The expression for Joul-Thomson coefficient 5 is ne (B fa OE30. ter aftantas a tegtaia arr? (A) CHzCH,CH,CHO (B) (CH,),C(OH)CH,CH,C(OH)(CH,), (C) CHyCH,CH,COOH (D) (CHy)C(OH)CH = CHO(OHVCH,)2 aie Preaferftaa Hi fara afte actorrae7 & Haedegs arate ? (A) fare actrees (©) Saar aeiteS (©) aaitgreretires (0) astraregreet 32, wife (1) wee wEgzTH Cr—- OHA Fone (A) 2 (B) 9 (C) 10 (D) 8 33. aiff: : 00(g) + 30,(9) + 60,(9) 3 fare aha mean a? (A) 4H = AE (B) AH=AE+RT (C) AH=AE+ 3RT (0) AH= ae- 4 dar 12 30. With Fenton's reagent t-butanol fc 31. 32. 33. (A) CHj;CHjCH,CHO (8) (CHy,C(OH)CH,CH,CIOHNC (C) CHsCHsCH2COOH >) (CHy,C(OHCH = CHCIOHIC rolysis of which of the followit Hyd forms benzaldehyde ‘compounds (A) Benzyl chloride (B) Benzal chloride (Cc) Benzotrichloride (D) Benzonitrile Number of Cr—O bonds in Chromiun acetate hydrate are (A) 2 (8) 9 (C) 10 (0) 8 Which of the following relati true for the Seton? ey 1 CO(g) + 3 P29) > COz(9) (A) AH= ac (B) AH=AE+ RT (C) AH=aE4 I pT 2 (0) SH= AE — pat34, AAIM(NH,) Cl, Safe -BATAAT EF 35. 36. aglat 2, afe gaa Sega enfeas SI mere (a) Ni? (B) Cu (C) Zn (0) Pte 1 freer am, ot fee Hel FT (2a, 3b, c) 1 area @, aI fe ease (A) (231) (B) (312) (C) (623) (D) (326) Prafetiad afta OH OH Ol CH, I il) I Honea aS (A) I> IV>1>T1 IH OH 10, y M1 IV (B) I> IV> I> (C) I> I> Ila iv (0) V> I> toil 34. 35. 36. The complex M(NH,),Clp does not show geometrical isomerism, if the central metal ion, M is (A) Ni2* (B) Cu (C) Zn?* (D) Pte The Miller Indices of a crystal plane which cut through the crystal axes at (2a, 3b, c) is (A) (231) (B) (312) (C) (623) (D) (326) In the following compounds OH OH OH OH I MW Vv the order of acidity is (A) Ill>IV>1>01 (8) 1>IV>I>0 (C) >1> I> Iv (D) V>ll>t>n gia37. afefyat CéHsCH5+2CrO,Cl -> CeHgCH(OCICI,OH), {4,0 CsHsCHO+2CrC1,(OH), weet (A) fergaaré softer (8) Sf after (C) gare after (0) Bax afta 38, Bilge stfactaren ara & safe sferee ait anetza stadt wei art & Ritts (a) Cr Pref oft orfefionen aac anfear erat & (B) Mo ait W Sea siteefianor sraee H fer wae (C) Mo sie w fret sifaettertor srereat FH fan dae (D) Cr sea sitaefteror oraee F fear aie [UO,(NO,), oar aisiefeter er si 37. The reaction GglHsCH+2C10z Cl CHgCH(OCrC1,0H, LH0 CyHsCHO+20rC1L(0H, is called (A) Leukart reaction (B) Dakin reaction (C) Etard reaction (D) Strecker reaction 38. The chromates are oxidising while molybdate and tungstates are non-oxidising because (A) Cr is unstable in all its oxidatior states (8) Moand Ware stablein their highe oxidation states (C) Moand W are stable in their lowe oxidation states (D) Cris stable in its higher oxidatier state 39. In [UO,(NO,),), the coordination number and geometry are (A) 8 and hexagonal bipyramidal (8) 8 and square antiprism (©) Sand square pyramidal (0) 5 and trigonal bipyramidal oi keEB 40. 41. 42. “fem gard eas Pa aT HHH ANE 3 afr A > TETET erg oar at WTF 200 BFS 2, arattitaeer ar an fear am (A) 3.46x10-2 5-1 (@) 346x109 S41 (0) 346x104 st (2) 3.46x10-5 5-1 preterftaa Hi Fave a-apatia ISAS quae? (a) CF; (6) CCI, (0) CH, (0) CHF, agitta tare 4 abaet 3 67 Ft reaattaa H a ara eI @ ? (A) Mg?