clectrical

conduc
luctivity, chemia OBJECTIVE CHEMISTRY-XIID are ZrO,, NaCl and benzene.
strength,
are weakly repelled by
a magnetic field. Examples
mechanical
62. Diamagnetic materials subshells.
SOLID STATE solids
like erystal
defects.
in thes solids a is associated with completely
filled electronic
yby The property of diamagnetism
defects
of the
crystalline affected
ffected The
63. field. Examples are O, Cu, Ti,O VO2
The properties attracted by a magnetic
compounds,
9. profoundly
catalytic activity
are 'daltonide defect)
Paramagnetic materials
are weakly
eu Vy, calledas
(dislocation
64.
40. The
stoichiometric solids are
also
defect
and
Frenkel
defect
tenmperature.

ence
Hence they are
also known NO, Na vapour.
due to the presence of permanent
magnetic dipoles as a
result of unpaired
(vacancy Paramagnetism is observed
increasing
defect
Schottky Increases

with
65.
frenkel defects molecules.
oth schottky and om their
from their normal lattice electrons in atoms, ions or associated
as thermodynamic defects. particles Sites to spontaneous alignment
of magnetic moments
Ferromagnetism o c c u r s due
constituent
of
arises due to
the missing 66. same direction. eg. Fe, Co,
Ni, CrO,
42. Schottky defect defect.
he .solid with unpaired electrons in the
and AgBr can
show Schottky
sites. the
density
of the
t decrease due when the alignments of magnetic
moments are equal and
in opposite
Nacl, KCI, CSC lattice
The antiferromagnetism is shown
fronm their 67. Nio.
ions are issing moment zero. eg. Mn0, V2O3,
43. Since some of the direction so as to give the net magnetic
o c c u p i e s aan interstitial
la
Schotky defect. because an
1on are in parallel and antiparallel
the alignment of magnetic moments
exists in the
crystal
lattice
this defect.
68. Ferrimagnetism arises due to moment and shows
44. When a 'hole' or 'vacancy ZnS can show a result the
material has net magnetic
defect. AgCI. Agl.
AgBr and direction in unequal number. As
to Frenkel
Stte, it gives rise
effect on density
of solid. ferrimagnetism. ferrites of the
45. Frenkel defect has no materials show small para-magnetic character. Examples
are Fe,O4,
defect and Frenkel
defect. 69. Ferrimagnetic
46. AgBr contains Schortky structure and composition. Examal where M Mg, Cu, Zn.
between the properties
of a solid, its formula M* Fe,O4. =
47. There is a close relationship
of these properties are electrical and magnetdc properties.
48. Based on their electrical conductivity,
solids can be broadly classified into three types Metal LEVEL 1
Semi-conductors.
or Non-conductors
and
(Conductors), Insulators EXERCISE - I |
electric current through them conductors. are called
49. The metals which allows the passage of
50. Their conductivities of metals value is in the order of
10- 0°ohm cm at room temperature Types of Solids & Crustal structures
which decreases with rise in temperature due increase in lattice vibrations.
to Which of the following is amorphous in nature?
3) Dry ice 4) fused silica glass
51. At laboratory temperatures the conductivity of metals is almost independent of impurities and defects 1) Quartz 2)CuSO4 5H,O
Which of the following is covalent solid
52. At low temperatures the latice vibrations negligible and hence the conductivity should ba
are
large, however it is not true because of lattice imperfections and impurities. 1) Fe 2) Diamond 3) NaC1 4) Cu
example of
substanceslie 3.
NaCl is an
53. Non-metals like diamond P and S, solutions of non-electrolytes like sugar and urea,
1) Ionic solid 2) Covalent solid 3) Metallic solid 4) Molecular solid
wood, rubber and plastics are all examples of insulators.
Which of the following melts below 298 k.
54. Conductivity of insulators is extremely low and is in the order of 100 to 4.
temperature.
