Aits 2223 PT II Jeem Sol

FIITJEE
ALL INDIA TEST SERIES

PART TEST – II
JEE (Main)-2023
TEST DATE: 03-12-2022
ANSWERS, HINTS & SOLUTIONS

Physics PART – A
SECTION – A
1. C
Sol. Pt = Qsystem + Qlost
750  4  60 = 0.5  4200  70 + Qlost
Q
 Plost  lost
time
2. B
Sol. (m0 – t) CdT = Rdt
3. A
Sol. At steady state
Let the temperature at the junction be T X Y
100C
kA 4nknA
 (T  100)  (0  T)
 2n2 
 T is independent of n.
4. A
Sol. P1  2AT14  AT24 1 2
AT14  2AT24
T1 T2
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AITS-PT-II-PCM(Sol.)-JEE(Main)/2023 2
5. A
300 2(2R2 )e(5004  3004 )
Sol. 
600 2R2 e 500 4  3004   2R2  500 4  3004 
   
6. B
1
Sol. 2 
LC
7. D
Sol. cos 1  0.6 cos 2  0.5 cos 3  1
XL XC  XL  XC
tan 1  tan 2 
R1 R2 R1 tan 1  R2 tan 2
8. B
Sol. The force exerted by gas on the piston when spring has compression x is
F  P0 A  kx

W  Fdx
0
9. D
Sol. Pitch (along x-axis) = V0t
Magnetic force is towards negative z-axis
  = t = 
 at this instant y = 0 and z = 2radius
10. C

Sol. u  ux ˆi  uy ˆj

E  Ejˆ

B  Bkˆ
   
      
F  e E  u  B    e  Ejˆ  ux ˆi  uy ˆj  Bkˆ 

Fx  euyB, Fy  e E  ux B 
eB
 ax  uy
m
e
ay  E  u xB 
m
 uy  A sin  t    , a y  A cos  t   
At t = 0, uy = 0   = 0
Fy eE
ay  
m m
eE E
 A 
m B
E
 uy  sin t
B

3 AITS-PT-II-PCM(Sol.)-JEE(Main)/2023
The velocity is along x-axis implies final velocity along y-axis is zero.
/
dy
uy 
dt
 dy    u dt .
0
y
11. C
d
Sol. 
dt
12. D
Sol. At point A, E along the rod = 0 Y
x cos 45° = y sin 45°
 x=y (0, L) 45°
If the particle just reaches point A with velocity tending toward
zero, then it will be able to reach the other end. A 45°
45°
Apply work energy theorem X
(L, 0)
13. D
i R /2 R
x  x
Sol.  di  
0 0
 R/2
R 
J0   12xdx  J0 (2x)dx
R
x
dx
14. D
Sol. Apply PV = nRT
P R

nT V
15. A
Sol. Magnetic field is along the tangent
16. B
 0I  sin60  ( k)
ˆ ˆ
0I sin30  ( k)
Sol. B 
4 (2R sin30) 4(2R sin60)
17. B
1 2
Sol.  t
2


d Ba 2 / 2 
dt
18. A
Sol. mg = kx
q2
and kx 
20 A

19. C
1
Sol. T0 
0
P0  T04
1 256P0 1
 P0  and  4
04 81 
P0 4
  4
256P0 0
81
20. D
Sol. PV = RT
A
and P  ;
B2
1
V2
RT A

V B2
1
V2
VA
T
 B2 
R 1  2 
 V 

SECTION – B
21. 2
Sol. V = I1R1 and V = I2R2
NIAB = k
k 1
I1 
N1AB
k 2
 I2 
N2 AB
k 1R1 k2R2
V 
N1AB N2 AB
22. 4
kq1 kQ k(q2 )
Sol. VA  0   
R 2R 3R
k(q1  Q  q2 )
VB  0  q1
3R R Q
A
2R
3R
q2

