FOR INTERNAL USE ONLY

DSM Nutritional Products

Safety, Health and Environment

P.O. Box 2676, CH- 4002 Basel, Switzerland

Telefone +41 (0)61 815 8827, Fax:+41 61 815 7253

Internal Document of DSM Nutritional Products AG:

The Information provided herein is for internal use only. No part of this document may be reproduced or distributed in any form
or by any means to a Third Party without the prior written permission of DNP Nutritional Products AG. DSM makes no
representation or warranty of the accuracy, reliability, or completeness of the information towards any Third Party.

PU Assessment
Design Phase Risk Assessment (DHS)

Final HAZOP Risk Assessment

PU Assessment Risk Assessment

Document- No.: 001

Site : Piura

Product: Mix of biological and physicochemical sludge

Step / Node: N/A

Version / Revision index: 01

Valid as per : 18/10/2021

Next review: 15/12/2021
File Name: 631536112.docx

Overall Summary
Process Safety RLa RL1 RL2 RL3 RL4
Identified Scenarios classified according Scenario
DSM Risk Graph (RL) Number 0 0 0 0 0
DSM HSE req. annex-3 and PSN-GN014
Hazard-No. 0 0 0 0 0

Identified scenario classified according Safety Critical 1-layer 2-layers 3-layers 4-layers 5-layers
DSM risk graph according PSN-GN015 Procedure
Number 0 0 0 0 0
Hazard-No. 0 0 0 0 0

All actions, according action list at the end of this document are closed
0 remaining actions have been transferred to the project list and will be closed before startup
0 actions have been communicated to the site and will be dealt outside this HAZOP/Project
General Concerns / Comments

Registered as DSM Nutritional Products Ltd, Wurmisweg 576, CH-4303 Kaiseraugst

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DSM Nutritional Products
PU Assessment Risk Assessment (PU) Version: 0 Valid from: 2/11/21
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Document Information

Position / Function
Name Signature Date
Department

Document
Site Director
Owner

Reviewer
SHE Coordinator
Participant

Reviewer
CI Coordinator
Participant

Approval
Production Manager
Operation

Approval
SHE Manager
SHE Manager
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PU Assessment Risk Assessment (PU) Version: 0 Valid from: 2/11/21
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Document History

Version Reason of change /Project MOC-No. Valid as of

01 MOC Piloto Deshidratador de lodos 18/10/2021

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Table of Content

1 Participants / Responsibilities.........................................................................................5

2 Basic Information............................................................................................................. 5
2.1 Pre-conditions, Considerations and Assumptions for this Package Unit..................5
2.2 Process description / Reviewed operation conditions.............................................9
2.3 Node borders........................................................................................................... 9
2.4 Equipment............................................................................................................... 9

3 Basic Documents............................................................................................................ 10

4 Checklist........................................................................................................................ 11

5 Action points.................................................................................................................. 12

6 Attachments................................................................................................................... 12
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PU Assessment Risk Assessment (PU) Version: 0 Valid from: 2/11/21
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1 Participants / Responsibilities

Sessions date
Roles and responsibilities (mark applicable choice X)
attended

Executed (%)
Instrumental

Maintenance

Planned (%)
Production
& control

15/10/21
Engineer

Engineer

Engineer

7/09/21
Process

Safety
Scribe
Position / Function Chair
Name Comments
Department

SHE Coordinator X X X 100% 100%

Supplier X X X 100% 100%
CI Coordinator X X X 100% 100%

2 Basic Information

2.1 Pre-conditions, Considerations and Assumptions for this Package Unit

a) This Package Unit follows the PSN Guidance Standard.

b) The information/documentation presented below is sufficient to execute a SHE
assessment on its integration in the other process parts, ensure a safe and
sustainable operation during its life cycle and fulfil the legal requirements.
c) Plano del equipo:

d) The selected area is far from the ATEX zone, in a open area.
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Área seleccionada

e) The information/documentation provided by the supplier are:

a. Equipment and instrument List with material, line, function, type, weight,
potency and model included in the vendor document: “abcdfg.pdf”.

f) MSDS: “abcdfg.pdf”

g) System Layout: N/A

h) Boundaries of nodes general.

See the vendor document “Descripción de planta abcdfg.pdf”

Operation/maintenance of PU by supplier

a. Risk assessment reports or an enumeration and description of the risks

(needed to inform personnel on the risks).::

b. A list of the safety provisions and measures linked to the risks (to verify their
applicability and functionality).
Comments:
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See 4.1

c. Design cases of reliefs and other emission points (needed for safe location
design and processing emissions).
Comments:
Physicochemical and biological sludge are not dangerous. The whole system
comes in a container and there will be anti-spill equipment nearby.

d. Information on safety provisions (make, type) and safety measures (to verify
their quality).
Comments:
See 4.1

e. Information on waste streams (needed to safely process waste streams).

Comments:
No waste streams will be released to the environment. Close system.
Dewatered sludge will be disposed by supplier “ABCDFHIJ”.

f. Information on maintenance process (fulfilment of legal compliance issues).