° (B) Mo (0) cur? (0) zn2® aft fas eaagis FI 25°C TAF araefiener far 0.763 az, asa at afer ets 0.01M fer at (A) 0.822 ate (@) 8.2242 f (0) s2.2atee (0) 0.0591 atee 4 s 41. 42. 43. If the halt A+ Mie for first order reaction value of rate cp eon, eons the He constant will be (A) 3.46x10-25-1 (B) 3.46x10-35-1 (C) 3.46x10-45+1 (D) 3.46x10-55+1 pa In which of the following d-orbital resonance is possible 7 (A) CF, (B) CCl, (C) CH, (0) CHF, Nitrogenase enzyme involves which of the following as co-factor ? (A) Mg? (B) Mo (c) cur® (0) 2n2® oxidation potential of (0.763 volt at 25°C, tential of half cell Jectrode dipped in 25°C will be If the standard zinc electrode is the electrode po! consisting of zinc el 0.01M ZnSO, solution at (a) 0.822 volt (8) 8.22 volt (C) 82.2 volt (0) 0.0591 volt44, Freaferfian aafiitiear s [x ]aA Are | [x] Wear R Br Xo, BL [x}, RCH=C =CHR Br R 0 DS, R. R bX< a (B) R 45, aifieélea aiteit & fore arecfers oraé ea ae (A) 2, 8, 20, 52, .... (D) 2, 8, 26, 80, .... 46. Hem mae site A fae fargait Aone (A) 8: (8) a oa 44. Identify [X] in the following reaction R Br j xX C=CHR SS Buli_,[X]+ACH= att a Dc a o> 45. The correct set of magic numbers for nuclear shells is (A) 2, 8, 20, 52, .... (B) 2,8, 16, 32, (C) 2, 8, 32, 64, .... (D) 2, 8, 26, 80, .... R The number of triple points in phase diagram of sulfur are (A) Six (B) Three (C) Two (D) One 46.is 47, ASA gal 48. 49. aaa ere, amy # fee gagri-faas qra-FAAET Sg F | TAHT TT PATA FH Apel ecg A, afta ? (a) te @) ts (0) tas (0) te es (A) + NaCl + H,0 ferge4z NaOH Cl; RSG eenaon? ©) * NaCl +H,0 aitfies (A) va (B) are; aa 8 2 (A) NaCiO 37k Nacio, (8) NaCiO,, 37% NaOCl (C) NaCio, 3% NaOCl (0) NaOCl 3i% NaOCl, Rays reais ale Pera aren Hatt aaa e (a) Sr 2 1 (8) git (©) kT (0) 2kT 47. 48. 49. The ground state electronic Configurations of the central metal atom in some octahedral complexes are given below. in which case tn@ electronic transition js forbidden 2S Per the spin selection rule ? (A) the! (B) thet (C) te; (0) tSe? Cold and fataan 1+ H,0 GiLNaoH > (4) + NAGl# Ts c— [Hot and ‘Conc. NaOH Compounds (A) and (B) are respectively (A) NaClO and NaClO, (B) NaClO, and NaOCl (C) NaCiO, and NaOCl (D) NaOCl and NaOCl, (8) + NaCl + H,O A molecule in vibrational motion is associated with energy equal to the following (A) 3kT 2 (8) pet (© KT (0) 2kT PG-02/A83, 54, Hey cH, Het “Seu, The above mentioned ont precisely termed as 3 (A) Base ng (B) Proton sponge (C) Electron sponge (D) Acid 1, +1*— 156) (A) pre 13(C) Correct order of vi in A, B, ai APT (A) A>B>C (8) AA>C ae57. 58. ‘59. fret sft A arena (AG)p 7 Fae (A) It (8) +ve (C) -ve (D) sfiBeen oe ek eee? N(CH,), 37% N(SiHq), 3 S15 HART: ane? (A) err otk fattest (8) er at at (C) frafrsct stk aK (D) fafisa sik fraftea fea @, AH; (HCI) = -92.3 kJmol~1 afk AH,(HCI.100 H,O) = -168.1 kJmol1. 