23. 3
IgG 
Sol. S 
I  Ig A
24. 75
(30)2  1 1 1   (15)2  1 1  (45)2 
Sol. H =        75 J
2  3 6 6   2  3 6  2  6 
25. 3
nA RT nA RT
Sol. P   …(i)
2V V
nBRT nBRT
1.5P   …(ii)
2V V
Solve equation (i) and (ii)
26. 5
Sol. PT = constant
PV1/2 = constant
1
x
2
R
C  Cv 
1 x
9R fR
  2R
2 2
 f=5
27. 7
Sol. Q = nCPT
7
Q = nRT
2
W = PV = nRT
Q 7

W 2
28. 3
Sol. PV
PV1 = constant
 x = 1
R
C  Cv 
1 x
5R R 6R
    3R
2 2 2
29. 1
2R1
Sol. Resistance, R =
r 2
2
m  d( r )2R1
d
R  (2R1 )2
m

2
dB R1
Induced current in the loop, I =
dt R
30. 3

Sol. I  3A
R
1 1
H  LI2   2  106  (3)2  9 J
2 2
H 9
H1 =   3 J
3 3

Chemistry PART – B
SECTION – A
31. B
Sol. P  C2H4 O  and Q  C3 H6 O  must be carbonyl compounds as they both show +ve NaHSO3 test. P
must be ethanal as it gives haloform test.
P  CH3  C  H, Q  CH3  CH2  CHO
||
O
1. NaOH
CH3  CHO  CH3  CH2  CHO 2. 
 CH3  CH  CH  CHO
+
CH3
|
CH3  CH2  CH  C  CHO
+
CH3
|
CH3  CH  C  CHO
+
CH3  CH2  CH  CH  CHO
Total 4 products obtained if we exclude stereoisomerism.
32. D
Sol. Cl
CH3 HC HC O
Cl
2 Cl H O

h
 2

373 K
(P) (Q) (R)

Free-radical substitution is involved in conversion of P to Q.
33. C
4  i LiAlH
Sol. H3C C OC2H5 
ii H O
2CH3  CH2 OH
2
O
 4 i LiAlH
H3C C O C CH3 
ii H2O
2CH3  CH2 OH
O O
 i DIBAL H
H3C C OCH2CH3 
 ii H O
 H3C C H
2
O O

CH3  CH2  OH

Na
H3C C OCH3 
C H OH
 CH3  CH2  OH
2 5

O
CH3  OH
34. C
H OH
Sol. O C C C
P2O5 / 
O  O  C  C  C  O
2H O 2
OH H  C3 O 2 
Malonic acid
35. D
Sol. This is Hoffmann bromamide reaction which involved intramolecular migration. No cross-over
product is formed. Stereochemistry is retained.
Me Me
NaOH/Br
H CONH2  H CONH2 2
 
Et CD3
Me Me
H NH2 + H NH2
Et CD3
36. B
Sol. The lone pair on N-atom in pyridine N is localised but – I effect of N-atom deactivates
N
H
benzene ring. On the other hand, the lone pair on N-atom in pyrrole is de-localized
and hence activates the ring towards EAS.
 Order of reactivity is : III > II > I.
37. A
Sol. In the first reaction, the lone pair on nitrogen atom takes part in resonance with benzene ring and
hence activates benzene ring towards EAS. But in second reaction, the lone pair on nitrogen
atom does not take part in resonance with benzene ring due to SIR-effect and hence does not
activate benzene ring.
 r1  r2 .

38. D
Sol.
H3C C N  HCl  H3C C NH
Cl
Anhydrous AlCl3
H3C C NH
H3C C O
H2 O
NH3
39. C
Sol.
N2Cl OH OH
Br Br Br Br
Boil Br2 Zn dust

H2O
   

H2 O
(P)
Br Br
(Q) (R)
Q is polar while R is non-polar.

