$ Generated by PRO/II Keyword Generation System <version 9.

3>
$ Generated on: Mon Nov 21 10:46:15 2022
TITLE
DIMENSION METRIC, PRES=BAR, STDTEMP=0, STDPRES=1.01325
SEQUENCE SIMSCI
CALCULATION TVPBASIS=37.7778, RVPBASIS=APIN
COMPONENT DATA
LIBID 1,METHANE/2,ETHANE/3,PROPANE/4,IBUTANE/5,BUTANE/6,IPENTANE/ &
7,PENTANE/8,HEXANE/9,HEPTANE/10,OCTANE/11,NONANE/ &
12,DECANE, BANK=SIMSCI,PROCESS
ASSAY FIT=ALTERNATE, CONVERSION=API94, CURVEFIT=CURRENT, &
KVRECONCILE=TAILS, FORMATION=VER91
THERMODYNAMIC DATA
METHOD SYSTEM=GS, SET=GS01, DEFAULT
WATER PROPERTY=IF97, TRANSPORT=IF97
STREAM DATA
PROPERTY STREAM=S1, TEMPERATURE=195, PRESSURE=13, PHASE=M, &
RATE(M)=400, COMPOSITION(M)=1,1.4/2,2.6/3,8/4,12.5/5,16.5/ &
6,20/7,14.5/8,9/9,6.5/10,4.5/11,2.6/12,1.9, NORMALIZE
UNIT OPERATIONS
SHORTCUT UID=SCD1
FEED S1
PRODUCT STREAM=S2, RATE(M)=164, PHASE=L, PRESSURE=12
PRODUCT STREAM=S3, PHASE=L, DP=0
CONDENSER TYPE=BUBB
EVALUATE MODEL=CONV, TRIAL=50, KEYLIGHT=5, KEYHEAVY=6, RRMIN=2
FINDEX 2
SPEC STREAM=S2,PCT, COMP=5,WET, VALUE=39.5
SPEC STREAM=S3,PCT, COMP=5,WET, VALUE=0.6
END
SIMULATION SCIENCES INC. R PAGE R-1
PROJECT PRO/II
VERSION 9.3 ELEC V9.1.3
PROBLEM INPUT
THERMODYNAMIC DATA
==============================================================================

DATA FOR SET 'GS01'

GRAYSON STREED PURE COMPONENT DATA

COMP CRITICAL CRITICAL ACENTRIC MOLAR SOLUBILITY

TEMPERATURE PRESSURE FACTOR VOLUME PARAMETER
DEG C BAR M3/KG-MOL
---- ---------- ---------- ---------- ---------- ----------
1 -82.59 45.99 0.0115 0.0380 5.6704
2 32.17 48.72 0.0995 0.0552 6.0614
3 96.68 42.48 0.1523 0.0757 6.4036
4 134.99 36.48 0.1808 0.1052 6.1445
5 151.97 37.96 0.2002 0.0965 6.6969
6 187.28 33.81 0.2275 0.1171 6.7751
7 196.55 33.70 0.2515 0.1160 7.0391
8 234.45 30.25 0.3013 0.1314 7.2835
9 267.05 27.40 0.3495 0.1470 7.4301
10 295.55 24.90 0.3996 0.1634 7.5279
11 321.45 22.90 0.4435 0.1796 7.6257
12 344.55 21.10 0.4923 0.1958 7.6745
SIMULATION SCIENCES INC. R PAGE R-2
PROJECT PRO/II VERSION 9.3 ELEC V9.1.3
PROBLEM INPUT
THERMODYNAMIC DATA
==============================================================================

THERMODYNAMIC SETS USED FOR EACH UNIT OPERATION

DEFAULT METHOD IS GS01

THERMODYNAMIC SET UNIT OPERATIONS

----------------- ---------------
GS01 SCD1

UNIT IDENTIFIER UNIT OPERATION THERMODYNAMIC SET

--------------- -------------- -----------------
SCD1 SHORTCUT COLUMN GS01
SIMULATION SCIENCES INC. R PAGE R-3
PROJECT PRO/IIVERSION 9.3 ELEC V9.1.3
PROBLEM INPUT
THERMODYNAMIC DATA
==============================================================================

THERMODYNAMIC METHODS USED FOR EACH SET

THERMODYNAMIC SET GS01 (DEFAULT)