10-2ohm cm at roo 1) NaCl(s) 2) Si(s) 3) Ar () 4) Na(s)
55. The solids possess . For a covalent solid, the units which occupy lattice points are
conductivity values which are intermediate between those of
insulators i.e. in the range 10° to 10" ohm' typical meta nd 1) Atoms 2) Tons 3) Molecules or atoms 4) Electrons
cm are called semi conductors. 6. Which of the following does not give any diffraction bands with X-rays?
56. The conductivity of
semiconductors increases with
gap between valence and conduction bands. temperature, because there is a
sma norgy 1) BaSO4 2) Graphite 3) Diamond 4) Plastic
Which of the following is not a crystalline solid ?
57. Pure semi conductors are called intrinsic semi
58. The process in which a small
conductors. eg. pure Si, 1) KCI 2) CsCI 3) Glass 4) Rhombic S
amount of pure Ge.
forejgn impurity is added to a crystal is called 8. Covalent solid among the following is
59. The conductivity of
semiconductors abnormally increases because of op 1) solid Ar 2) MgO 3) Fe 4) BN
60. If Si (or) Ge is
doped with a pentavalnet atom doping. 9. (A): Glass possess sharp melting point.
Si (or) Ge is (, As, Sb), n type of
doped
with a trivalent atom
(B, Al, Ga, "Ype semiconductors
-
of semiconductors are forme (R): Glass is a pseudo solid
61.Materials be divided into diferent
can In),
p type of -
1) Both (A) and (R)
magnetic field.
classes
depending semiconductors are
2) Both (A) and (R)
true and (R) is the correct explanation of (A)
and
are
upon the behaviour of substane s towar (R) is not the correct explanation of (A) are true
3) (A) is true but (R) is false 4) (A) is false but (R) is true
44
APEX SERIES for Sri APEX SERIES for Srl Chaltanya cBsE XII Students 45
Chaitanya CBSE
cBSE XII
AI
Studen
 OBJECTIVE CHEMISTRY
OBJECTIVE CHEMISTRY-XIID p SOLIDSTATE
SOLIDSTATE is
exhibted D (Unitcell) (no of atoms per unitcell)
melting point 2 ) lonic solids
T0. Anmong solids, the highest 4) Molecular solids A) Simple cube 1) 4
1) Amorphous solids 2) 2
B) fec
3) Pseudo solids C) bcc 3) 1
slatemena zing
freezing it's vapour
it's melt (or)
is not a comt
11. Which of the following The correct match is
amorphous by quenching crystalline
1) Any material can be made cooled
becomes B C
solid when slowly
of an amorphous
melt 1)
ne
3) Glass melts over a range of temperatues 3) 3 2
of Sio, unmtS for the crystallographic dimensions # 5#7.
4) Quartz has iregular chains Column-B 25. The number of space lattices possible
Column-A 1) Framework silicate 1) 1 2) 2 3) 3 4)4
12.
A) Glass
2) Malleable
& ductile 26. In which of the following crystal systems F.C.C unit cells exists ?
B) Quartz 3) Pseudo solid 1) Cubic, hexagonal 2) Tetragonal, orthorhombic
C) Metallic crystal 3) Orthorhombic, cubic 4) Triclinic, monoclinic
The correct match is A B C
centred unit cell ?
A BC
3) 2
4) 1 2 3 27. Out of seven crystal systems how many have body
1)1 3 2 2)312 1) 4 2) 3 3) 2 4) 7
15. Which is not corect about valence bond theory of metais 28. How many unit cells are possible for the crystallographic dimensions as absc; a=7=90" #
1) It is also called resonance theory 1) 2 2) 1 3) 4 4) 3
2) It was proposed by Linus Pauling Which of the following systems is not characterised ?
bond
29. correc
3) The metallic bond is essenüally a polar (or) non polar covalent 1) cubic: a =b= c; =ß=y=90° 2) tetragonal a = b #c; a=ß=7=90"
4) It explains metallic lustre. 3) orthorhombic: a b # c; o =ß =y =90 4) rhombohedral: a = b#c; a=ß=7=90"
The maximum displacement perpendicular to the motion of the wave is known as
30. The crystal system having one 6 fold axis is
1) wavelength 2) intensity 3) amplitude 4) frequency 1) hexagonal 2) tetragonal 3) cubic 4) monoclinic