 Q   R .
40. B
Sol. F C C Ph C C Ph C C Ph
PhCCNa 
 Fe/HCl NaNO  HCl
  2

o 
0 5 C
NO 2 NO 2 NH2 N2 Cl Q 
P 
C2 H5 OH
C C Ph
O C CH2
O H2 SO 4
Br2
C CH2 Br HgSO 4
T  Fe
R 
S

41. C
Sol. OH OH OH
CHO COOH
 i CHCl3 NaOH, KMnO4

  
 ii H3 O H ,
P  Q
O
||
PhC Cl
O
O
O C Ph
O C Ph
COOH
COOH Br2
Fe
R 
Br
S
42. B

Cold conc.  
Sol. CH3 CH2 OH 
H2SO 4
  CH3  CH2  O H2  HSO 4
 
Oxonium salt
i  2
Cold conc.
Ph3 C  OH 
H SO
 Ph3 C  H3 O  2HSO4
2 4
i  4 
43. D
Sol. 2 2H g
H3C CH CH2 C CH   H3C CH CH2 CH2 CH3
CH3 CH3
(P) 2-methyl pentane
H2 SO 4 HgSO 4
H3C CH CH2 C CH3

CH3 O
(Q)
The ketone (Q) gives positive Iodoform test and shows 2,4-DNP test. It also forms white
crystalline product with NaHSO3.

Ammonical +
H3C CH CH2 C CH 
AgNO3
 H3C CH CH2 C C Ag
CH3 CH3
(White ppt.)
Ammonical Cu2 Cl2
+
H3C CH CH2 C C Cu
CH3
(Red ppt.)
44. A
 
Sol. Phenol  H  CHO   Novolac P  
H CHO
 Bakelite  Q 
45. A
Sol. It’s a Reimer-Teimann reaction. Dichloro carbene (Singlet) is formed as an intermediate in this
reaction.
46. B
Sol. Order of basic strength in aqueous medium is
Me2NH  MeNH2  Me3 N
II I  III
47. A
Sol. Picric acid pK a  0.4
Squaric acid pK a1  1.5
Phenol (Carbolic acid) pK a  9.98
Carbonic acid pK a1  6.37
48. A
Sol. There is only geometrical isomerism in the given molecule around C = C. There are two
geometrical isomers possible for the given molecule.
49. C
Sol. Assymetric compounds are P, Q and R as these do not contain POS (Plane of Symmetry).
50. B
Sol. N
C
No. of  bonds  8
C
C C No. of  bonds  8
N C N
N

  1: 1 .


SECTION – B
51. 13
Sol.  
KCN aq.
CH  Ph C CH Ph (P)
O O OH
PCC
Ph C C Ph (Q)
O O
 i OH /
 ii  H
Ph
Ph C C OH
OH O
(R)
2
Number of sp hybridised carbons in R = 13.
52. 3
Sol. Soda lime is a mixture of 3 moles of NaOH and 1 mole of CaO.
53. 4
Sol. Pressure = 802 – 42 = 760 mm Hg
= 1 atmosphere
Volume = 110 mL = 0.11 L
PV 1  0.11
n   4.47  10 3 moles
RT 0.0821  300
Weight of N2  n  28
 4.47  103  28  0.125 g
Wt. of nitrogen
% of nitrogen   100
Wt. of organic compound
0.125
  100  25%
0.5
Molecular formula  C12H24 Nx
Molecular weight = 168 + 14x
14x
% of nitrogen   100  25
168  14x
x=4
 Molecular formula = C12H24 N4
54. 0
Sol. S 2  Na2 Fe  CN5 NO    Na 4 Fe  CN 5 NOS 
' X ' Violet colour
Compound ‘X’ is sodium nitroprusside and its magnetic moment is (0.0 B.M.)

55. 8
Sol. Only primary alcohols give aldehydes on oxidation with PCC. 8 structural isomers are possible for
such alcohol.
1. CH3  CH2  CH2  CH2  CH2  CH2  OH
2. H3C CH2 CH2 CH CH2 OH
CH3
3. H2C CH2 CH CH2 CH2 OH
CH3
4. H3C CH CH2 CH2 CH2 OH
CH3
5. CH3
H2C CH2 C CH2 OH
CH3
6. H2C CH CH CH2OH
CH3 CH3
7. CH3
H3C C CH2 CH2 OH
CH3
8. H2C CH2 CH CH2OH
CH2
CH3
56. 6
Sol. With C  CH  1 mole G.R. reacts
With OH  1 mole G.R. reacts
With CN  1 mole G.R. reacts
With CHO  1 mole G.R. reacts
With COOCH3  2 mole of G.R. reacts
Thus, total 6 moles of G.R. are consumed
57. 4
Sol. On acetylation, –OH group gets converted into OCOCH3 per –OH group. It means that
molecular weight increases by 42.
Molecular weight of ‘A’ = 166
Molecular weight after acetylation = 334
Increase in molecular weight = 168
168
 Number of OH group  =4
42
58. 5
Sol. The compounds which are more acidic than benzoic acid are
COOH
COOH COOH COOH COOH
CH3
OH
OCH3 NO 2
Cl