PROPERTY METHOD
-------- ------
KVALUE(VLE) GRAYSON-STREED
KVALUE(LLE) UNSPECIFIED
KVALUE(SLE) UNSPECIFIED
LIQUID ENTHALPY CURL-PITZER
VAPOR ENTHALPY CURL-PITZER
LIQUID DENSITY API
VAPOR DENSITY SOAVE-REDLICH-KWONG
LIQUID ENTROPY CURL-PITZER
VAPOR ENTROPY CURL-PITZER
LIQUID VISCOSITY IDEAL
VAPOR VISCOSITY IDEAL
LIQUID CONDUCTIVITY IDEAL
VAPOR CONDUCTIVITY IDEAL
SURFACE TENSION IDEAL
LIQUID DIFFUSIVITY UNSPECIFIED
SIMULATION SCIENCES INC. R PAGE H-1
PROJECT PRO/IIVERSION 9.3 ELEC V9.1.3
PROBLEM CALCULATION
HISTORY 11/21/22
==============================================================================

*** PROBLEM SOLUTION BEGINS

FEED FLASH COMPLETE
UNIT 1 SOLVED - 'SCD1 '
*** PROBLEM SOLUTION REACHED

*** THIS RUN USED 21.73 PRO/II SIMULATION UNITS

*** RUN STATISTICS

STARTED 10:45:47 11/21/22 NO ERRORS
FINISHED 10:45:48 11/21/22 NO WARNINGS
RUN TIMES NO MESSAGES
INTERACTIVE 0 MIN, 0.00 SEC
CALCULATIONS 0 MIN, 0.26 SEC
TOTAL 0 MIN, 0.26 SEC
SIMULATION SCIENCES INC. R PAGE I-1
PROJECT PRO/II VERSION 9.3 ELEC V9.1.3
PROBLEM OUTPUT
INDEX 11/21/22
==============================================================================

PAGE CONTENTS
------ ----------------------------------------------------------------
1 COMPONENT DATA
3 CALCULATION SEQUENCE AND RECYCLES
3 SEQUENCE MAP
4 PLANT MATERIAL BALANCE
SHORTCUT COLUMN SUMMARY
5 UNIT 1, 'SCD1'
6 STREAM MOLAR COMPONENT RATES
7 STREAM SUMMARY
SIMULATION SCIENCES INC. R PAGE P-1
PROJECT PRO/II VERSION 9.3 ELEC V9.1.3
PROBLEM OUTPUT
COMPONENT DATA 11/21/22
==============================================================================

COMPONENT COMP. TYPE PHASE MOL. WEIGHT DENSITY

KG/M3
--------------------- ----------- ----------- ----------- -----------
1 METHANE LIBRARY VAP/LIQ/SOL 16.043 299.704
2 ETHANE LIBRARY VAP/LIQ/SOL 30.070 355.041
3 PROPANE LIBRARY VAP/LIQ/SOL 44.097 505.787
4 IBUTANE LIBRARY VAP/LIQ/SOL 58.123 563.835
5 BUTANE LIBRARY VAP/LIQ/SOL 58.123 584.335
6 IPENTANE LIBRARY VAP/LIQ/SOL 72.150 625.850
7 PENTANE LIBRARY VAP/LIQ/SOL 72.150 631.126
8 HEXANE LIBRARY VAP/LIQ/SOL 86.177 664.452
9 HEPTANE LIBRARY VAP/LIQ/SOL 100.204 689.489
10 OCTANE LIBRARY VAP/LIQ/SOL 114.231 706.614
11 NONANE LIBRARY VAP/LIQ/SOL 128.258 721.347
12 DECANE LIBRARY VAP/LIQ/SOL 142.285 733.517

COMPONENT NBP CRIT. TEMP. CRIT. PRES. CRIT. VOLM.

C C BAR M3/KG-MOL
--------------------- ----------- ----------- ----------- -----------
1 METHANE -161.490 -82.586 45.990 0.0986
2 ETHANE -88.600 32.170 48.720 0.1455
3 PROPANE -42.040 96.680 42.480 0.2000
4 IBUTANE -11.720 134.990 36.480 0.2627
5 BUTANE -0.500 151.970 37.960 0.2550
6 IPENTANE 27.844 187.280 33.810 0.3058
7 PENTANE 36.070 196.550 33.700 0.3130
8 HEXANE 68.730 234.450 30.250 0.3710
9 HEPTANE 98.430 267.050 27.400 0.4280
10 OCTANE 125.680 295.550 24.900 0.4860
11 NONANE 150.820 321.450 22.900 0.5440
12 DECANE 174.155 344.550 21.100 0.6000

COMPONENT ACEN. FACT. HEAT FORM. G FORM.