B passingXTaY's through copper sulphate crystals diffraction band is obtained. It was first observed by 31. The total number of crystal forms possible is around
1) Max Van Laue 2) W.L Bragg 1) 32 2)14 3) 230 4) 7
3) W.H. Bragg 4) W.L.Bragg & W.H.Bragg 32. Which of the following may have hexagonal or trigonal crystals
16. The structural unit of a er stal is called
1) K, [Fe(CN)J 2)ice 3) K,CrO, 4) Diamond
1) unit cel 2) crystal lartice 3) space lattice 4) structural motif
17. The ratio of 'd' values in NaC! erystal is Close packed structures and voids
33 List-I List-I
1)0.703: 1: 1.134 2) 1:0.703 1.134 3) 1: 1.134:0.703 4)0.703 : 1.1341 A) cCp 1) ABAB
18. The angle corresponding to maximum
diffraction of x-rays on solid B) hcp 2) BCC
electrometre reading in crystal is determined C) CsCI 3) ABC ABC
1) Bragg's experiment
2) Powder method The correct match is
3) Debye- Hull method
4) Max Von Laue A B C
19. In a
crystal lattice a
specitie fundámental structure appears
experiment ) 2 3 1
1) triangle 2) rectangle again and again which is a 3) 3 2
3) tetrahedron 4)
20. Graphically the total number ol
Tundámental spalial arrangements
4) parallelogram 34. Which of the following has hcp crystal structure ?
1)3 2) 7 possible (MPPMT9 1) NaCI
) 10
are 2) CaCl 3) Zn 4) RbCl
21. In case of cubic 4) 14
a
sysiem, the number ol
types of space 35. Coodination number for Cu is
1) 3 2) 7 lattices are I) 2) 6 3) 8 4)112
22. The number of latlice
3)114
pOinis 4) 12 Which of the following is an example of body centred cube ?
1) 1
at the
centre ol the
primitive 36. (MPPMT 98)
2) 0 unit ccll is Mg 2) Zine 3) Copper 4) Potassium
23. How many kinds of 3) 2
primitive unit cells are 4) 3 37. The co-ordination number of a metal erystallising in a
hexagonal close packed structure is (11T 99)
1) 23 2) 3 possible
12 2) 4 3) 8 4)6
46 3) 230
APEX SERIES for Sri 4) 14 APEX SERIES for Sl Ghaltanya CBSE X Students 47
Chaltanya cBSE XI. Student
 OBJECTIVE CHEMISTR
OBJECTIVE CHEMISTRY-XIID_
and negative ions as indicated by chemical formula
In defects, the ratio of positive
stoichiometric
4)112 54.
spheres
of the compound 4) Cannot be predicted
sOLID STATE = by how many3) 8
3) Remains same
An
octahedral
void is
surrounded
2) 4 NaCI
erystal 4) 8
(MPCEBE 1) Decreases
2) Increases
has left a lattice site and is located
at an interstitial position, the lattice
1) 6 ion in In a solid lattice the cation
there
around
around
Na* 1on
Na" 3) 6 55.
How many
C i ions are nheres in adjacent ayers is call defect is 3) Frenkel defect 4) Schottky defect
2) Vacancy defect
9.
2) 4 defect
1) 3
directed
2) Tetrahedred
planar tnng void 1) Metal excess
void between
two oppositly
(or)
Octahedrol viod
Non stoichiometric solid among the following 4) TiO
0
The
4)
Tetrahedral 56. 2) CaO 3) Na,O
1) Cubic void
for a ven
given lattice point is 1). MgO
3) Octahedral void neighbours,
and Frenkel defects.
4) 14 following has both Schottky
nearest
of Which of the
cture the
number
57. 3) NaCl 4) KC
In cubic close packed 3) 12 2) ZnO
41. a
2) 8 1) AgBr
1) 6 nctlls
"thermo dynamic deffects
for
4) H.C.P. defets are also called as
(A) : Schottky and Frenkel
uncommon
most
Which of the following
strucrure is
3 ) C.C.P. 58. Frenkel defects increase
with increase in temperature.
1) simple cubic
2) B.C.C. (R): Both Schottky and of (A)
true and (R) is the corect explanation
1) Both (A) and (R) are
efficient:
is more
close packing
Which of the following packing of (A)
+5. 2)hexagonal and (R) is not the correct explanation
1) square close packing none of the above 2) Both (A) and (R) are true
4) false
3) tetrahedral arrangeement Is 3) (A) is true but (R) is
system of crystals
Ihe packing efficiency
in a simple cubic cell 4) 92% 4) (A) is false but (R) is
true
) 74%
2) 52
1) 68 (M.P.PMT 2000 Properties of solids one gets
+5. The packing iraction for a body
