Rev.1 ATCT Teaching Syllabus-031318

Revision Page no.
no.: FEMFI-A-TD-SY096 Issued Date: 1 of 65
ADVANCED TRAINING FOR CHEMICAL TANKER

CARGO OPERATIONS
(MATP-031) Approved
by: CAS
Far East Maritime PART C: Detailed Teaching Syllabus
Foundation Inc.
TOPICS 1.1 KNOWLEDGE OF CHEMICAL TANKER DESIGN, SYSTEM AND

EQUIPMENT
1.2 KNOWLEDGE OF PUMP THEORY AND CAHARACTERISTICS,
INCLUDING TYPES OF CARGO PUMPS AND THEIR SAFE
OPERATION
1.3 PROFICIENCY IN TANKER SAFETY CULTURE AND
IMPLEMENTATION OF SAFETY MANAGEMENT SYSTEM
1.4 KNOWLEDGE AND UNDERSTANDING OF MONITORING AND
SAFETY SYSTEMS, INCLUDING THE EMERGENCY SHUTDOWN
SYSTEM
1.5 ABILITY TO PERFORM CARGO MEASUREMENTS AND
CALCULATIONS
1.6 KNOWLEDGE OF THE EFFECT OF BULK LIQUID CARGOES ON
TRIM AND STABILITY AND STRUCTUREL INEGRITY
1.7 KNOWLEDGE AND UNDERSTANDING OF CHEMICAL CARGO-
RELATED OPERATIONS
1.8 DEVELOPMENT AND APPLICATION OF CARGO-RELATED
OPERATION PLANS, PROCEDURES AND CHECKLIST
1.9 ABILITY TO CALIBRATE AND USE MONITORING AND GAS-
DETECTION SYSTEMS, INSTRUMENTS AND EQUIPMENT
1.10 ABILITY TO MANAGE AND SUPERVISE PERSONNEL WITH
CARGO-RELATED RESPONSIBILITIES
COMPETENCE 1: ABILITY TO SAFELY PERFORM ABD MONITORS ALL CARGO

OPERATIONS
TRAINING OUTCOMES:
Demonstrates a knowledge and understanding of:
1. Chemical tanker designs, systems and equipment, including:

- general arrangement and construction
- pumping arrangement and equipment
- tank construction and arrangement
- pipeline and drainage systems
- cargo heating system
- tank and cargo pipeline pressure and temperature control systems and alarms
- gauging control systems and alarms
- gas-detecting systems
- cargo heating and cooling systems
- cargo tank environmental control systems
- ballast sytems
- cargo area venting and accommodation ventilation
- vapour return/recovery systems
- fire-fighting systems
- tank, pipiline and fittings’ material and coatings
- slop management
2. Pump theory and characteristics, including types of cargo pumps and their safe operation
3. Tanker safety culture and implementation of safety-management system
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CARGO OPERATIONS
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4. Monitoring and safety systems, including the emergency shutdown

5. Cargo measurement and calculation
6. Effect of bulk liquid cargoes on trim, stability and structural integrity
7.Chemical cargo-related opearations, including:
- loading and unloading plans

- ballasting and deballasting
- tank cleaning operations
- tank atmospher control
- inerting
- gas-freeing
- ship-to-ship transfer
- inhibition and stabilization requirements
- heating and cooling requirements and cosequences to adjacent cargoes
- cargo compatibilty and segregation
- high-viscosity cargoes
- cargo residue operations
- operational tank entry
8. Development and application of cargo-related operation plans, procedures and checklist
9. Calibrate and use monitoring and gas-detection systems, instruments and equipment
10. Manage and supervise personnel with cargo-related responsibilities

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CARGO OPERATIONS
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IMO Textbooks, Teaching

Intended Learning Outcomes Reference Bibliography Aid
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CARGO OPERATIONS
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COMPETENCE 1: Ability to safety perform and

monitor all cargo operations
Design and characteristics of a chemical tanker
1.1 Knowledge of chemical tanker, designs,

systems and equipment, including: R1,R2,R3,R7, T2, R7, R8, R9, A1, A11,
.1 General arrangement and construction R8,R9,R12 B2, B4, B6, B7, A11, A13,
 Identifies with the aid of a sketch the B8, B10, B11 & A14, R12,
general tank arrangements of an B12 V05, VC1,
chemical tanker, including: VC2, VC6,
- Cargo tanks CBT
- Explain that cargo tanks may also be
used for ballast
- Pump-rooms
- Segregated ballast tanks
- Slop tanks States that mixtures of
water and cargo from tank-washing
operations are called “slops”
- Explain that tanks which contain this
sort of mixture are called “slop tanks”
- Explain that slop tanks should be
placed inside the cargo area
- Explain that slops may be stored in
slop tanks or in cargo tanks
- Explain that slops from different
cargoes may be incompatible
- Describes, with the aid of a drawing,
a tank-washing and slop retaining
system
- Cofferdams
- Peak tanks
- Deep tanks
- Venting arrangements
- Explain that the main purpose of the
ventilation line is to lead vapour from
the cargo tank to the cargo
ventilation riser
- Explain that the vapour pressure
may be regulated by a
pressure/vacuum relief valve in the
ventilation line

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CARGO OPERATIONS
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- Explain that the vent outlets are
arranged to prevent the entry of
water into the cargo of the cargo
system, in order to avoid
contamination by cargoes
T2, R7, R8, R9,
.2 Pumping arrangement and equipment
R1,R2,R3,R7, B2, B4, B6, B7,
 Explain that the main cargo pumps fitted
R8,R9,R12 B8, B10, B11 & A1, A11,
on tankers are mainly of the centrifugal
B12 A11, A13,
type
A14, R12,
 Explain that these pumps may be of the
V05, VC1,
deep well type in the cargo tanks or
VC2, VC6,
placed in a pump-room
CBT
 Explain that screw pumps and piston
pumps are used also in some unloading
systems
 Explain that the cargo-pumping systems
on tankers are designed to minimize
cargo residues after unloading
 Explain that alternative unloading may
be done by means of portable cargo
pumps or educators
 Describes generally an unloading
system consisting of submerged cargo
pumps
system consisting of pumps placed in
pump rooms
 Describes generally the safe handling of
a cargo pump
T2, R7, R8, R9,
R1,R2,R3,R7, B2, B4, B6, B7,
3 Tanker construction and arrangement R8,R9,R12 B8, B10, B11 & A1, A11,
 Explain that some chemical tankers
B12 A11, A13,
have small additional cargo tanks
A14, R12,
located on deck
V05, VC1,
 Explain that slop tanks are tanks
VC2, VC6,
designated or used for tank washings
CBT
and cargo residues
 Explain that segregated ballast tanks
are equipped with a pumping system
that is independent
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CARGO OPERATIONS
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 Explain that the cargo tank may be
constructed with mild steel and coated
or stainless steel depending on the
cargo to be carried
R1,R2,R3,R7,
.4 Pipeline and drainage systems R8,R9,R12 T2, R7, R8, R9, A1, A11,
 Describes the piping arrangements of an B2, B4, B6, B7, A11, A13,
oil tanker, including: B8, B10, B11 & A14, R12,
- Internal piping in tanks and pump- B12 V05, VC1,
rooms VC2, VC6,
 Explain that some commonly fixed CBT
piping arrangements in a cargo tank are:
- Unloading line
- Cargo ventilation line
- Drop line
With the help of a diagram point out:
- External piping (deck lines)
- crossovers
- by-passes
- ring-main systems
- direct piping systems
- valves
 Explain that there are several types of