100 Hite Stet # Uap te HCI ater =A weet a (A) -260.4 kJ (B) +260.4 kJ (C) -75.8kJ (D) +75.8 kJ 56. Which carbanion is most stable Mong given below ? @ (A) R-C=C Ry 8) goo= Oo R no (©) B5C-Ch, (o) 6H, 57, Fora reaction in equilibrium state, the value of (AG)p, is (A) Zero (B) +ve (C) -ve (D) Depends on the reaction 58. Geometries of N(CH;), and N(SiH,), are respectively (A) Planar and Pyramidal (B) Planar and Planar (C) Pyramidal and Planar (D) Pyramidal and Pyramidal 59. Given that, AH; (HCI) = -92.3 kmor’ and AH,(HCI.100H,O)=—168.1kJmot-’ The enthalpy of dissolution of one mole of HCI in 100 moles of water is (A) -260.4 kJ (B) +260.4 kJ (C) -75.8 kJ (D) +75.8 kJ80... Indicate the product P in the | reaction. Caan 4 700 2) He (A), SER rosa ae eae | 61, Inthe following reaction a ith ) + (CH,),ccocl adie | “the product P is= 62. fra dgas os fore CFSE wad sare 63. (A) [CoF,|3° (B) [Co(NCs),]2° (C) [Mn(H,0),]2® (0) [Co(NH,),]3® Satire eetacts UH saree (A) egg srs eeARTS (B) ergs eas (C) sitaefianor-srraert eetagis (O) erg-sifaera eg srert- act facta FRUIT FARTS faeaferfta orfirfazar a seare (A) sft (B) FAT: ee? NaOH(*RH Sit ZT) + Cl, —> A+ args sere Ca(OH), (El) + Cl, —>B+ aigs-seae (A) NaClO, HK Ca(CIO,). (B) NaOCl 3ik Ca(ClO;), (C) NaClO, 3% Ca(OCl), (D) NaOCl 3K Ca(OCl) 65, arama agra x eraren saa fr arn wae (A) agate (8) vette (C) saageren ara oa TR Fe edhe (0) Fo% fore aah 8 wa Ges fee aed & 63. 62. CFSE will be highest for (A) [CoFg]3° (B) [Co(NCS),]2° (©) [Mn(H,0),]2° (D) [Co(NH,),]3° Calomel electrode is an example of (A) Metal-metal ion electrode (B) Metal-amalgam electrode (C) Oxidation-reduction electrode (D) Metal-insoluble metal ion-soluble same anion electrode 64, Inthe following reactions, products (A) and (B) respectively, are NaOH(hot and conc.) + Clp — A+ side-product Ca(OH), (dry) + Cl, —>B + side product (A) NaCiO, and Ca(CIO3)y (B) NaOCl and Ca(ClO,)> (C) NaCl, and Ca(OCl), (D) NaOCl and Ca(OCl), 65. The effect of increase in temperature on rate of enzyme catalyzed reaction is (A) Increases (B) Decreases (C) Reaches to an optimum value and then decreases (D) For some increases and for some decreases70. wal 72. (A) Cac, Hg¢tn) (8) Cu(th, Hg(1y (C) Cutt), Haq (0) Cu(), Hg Seiae a ee sree (A) sfat (8) Ufesné (C) Berar eta (D) Aa nts freee ayers a afte frat aie aafata 7a & (A) egritaet (B) Attach (C) greactifre (D) eaaritrct aga Cl Br HZ "Spy ai Prater K,{PtCL,] % mee @ cites ara & fra en 3 free @ fer waa e ? Py, BP, NH, 69. 70. 7h 72. The pair of ions that most commonly forms complexes with coordination number two (A) Cd(Il), Hg(tl) (B) Cutt), Ha() (C) Cul), Ho(1) (D) Cu(1), Hg(tt) The example of a vat dye is (A) Indigo (B) Alizarin (C) Malachite green (D) Methyl orange Select the crystal system whieh has no symmetry (A) Tetragonal (B) Monoclinic (C) Triclinic (D) Hexagonal The complex Cl” er HN“ ™Py can be formally formed from K,IPIcl) bywhich one of the following sequences of substitutions of the chloride ions? (A) Py, B®, NHs (B) Br®, Py, NH3 (C) Br, NH, Py (D) NHg, BP, Pyi 73. 74, 75. 