59. 4
Sol. 1. CH3  CH  CH  CH2  CH2  CH3
2. H3C CH CH CH CH3
CH3
3. H2C CH C CH2 CH3
CH3
4. H2C CH2 CH CH CH2 CH3
60. 4
Sol. Number of meso-isomers for a symmetrical molecule having odd number of chiral carbon
 n 1 
 
 2 
2 , where n = number of chiral carbon
 5 1 
 
 Number of meso isomers  2 2 
 22  4 .

Mathematics PART – C
SECTION – A
61. C
Sol. From the diagram, AOB = BOC =  COD = 60° B C

 YOD =
6
a Y
 Let X be the centre of right hand circle,
OXsin30° = a X
 OX = 2a a
Now 30°
r = OY = 2a + a A O D
r
a=
3
62. A
Sol. Let AB = BO = R and radius of smallest circle is r, OA = 2R, ON = 2R  r and BN = R + r
In OBN
BN2 + OB2 = ON2
(R + r)2 + R2 = (2R  r)2
2R2  6Rr = 0
R(R  3r) = 0
Considering OBN, perimeter
OB + BN + NO = R + (R + r) + (2R  r) = 8
 R=2
1 2
r= R
3 3
63. A
Sol. Square and add
24(sinA cosB + cosA sinB) = 12
1
 sin(A + B) = sin(  C) =
2
1
 sinC =
2
 5
 C= or
6 6
5  3
but if C = , then A < so 3sinA + 4cosB =  4  6
6 6 2

 C= only.
6
64. B
1 1
Sol. (sin4x + cos4x)  (sin6x + cos6x)
4 6
1
 [3(sin4x + cos4x)  2(sin6x + cos6x)]
12
1
 [3((sin2x + cos2x)2  2sin2xcos2x)  2{(sin2x + cos2x) (1  3sin2xcos2x)}]
12

1 2 2 2 2
 {3  6sin xcos x  2(1  3sin xcos x)}
12
1 2
 =
12 24
65. B
a
1
b  A B C
Sol.  tan   tan
a  2  2
1
b
1 3  A B  C  A B 1
  tan   tan  tan  
3 3  2  2  2  3
 A B 
 tan   1
 2 
 2
 AB= and A + B =
2 3
 A = 105°, B = 15°
66. D
Sol. AO2 = OB2 = OC2
2 + 4 = 2 + 4   =  
  =  (if  =  then no triangle is formed)
ABC is right angled triangle at A
 (, 2) is orthocentre   = 3,  = 2
 vertices are (3, 2), (3, 2) and (3, 2).
67. B
15 / 2 15
Sol. tan = 
4 8
4 C(3, 4)
In RSQ tan = 17/2 17/2
RS
S 15/2 
15 4 32 P 4 4 Q
   RS =
8 RS 15

R
68. D
Sol. Image of vertex of P1 in 3x  y + 10 = 0 will be vertex of P2
x 2  1 y 2  3 2  3  8  10 
 
3 1 10
 vertex of P2 = (2, 9)
Similarly focus of P2 is (9, 3)   = 9 and  = 3
7
Slope of directrix = 
6
7
Equation of directrix y  15 =  (x  5)
6
7x + 6y = 125   = 125.