valves used in cargo-handling systems
on tankers
 Explain that tankers may be provided
with cargo hoses
 Explain that the cargo hose constitutes a
weak part of the cargo-handling system
and that incorrect handling of the hose
will increase the danger of fire, health
hazard and pollution
 Describes, with the aid of a simple
drawing, a cargo-loading arrangement
 Describes, with the aid of a drawing, a
simple cargo-unloading arrangement
 Describes correct handling, storage and
inspection of the ship’s cargo hoses
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CARGO OPERATIONS
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.5 Tank and cargo pipeline pressure and R1,R2,R3,R7, T2, R7, R8, R9, A1, A11,
temperature controls systems and R8,R9,R12 B2, B4, B6, B7, A11, A13,
alarms B8, B10, B11 & A14, R12,
B12 V05, VC1,
 Understand the cargo piping diagram VC2, VC6,
and at its parameters. CBT
 Understand the proper procedures of
testing the cargo pipeline, controls and
alarm system prior cargo operation and
as per PMS
T2, R7, R8, R9,
.6 Gauging control system and alarms R1,R2,R3,R7, A1, A11,
B2, B4, B6, B7,
 Describes, with aid of drawing, the R8,R9,R12 A11, A13,
B8, B10, B11 &
operating principle of: B12 A14, R12,
- mechanically operated float gauges V05, VC1,
- electrically powered servo-operated VC2, VC6,
gauges CBT
- pneumatic or hydraulic level gauges
using a closed cell
- other differential-Pressure-type
gauges
- ultrasonic and sonic gauge
- radioactive gauges
- surface-sensing-type-gauges
 Describes the terms 'accuracy' and
'repeatability' and the factors influencing
both
 Explains that high level alarms shall be
independent of the closed level
measuring system.
 Explains that two combined level
measuring and high level alarm systems
may be accepted as equivalent to
independent measuring systems
 Explains that generally extensive self-
monitoring is incorporated in the system
covering all credible faults.
 Explains that the gas detection system
should be fully operational during
voyage, loading, unloading and tank
cleaning operation
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CARGO OPERATIONS
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.7 Gas detecting system R1,R2,R3,R7, T2, R7, R8, R9, A1, A11,
 Describes the instruments necessary R8,R9,R12 B2, B4, B6, B7, A11, A13,
for detecting toxic and flammable B8, B10, B11 & A14, R12,
gases. B12 V05, VC1,
 Explains the differences between fixed VC2, VC6,
and portable vapour-detection CBT
instruments.
R1,R2,R3,R7, A1, A11,
.8 Cargo heating and cooling system R8,R9,R12 T2, R7, R8, R9, A11, A13,
 Explain that some cargoes, having high B2, B4, B6, B7, A14, R12,
melting point, must be heated to prevent B8, B10, B11 & V05, VC1,
them from solidifying B12 VC2, VC6,
 Explains that heating medium may be CBT
steam, water or thermal oils
 describes, with aid of a drawing, a cargo
heating system that uses heating coils
fitted inside the cargo tanks
 describes, with the aid of a drawing, a
cargo heating system that uses a heat
exchanger placed outside the cargo tank
 describes, generally, the IMO
requirements concerning cargo
heating systems R1,R2,R3,R7,
R8,R9,R12 A1, A11,
.9 Tank cleaning system A11, A13,
 Explains that the type of cleaning T2, R7, R8, R9, A14, R12,
system on chemical tankers depends on B2, B4, B6, B7, V05, VC1,
the ship's cargo and its trade B8, B10, B11 & VC2, VC6,
 Explains that a sophisticated cleaning B12 CBT
system normally consists of the
following main components:
- tank cleaning pump
- tank cleaning heat exchanger
- tank-washing machines
- water distribution pipeline
 Explains that the tank cleaning heat
exchanger and the tank cleaning pump
must be of approximately the same
capacity
 Explains that the tank-washing
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machines are either portable or fixed

 describes a tank-washing and slops-
retaining system

 describes, with the aid of drawing, the
construction of a tank-washing machine
.10 Cargo tank environmental control

R1,R2,R3,R7, T2, R7, R8, R9, A1, A11,
system
R8,R9,R12 B2, B4, B6, B7, A11, A13,
 Explains that automatic detection B8, B10, B11 & A14, R12,
systems consist of electrical or B12 V05, VC1,
electronic devices that detect VC2, VC6,
environmental changes created by fire CBT
or by the presence of toxic or
combustible gases
 Explains that heat sensing fire detectors
fall into two general categories, fixed
temperature devices and rate-of-rise
devices.
 Explains that the inert gas system is
provided with a pressure regulating
control system
 Explains that some types of Individual
overfill alarms may be provided with an
electronic self-testing capability which
monitors the condition of the alarm
circuitry and sensor and confirms the
instrument set point.
 Explains that modern developments in
gas detection technology have resulted
in the introduction of electronic
instruments using infra-red sensors that
can perform the same function as the
Tankscope.
 Explains that electrical and electronic
tank level indication is provided in the
cargo control room
 Explains that all instrumentation in
dangerous areas must be intrinsically R1,R2,R3,R7,
safe A1, A11,
R8,R9,R12
A11, A13,
.11 Ballast system T2, R7, R8, R9, A14, R12,
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 Explains that the ship should at all times B2, B4, B6, B7, V05, VC1,
during loading and unloading operations B8, B10, B11 & VC2, VC6,
be stable and in good trim, to allow for B12 CBT
an emergency departure if necessary

 Explains that the stability of most
chemical tankers is good in normal
conditions, due to the large number of
relatively small cargo tanks
 Explains that chemical tankers may
have to undertake ballasting or
deballasting during cargo operations to
obtain adequate trim and prevent undue
list
 Explains that chemical tankers may be
equipped with SBT
 Explains that line, pumps and equipment
serving SBT are independent of similar
equipment serving cargo tanks
 Explains that cargo tanks may be used
for ballast and lists general precautions
that should be taken when ballasting a
cargo tank
 Explains that ballasting or de ballasting
of cargo tanks after they have contained
a NLS should be done in accordance
with the ship's P & A Manual, thereby
ensuring compliance with Annex II of
MARPOL
 Explains that the responsible officer
should see to it that the distribution of
cargo and ballast at no time creates
excessive stress on the ship's hull
 Explains, generally, the effect of free
surface in cargo tanks and ballast tanks
 Explains that ballast operations in
port should be in compliance with
local regulations
12 Cargo area venting and accommodation R1,R2,R3,R7, T2, R7, R8, R9, A1, A11,
ventilation R8,R9,R12 B2, B4, B6, B7, A11, A13,
 Explains that it is required to ensure all B8, B10, B11 & A14, R12,
external doors and ports in the B12 V05, VC1,
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CARGO OPERATIONS
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accommodation are closed when cargo VC2, VC6,

area venting is carried out. CBT

 Explains that if there is a wind, eddies
can be created on the lee side of a
tanker's accommodation or deck
structure which can carry vented gas
towards the structure.
 Explains that a positive pressure must
be maintained inside the
accommodation, and air conditioning
intakes, which may permit the entry of
cargo vapours, must be closed.
 Explains that engine room vents may be
left open. However, consideration
should be given to closing them where
such action would not adversely affect
the safe and efficient operation of the
engine room spaces served.
T2, R7, R8, R9, A1, A11,
.13 Vapour return/ recovery system R1,R2,R3,R7, B2, B4, B6, B7, A11, A13,
R8,R9,R12 B8, B10, B11 & A14, R12,
 Explains that special vapour recovery B12 V05, VC1,
requirement may apply at certain VC2, VC6,
terminals. CBT
 Explains that the use of insulating
flanges or an electrically discontinuous
length of hose also apply to the vapour
recovery systems
 Explains that the terminal's operating
manual should include a full description
of the system and the requirements for
its safe operation.
 Explains that some terminals are
equipped with apour emission control
systems to receive and process vapours
displaced from a ship during loading
operations.
 Explains that ship with reference to the
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CARGO OPERATIONS
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VOC management plan and shore

personnel with reference to terminal's
operating manual should agree to any
constraints associated with the
operation of the vapour emission control
system during pre-transfer discussions.