centred cube is
4) 0.86 59. On doping Ge metal with a little of gallium
conductor
3) 0.68 2) n-type semi
1) 0.74 2) 0.76 1) p-type semi conductor 4) Rectifier
6. Density of a cry stal is gTven b
3) Insulator
from the following is
M a XNO 60. A solid with high electrical and thermal conductivity
a' xM 2) M 3) NaCl 4) Ice
1) 2XNo 2) Zxa 3)axNo 7.M 1) Si Li
in the soild state
61. Which substance will conduct the current
47. The percent of void space in a body centred cubic lattice is: 3) Iodine 4) Sodium chloride
1) Diamond 2) Graphite
1)332% 2))48% 3) 52% 4) 68%
62. Metals have conductivity in the order of (ohml cm)
48. The packing effciency in a face - centred cubic cell system of crystals is
1) 1012 2) 10 3) 102 4) 106
1) 52% 2) 68% 3) 74% 4) 92% An example for metallic conductor and semiconductor is
63.
49 The limiting radius ratio for tetrahedral shape is 1) TiO 2) FeO 3) V,O NiO
1) 0 to 0.155 2) 0.115 0.225 3) 0.225 0.414 4) 0.414- 0.732
64. Molten sodium chloride conducts electricity due to the presence of
50. AB is an ionic solid. If the ratio of 10mc radii of A" and B is 0.52. 1) Free electrons 2) Free ions
What is the co-ordination nu
f B-? 3) Free molecules 4) Atoms of sodium and chlorine
1) 2 2) 3 3) 6 4) 8 65. A diode is
For an octahedral arrangement the lowest radius ratio or pnp type of semiconductor
limit is 1) only n type of semiconductor 2) npn
1) 0.155 2) 0.732 4) only npn type of semiconductor
3) 0.414 4) 0.225 3) only p type of semiconductor
Defects
52. (A) :
Thermodynamically all solids possess a tendency to acquire 66. Which of the following is ferromagnetic ?
1) Ni 2) Co 3) CrO 4) All
(R): During defects the entropy of the defects
system increases in solids. 67. Ferromagnetic substances have
1) Both (A) and (R) are true and (R) 1s the correct
explanation of (A) 1) Zero magnetic moment 2) Small magnetic moment
2) Both (A) and (R) are true and (R) 1s not
the correct 3) Large magnetic moment 4) Any value of magnetic moment
3) (A) is true but (R) is false explanation of (A)
4) (A) is false but is maximum in
53. At zero kelvin, most of the jonic crystals (R) is true 68. Ferromagnetism
1) Frenkel defect possess ) Fe 2) Ni2* 3) Co* 4) Cu2+
2) Schottky defect
3) Metal excess
48 9 defect 4) No defect APEX SERIES for SrlChaltanyacBSE XIu Students a 49
APEX SERIES for Srl
Chaltanya CBSEXII
X
Stude
 OBJECTIVE CHEMISTRY-XiID
OBJECTIVE CHEMISTRY-XIID = S sOLID STATE
SOLID STATE 13. The first order diffraction of x-rays from a certain set of crystal planes occurs at an angle of 11.80
EXERCISE -II from the planes. If the planes are 0.281 nm apart, the wavelength of x-rays is
(sin 11.8 =0.2,sin5.9 = 0.103)
structures
Types of Solids & Crystal not true about crystalline
solids
1) 0.1124 nm 2) 1.124 nm 3) 0.0578 nm 4) 0.578 nm
is
I. Which of the following
rigid and hard 14. In x-ray diffraction experiment at which one of the following path difference between the two
1) They are
waves, destructive interference is observed ( a = wavelength o f x- rays)
2) They possess plane surfaces substances
of molten
3) They are obtained by rapid cooling 1) 2) 2 3) 3 4) 1.5
have definite geometric
configuration.
4) They 15. At what angle for a first order diffraction, the distance between two adjacent planes of crystal is
carborundum
2. The consitutent particles in equal to the wavelength of x-rays used
3) +ve ions
2) molecules
1) atoms 1) 300 2) 600 3) 900 4) 450
electrons
4) +ve ions in a sea of
associated with 16. If two waves with the amplitude of E, each undergo constructive interference, the amplitude of the
point is
3. Among the following highest melting 4) K resulting wave is
2) graphite 3) P4
1) NaCl 1) 0
model ? 2)<2E 3) 2Eo 4) Eo
4. Which is correct about electron sea