69. C
Sol. Equation of asymptotes x  3y = 0 and x + 3y = 0
If tangents to different branches are drawn then
2 2
(  9  9) < 0 and (  3) ( + 3) < 0
i.e.  < 92 + 9 and 2 < 92.
2
70. B
1 2 1
Sol. a2 = ,b = let P be (x1, y1)
4 9
1x 1y 5
Equation of normal  
4x1 9y1 36
 5y  5y1 5 1 1
It cuts y-axis at  0 ,  1     y1 =  x1 =
 4  4 8 3 2 3 4
5
Thus  =
36
1 5 5 25
Area of OAB =   
2 36 8 3 576 3
71. B
Sol. x2 + 24x = 25  x = 25, 1
  
P 1,2 6 and Q 1, 2 6  
Equation of tangent at P and Q to the circle
x  2 6y  25 and x  2 6y  25
 R is (25, 0)
Equation of tangent at P and Q to the parabola
2 6y  12  x  1 and  2 6y  12  x  1
 S is (1, 0)
1
Area of PRS =  2 6  26  26 6
2
abc 26  2 7  10 6
R  5 7
4 4  26 6
72. D
2 2 2
Sol. a + b = 18 and b = 6
1
 a2 = 12  6 = 12(1  e2)  e =
2
73. B
Sol. x(y  1) = 8
Equation of directrix x + (y  1) = 2 2  2
 x + y = 5  y = x + 5 touches
x2 y2 30
  1  25 = 30  1   k = 6.
30 30 / k k

74. A
Sol. P  (|OP| cos, |OP| sin)
     
Q  (|OQ|  cos     , sin     
  2  2 
1 sin2  cos 2 
 2
 
OP b2 a2
1 sin2  cos2 
 2
 
OQ a2 b2
1 1 1 1
 2
 2
 2

OP OQ a b2
2a2b2
 |OP  |OQ| reaches
a2  b2
75. B
Sol. Suppose there is a point P(4cos, 3sin) on the ellipse, then distance of P to AB is
3  4 cos    4  3 sin    12
=
5
12
= cos   sin   1
5
12 6

5
2 1 
5

1 6
But AB = 5 so APB  5 =3
2 5
So exactly two points.
76. C
Sol. PF1 + PF2 = 2a = 6
PF1 2
 ; PF1 = 4 and PF2 = 2
PF2 1
F 1F 2 = 2 5
2
there PF12  PF22  F1F2 
2
16 + 4 = 2 5  
So PF1F2 is right angle triangle
1 1
area =  PF1  PF2   4  2  4
2 2
77. B
  
Sol. Since 2  3  ,  2 3 
2 2 2
     
 cos   2   cos  3  
2   2
  2   sin  3 
sin
again cos  2   0 and cos  3   0

cos 2  cos 3  0

 given curve will be ellipse

  
Now sin 2  sin 3  cos 2  cos 3 
 2  3   2  3 
= 2 2 sin   sin   
 2 2 4 
  
 2 3
and   0
2 2
 2 3  2  3 3
 sin    0 and  
 2 2 2 4
 
 2  3 
 sin   0
 2 4 

 2  3   2  3 
 2 2 sin   sin   0
 2 2 4 
  
 ellipse is vertical ellipse.
78. C
Sol. Assume AB is on the line y = 2x  17 and coordinate of other two are on parabola are C(x 1, y1)
and D(x2, y2), then CD is on the line L whose equation is y  2x = b
by solving with curve we get
x2  2x  b = 0  x1, x2 = 1  b  1
assume length of one side of square is a
 a2 = (x1  x2)2 + (y1  y2)2
= 5(x1  x2)2 = 20(b + 1) …(1)
17  b
Now a  …(2)
5
 b = 3 or 63  a2 = 80 or 1280.
79. A
Sol. Equation of AB  y  3x by solving with parabola y2 = 8(x + 2)
3x2  8x  16 = 0
4
E is mid point of AB then x coordinate of E is , then
3
1 4 8 16
|FE| =   , |PF| = 2  |FE| = where F is focus
cos60 3 3 3
80. A
Sol. In ABC
A
A
A/2 A/2
C1
B1
B
B A/2
C
B
C
A1
A1

A
B = ABC +
2
AA 1
= 2R = 2
 A
sin  B  
 2
 A B C
AA1 = 2sin  B    2cos   
 2  2 2
A B  C A
 AA 1 cos  2cos   cos  
2  2  2
   