 Describes Vapour Emission Control
Systems
 Describes Vapour Pressure Release
Control Valve
 Describes the Cargo Pipeline Partial
Pressure control system
 Describes Vapour Recovery Systems
condensation systems
- Absorption Systems
- Absorption Carbon Vacuum-
Regenerated
- Adsorption
.14 Fire-fighting system R1,R2,R3,R7, T2, R7, R8, R9, A1, A11,
 explains the chemistry of fire and the R8,R9,R12 B2, B4, B6, B7, A11, A13,
classes of fire B8, B10, B11 & A14, R12,
 lists the elements necessary for a fire B12 V05, VC1,
and explains the fire triangle VC2, VC6,
 lists possible ignition sources and ways CBT
of excluding them from gas-dangerous
places
 explains that ignition can occur when an
ignition source with a temperature at or
above the auto-ignition temperature of a
cargo is introduced into the vapour
phase of a flammable cargo
 lists sources of emission of flammable
cargo vapour as leaks from pumps,
flanges, hoses, relief valves etc.
 explains that most ignition sources on
board have a higher temperature than
the auto-ignition temperature for most
chemical cargoes
 explains temperatures of common
ignition sources as:
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- the flame of a match = 1100°C

- electrical sparks = 1100°C
- the light of a cigarette = 300-800°C
 explains that the auto-ignition
temperature of chemical cargoes may
be as low as 30°C (for phosphorous)
lists principles of controlling fire, in
general, as:
- removal of oxygen
- cutting off the supply of fuel
- removing the sources of heat by
cooling
- inhibiting the burning process
 explains that some liquid chemicals R1,R2,R3,R7, T2, R7, R8, R9, A1, A11,
have unusual properties with regard to R8,R9,R12 B2, B4, B6, B7, A11, A13,
fire and firefighting compared with B8, B10, B11 & A14, R12,
hydrocarbons B12 V05, VC1,
 lists the properties referred to under VC2, VC6,
objective CBT
 explains that chemical tankers are fitted
with a fixed foam system for firefighting
that is capable of delivering foam to the
entire cargo area i.e. to the deck area as
well as to any cargo tank
 explains that chemical tankers are fitted
with a fixed fire- extinguishing system in
cargo pump rooms
 explains that extinguishing agents for
systems referred to under objective
7.2.13 are normally a halon or carbon
dioxide, but water or high-expansion
foam may be used in certain vessels
 explains that the fire-extinguishing
media that are considered to be suitable
for specific cargoes are listed in Chapter
17 of IBC Code
 describes water as a firefighting agent in
terms of:
- it is easily available
- it is an excellent cooling agent
- it may be used in a fog/spray form to
create a protection screen for
firefighters when they are
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CARGO OPERATIONS
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approaching a fire
 describes foam as a firefighting agent in
terms of:
- it should be a type suitable for
fighting fires in chemicals
- it has a good smothering effect on
flames

- it is less effective against fires in
chemicals that have a low flashpoint
- it has limited heat absorbing effect
- it should not come in contact with
live electrical equipment
 describes dry chemical powder as a
firefighting agent in terms of: R1,R2,R3,R7, T2, R7, R8, R9, A1, A11,
- it has a good smothering effect R8,R9,R12 B2, B4, B6, B7, A11, A13,
- it has an inhibiting effect B8, B10, B11 & A14, R12,
- it can be used in electrical plants B12 V05, VC1,
- it is not toxic VC2, VC6,
- it has a low cooling effect CBT
- it should not be used on electronic
instruments, control panels etc.
 describes carbon dioxide as a
firefighting agent in terms of:
- it is an excellent smothering
agent
- it can be used on fires in
electrical equipment and
instruments
- it should not be injected into
explosive atmosphere as it may
generate static electricity
- personnel must have left the
space into which carbon dioxide
is to be injected
 lists the items of equipment of a
fireman's outfit
 explains that prior to commencing cargo
operations the ship's firefighting
equipment should be made ready and
the international shore connection
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CARGO OPERATIONS
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should be at hand
 explains the importance of fire
prevention procedures, and lists
precautions with regard to:
- smoking
- electrical equipment
- tools
- flame screens
- bonding
- static electricity

- electrical storms
- auto ignition
- spontaneous combustion
.15 Tank, pipeline fittings material and R1,R2,R3,R7, T2, R7, R8, R9, A1, A11,
coatings R8,R9,R12 B2, B4, B6, B7, A11, A13,
 Explains that tank coatings usually B8, B10, B11 & A14, R12,
inhibit the formation of pyrophores in the B12 V05, VC1,
cargo tanks of tankers. VC2, VC6,
 Explains that if cargo is heated to a high CBT
temperature it can damage tank
coatings and tank structure.
- Explains different properties associated
with Zinc
- Silicate, Epoxy and Polymer coatings
- Explains that tank coating
compatibility/resistance tables
provided on ships with coated tanks
must be referred to before handling
product cargo
 Explain the use of "Coating resistance
List"
 Explain about coating resistance to
different oil cargoes types
 Explain coating type effects on tank
cleaning Operations
A1, A11,
.16 Slop management R1,R2,R3,R7, T2, R7, R8, R9, A11, A13,
 Explains that slops area mixture of R8,R9,R12 B2, B4, B6, B7, A14, R12,
cargo residues and washing water, rust B8, B10, B11 & V05, VC1,
or sludge which is either suitable or not B12 VC2, VC6,
CBT
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CARGO OPERATIONS
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suitable for pumping.

 Explains that effective oil/water interface
detectors approved by the
Administration shall be provided for a
rapid and accurate Determination of the
oil/water interface in slop tanks
 Explains that the arrangements of the
slop tank or combination of slop tanks
shall have a capacity necessary to retain
the slop generated by tank washings, oil
residues and dirty ballast residues.

 Explains that the total capacity of the
slop tank or tanks shall not be less than
3 per cent of the oil carrying capacity of
the ship, except that the Administration
may accept:
- A 2 percent of the oil carrying
capacity for such oil tankers where
the tank washing arrangement are
such that once the slop tank or tanks
are charged with washing water, this
water is sufficient for tank washing
and, where applicable,for providing
the driving fluid for eductors, without
the introduction of additional water
into the system;
- A 2 percent of the oil carrying
capacity where segregated ballast
tanks or dedicated clean ballast
tanks are provided or where a cargo
tank cleaning system using crude oil
washing is fitted. This capacity may
be further reduced to percent for
such oil tankers where the tank
washing arrangements are such that
once the slop tank or tanks are
charged with washing water, this
water is sufficient for tank washing
and, where applicable, for providing
the driving fluid for eductors, without
the introduction of additional water
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CARGO OPERATIONS
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into the system;
1.2 Knowledge of Pump theory and R2 B2, B7 A1, A11,

characteristics, including types of cargo A12, A13
pumps and their safe operation
 Explains that the main cargo pumps
fitted on tankers are mainly of the
centrifugal type
 Explains that these pumps may be of
the deep well type in the cargo tanks or
placed in a pump-room

 Explains that screw pumps and piston
pumps are used also in some unloading
systems
 Explains that the cargo-pumping
systems on tankers are designed to
minimize cargo residues after unloading
 Explains that alternative unloading may
be done by means of portable cargo
pumps or educators
system consisting of submerged cargo
pumps
system consisting of pumps placed in
pump rooms
 Describes generally the safe handling of
a cargo pump
1.3 Proficiency in tanker safety culture and R1, R2, T1, B1, B2, B3, A1, A11,
implementation of safety management R6, R7 B5, B6, B7 A13, A14
system including emergency shutdown VC2, VC8
Explains that the monitoring of
atmosphere in gas dangerous and gas
safe zones must be carried out regularly
 Explains that safety system of a tanker
must be checked and calibrated as per
safety management systems
requirements.
 Explains that the pressure in any tank
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segregated from the main venting

system should be carefully monitored to
ensure that individual tank venting
arrangements are adequate to prevent
formation of vacuum or a build-up of
pressure.
 Explains that ships will require the
means to enable closed monitoring
of tank contents, either by a fixed
gauging system or by using portable
equipment passed through a vapour
lock.