KCAL/KG-MOL KCAL/KG-MOL
--------------------- ----------- ----------- -----------
1 METHANE 0.01155 -17798.80 -12059.33
2 ETHANE 0.09949 -20020.06 -7623.96
3 PROPANE 0.15229 -25002.39 -5825.45
4 IBUTANE 0.18077 -32048.34 -4958.44
5 BUTANE 0.20016 -30044.43 -3988.73
6 IPENTANE 0.22746 -36710.61 -3355.78
7 PENTANE 0.25151 -35053.02 -2104.95
8 HEXANE 0.30126 -39872.93 -15.85
9 HEPTANE 0.34947 -44819.43 1950.18
10 OCTANE 0.39955 -49859.08 3821.53
11 NONANE 0.44346 -54633.61 5966.37
12 DECANE 0.49233 -59582.50 7924.91
SIMULATION SCIENCES INC. R PAGE P-2
PROJECT PRO/II VERSION 9.3 ELEC V9.1.3
PROBLEM OUTPUT
COMPONENT DATA 11/21/22
==============================================================================

COMPONENT DATABANK(S) USED

--------------------- ---------------------
1 METHANE SIMSCI
2 ETHANE SIMSCI
3 PROPANE SIMSCI
4 IBUTANE SIMSCI
5 BUTANE SIMSCI
6 IPENTANE SIMSCI
7 PENTANE SIMSCI
8 HEXANE SIMSCI
9 HEPTANE SIMSCI
10 OCTANE SIMSCI
11 NONANE SIMSCI
12 DECANE SIMSCI
SIMULATION SCIENCES INC. R PAGE P-3
PROJECT PRO/II
VERSION 9.3 ELEC V9.1.3
PROBLEM OUTPUT
CALCULATION SEQUENCE AND RECYCLES 11/21/22
==============================================================================

CALCULATION SEQUENCE

SEQ UNIT ID UNIT TYPE

--- ------------ ----------
1 SCD1 SHORTCUT

SEQUENCE MAP

SEQ DESCRIPTION
---- -----------------------------------------
1 SHORTCUT 'SCD1'
SIMULATION SCIENCES INC. R PAGE P-4
PROJECT PRO/IIVERSION 9.3 ELEC V9.1.3
PROBLEM OUTPUT
PLANT MATERIAL BALANCE 11/21/22
==============================================================================

FEED STREAMS: S1

PRODUCT STREAMS: S2 S3

OVERALL PLANT MOLAR BALANCE

---------------- KG-MOL/HR ---------------- PERCENT

COMPONENT FEED +REACTION -PRODUCT =DEVIATION DEV
--------------------- ---------- ---------- ---------- ---------- -------
1 METHANE 5.600 0.000 5.600 0.000 0.00
2 ETHANE 10.400 0.000 10.400 0.000 0.00
3 PROPANE 32.000 0.000 32.000 0.000 0.00
4 IBUTANE 50.000 0.000 50.000 0.000 0.00
5 BUTANE 66.000 0.000 66.000 0.000 0.00
6 IPENTANE 80.000 0.000 80.000 0.000 0.00
7 PENTANE 58.000 0.000 58.000 0.000 0.00
8 HEXANE 36.000 0.000 36.000 0.000 0.00
9 HEPTANE 26.000 0.000 26.000 0.000 0.00
10 OCTANE 18.000 0.000 18.000 0.000 0.00
11 NONANE 10.400 0.000 10.400 0.000 0.00
12 DECANE 7.600 0.000 7.600 0.000 0.00