Close packed structures and voids
1) It was proposed by Lorentz 17. How many atoms are there in a cube based unit cell having one atom on each corner and two
ionic compounds
2) It explains the lattice energies of atoms on each body diagonal ?
of metals all
3) It can explain the electrical conductivity 1)8 2) 6 3) 4 4) 9
is
5. The crystal system having rectangular prisms 18. A point that is located at the of unit cell is shared
2) rhombic 3) trigona 4) Hexagonal corner a by how many unit cells ?
1) Triclinic
1) 2 2) 4 3) 6 4) 8
of symmetry is
The crystal system without any element 19. The number of lattice points per unit cell in B.C.C and end centered lattice
1) monoclinic 2) hexagonal 3) triclinic 4) cubic respectively
1) 6, 6 2) 9, 10 3) 6, 8 4) 6, 10
of the seven crystal systems. The number of Bravais lattices possible for
White Sn belongs to one
20. The minimum radius ratio that
that crystal system
can give a specific coordination number to the compound is
3) 4 4) 3 1) 0.225 2) 0.15 3) 0.414
1) 2 2) 1 4) 0.73
21. The coordination numbers of oxygen and silicon in
8. In KMnO the crystallographic parameters are SiO, respectively
1) 1, 2 2) 2, 1 3) 2, 4
1) a=B=y#90° 2) =B=Y=90 4) 4, 2
3) a#B#y#90 4) 0=y=90 B>90 22. In metal lattices the co-ordination number of metal atom is usually
Among the unit cells given below, which are highly symmetric and unsymmetric respectively 1) 2 (or) 4 2) 4 (or) 6 3) 6 (or) 8
9 4) 8 (or) 12
1) Hexagonal, cubic 2) Orthorhombic, cubic 23. Na and Mg crystallize in BCC and FCC type of crystals
3) Cubic, triclinic 4) Monoclinic, cubic Na and Mg present in the unit respectively, then the number of atoms of
cell of their respective crystals is
10. Copper metal belongs 1) 4, 2 2) 9, 14
to a crystal system represented by the crystal dimensions as 3) 14, 9 4) 2, 4
1) a=p=y=90" ;a =b=Fc 2) a B*Y:a =b=c 24. Potassium crystallises in a body centred cubic unit cell. The mass of one unit cell is
3) a=B=90°:y*90° a=b=c 4) =B= y=90°, a#b#c 1) 1.29x10-25 gm 2) 1.295x10-22 gm 3) 6.2x1023 gm 4) 1.29x10-24 gm
11. From Bragg's equation which one of the 25. A metal 'M' is
following is wrong? crystallised in F.C.C lattice. The number of unit
cells in it having 2.4x1024 atoms
1) Incident angle (0) value is in between 0 to 900 1) N 2) N/2 3) 2N 4) 4N
2) 2d <na 26.
3) order of diffraction "n' is an integer Among the following which has a different structure from others ?
4) as of x-rays increases, incident angle for first order 1) Ba
diffraction increases 2) Cr 3) Mo
12. For a crystal the
4) TI
angle of diffraction (20) is 90" and the second order A27. In a
hexagonal closest packing in two
The wave length (in A) of line has a 'd' value of
Z.o sphere will be
layers one above the other, the coordination
number of each
x-rays used for Bragg's diffraction is :
1) 1.61 A 2) 1.14 A0 1) 4
3) 2.28 A 2) 6 3) 8
4) 2.0 AO 4) 9
50 APEX SERIES for Sri Chaitanya CBSE XII Student" APEX SERIES for Sri Ghaitanya CBSE XII Students he
51
 9OBJECTIVECHEMISTRY-XIID
OBJECTIVE CHEMISTRY-XIID would you expect maximum distance
octahedral void the following ionic compounds
tetrahedral
and
39. In the crystals of which of (CBSE 1998)
of
the
number
between the of the cations and anions
centres
SOLID STATE= 'n' particles,
3) CsI 4) Lil
containing 4) 2n, n/2 2) CsF
close packed
lattice 1) LiF
28. In a
3) 2n, n
respectively
structure1s
40. Gold crystallizes with a
4) orthorhombic
2) n, n close packed 3) simple cubic
1) n, 2n unit cell of cubic 4) 8 1) fcc 2) bcc
Then the number of
in a nearest
voids structure.
HCP
to solid state, it
octahedral
The number of 3)4 When molten zinc is cooled
assumes
29.
2) 2 'c? 41.
is
be
4) Rb neightbours of zinc atom will
1) 1 void efficieney
crystal the 3) 6 12
of the following 3) Cu called tetrahedral 2) 8