76. eater? a) ARTE (2, 0, 2) Saeed (@) AeA (2, 1, 2) tamer (0) SEAT (1, 0, 2) Raareréa (0) AATEC (2, 2, 0) Rarer pected Bra seat eae! 0 i) Cc oO KA, see ‘CH, (a) feet (e) aR (0) 2farge ware (0) ara C,H,CONH,+P,0, —4-» See | ‘seeae af fseen a1 ses e (A) CyHgNH (®) C,H,CN (©) C,H,CH.NH, (0) C,HgNC ‘Whte-aa sraerem faereft eS fea a Pet 2 feat entire ect @ 7 (A) sefaa saree (8) rati-giees stare (0) aa-qers sae (0) fa stereo 7 3. Dewar benzene ig (A) bicycto 2 +, 2] (B) bicyco fa, | hexadiene (C) bicyclo (1, 9, 2Ihexadiene (D) bicyclo (2,2, 0) hexadiene 74, Identify the Produr reaction, 9 i c CY IS. Product CH, (A) Phenanthrene (B) Naphthalene (C) 2-Methylanthracene (D) Anthracene Ct of the following 75. CgHsCONH,+P,0; —* , Product. The product of the above reaction is (A) CgHgNHp (B) CgHsCN (C) CgHsCH.NH, (D) CgHsNC 76. The acid-base concept involving molten condition is (A) Arrhenius concept (B) Lowry-Bronsted concept (C) Luxlood concept (D) Lewis concept PG-02/ABi 77. 78. 79. 80. rer 8 hen pa a a8 7 (A) Cu?® sa Mn2e area a ana wen sree (8) Cs? stra (@ area at qerar a ate sR (C) NH, CoHaNH, ft ger arate ane (D) (CoH) NH Ua ag aI 25°C 1 Frail wm anita sree at Feist FRR 1.8x10-5 Hae | FAH 0.20 M “aaa el seh aa eR Pe HATS (A) 0.00949 (B) 0.00849 (C) 0.00994 (D) 0.00489 seagate sfeeares fatetia a ata a fra ar & ere? (A) 2 (8) 3 ()7 (0) 8 ahaa Al o-gvecht dea eanfrea wT aad ® (A) ergs aH ar (8) aret-are ae aT 78. Which of the following statement is, correct ? (A) Cu?® ion behaves as harder a, than Mn?® ion (8) Cs® ion is harder acid than j ion (C) NH is harder base than CgHsNH, (D) (CeHs)2NH is a soft base A monobasic acid has a dissociate, constant equal to 1.8x10 at 255 Its degree of dissociation a; concentration of 0.20 M at the san, temperature is (A) 0.00949 (B) 0.00849 (C) 0.00994 (D) 0.00489 Electrophilic substitution in quinoire takes place preferentially at whcr position ? (A) 2 (B) 3 (7 (Dd) 8 . The a-Helix structure of protein 's stabilised by (A) Peptide bond (8) Vander-Waals forces (C) Hydrogen bond (D) Dipole-dipole force4 “ oe (Cap) 4 OT ar fen sre 8 8 Most Prob; Molacuie ve “rn ee 4 : a hy (8) Cro = a (©) Sm = a (0) One = er 82. GAPAM??, IMHO), (Mien) | go ca anee forms the complex TE IMBIG] © eget sare Bl ga eget [M(H,0),:2, 1M ana UFR: FT eit? Match the complex with appropriate colour. (A) @, Aten, aire hy (A) green, blue, red Ol (B) blue, red, green as, tn (©) green, red, blue ©) sae, en, er (0) red, blue, green 83, Faget sara fea & wat art Rare | 83. Bond enthalpy is evaluated by using oma’ following (A) Parca afer (A) Kirchoff's equation (8) fea eyeq acter (B) Gibbs Duhem equation (©) tea Ran (C) Hess law (D) Maxwell's relations (0) dade 3 aaa PG-02/Aa4, FATT Tess Ger as PT Stree aReOT Bae O I C. ar > s Ry 85. fic-OH+ SOC! &, R. noe -Cl + SO,+HCI ea often at aren Bera B (A) SN, fer fate art (8) SN, fren fate art 84, Naphthalene on oxidation with chromiumtrioxide and acetic acid give, 9° ul ~ (a) Cx» I 3° ‘OOH ®) OOH 9° oO CHO 0G ‘COOH R Eth 8; 9 -@ 0H +800y tae R. ny —Cl + SO,+HCI This reaction can be explained by (A) SN, mechanism (8) SN2 mechanism (C) E2 mechanism (D) SN; mechanismSEE ¢ oak a4 acetic : 86. Which one of cig is used to opie