TOTAL 400.000 0.000 400.000 0.000 0.00

OVERALL PLANT MASS BALANCE

------------------ KG/HR ------------------ PERCENT

COMPONENT FEED +REACTION -PRODUCT =DEVIATION DEV
--------------------- ---------- ---------- ---------- ---------- -------
1 METHANE 89.84 0.00 89.84 0.00 0.00
2 ETHANE 312.72 0.00 312.73 0.00 0.00
3 PROPANE 1411.09 0.00 1411.09 -0.01 0.00
4 IBUTANE 2906.17 0.00 2906.18 -0.01 0.00
5 BUTANE 3836.14 0.00 3836.16 -0.02 0.00
6 IPENTANE 5772.02 0.00 5772.01 0.02 0.00
7 PENTANE 4184.72 0.00 4184.70 0.01 0.00
8 HEXANE 3102.38 0.00 3102.37 0.01 0.00
9 HEPTANE 2605.30 0.00 2605.30 0.01 0.00
10 OCTANE 2056.16 0.00 2056.15 0.01 0.00
11 NONANE 1333.88 0.00 1333.88 0.00 0.00
12 DECANE 1081.36 0.00 1081.36 0.00 0.00

TOTAL 28691.79 0.00 28691.76 0.02 0.00

SIMULATION SCIENCES INC. R PAGE P-5
PROJECT PRO/II
VERSION 9.3 ELEC V9.1.3
PROBLEM OUTPUT
SHORTCUT COLUMN SUMMARY 11/21/22
==============================================================================

UNIT 1, 'SCD1'

FEEDS

STREAM PHASE
------------ ------
S1 VAPOR
PRODUCTS

------------- TOTAL STREAM RATES -------------

MOLES WEIGHT LIQUID VOL NORM VAPOR(1) NUM
STREAM + PHASE KG-MOL/HR KG/HR M3/HR M3/HR SECTION TRAYS
------------ - ---------- ---------- ---------- ---------- ------- -----
S2 L 163.50 8539.80 15.65 3664.60 1 15.12
S3 L 236.50 20151.97 30.57 5301.00

TOTALS 400.00 28691.76 46.22 8965.60 15.12

SPECIFICATIONS

PARAMETER COMP. SPECIFICATION SPECIFIED CALCULATED

TYPE NUM TYPE VALUE VALUE
----------------- ------- ------------- ---------- ----------
STRM S2 5 MOL PERCENT 3.950E+01 3.950E+01
STRM S3 5 MOL PERCENT 6.000E-01 5.995E-01

SUMMARY OF UNDERWOOD CALCULATIONS

MINIMUM REFLUX RATIO 2.93495

FEED CONDITION Q -0.09957
FENSKE MINIMUM TRAYS 15.12158

OPERATING REFLUX RATIO 2.00 * R-MINIMUM

TOTAL FEED R/R-MIN M/M-MIN REFLUX DUTY, M*KCAL/HR

TRAYS TRAY RATIO CONDENSER REBOILER
----- ---- ------- ------- ------ ---------- ----------
25 14.19 1.500 1.675 4.402 -4.206E+00 1.173E+00
23 13.12 1.750 1.544 5.136 -4.777E+00 1.744E+00
22 12.38 2.000 1.454 5.870 -5.348E+00 2.315E+00
21 11.85 2.250 1.389 6.604 -5.920E+00 2.887E+00
20 11.44 2.500 1.339 7.337 -6.491E+00 3.458E+00
(1) NORMAL VAPOR VOLUME IS 22.414 M3/KG-MOLE (0 C AND 1 ATM)
SIMULATION SCIENCES INC. R PAGE P-6
PROJECT PRO/II VERSION 9.3 ELEC V9.1.3
PROBLEM OUTPUT
STREAM MOLAR COMPONENT RATES 11/21/22
==============================================================================

STREAM ID S1 S2 S3
NAME
PHASE VAPOR LIQUID LIQUID
THERMO ID GS01 GS01 GS01

FLUID RATES, KG-MOL/HR

1 METHANE 5.6000 5.6000 2.3756E-17
2 ETHANE 10.4000 10.4000 2.1907E-10
3 PROPANE 32.0000 32.0001 2.3029E-05
4 IBUTANE 50.0000 49.9782 0.0220
5 BUTANE 66.0000 64.5825 1.4178
6 IPENTANE 80.0000 0.8752 79.1245
7 PENTANE 58.0000 0.0600 57.9398
8 HEXANE 36.0000 1.2103E-06 35.9999
9 HEPTANE 26.0000 4.1171E-11 25.9999
10 OCTANE 18.0000 1.5838E-15 17.9999
11 NONANE 10.4000 8.0440E-20 10.4000
12 DECANE 7.6000 0.0000 7.6000