30. In which
2) Po another sphere is 1) 4
sodium metal is
by coordination number of sodium in
1) Zn
surrounded by a triangle of spheres capped 42. Sodium crystallizes in a bcc lattice, hence the
4) 8
31. (A) A void 3) 6
void. arrangement 1) 0 2) 4
in tetrahedral 1s
(R) Tetrahedral voids are
explanation
of (A)
The metal having 26% void space in
its crystal structure
and (R) is the
correct 43. .3) Mo 4)1Be
explanation of (A)
true
(R) and are
Cs 2) Po
1) Both (A) is the correct 1) ABCABC ..type lattice
are true and (R)
not
in a
metallic element crystallising'
2) Both (A) and (R) The percentage of void space of
a
but (R) is false 44.
3) (A) is true two corner
pattern is 4) 74%
is true Atoms of 'A Occupy
3) 34%
4) (A) is false but (R) A and B. 1) 24% 2)26%
cubic solid is made up
of two elements "B. The formula of radius of the metal atom is
the atoms of edge length 6.22 A". The
are occupied by cubic unit cell of
centered
A body simple
32.
of the unit cell 45. A metal crystallises in a
4) 2.45 A
of the Remaining positions
cube. 3) 6.22 A
1) 1.55 A0 2) 3.11 A
the compound is : 4) AB with the cell edge, 'a'
= 4.29A. The radius
2) AB 3) AB Sodium metal crystallises in body-centred cubic lattice
a
1) AB at the corners
or tne
la *
cub the compound is 46.
W atoms are located of the Na-atom will be.
structure in which of
33 A solid has a centre of the
cube. The
formula
3) 1.86A 4) 0.2A
and Na atom at the (Ceet Kurukshetra 1996) 2) 1A
the centre of the edges 1) 5.78A
3.63 A°. The radius of Cu-atom is
4) NaWO Copper crystallises in a f.c.c. lattice, the length of the unit cell is
2) Na,WO 3) NaWO,
in which the X atoms are
ATO 47. 3) 1.28 A° 4) 5.7 A
1) NaWO, in a cubic structure 1) 0.6 A° 2) 2.9 A°
elements X and Y crystallizes the compound isS
A compound formed by face-centres. The formula of body centred cubic lattice, what
34.
corners of a cube
and the Y atoms are
at the
48. The radius of an atom of an element is
80 pm. If it crystallises as a
at the
2) XY 3) XY2 4) XY is the edge of its unit cell ?
1) XY where the A
A and. B. This crystallizes
in the cubic structure
2) 184.7 pm 3) 209.2 pm 4) 147.5 pm
formed by elements 1) 140 pm
35. A compound is centres. The simplest formula o
atoms are at the body
of the cube and B its unit cell is 3.04 A. The volume of the unit cell
the
A metal has bcc structure and the edge length of
corners
atoms are at
the compound is
49.
in cm will be
3) AB 4) AB 3) 6. 02 x 103 cm 4) 6. 6 x 10-24 cm3
1) AB 2) AB 1) 1.6 x 10-2 cm3 2) 2. 81 x 10-2 cm3
element Y' form C.C.P. lattice and
those of element "X' occupy 2/3rd o
In a compound atoms of distance between K* and F in
36.
will be 50. If the radius of K* and Fare 133 pm and 136 pm respectively. the
tetrahedral voids. The formula of the compound
KF is
2) X,Y 3) X,Y4 4)X,Y
1) X,Y of X. Its unit cell structure is show 1) 269 pmn 2) 134.5 pm 3) 136 pm 4) 3 pm
37. A compound M,X, has cubic close packing (ccp) arrangement
below. The empirical formula of the compound is IIT-2012 Defects
defeet
1) MX 51. Schottky causes
2) Decrease in the density of solid
1) Increase in the density of solid
2) MX M 4) Decrease in the conductivity of solid
OX 3) No change in the density of solid
What type of erystal defect is indicated in the diagram below (AIEEE 2004)
3) 52.
1) Frenkel defect Na C Na C Na* C
4) MX14
2) Frenkel and Schottkydefects C aC Na Na
38. The intermetallic compound LiAg crystallizes in cubic lattice in which both lithium and silver ha
co-ordination number of eight. The crystal class is (CBSE 1990 3) Interstitial defoct Na C CI Na Ci
1) simple cubic 2) body centered cubic 4) Schottky defect CI Na CI Na" Na"|
3) face-centered cubic 4) none of these
APEX SERIESfor Srl Chaltanya cBSE XIl Students 53