 Explains that exposure levels in all work R1, R2, T1, B1, B2, B3, A1, A11,
locations should be monitored by using R6, R7 B5, B6, B7 A13, A14
suitable instrumentation for detecting VC2, VC8
and measuring the concentration of the
gas.
 Explains that H2S over time may have a
damaging effect on electronic
instruments. Detector tubes should
therefore be used if it becomes
necessary to monitor a known high
concentration.
 Explains that Bridge, control room,
accommodation and engine spaces
should be monitored regularly, if H2S
may be present. Ventilation systems
should be operated as far as possible to
prevent H2S vapours entering the
accommodation and engine spaces.
Explains that personnel should always
carry personal monitors when working in
enclosed spaces, gauging, sampling,
entering a pump-room, connecting and
disconnecting loading lines, cleaning
filters, draining to open containments
and mopping up spills as H2S
concentrations may exceed the TLV-
TWA.
 Explains that measurement of
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CARGO OPERATIONS
(MATP-031) Approved
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Foundation Inc.
hydrocarbon gas in air must be checked

to ensure concentrations are below 1%
LFL. (Lower Flammable Limit)
 Explains s that the measurement of
hydrocarbon gas must be taken as a
percentage by volume of the total
atmosphere being measured.
 Explains that modern flammable gas
monitors (Explosimeters) have a
pellistor as the sensing element.
Pellistors rely on the presence of oxygen
(minimum 11% by volume) to operate
efficiently and for this reason flammable
gas monitors should not be used for
measuring hydrocarbon gas in inert
atmospheres.
 Describes and explains Fixed Gas R1, R2, T1, B1, B2, B3, A1, A11,
Detection Installations R6, R7 B5, B6, B7 A13, A14
 Performs measurement of oxygen VC2, VC8
concentrations
 Explains calibration and test procedures
of gas measuring instruments
 Explains that multi gas instruments are
commonly used nowadays
 Explains that the multi-gas instruments
may be supplied as compact units fitted
with an alarm function for personal
protective use during tank entry.
 Explains that the personal multi gas
detectors are capable of continuously
measuring the content of the
atmosphere by diffusion. They usually
employ up to four electrochemical
sensors and should automatically
provide an audible and visual alarm
when the atmosphere becomes unsafe,
thereby giving the wearer adequate
warning of unsafe conditions.
 Explains that disposable personal gas
monitors are also us
 Explains that cargo tank oxygen levels
should be monitored so that any
necessary precautionary measures can
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CARGO OPERATIONS
(MATP-031) Approved
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be taken prior to the commencement of

discharge.
 Explains that throughout the discharge
of cargo, particularly when the boiler
load is low or fluctuating, the oxygen
content of the inert gas supply must be
carefully monitored.
 Explains that individual Tank Pressure
Monitoring and Alarm Systems must be
checked regularly.
 Explains that residual water in the inert
gas may freeze in the inert gas main.
Operators should be aware of this and
should therefore operate the system to
minimize residual water and closely
monitor the system's operation.

 Explains that a close monitoring of R1, R2, T1, B1, B2, B3, A1, A11,
vapour line pressures on inerted ships R6, R7 B5, B6, B7 A13, A14
and limiting loading rates on non-inerted VC2, VC8
ships throughout the loading period or
during crude oil washing during
discharge operations is to be carried
out.
 Explains that void and ballast spaces
located within the cargo tank block
should be routinely monitored to check
that no leakage has occurred from
adjacent tanks. Monitoring should
include regular atmosphere checks for
hydrocarbon content and regular
sounding/ullaging of the empty spaces
 Explains that the external atmosphere
should be monitored for hydrocarbon
and toxic vapours prior doing any hot
work
 Explains that enclosed spaces must be
monitored prior tank entry for 21%
oxygen, (no toxic vapours) not more
than 50 % of the occupational exposure
limit (OEL) of any toxic vapours and
gasses and a reading of less than 1%
LFL must be obtained on suitable
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CARGO OPERATIONS
(MATP-031) Approved
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monitoring equipment
 Explains that the accuracy of
measurement equipment should be in
accordance with the manufacturer's
stated standards. Equipment should, on
initial supply, have a calibration
certificate, traceable where possible to
internationally recognized standards.
 Explains that SOLAS requires that ships
built from July 2002 be provided with
continuous monitoring of the pump-room
atmosphere and an audible and visual
alarm system which will activate when
the hydrocarbon gas concentration in
the pump-room exceeds a pre-set level,
which should not be more than 10%
LFL.

 Explains that throughout loading, the R1, R2, T1, B1, B2, B3, A1, A11,
ship should monitor and regularly check R6, R7 B5, B6, B7 A13, A14
all full and empty tanks to confirm that VC2, VC8
cargo is only entering the designated
cargo tanks and that there is no escape
of cargo into pump rooms or cofferdams,
or through sea and over board
discharge valves.
 Explains that monitoring inert gas main
pressure where this gives an indication
of the cargo tank pressure
corresponding to the maximum
permissible pressure should be used
and the loading rate adjusted
accordingly.
Explains that tank pressures and
pressures within vapour collection piping
systems should be continuously
monitored by sensors that incorporate
high and low pressure alarm
functionsconnected to audible and visual
alarms.
 Explains that atmosphere testing in non
inerted vessels should be frequent and
taken at various levels inside the tank
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CARGO OPERATIONS
(MATP-031) Approved
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during washing to monitor the change in

LFL percentage
 Explains that if the hot wash water
temperature is above 60ºc, monitoring of
the gas concentration level should be at
an increased frequency
 Explains that atmosphere testing should
be undertaken regularly during the gas
freeing operation to monitor progress.
 Explains that the use of an oil discharge
monitoring equipment for monitoring the
discharge of clean ballast will give an
early warning of any undiscovered
contaminated ballast caused by, for
example, inter-tank leakage when
loading and deballasting are being
carried out simultaneously.

 Explains that the emergency shutdown R1, R2, T1, B1, B2, B3, A1, A11,
of cargo pumps, alarms and trips, level R6, R7 B5, B6, B7 A13, A14
alarms, etc., where fitted, should be VC2, VC8
tested regularly to ensure that they are
functioning correctly
Loading, unloading, care and handling of cargo
1.5 Ability to perform cargo measurements R2, R6 B1, B2 A1, A11,

and calculations A12, A13
 Explains 98% filling limit of cargo tanks
as required by the IBC Code.
 Performs cargo calculations given:
- temperature;
- trim and list;
- soundings or ullage measurements
using the vessel's ullage tables; and
- specific gravity, density in vacuum,
density in air, or API gravity.
 Determines the volume in:
- Cubic meters [m3]
 Determines the weight in:
- Metric tonne [t]
 Performs cargo calculations and
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CARGO OPERATIONS
(MATP-031) Approved
by: CAS
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determines the mass of full cargo to be

loaded, given:
- deadweight scales;
- loading and discharge port
limitations;
- length of voyage;
- ballast; and
- fuel, stores and consumption for
multiple load and discharge ports.
 Determines cargo quantities for petro
chemicals using ASTM Tables T1, B1, B2 A1, A11,
R1, R2, R6 A12, A13
1.6 Knowledge of the effect of bulk liquid
cargoes on trim and stability and
structural integrity.
 Performs stability calculations.

 Explains the use of approved manuals
for trim and stability, and the
requirements to maintain a sea-going
condition throughout loading and
unloading operations with respect to
structural integrity.
 Explains that it is required to comply
with the approved stability booklet for
the ship and endeavour to have
minimum slack tanks to prevent sloshing
damages.
1.7 Knowledge and understanding of

chemical cargo-related operations,
including: A1, A11,
.1 Loading and unloading plans R1, R2 T1, B1, B2, B3, A12, A13
 Explains that plan should cover all R4, R6 B5, B6, B7
stages of cargo operation
 Explains that the plan must contain a
detailed sequence of cargo and
ballast transfer
 Explains that an emergency
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CARGO OPERATIONS
(MATP-031) Approved
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shutdown procedure must be agreed

upon between ship and terminal
 Explains that loading should
commence initially by gravity or at
very slow rate
 Explains that the manifold area must
always be manned
 Explains the checks to be carried out
after shore pumps have been started
 Explains that when unloading is
about to begin, the shore valves to
receiving tanks must be opened
before the tanker's manifold valves
are opened
 Explains that special measures are
necessary when pressure might exist
in the shore line and no check valves
are fitted
 Explains the danger of line blowing
and the precautions to be taken