= cos   C   cos   B   sinB  sinC
2  2 
B
 similarly BB1 cos  sin A  sinC
2
C
CC1 cos  sin A  sinB
2
SECTION – B
81. 2022
Sol. Let xn = tanan
1  tanan  
 tanan1   tan   an 
1  tanan 4 
 
 tanan1  tan   an 
4 

 an 1  an   n
4
 an+4 = an + k. ; k  I
 xn+4 = tanan+4 = tanan = xn
 xn is periodic for period 4
 x2024 = x0 = 2022
82. 36
Sol. Let assume x = cos2cos2, y = cos2sin2, z = sin2
Now x + y + z = 1
 P = sec2sec2 + 4sec2cosec2 + 9cosec2
 P = (tan2 + 1) (tan2 + 1) + 4(tan2 + 1) (cot2 + 1) + 9(cot2 + 1)
= 14 + 5tan2 + 9cot2 + (tan2 + 4cot2) (1 + tan2)
 14 + 5tan2 + 9cot2 + 2tan.2cot(1 + tan2)
= 18 + 9(tan2 + cot2)  18 + 9.2tancot = 36
1 1
Equality hold when cos2 = , cos2 =
2 3
1 1 1
 x  , y  ,z 
6 3 2
83. 2
Sol. (1  cot22°) (1  cot23°)
 cos 22   cos 23 
 1   1  
 sin 22   sin23 

 sin22  cos 22  sin23  cos 23 

   
 sin22  sin23 
2  sin  22  45   2 sin  23  45 

 sin 22 sin 23
2 sin  22  sin  23 
 =2
 sin 22  sin23 
84. 2
3 1 3 1
Sol. 4  4  2
sin x cos x
     
sin   cos  
 12   12   2
 
sin x cos x
     
 sin   cos x  cos   sin x  2 sin x cos x
 12   12 
  
 sin   x   sin2x
 12 
 
  x  2x or  x    2x
12 12
 11
 x or x 
12 36
85. 1011
Sol. Let P denote the desired product and Q = sin.sin2.sin3 …… sin(1011)
then 21011PQ = sin2.sin4.sin6 ….. sin(2022)
= (sin2.sin4 ….. sin(1010) (sin(  1012)) …. (sin(  2020) (sin(  2022))
 21011PQ = sin.sin2.sin3 ….. sin(1011) = Q
 21011PQ = Q
1
P = 1011
2
86. 9
Sol. A B P P
x 2  900
h h
30° 
D C B C B 2 D
x  900
h
tan30° = x= h 3
x
h 8
tan   
2
x  900 17 3
h 8

2 17 3
3h  900

289  3  h2 = 192h2 + 64  900

675h2 = 64  900
16
h=
3
87. 21
Sol. Asymptotes 3(x – 1) – 2(y + 3) = 0 and 3(x –1) + 2(y + 3) = 0
3x – 2y –9 = 0 and 3x + 2y + 3 = 0
It touches x2 + y2 –2x + k/13 = 0
 5 12   31 12 
 A   ,   and B  ,  
 13 13   13 13 
 k = – 23
88. 1
Sol. (sin2)3 + (cos2)3 + (1)3  3sin2cos2(1) = 0
2 2 2
 sin  + cos   1 = 0 or sin   cos2   1

not possible
 sin2 = 1  cos2
 sin2 = sin2
=
89. 315
ab 
Sol. Let M is mid point of AB, M =  ,24 
 2 
OM  MA, |OM| = 3 MA
ab ab
  13 3, 8 3
2 2
 a  21 3 and b  5 3
90. 1
Sol. P(x, y) = (14cos  5, 14sin + 12)
minimum value of g() where
g() = (14cos  5)2 + (14sin + 12)2
= 365 + 28(12sin  5cos)
g()  1

Aits 2223 PT II Jeem Sol

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FIITJEE

ALL INDIA TEST SERIES

ANSWERS, HINTS & SOLUTIONS

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(P) (Q) (R)

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Q is polar while R is non-polar.

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H3C CH CH2 C CH3

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again cos  2   0 and cos  3   0

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 given curve will be ellipse

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 sin22  cos 22  sin23  cos 23 

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289  3  h2 = 192h2 + 64  900

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