52 APEXSERIES for Sri Chaltanya cBSE XII Stude
 OBJECTIVE CHEMISTRY-XIID with
be made n-type
semi conductor by doping
Germanium can Ga
4) either As (or)
n
SOLIDSTATE are mostly
tound 64 3) gallium
defects
nub 2) arsenicC
- Wagner co-ordination 1) silicon
3. Schottky
with high
compounds numoer statements is wrong
) lonic co-ordination
Which one of the following
with low numoer
65 of Germanium decreases
the electrical conductivity
lonic compound coordination
)
with low
compounds
coordination
number
1) With increasing temperature conductor
covalent
with high is n-type semi
Silicon dopped with phosphorus
detect.
compound
COvalent to
have
Schottky 4) MgCl, 2)
semi conductor
ikely is
54. Which among the
following 3) TICI
3) Germaniumdopped with indium p-type
2) NaCl of semi conductor
1) Ag CI increases the conductivity
4) Doping
decrexses
of solid
defect the density
of solia different from others in
. (A) : During
vacancy
lattice lower
the density
or (A) 66 The magnetic behavior is
(R): The
vacancies in the explanation 3) ZrO, 4) Ti,O
is the comect 1) O, 2) VO,
are true and (R) of (A)
B o t h (A and (R) corect explanation as
the be expressed
and (R) is not substance can
is true The magnetic susceptibility of
a
and (R) are true false but (R) 67
) Both (A) 4) (A) is
false
2) volume susceptibility
3) (A) is true but (R) is (CBSEI 1) gram susceptibility
is observed
when 4) all
56. Schottky defect in erystals lattice the 3) molar susceptibility
anions are missing from
)Unequal number of cations and the lattice Which of the following is correct
statement
cations and anions are missing from 68 semiconductor
2) Equal number of interstitial cells silicon doped with boron is n-type
normal site and occupies
an 1)
3) An ion leaves its semiconductor
increased 2) silicon doped with arsenic is a p-type
4) Density of the crystal is List. ] 3) metals are good conductors of electricity
57. List I
semiconductors decreases with increasing temperature
1) Amorphous 4) electrical conductivity of
A) Crystal defect
2) Frenkel Where 'M' would not be
B) Carborundum The general formula of ferrites is MFe,O4.
4
3) Covalent crystal 69. 3) Al 4) Zn
C) Pitch 2) Cu
The correct match is
1) Mg
A BC A B C Which substance shows anti
ferro magnetism?
A BC B
70.
1) 3 1 2 2) 2 1 3 3) 2 3 1 4) 1 2 3 2) CdO 3) CrO 4) V,O3
1) ZrO
58. Which of the following is a "Bertholide Compound? shown below T T represents which of the
71. The allignment of magnetic dipoles
MgO 2) AL;O, 3) Na,O 4) ZrH
following
2) Ferri magnetism
Properties of solids 1) Diamagnetism
59. To get n-type semiconductor, impurity to be added to silicon 4) Anti-ferromagnetism
should have the following nuio 3) Ferro magnetismn
valence electrons (KCET20
List I List II
1) 2 2) 3 3) 1 4) 5 A) Antiferromagnetic 1) ZnFe,O
60. The mechanism of electrical 2) Nio
conductivity may be given in
terms of B) Covalent crystal
1) vacancy mechanism
2) interstitial mechanism 3) Diamond
3) Interstitialcy mechanism C) Ferrimagnetic
4) all
The. correct match is
61. The oxide that is insulator is A B C
AB C ABC
A BC
1)Vo 2)MnO 3) 1 2 3 4) 1 3 2
3) ReO, 1) 2 31 2) 3 2 1
62. In which of the following the 4) Ti,O answering following questions use these conditions (73 77) to
conducivity would be in the
order of
For
1) NaCl 2) Na 104 ohm cm 1) Both (A) and (R) are true and (R) is the correct explanation
of (A)
3) diamond of (A)
63. Which one of the following ratio
gives the
4) Ge 2) Both (A) and (R) are true and (R) is not the correct explanation
P300 c purity of the metal 3) (A) is true but (R) is false
P300K (p-resistivity (or) speci resis
P42c 3) Pso0 K
4) (A) is false but (R) is true
4K 4) Pec
54 APEX SERIES for Srl Chaltanya CBSE XII Students 55
4 APEX SERIES
for Sri Chaitanya cBSEXII Stud
 OBJECTIVE CHEMISTRY-X