.2 Ballasting and deballasting R1, R2 T1, B1, B2, B3, A1, A11,
 Explains that ballast quantity is at the R4, R6 B5, B6, B7 A12, A13
discretion of the master
 Describes and Explains
considerations affecting ballast
quantity and the tanks to be used
 Explains that due account should be
taken of stresses while ballasting or
de-ballasting is in progress
 Lists and Explains additional

considerations influencing ballast
quantity as:
a. lightening operations,
b. air draft constraints,
c. berth constraints and
d. draught requirements for
fairway/channels
 Explains that ballasting and de-
ballasting often take place in stages,
such as:
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CARGO OPERATIONS
(MATP-031) Approved
by: CAS
Foundation Inc.
a. At the discharge terminal

b. During sea passage
c. When heavy weather is
expected
d. Prior to arrival in loading port
e. At the loading terminal
 Explains that ballasting operations
whilst alongside should be discussed
with the terminal prior to
commencement
 Explains that, in earlier times, ballast
was always taken into cargo tanks
 Explains that, at a later period,
tankers were provided with
segregated ballast capacity for
coming alongside and leaving the
jetty
 Explains that, on oil tanker provided
with SBT or operating with CBT, there
may be reasons for taking additional
ballast in cargo tanks

 Explains CBT operations during a R1, R2 T1, B1, B2, B3, A1, A11,
normal tanker voyage. R4, R6 B5, B6, B7 A12, A13
 Explains that CBT operations
appropriate to a ship are contained in
an approved dedicated clean ballast
tank operation manual
 Explains that, if no SBT or CBT
capacity has been provided, or if
additional ballast is required , ballast
must be taken into dirty cargo tanks
 Explains that on crude tankers, if
ballast is to be taken into a cargo
tank, it must be crude oil washed
 Explains that this will constitute dirty
ballast
 Explains that the discharge of dirty
ballast is subject to discharge
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CARGO OPERATIONS
(MATP-031) Approved
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provisions of MARPOL Annex I.

 Explains the discharge provisions for
oil and oily mixtures from the cargo-
tank area of all oil tankers should be
in accordance with MARPOL Annex I
 Explains that the discharge provisions
do not apply to clean ballast or to
segregated ballast
 Explains that "Clean Ballast" as the
ballast in a tank which since oil was
last carried therein, has been so
cleaned that effluent if discharged
from a ship which is stationary into
clean calm water on a clear day
would not produce visible traces of oil
on the surface of the water.
 Describes and Explains the change of
ballast at sea in compliance with the
discharge requirements
 Explains that the ballast change is
necessary to arrive in the loading port
with clean ballast discharge
provisions apply in certain sea areas,
called special areas

 Explains that more stringent Lists and
Explains the special areas under
Annex I of MARPOL as amended as:
a. Antarctic area
b. Baltic sea area
c. Mediterranean sea
d. Black sea
e. Gulf area
f. Gulf of Aden area
g. Red sea
North - west European waters
h. Southern South Africa Waters
 Explains that more areas can be
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CARGO OPERATIONS
(MATP-031) Approved
by: CAS
Foundation Inc.
declared as special areas in the future

 Explains that only clean and segregated
ballast may be discharged within special
areas
.3 Tank cleaning operations R1, R2 T1, B1, B2, B3, A1, A11,
 Lists and Explains the reason for tank R4, R6 B5, B6, B7 A12, A13
washing as:
a. cleaning cargo tanks for the
next cargo,
b. cleaning cargo tanks for clean
ballast,
c. sludge control,
d. tank entry for repairs, or -dry-
docking
 Describes and Explains tank cleaning
with:
- Cold water
- Hot water
- Chemicals
 Explains that tank cleaning produces
large quantities of oil-contaminated
water
 Explains s that the volume of oily water
may be reduced if tanks have first been
crude oil washed
 Describes and Explains tank washing
with portable and fixed machines
 Describes and Explains movements of
single- and multiple-nozzle machines

 Explains that tank washing stirs up oily
residues within a tank, thereby
generating hydrocarbon gas
 Explains that tank washing also causes
electrostatic hazards as a result of water
mist, water slugs and introduction into
the tanks of portable tank-washing
machines
 Explains that, the tank atmosphere
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CARGO OPERATIONS
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Foundation Inc.
should be made safe against

explosions.
 Explains that this could be done by
washing tanks in an inerted or non-
inerted atmosphere
 Explains that washing in an inerted
condition is the safest method
 Explains that an inert atmosphere is a
regulatory requirement if using high-
capacity washing machines, crude oil
washing, or washing in the re-circulation
mode
 Explains that tank washing water should
be transferred to the slop-tank
 Describes and Explains tank washing
with the open - cycle and closed- cycle
(re-circulation) modes
 Lists and Explains the precautions to be
taken when tanks must be washed in
non inerted atmosphere
.4 Tank atmosphere control R1, R2 T1, B1, B2, B3, A1, A11,
 Understand the equipment on how to R4, R6 B5, B6, B7 A12, A13
determine the tank atmosphere during
cargo operations and ballast conditions
.5 Inerting R1, R2 T1, B1, B2, B3, A1, A11,

 Explains that hydrocarbon gas remains R4, R6 B5, B6, B7 A12, A13
inside a tank after cargo discharge
 Explains that such vapours may be
mixed with inert gas in IGS-fitted ships
or with air in ships not fitted with an IGS

Revision Page no.

CARGO OPERATIONS
(MATP-031) Approved
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Foundation Inc.
 Explains that the atmosphere in an

inerted tank is not explosive
 Explains why atmosphere should
never be allowed to come within the
flammable range whengas-freeing an
inerted tank
 Explains that "purging" means
replacement of hydrocarbon vapours
with inert gas
Explains, with the aid of a flammability
diagram, how purging will prevent a
flammable atmosphere developing
within a tank and prevent primary and
secondary explosions
.6 Gas freeing R1, R2 T1, B1, B2, B3, A1, A11,

 Explains how gas-freeing a non-inerted R4, R6 B5, B6, B7 A12, A13
tank will result in the tank atmosphere
being in the explosive range for some
time
 Explains that gas-freeing is done by
portable fans or fixed ventilating
systems
 Explains that the IGS is used for purging
and the blowers may also be used for
gas-freeing
 Explains that gas-freeing may take place
through displacement or dilution.
 Describes and Explains both
displacement and dilution methods in
general terms
 Explains that gas-freeing means
replacement of hydrocarbon vapour
below LFL with inert gas by air
.7 Ship-to-ship transfers R1, R2 B3 A1, A11,

 Explains that STS operation can be R4, R6 A12, A13
performed under the STS Plan while
ships are at anchor or underway.
 Explains that checklists as per STS
transfer guide must be complied with
 Explains that proper STS equipment to
be present on both the vessels and they
should be in good condition.
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CARGO OPERATIONS
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Foundation Inc.

 Explains that proper attention to be paid
to the difference in freeboard and listing
of both the vessel while transferring oil.
 Explains that a proper communication
channel to be established between the
ships.
 Explains that firefighting and oil spill
equipment to be present and crew to be
well trained to use them in emergency.
 Explains that all guidelines to be
followed as per MEPC 59, MARPOL
Annex 1 chapter 8, SOPEP, SMPEP,
STS transfer guide and operational plan.
 Explains that the guidelines of the STS
plan should be in accordance with the
requirements of IMO "Manual on oil
pollution prevention, amended section
1", ICS and OCIMF "ship to ship transfer
guide
 Explains that Any oil tanker operate in
the territorial waters or exclusive
economic zone of a party to MARPOL,
must notify the required information to
relevant coastal authority prior to 48
hours of the commencement of the STS
operation
 Explains that the STS plan may be
incorporated in the SMS as required by
the Chapter IX of SOLAS 74 as
amended and has to approved by the
administration
A1, A11,
.8 Inhibition and stabilization requirements R1, R2 T1, B1, B2, B3, A12, A13
R4, R6 B5, B6, B7
 Understand the Inhibition and
stabilization requirements during cargo
operation and ballast conditions.
.9 Heating and cooling requirements and A1, A11,

consequences to adjacent cargoes R1, R2 T1, B1, B2, B3, A12, A13
 Explains that some cargoes have to be R4, R6 B5, B6, B7
heated by the ship’s cargo heating
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CARGO OPERATIONS
(MATP-031) Approved
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Foundation Inc.
system

 Explains that the main reason for
heating a cargo is to:
- prevent it from solidifying
- keep the viscosity below a certain
level during unloading
 Explains that the heating medium
maybe water, steam, or thermal oils
 States that means are provided to
ensure that cargo does not enter boilers
or the engine-room through leakages in
cargo heating coils
 Describes, with the aid of a drawing, a
cargo heating system:
- using heating coils fitted inside the
cargo tank
- using a heat exchanger placed
outside the cargo tank
.10 Cargo compatibility and segregation R1, R2 T1, B1, B2, B3, T1, B1, B2,
 Explains that a cargo may contaminate R4, R6 B5, B6, B7 B3, B5, B6,
another cargo or odorize another cargo B7
when incompatible cargoes come in
contact with each other.
 Explains that between some chemicals
violent reactions may occur if the
chemicals are mixed in certain
proportions. The result may possibly be
an eruption and tank rupture
 Explains that such an occurrence must
be prevented
 Explains that water may also have to be
considered in this respect
 Explains that Leakages through
bulkheads occur at times in any tanker
 Explains that legislation as expressed in
the IMO Chemicals Bulk Code and ICS
tanker safety guide expressly prohibits
the placement of inter-reactive cargoes
on both sides of a bulkhead
Revision Page no.