ming theories catalysis ? lomogeneous (A) Intermediate Compound theory (8) Adsorption theory (C) Arrhenius theory (D) Dalton’s theory 87. Select the photochemical reaction _ quantum yield two, ne (A) Hp + Cl oH) 7 (8) Hp + Br. —™ , ater (© 2Her—™ 4, sa, (0) $0, +c," , 50,61, SF WR 88. re reaction with dilute sulphuric (A) CH,CH,CHO (®) CH,cocH, (©), CHycocooH (D) CH,CH,CH, explained by | 89, NOC and NaNO, react in liquid NO, to produce (a) No® “(B) NOP (©) NzOg and NaCl (D) NaNO, and NaClEs 90, frees t LCT sal ard wre? (A) Mn0,° < Cr0,2° < VO,3° (B) Mn0,° > Cr0,2° > VO, (©) Mn0,2> Cr0,?° < vo, (0) Mn0,° < Cr0,?° > vo,? gt, BME? (A) (CH) _cHCocH =C(CHs)a (B) (CHa)2e =CHCOCHs (C) (CHs)2e =cHCOCH,OH (0) CHjCOCH:CH_COCHs ) 92. Cry COONH, A AAAI ST pen dtr are Rare aT A ® (a) fer aR (8) piensa #1 Fa (c) aera a frat (0) argo ite HTT 90. gt. 92. 93. rder of LMCT energies is “ mn0,2 cr0,> vo,” (c) MnO." > cr0,? < vos? (0) Mn0,° < C10. o> vo,” The correct OF what is phorone ? (A) (CH,),6 =CHCOC! (@) (CHa)o° = CHCOCHs H = ClCH), (©) (CH3)20 = CHCOCH,OH (0) CHgCOCH,CH,COCHs Conductivity at infinite dilution of “CH,COONH, can be determined by using following (A) Hittorf method (8) Kohlrausch law (©) Arrhenius theory (D) Debye-Huckel-Onsagar equation The edral complex which ‘shows _ both fac- and mer- isomerism (A) triglycinatocobalt(t1}) ediamine)cobalt(I11) (B) tris(ethylen ycinatocobalt(I1!) (C) dichlorodig! (D) trioxalatocobaltate(II})94. 95. 96. 97. at F—en tore te aie? “ GH,- CHO II @ GH,—C —CH, 9° (0) CH,—CH, ~ g —CH, 9 Il (0) CH,—CH, - C-CH,-CH, Prater witeontig fraa a a Pret aagiatta 1 ata—faas fates cifemn A sfea t 7 (A) RsiC! @) Asi (C) RSICI, (0) R,SiCl, frefefad 4 8 aaa EAN fram ar We el rae? (A) Fe(Co), (8) V(CO), (C) K,{(Fe(CN),] (0) Mn.(CO), 20H UH 0.01 M& fqa smeeT Sr afet 210 ohm 81 fae A Ate are (@a Frais = 0.90) (A) 0.0410 sm? mot-1 (8) 0.0419 sm? mot" (C) 0.0423 sm? molt (2) 0.0429 sm? mot an 95. 96. 97. Which of ¥ the follow 4 ‘aloform reaction »'""9 will not give (A) CH5~CHo i (8) CH,-C ou, 9° I] C-cH, 9 (0) cH,-cu,-l (©) CH,-CH, ~ ~CH,-CH, Among the following substituted silanes the one which will give rise to cross linked silicone polymer on hydrolysis is (A) R,SiCI (®) R,si (C) RSicl, (0) R,SiCl, Which of the following does not obey EAN rule ? (A) Fe(CO), (B) VCO), (C) K,{Fe(CN),] (D) Mng(CO);o The resistance of 0.01 M solution of an electrolyte is 210 ohm at 25°C. The molar conductance of solution is (cell constant = 0.90) (A) 0.0410 sm? mot (8) 0.0419 sm? mol" (C) 0.0423 sm? mot-* (0) 0.0429 sm? mol PG-02/A98. a 314 afer a ae ae (A) 0.02 (B) 0.01 (C) 0.04 (D) 0.05 cee Bie er Tae (A) gatteerr (8) d-daarm (C) ahi qatar ed d- dat (D) Srraer Feria SHAT 100. gat fae CFSE 180000m" Bl [CoCl,2° eee > Fore A, FIAT AT am? : ; (A) 18000 cm-* (B) 46000 cm (C) 8000.cm~1 (D) 7450.cm~" 101. Rerttite tS “ 1,2 A sa fafsrarettct ) ~ 98. If 3g urea is dissolved in 45g water, the relative loweri cola ing of vapour pressure (A) 0.02 (B) 0.01 (C) 0.04 ~ © 0.05 99, In potassium permanganate the dark colour arises because of (A) Polarisation (6) d—ditransition (C) Both polarisation andd—d transition (D) Charge transfer transition 400. The CFSE for [CoCl,]*?is 18000cm- 101. 