decreases.
SOLID STATE= the condicutivity
of metals
in temperature metals.
73. (A) : With
increase
increase in
vibrations
lattice
With increase in temperature
(R) conductors of electricity
Metals are generally good defects
74, (A): type
is due to Schottky
(R): Electrical conductivity of metals moment
almost zero magnetic
substances possess
75. (A): Antiferromagnetic in anti-ferromagnetic
substances
electrons
(R): There are no unpaired

76. (A) : Benzene is diamagnetic zero magnetic moment

in compensatory
to give
of magnetic dipoles
are
(R): The allignment paramagnetic at
850 K
becomes
temperature but
is ferrimagnetic at room
77. (A) : Fe,O, in parallel and antiparallel direction
(R): The magnetic
moments in Fe,O, are aligned equally
which on heating randomise

KEY SHEET (LEVEL-I)

EXERCISE -1
8) 4 9)4 10) 2
6) 4 7) 3
1)4 2) 2 3) 1 4) 3 5)1
17) 2 18) 1 19) 4 20) 4
11) 4 12) 2 13) 4 14) 3 15) 1 16) 4
27) 2 28)2 29) 4 30) 1
21) 1 22) 2 23) 2 24) 3 25)1 26)3
4 36)4 37) 1 38) 1 39) 3 40) 3
31) 3 32) 2 33) 2 34) 3
45) 3 46) 3 47) 1 48)3 49)3 50)3
41) 3 42) 1 43) 2 44) 2
55) 3 56) 4 57)1 58)1 59) 1 60) 2
51) 3 52) 1 53) 4 54) 3

61) 2 62) 2 63) 3 64) 2 65)2 66) 4 67)3 68) 1

EXERCISE -II

1)3 2) 1 3) 2 4) 3 5) 2 6)3 7)1 8) 1 9)3 10)1

11) 2 12) 1 13) 1 14) 4 15) 1 16)3 17)4 18)4 19) 2 20) 2

22) 4 23) 4 24) 2 25) 1 26) 4 27)4 28)3 29) 3 30) 4

21)3
31) 3 32)3 33)3 34) 4 35) 1 36) 4 37) 2 38) 2 39) 3 40) 1

41) 4 42) 4 43) 4 44) 2 45) 2 46) 3 47)3 48)2 49) 2 50) 2
51) 2 52) 4 53) 1 54) 2 55) 1 56) 2 57) 3 58)4 59) 4 60) 4
61) 2 62) 4 63) 2 64) 2 65) 1 66)3 67)4 68)3 69) 3 70) 4
71) 2 72)1 73) 1 74) 3 75)3 76) 3 77)3

56 APEX SERIES for Srl Chaitanya CBSE XIl Students