CARGO OPERATIONS
(MATP-031) Approved
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 Explains that there must be an empty

tank, a cofferdam or a tank with a cargo
neutral to both products in between.
"Diagonal contact'' between tanks is
normally considered as sufficient

separation between reactive cargoes
 Explains that complete separation of
piping systems are required on a
chemical tanker so that one product
cannot inadvertently be pumped into
another. States that to this effect
strategic pipe bends may have to be
removed and blind flanges fitted on each
pipe end.
 Explains that particular caution must be
exercised to ensure that incompatible
cargoes are not mixed by way of
common venting systems and how such
mixing is prevented
.11 High viscosity cargoes R1, R2 T1, B1, B2, B3, T1, B1, B2,
R4, R6 B5, B6, B7 B3, B5, B6,
 Determine the different cargoes with B7
high viscosity as per IMDG Code
.12 Cargo residue operation R1, R2 T1, B1, B2, B3, T1, B1, B2,
R4, R6 B5, B6, B7 B3, B5, B6,
 Determine the proper procedures of B7
handling and disposal of cargo residue
as per international regulations.
.13 Operational tank entry R1, R2 T1, B1, B2, B3, T1, B1, B2,
 Lists circumstances when the R4, R6 B5, B6, B7 B3, B5, B6,
atmosphere in cargo tanks and enclosed B7
spaces must be tested as:
- Prior tank washing
- Prior to entry by personnel
- To establish that there is a gas-free
condition prior to repair work, entry
to a shipyard or dry-docking
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CARGO OPERATIONS
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- During inerting, gas-freeing and

purging operations
- As a quality control before
loading/changing Cargo
 Explains that an evaluation is the only
way to get correct information about the
composition of the tank atmosphere

 Lists the information essential to R1, R2 T1, B1, B2, B3, T1, B1, B2,
evaluation of the tank atmosphere as: R4, R6 B5, B6, B7 B3, B5, B6,
- the nature of the constituent gases B7
- flammability
- toxicity/oxygen deficiency
- reactivity
 Explains that the atmosphere in tanks or
enclosed spaces must be considered
dangerous unless proper and
continuous checks prove otherwise
 Explains that for the control of the tank
atmosphere, in addition to the oxygen
analyzer, explosimeter and tank scope
instruments, there is a requirement for
an additional portable instrument, (gas
detecting tubes) for measuring toxic gas
vapour concentrations.
 Explains that Suitable equipment is to
be provided for calibrating permanently
installed and portable gas measuring
appliances
 Explains the importance of taking
measurements of the atmosphere at
several positions within a tank
 Explains that before entry in enclosed
spaces:
- oxygen content must be 21% by
volume
- hydrocarbon content must be less
than 1% LFL
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CARGO OPERATIONS
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- toxic gas concentration must be less

than 50% of its OEL (R14)
 Explains that after tank washing, manual
removal of residue may be necessary.
- That residue removal may generate
more hydrocarbon gas.
- That gas-testing operations must
therefore be continuous
 Explains that adjacent bulkheads,
pipelines and leaking heating coils may
constitute additional sources of
hydrocarbon gas

 Explains that venting / inert gas supply
to the tank should be shut off during the
testing
 Explains that Carbon monoxide in the
inert gas can be a potential hazard as
during gas freeing operation carbon
monoxide may not be easily displaced
from the tank
1.8 Development and application of cargo R1, R2, R3, B1, B2, B3, A1, A11,
related operations plans, procedures R4, R6, R8 A12, A13,
and checklists A14,VC4
 Explains which information is
exchanged between the tanker andthe
terminal for cargo operations.
 Describes the operational agreement
which should be made in writing before
loading or unloading.
 Describes pre-transfer tank inspection
procedures.
 Describes procedures for cargo
sampling, safety precautions when
sampling and safe storage of cargo
samples.
 Lists main points in cargo planning
such as cargo requirements, cargo
compatibility, resistance list of tank
material/coating, tank cleanliness, tank
capacity and port rotation.
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CARGO OPERATIONS
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 Explains that ship/shore safety

checklist should be completed jointly by
ship and shore staff.
 Describes the checklist and explains
the reason for and relevance of the
checklist items.
 Explains the names of some common
chemicals carried on chemical tankers,
identifies the minimum requirements for
carriage set out in chapter 17 of the
IBC Code and current IMO
MEPC.2/Circular.

 Identifies the physical and chemical
properties of the cargoes by using
Cargo Data Sheets.
 Identifies with the aid of cargo
compatibility chart, whether or not a
cargo can be loaded adjacent to
another cargo.
 Determines compatibility of cargoes
with tank coating.
 Explains the requirements for tank
cleanliness prior to loading cargo.
 Lists the reference publications that
provide useful information for planning
cargo operations.
1.9 Ability to calibrate and use monitoring R1, R2, T1, B1, B2, B4, A1, A4, A5,
and gas-detection systems, R6, R8 B6, B7 A6, A7, A8,
instruments and equipment A9, A11,
 Demonstrates correct instrument- A12, A13,
check, calibration procedures and gas A14, VC1
measurements
1.10 Ability to manage and supervise R1, R2, T1, B1, B2, B3, A1, A11,
personnel with cargo related R6, R8 B5, B6, B7 A13, A14
responsibilities VC5
 Explains why the responsible officer
on watch supervises and directs the
cargo operations ensuring that the
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CARGO OPERATIONS
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stresses and stability of the ship are

always within limits, and that sufficient
qualified personnel are on duty.
 Explains how the responsible officer
ensures and maintains:
- Suitability of ship's cargo
containment prior loading;
- Cargo is loaded as per stowage
plan;
- Cargo is cared for during transit
with respect to monitoring its
parameters, ventilation, cooling,
heating etc. as required;
- Cargo is unloaded safely as per
plan. Issuing relevant
standing/night orders;
- Records for cargo and ballast R1, R2, T1, B1, B2, B3, A1, A11,
operations are maintained as per R6, R8 B5, B6, B7 A13, A14
regulations, industry standards and VC5
company's SMS procedures; and
- Ship's working language is
employed.
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CARGO OPERATIONS
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TOPICS 2.1 KNOWLEDGE AND UNDERSTANDING OF THE CHEMICAL AND

PHYSICAL PROPERTIES OF NOXIOUS LIQUID SUBTANCES
2.2 KNOWLEDGE OF PUMP THEORY AND CHARACTERISTICS,
INCLUDING TYPES OF CARGO PUMPS AND THEIR SAFE OPERATION
COMPETENCE 2: FAMILIARITY WITH PHYSICAL AND CHEMICAL PRPERTIES OF

CHEMICAL CARGOES
TRAINING OUTCOMES:
1. Chemical and physical properties of noxious liquid substances, including:

- chemical cargoes categories (corrosive, toxic, flammable, explosive)
- chemical groups and industrial usage
- reactivity of cargoes
2. Information contained in a Material Safety Data Sheet (MSDS)
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CARGO OPERATIONS
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COMPETENCE 2:Familiarity with the physical
and chemical properties of chemical cargoes
2.1 Knowledge and understanding of the R1, R2, R3, T2, B2, B4, B6, A1, A11,
chemical and the physical properties R7, R8, R9 & B7, B8, B10, B11 A11, A13,
of noxious liquid substances, R12 & B12 A14, V05,
including: VC1, VC2,
.1 Chemical cargoes categories VC6, CBT
(corrosive, toxic, flammable
explosive)
 Explain the physical properties of
Chemical cargoes
1. Specific Gravity (Density)
2. Flash Point
3. Auto Ignition Temperature
4. Flammable / Explosive Limits
5. Vapour pressure/Boiling point
6. True vapour pressure (TVP)
7. Freezing point/Melting Point
8. Solidifying/non-solidifying
9. Pour Point
10. Viscosity
11. Electrostatic charging
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CARGO OPERATIONS
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12. Cubic expansion