Comments: abcdfghidfdfdsf fsdf

g. Proof test procedures (initial and periodic to fulfil legal requirements, verify
their applicability and manage/control supplier’s operators during their
presence on site).
Documents:
Abcdfefer er

h. Results of proof testing during its operation (control of PU SHE performance

and fulfil legal requirements).
Comments:

i. All other information needed to fulfil legal requirements on License to operate

Comments:
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DSM Nutritional Products
PU Assessment Risk Assessment (PU) Version: 0 Valid from: 2/11/21
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Title: P.U. – Waste Water Treatment – Industrial Treatment Page 8 of 12

Operation/maintenance of PU by DSM

a. Risk assessment reports or an enumeration and description of the risks

(needed to inform personnel on the risks and/or their magnitude).
Documents:
See the vendor document “DHS – Piloto deshidratador HUBER 2021
(003).xlsx ” actualizar documento

b. A list of the safety provisions and measures linked to the risks (to verify
their applicability and functionality).

c. Design information on safety provisions and measures (make, type).

Comments:

d. Verification reports of all safety provisions (incl. PFD calculations).

Documents:

e. Validation reports of all safety provisions (functional test, calibration).

f. Design cases of reliefs and other emission points (needed for safe location
design and processing emissions).
Comments:
Close System. No emissions will be returned in the environment before
treatment. There will be recirculation system to guarantee that the effluent do
not reach the environment.

g. Design information on waste streams (needed to safely process waste

streams).
Documents:
Presented in the Project Details (Explanatory Memorial).

h. List of personal protection means (PPM).

Documents:
No special PPEs are expected.

i. Operating Operation instructions.

j. Training requirements and instructions.

k. Maintenance/inspection instructions for safety devices.

l. Proof test procedures for safety provisions (incl. Maintenance Override

Switches).

m. Needed spare parts for safety provisions.

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PU Assessment Risk Assessment (PU) Version: 0 Valid from: 2/11/21
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n. Compliancy (certificates) with National standards (EU regulation or US

regulation, PED, CE marking).
Comments:
Completar el formato MSA

o. All other information needed to fulfill legal requirements on License to

Operate.
Comments:
L

2.2 Process description / Reviewed operation conditions

Start-up/shut-down: information for operation of the plant

2.3 Node borders

2.4 Equipment
Add document
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DSM Nutritional Products
PU Assessment Risk Assessment (PU) Version: 0 Valid from: 2/11/21
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3 Basic Documents

Check on presence of documentation and preparation by participants with assigned roles

Nr Subject Detailed issues Is sufficient information available? Action / remark

0 Information
0.1 CHA  Chemical Hazard Analysis - Present; (Yes) /No
DNPAM-OPS-REP-105379
0.2 P&ID  P&ID
0.3 Mass & Energy  Mass & Energy balance
balance
0.4 Instrumental &  Instrument Index List
control engineer  Bill of materials
checked; Instruments
 Process Control Diagrams
Logic / Sequence diagram
 Final Mechanical Element
Analyses
0.5 Mechanical  Equipment Lists
engineer  Process Integrity Database
checked;  Piping classes / Line
schedule list.
0.6 Process engineer  Previous HAZOP Study
checked;  Process Hazard Review
 Maximum Credible
Accident
 Process Data Sheets
 Process Flow Diagram
 Safety Relief Valves List
0.7 Production  Working instructions.
checked;  Normal procedure.
 JSA (job safety analyses).
 Process manual.
0.8 Safety engineer  MSDS
Checked;
0.9 Other information  System HAZOP
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4 Checklist

1. Risk assessment reports or an enumeration and description of the risks (needed to inform personnel on the risks). (Complete Study: )

Technology & Quality Risk Assessment: Industrial Effluent Treatment Plan Rev.01 Reference Document: Y-062-001 R 4
You have completed 0 Risk Assessments out of a total of 5
Gross Risk Risk after known controls implemented
Nr Catalogue Risk Scenario Likelihood Impact Exposure Likelihood Impact Exposure Response

INDUSTRIAL TREATMENT
Obstruction of the Screw
Daily inspection of the sludge quality. We do not expect
Open

1 Press by non desired Detention of the system Low Low Low Very low Low Low Accept
solids as DSM have pretreatment.
solids as plastics
Open

2 Failure of pump Detention of the system Low Low Low System include 1 pump as spare. Very low Low Low Accept
Open

3 Low pressure of water No cleaning water for the system Low Low Low To use a manual Hidro Jet to clean system Very low Low Low Accept

Level sensor at the Floculator tank with sign to the feed

pump.
Failure in the Screw
Open

4 Overflow of the Flocutator Tank Low Low Low If sensor fails floculation tank will overflow and Operator Very low Low Low Accept
Press
must stop feeding and DSM will implement a overflow
contention system

System alarm about low level of polymers. We have an

Open

6 Failure in Polymer pump No polymer preparation Low Low Low Very low Low Low Accept
additional pump on Conteiner if necessary to change pumps.
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PU Assessment Risk Assessment (PU) Version: 0 Valid from: 24/06/2019 Page 12 of 12
Title: PU – Waste Water Treatment – Industrial Treatment Page 12 of 12

5 Action points
N/A

6 Attachments

MSDS