102. Ay for [CoCI,}°° will be (A) 18000 om~" (8) 16000 cmt (©) 8000 om" ape (D) 7450 cm" Which positions are very reactive in phenanthrene a (A) 1,2 (B) 9, 10 (C) 3,4 (D) 5,6 ediate forms: triptycene interm' ae ith anthracene ? ‘on reaction w'" (A) Benzyne (B) Carbene (C) Nitrene (D) Carbocation Ps103. Reaction Of ac dioxide forms °* "one with a (A) CHO me | CHO (8) CHO | CH,OH (C) CHCocHo (©) CH,cocooy 104. Match the follow (Colin — 1 ge Dwr their u (Column — ae: * eh Column =I 1 Ca(OH), a Cast of statues MW. Nach b. White wash Wh C8SO,05H,0 c. Antacids 'V. Caco, d. Washing soda’ preparation Code : 'ooomwy Aodo aoc b (B) bo dvac (de cod a () ¢c d ba 105. Which of the following reaction will be preferred to remain on the left side ? (A) CaS +H,0— CaO + H,S (8) HgF, + Bel, + Hgl, + BeF, (C) BeF, + Hgl, > HoF; + Bel, (D) Lil + CsF — LiF + CsI PG-02/A_i fi bt if 106. 107. 108. Oe on, (il) Ser safer a aed & (A) arifcttta saftiean (8) fafrafan arftigrar (©) dvsten sififirar (0) sear a 8 aig eh fitter + CygHpp0,4 +H,0 eb i,,0,+ Cet, 0, Sr aMER (A) (8) a (C) (Da $ =Osit S- OH aa A seem arefet area a sites A ga: Pott Behe? (A) (4 aft 2) afte (4 3 2) (8) (234% 4) ait (2 3h 4) (C) (4 af 2) aft (2 3 4) (0) (2.38 2) aft (2 ath 2) , Rreferan Ha aa ara areas Ae & oreadt tha Ah ger 4 aa cara & fore sera @ 7 (A) armpsit aor fafeera arent (8) armpit & nf sat H agteeth (C) Marat (0) sreaarrafas et A 106. 107. 109. () NaNH,, 110° (ii) Water Qi war at eel, Reaction is known as (A) Carbylamine reaction (B) Chichibabin reaction (C) Sandmeyer reaction (D) None of the above The order of reaction CygHopy3 + H20 — E+ CyHj105 IS (A) Zero (©) Halt (©) One (D) Two The number of S =O and S- OH bonds present in Marshall's acid and Oleum, respectively are (A) (4 and 2) and (4 and 2) (B) (2 and 4) and (2 and 4) (C) (4 and 2) and (2 and 4) (D) (2 and 2) and (2 and 2) Which one of the following is responsible for lesser pressure of a real gas (0 comparison to an ideal gas ? (A) Finite size of molecules (B) Enhancement of kinetic energy of molecules (C) Viscosity (D) Intermolecular forces‘110, 11, 112, 113. 114. only formula 7 Siven by spin (A) Gd and Lys (8) Ce* and ngs (C) Yb and Tins (D) Pm and Hos In liquid ammoni aa hae ag” SPhamic acid (A) Monobasic acig (B) Tribasic acig (C) Dibasic acig (D) Base Ethanol on reaction with bromine in aqueous solution gives (A) CH,COOH (8) CH,CHO (C) CH, =CH, Which one is not nucleophilic reagent in the following ? e () CH, (8) NH, (C) ‘CH, (0) R-O-R The unit of rate constant for zero order reaction is (a) s* 4 (B) mol dm x“ (C) mor drs st (D) mot? dm s~*i 115. 116. 117. wet TTA TH CO, BI Cy ATA & (HFT fife fa seer aro oe speafe ahrery 20% %) (A) 54.04 JK-!mol (B) 27.44 JK-Imot" (C) 22.44 JK-!mol (D) 12.44 JK-1mor4 after BrMg(CH,),MgBr + CH,CO,CoH; > P Hpane? ) Che oC 'H cafe atereat feet A, B wd C % fere _ Bl eT AMT: 0.1, 2.5 UF 208, ata arr rer a ea fa a STTETA ate eet (A) C>B>A (B) A>B>C (C) A=B=C (D) B>A>C 115. 