13. Vapour density
14. Solubility
15. Colour
 Defines a four-category categorization
system for noxious and liquid
substances.
1. Category X
2. Category Y
3. Category Z
4. Other Substances
.2Chemical group and industrial usage

 Explains the Periodic System and The
Periodic Table
 Identifies, from molecular drawings or
models, some common chemicals by
name
 Explains the meaning of the chemical
data for a common cargo, as given in
the ICS Cargo Data Sheets
 Explain that cargoes in chemical
tankers may be divided into four
groups:
1. Organic and Inorganic Chemicals
2. Petrochemicals
3. Alcohols and Molasses
4. Vegetable and animal oils & fats
5. Cargo information and basic usage
of chemicals based on MSDS R1, R2, R3, T2, B2, B4, B6, A1, A11,
R7, R8, R9 & B7, B8, B10, B11 A11, A13,
.3 Reactivity of cargo R12 & B12 A14, V05,
 Explain cargo compatibility and VC1, VC2,
reactivity for ships carrying dangerous VC6, CBT
chemicals in bulk
1. Cargo Interactions such as:
a. Chemical Reaction
b. Oxidation
c. Auto Reaction
2. Toxic vs Edible Products
3. Chemical Cargo Segregation
a. Why segregation?
b. Compatibility with Water /
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CARGO OPERATIONS
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Stowage of Heated Cargoes

c. Compatibility with the Coatings
of the Cargo Tanks R2, R3, R6, T1, B1, B5, B6 A1, A11,
d. Edible Oils Compatibility R7, R8 A13
2.2Material Safety Data Sheet

 Explain and show MSDS for Chemical
tankers and its requirements
 Explains the contents of MSDS
1. Sections 1 to 16
 Regulatory Environment
1. SOLAS Convention
2. IBC Code
3. IMO and UN Guidance
4. Transport in Bulk according to
Annex 1 of MARPOL 73/78
5. IMDG Code
6. EU Regulation
7. US Legislation
TOPICS 3.1 KNOWLEDGE AND UNDERSTANDING OF THE HAZARDS AND

CONTROL MEASURES ASSOCIATED WITH CHEMICAL TANKER
CARGO OPERATIONS
3.2 KNOWLEDGE AND UNDERSTANDING OF DANGERS OF NON-
COMPLIANCE WITH THE RELEVANT RULES/REGULATIONS
COMPETENCE 3: TAKE PRECAUTIONS TO PREVENT HAZARDS
TRAINING OUTCOMES:
1. Hazards and control measures associated with chemicak tanker cargo operations, including:
- flammable and explosion
- toxicity
- health hazards
- inert gas composition
- elctrostatic hazards
- reactivity
- corrosivity
- low-boiling-point cargoes
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CARGO OPERATIONS
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-high-density cargoes
-solodifying cargoes
-polymerizing cargoes
2. Dangers of non-compliance with relevant rules/regulations

COMPETENCE 3: Take precautions to
prevent hazards
3.1 Knowledge and understanding of the R2, R6 T1, B1, B2, A1, A2,
hazards and control measures R7, R8 B4, B6, A10, A11,
associated with chemical tanker cargo A13, A14
operations, including: V05, VC1,
VC2, VC6,
.1 Flammability and explosion CBT
 Lists the three essentials necessary for
a fire to commence as:
- Oxygen
- Flammable material (fuel)
- Source of ignition
 Explainthat when flammable vapour is
mixed with oxygen (usually from the
atmosphere) an explosive mixture may
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CARGO OPERATIONS
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be produced
 Explain that the ability of petroleum
and chemical products to generate
flammable vapour is a major factor for
starting a fire
 Explain that the ability of a substance
to vaporize is its volatility
 Explain that volatility increases with
temperature and reaches a maximum
at the boiling temperature of the
petroleum and chemical products
 Explain that the concentration of
hydrocarbon vapour present in air is
used to define “flammable range”
 Explain that the working flammable
range of a mixture of petroleum vapour
and air can be taken to be from 1% to
10% by volume; other chemical
vapours may have other ranges;
 Explains the flammability diagram with
respect to: Flammable range,
Flammable zone and show how use of
inert gas enhances safety in cargo
operations

 Explain that the flashpoint of an oil
indicates the lowest temperature at
which the oil will give off sufficient
hydrocarbon vapour to form a
flammable gas mixture with air near
the surface of the oil
 Explain that only the vapour from a
flammable material will combine with
oxygen to produce fire
 States that an explosive mixture may
be produced when petroleum and
chemical cargo vapours are mixed with
air
 Explain that corrosive liquids can
become flammable and produce
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CARGO OPERATIONS
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flammable gases when in contact with

certain materials
 Explain that a mixture of vapour and
air will only ignite and burn if its
composition is within the “flammable
range”
 Explain that within the
flammable/explosive range, if a heat
source is introduced, then it will result
in a flash fire and possible sustained
combustion R2, R6 T1, B1, B2,
R7, R8 B4, B6, A1, A2,
.2 Toxicity A10, A11,
 Explains that poisoning may occur A13, A14
orally, through inhalation or by skin V05, VC1,
contact VC2, VC6,
 Explains that poisoning may be acute CBT
or chronic
 Explains that the toxicity of a
substance is difficult to measure and
that it is therefore rated on the basis of
studies performed by way of LD50 and
LC50 tests performed on animals and
extrapolated for the human body
.3 Health hazards
 Describes and Explains the effects of
ingesting petroleum

 Describes and Explains the effects of
petroleum on the skin and in the eyes
 Explains that the main effects of
petroleum gas on persons and the
complications it may cause
 Describes and Explains the symptoms
of narcosis
 Explains that the toxicity of petroleum
gas varies widely, depending on its
main hydrocarbon constituents
 Lists and Explains typical toxic
constituents of petroleum gas
 Describes and Explains the threshold
limit value- Time weighted average
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CARGO OPERATIONS
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(TLV - TWA) and that is generally

accepted for petroleum gas
 Explains that this TLV-TWA must NOT
be taken as applicable to gas mixtures
containing benzene or hydrogen
sulphide
 Explains that the human body can
tolerate a concentration above TLV for
short periods.
 Describes and Explains STEL (Short
term exposure limit)
 Explains why:
- The absence of a smell of gas is
insufficient guarantee of its
absence
- A combustible gas indicator cannot
be expected to measure TLV
 Explains that leaded gasoline is
considerably more toxic than unleaded
gasoline if ingested or absorbed
through the skin but there is little
difference between toxicity of vapours R2, R6
of leaded and unleaded petroleum R7, R8
T1, B1, B2,
.4 Inert gas composition B4, B6, A1, A2,
 Explains that the main hazard A10, A11,
associated with inert gas is its low A13, A14
oxygen content, but that it may also V05, VC1,
contain toxic gases VC2, VC6,
CBT
 Explains the toxic constituents of inert
gas
 Describes and Explains the hazardous
properties of the nitrogen oxides in flue
gas
 Explains that nitrogen dioxide is more
toxic than nitric oxide.
 Explains that:
 The sulphur dioxide content depends
on the sulphur content of the fuel oil
and on the efficiency of the scrubber
 The carbon monoxide content depends
on combustion conditions
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CARGO OPERATIONS
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R2, R6 A1, A2,

.5 Electrostatic hazard R7, R8 T1, B1, B2, A10, A11,
 Explains what charge separation is and B4, B6, A13, A14
when it occurs V05, VC1,
 Explains that no hazard exists if the VC2, VC6,
different materials remain in contact CBT
and immobile relative to one another
 Explains that a large voltage
differential develops after charge
separation
 Explains the creation of an electric field
 Describes and Explains the charge
separation within a conductor in an
electrostatic field
 Describes and Explains the process of
charge relaxation and factors relevant
to relaxation
 Explains that highly conductive
materials can retain their charge if
insulated by a poor conductor
 Explains that an electrical breakdown
between two points, giving rise to a
discharge, depends on the strength of
the electrostatic field between the
points
 Explains that a field strength of 3000
KV per meter is sufficient to cause the
breakdown of air or petroleum gases