TOTAL RATE, KG-MOL/HR 400.0000 163.4961 236.5039

TEMPERATURE, C 195.0000 33.0720 151.5249

PRESSURE, BAR 13.0000 12.0000 12.0000
ENTHALPY, M*KCAL/HR 5.0783 0.1738 1.8713
MOLECULAR WEIGHT 71.7295 52.2324 85.2078
MOLE FRAC VAPOR 1.0000 0.0000 0.0000
MOLE FRAC LIQUID 0.0000 1.0000 1.0000
SIMULATION SCIENCES INC. R PAGE P-7
PROJECT PRO/II VERSION 9.3 ELEC V9.1.3
PROBLEM OUTPUT
STREAM SUMMARY 11/21/22
==============================================================================

STREAM ID S1 S2 S3
NAME
PHASE VAPOR LIQUID LIQUID
THERMO ID GS01 GS01 GS01

----- TOTAL STREAM -----

RATE, KG-MOL/HR 400.000 163.496 236.504
K*KG/HR 28.692 8.540 20.152
STD LIQ RATE, M3/HR 46.224 15.654 30.570
TEMPERATURE, C 195.000 33.072 151.525
PRESSURE, BAR 13.000 12.000 12.000
MOLECULAR WEIGHT 71.729 52.232 85.208
ENTHALPY, M*KCAL/HR 5.078 0.174 1.871
KCAL/KG 176.996 20.355 92.858
MOLE FRACTION LIQUID 0.0000 1.0000 1.0000
REDUCED TEMP (KAYS RULE) 1.0286 0.7779 0.8534
PRES (KAYS RULE) 0.3779 0.3051 0.3872
ACENTRIC FACTOR 0.2412 0.1722 0.2889
WATSON K (UOPK) 13.221 14.074 12.860
STD LIQ DENSITY, KG/M3 620.713 545.525 659.215
SPECIFIC GRAVITY 0.6213 0.5461 0.6599
API GRAVITY 96.239 127.627 82.937

-------- VAPOR ---------

RATE, KG-MOL/HR 400.000 N/A N/A
K*KG/HR 28.692 N/A N/A
ACTUAL K*M3/HR 1.030 N/A N/A
NORM VAP RATE(1), K*M3/HR 8.966 N/A N/A
SPECIFIC GRAVITY (AIR=1.0) 2.477 N/A N/A
MOLECULAR WEIGHT 71.729 N/A N/A
ENTHALPY, KCAL/KG 176.996 N/A N/A
CP, KCAL/KG-C 0.613 N/A N/A
ACTUAL DENSITY, KG/K*M3 27856.095 N/A N/A
Z (FROM ACTUAL DENSITY) 0.8600 N/A N/A
TH COND, KCAL/HR-M-C 0.02961 N/A N/A
VISCOSITY, CP 0.01070 N/A N/A
KVIS (VISC/DENS), CSTOKE 0.3842 N/A N/A

(1) NORMAL VAPOR VOLUME IS 22.414 M3/KG-MOLE (0 C AND 1 ATM)

SIMULATION SCIENCES INC. R PAGE P-8
PROJECT PRO/II VERSION 9.3 ELEC V9.1.3
PROBLEM OUTPUT
STREAM SUMMARY 11/21/22
==============================================================================

STREAM ID S1 S2 S3
NAME
PHASE VAPOR LIQUID LIQUID
THERMO ID GS01 GS01 GS01

-------- LIQUID --------

RATE, KG-MOL/HR N/A 163.496 236.504
K*KG/HR N/A 8.540 20.152
ACTUAL M3/HR N/A 16.353 39.899
ACTUAL GAL/MIN N/A 71.998 175.668
STD LIQ RATE, M3/HR N/A 15.654 30.570
SPECIFIC GRAVITY (H2O=1.0) N/A 0.5461 0.6599
MOLECULAR WEIGHT N/A 52.232 85.208
ENTHALPY, KCAL/KG N/A 20.355 92.858
CP, KCAL/KG-C N/A 0.697 0.717
ACTUAL DENSITY, KG/M3 N/A 522.230 505.079
Z (FROM ACTUAL DENSITY) N/A 0.0471 0.0573
SURFACE TENSION, DYNE/CM N/A 8.3192 4.8502
THERMAL COND, KCAL/HR-M-C N/A 0.08176 0.07478
VISCOSITY, CP N/A 0.11566 0.12135
KVIS (VISC/DENS), CSTOKE N/A 0.2215 0.2403