116. 117. Cy for CO, at room temper equal to (assume 20% vil contribution at room temperature (A) 54.04 JK-!mot™ (B) 27.44 JK-'mor (C) 22.44 JK-Imort (D) 12.44 JK-'mot In the reaction BrMg(CH,),MgBr + CH3CO-C; what is P ? If the gold number for the colloid? solutions A, B and C are 0.1, 252" 20 respectively, the order of protect’! powers of these colloids will be (A) C>B>A (8) A>B>C (C) A=B=C (0) B>A>C119. 120. 121. (A) CHCl (8) CHeCH,CI (©) CHy=CHCI (0) CH,OCH,c| Fda A aT HONS aera wea Sa Bara ae ea WE Ai afer ? (A) airs Pe acres sare (8) RA AG afteares sft (0) Bear Be aires sara (0) FIR Fe fee safe est =1e-<" aga ea aa aT R (A) trad re (B) arad—sttar Ray (©) mera ere (0) Rerb—sreea Fae ‘Sta 5.13% Facrr STaTA 0.9% Aeeran a are anrgetalfis 81 Fada Ways (A) 51.3 (8) Mo ©) 724 (0) 80.0 eBHiEpe 7 1g 119. 120. 121. Which on, ott ™Ore rapicy 9° vn nical A) CHcy ®) CHch,o) (©) CH, cho, (0) CH;0CH,6) What type of react treatment of ketor @ cyanohydrin > (A) Nucleophilic Addition reaction (8) Electrophitic substitution reaction (Cc) Electrophilic Addition reaction (0) Nucteophilic substitution reaction Hon takes place upon 8 with HON to form The expression I= -*4is known as (A) Lambert law (8) Lambert-Beer law (C) Grotthus-Draper law (0) Stark-Einstein law ‘5.13% sugar solution is isotonic with ‘a 0.9% unknown solution. The rholar mass of the solute is (a) 513, (8) 60.0 (©) 724 (0) 90.0 PG-02/Ai 122. 123. 124. NH, We HO* a eitaar a area feu MBA aa -maa ek? (A) NH art n—H saree aa ereang UW vaca & Bae (8) H,0* & aft o — H anare orang a ce (C) NHAN a H,Ot# ota eer seen orm (D) weRrAl geaer aa eT NCAT Wr th deg HOF O FAT ae ‘fen-siifetd HS, (50%) % Pt ytaetet ae sea faga ar ara qT srames HDs satan Bae (A) siferam, H,S,07 (8) searaifis stra, HjS,0, (C) Arter I SFA, HyS,0, (0) tt a1 ata, SO, Os0, + 9CO-+08(CO) + 460, ‘atta aaftifsper ea @ ? (A) sfeearea srfifeeer (8) 3a aia afi (C) fteftea araifiaer afta (0) =pfiene after 125, Freaferfiad 4 & fra Hereineroiren A fare wei ete? (A) arate afta (8) aaifte cess (©) aegis (0) sreaiten feeregtarta 122, 123, 124, 125. ‘Among the given statements ay, structure of NH, and HzO*, whi is incorrect ? (A) AlN —H bonds in NH, are e9,, in length and strength 7 (B) AllO—H bonds in Hg0* are eo, in length and strength (C) Nin NH, and O in H40™, both, atoms involve sp? hybridizatio, (D) Number of lone pairs of elect ‘on N atom is only one but itis in case of O in HgO* The anodic oxidation, in the elect of ice cold H,S0,(50%) betw electrodes at high current densi gives (A) Oleum, H,8,0, (B) Dithionic acid, H=S,05 (C) Marshall's acid, H,S0, (0) Caro’s acid, H>S05 Os0, + 8CO-40s(CO), + 4C0, The above mentioned reaction is (A) Substitution reaction (B) Direct carbonylation reaction (©) Reductive carbonylation reacier (D) Reduction reaction Which of the following metalloenzy™=* do not contain zinc ? (A) Carboxy peptidase (B) Carbonic anhydrase (©) Nitrogenase (D) Alcohol dehydrogenase PG-02/A