 Explains that field strength near R2, R6 T1, B1, B2, A1, A2,
protrusions is greater than the overall R7, R8 B4, B6, A10, A11,
field strength, and that a discharge A13, A14
may occur between a protrusion and V05, VC1,
the space around it or between a VC2, VC6,
protrusion and another object nearby CBT
 Explains that single-electrode
discharges are unlikely to lead to
explosions on tankers
 Gives examples of two-electrode
discharges and describes when these
discharges may cause ignition
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CARGO OPERATIONS
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 Describes and Explains the

instantaneous release of energy with
respect to:
a. Conductors
b. Liquid non-conductors
c. Solid non-conductors
d. Intermediate liquid & solid non-
conductors
 Explains when liquids are considered
to be non-conductors
 Defines and lists static accumulator
oils
 Explains the function of anti-static
additives
 Explains why all distillates must be
treated as static accumulator oils
unless they contain anti-static
additives
 Explains the processes giving rise to
charges within distillates
 Explains the electrostatic hazards of
equipment permanently mounted in the
upper part of a tank, and the measures
to minimize the hazards
 Explains how operations can cause a
charged mist to develop within a tank
 Explains the dangers of introducing
inert gas or carbon dioxide into a
charged atmosphere

.6 Reactivity R2, R6 T1, B1, B2, A1, A2,
 Explain that chemical cargo may react R7, R8 B4, B6, A10, A11,
in a number of ways, such as: A13, A14
- With itself (self-reaction) V05, VC1,
- With air VC2, VC6,
- With water CBT
- With another cargo
- With other materials
 Explain that reactivity data of
chemicals are given in the ICS or other
cargo Data Sheets
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CARGO OPERATIONS
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 Explain that polymerization is the

formation of larger molecules as a
result of self-reaction
 Explain the effects of temperature on
the reactivity of cargoes and
polymerization
 Explain that the presence of impurities
may act as catalysts on the reactivity of
cargoes and polymerization
 Explain that polymerization may,
under some circumstances, be R2, R6
dangerous R7, R8
T1, B1, B2, A1, A2,
.7 Corrosivity B4, B6, A10, A11,
A13, A14
 Explain that some cargoes may be
V05, VC1,
corrosive to human tissue and to a
VC2, VC6,
ship’s equipment and structure
CBT
 Explain that instructions about the use
of protective clothing should be
observed
 States that care should be taken to
ensure that unsuitable materials are
not introduced into the cargo system
 Explain the effect of concentration and R2, R6
evolution of hydrogen on corrosion R7, R8
 Explain the conditions under which A1, A2,
iron sulphide becomes pyrophoric T1, B1, B2, A10, A11,
B4, B6, A13, A14
.8 low boiling point cargoes V05, VC1,
 Explains why a heated cargo is not VC2, VC6,
stowed adjacent to cargoes which CBT
have a low boiling point.

 Explains why as a safe margin, the
maximum temperature of the heated
cargo must be below the boiling point
of the low-boiling-point cargo.
 Explains that chemical tanker cooling
systems are only designed to prevent
the cargo from heating in warmer
ambient conditions.
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CARGO OPERATIONS
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 Explains transportation of low boiling-

point cargoes under pressure.
R2, R6 T1, B1, B2, A1, A2,
.9 high density cargoes R7, R8 B4, B6, A10, A11,
A13, A14
 Explains the dangers of loading high V05, VC1,
density cargoes and list their control VC2, VC6,
measures. CBT
.10 solidifying cargoes

 Explains the hazards of carrying
solidifying chemical cargoes and their
control measures.
.11 polymerizing cargoes

 Describes the dangers of
polymerization and their control
measures to prevent polymerization.
 Explains that the IBC Code specifies
the precautions to be taken against
spontaneous decomposition and
polymerization by the use of additives
(stabilizers and inhibitors).
 Explains important issues related to
tank cleaning after carrying
polymerizing cargoes. R1, R2, R3,
R6, R7, R8
3.2 Knowledge and understanding of T1, B1, B2, B5, A1, A11,
dangers of non-compliance with B6, B7 A13
relevant rules/regulations
 Explains the damage the oil causes to
the marine environment as a result of
blanketing, ingestion by sea organisms
and the deterioration of amenities
 Explains the meaning of toxic load

 Explains that it is when the toxic load R1, R2, R3, T1, B1, B2, B5, A1, A11,
of an area, is exceeded after an R6, R7, R8 B6, B7 A13
incident that causes harm to the
marine environment
 Explains that oil can interfere with
other legitimate uses of the sea (water
inlets, fish farming, fishing industry and
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CARGO OPERATIONS
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coastal tourism)
 Explains that those who persist in
operating their vessels in contravention
to the IMO's body of environmental
regulations have direct repercussions
on the safety of vessels, the well-being
of crews and on the environment in
addition to criminal proceedings, heavy
fines and imprisonment.
 Explains that most ships and ship-
owner/operators actively seek to
comply with environmental regulations.
 Explains that compliance with
international environmental rules still
leaves something to be desired.
TOPICS 4.1 KNOWLEDGE AND UNDERSTANDING OF SAFE WORKING

PRACTICES, INCLUDING RISK ASSESSMENT AND PERSONAL
SHIPBOARD SAFETY RELEVANT TO CHEMICAL TANKERS
COMPETENCE 4: APPLY OCCUPATIONAL HEALTH AND SAFETY PRECAUTIONS

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CARGO OPERATIONS
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TRAINING OUTCOMES:
1. Safe working practices, including risk assessment and personal shipboard safety relevant to
chemical tanker:
- precations to be taken when entering enclosed spaces, including correct use of different types
of breathing apparatus
- precations to be taken before and during repair and maintence work
- precations for hot and cold work
- precations for electrical safety
- use of appropriate Personal Protective Equipment (PPE)

COMPETENCE 4:Apply occupational health
and safety precautions
4.1 Knowledge and understanding of safe R1, R2, R3, T2, B2, B4, B6, A1, A11,
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CARGO OPERATIONS
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working practices, including risk R7, R8, R9 & B7, B8, B10, B11 A13, A14,
assessment and personal shipboard R12 & B12 V05,VC1,
safety relevant to chemical tankers: VC2, VC6,
CBT
.1 Precautions to be taken when entering
enclosed spaces, including use of
breathing apparatus.
 Lists information to be obtained during
tank atmosphere evaluation as:
1. Type of atmosphere
2. Flammability
3. Toxicity/oxygen deficiency
4. Reactivity
 Explain that tank atmosphere
evaluation is to be carried out:
1. prior to entry of personnel into a
tank
2. during inerting, gas-freeing and
purging operations
3. To establish a gas-free condition
4. As a quality control before loading
 Explain that all procedures were made
based on the company procedures and
in accordance with the ISM and Safe
Working Practices.
1. Risk Assessment and Hazard
Recognition
2. Toolbox or safety meeting
3. Warning notices
4. Cargo Data Sheets
5. Entry Permit
 Explains the importance and
demonstrates the procedures in the
use of breathing apparatus and
emergency escape breathing device.
2 Precautions to be taken before and R1, R2, R3, T2, B2, B4, B6,
during repair and maintenance work. R7, R8, R9 & B7, B8, B10, B11
 Explain that Cold Work, Hot Work R12 & B12
Enclosed Space Entry, Electrical A1, A11,
A13, A14
Isolation and other permits need to be
obtained prior commencing such work
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CARGO OPERATIONS
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 Explain work on pipelines, valves or

pumps should only be permitted when
item is:
1. detached from the system by cold
work
2. remaining system is blanked off
3. item is cleaned and gas-freed
 Explains that great care needs to be
taken due to possible cargo residues
remaining
 Explain that work on control systems
may affect safe cargo handling
procedures
R1, R2, R3, T2, B2, B4, B6, A1, A11,

R7, R8, R9 & B7, B8, B10, B11 A13, A14,
.3 Precautions for hot and cold work R12 & B12
 Explain the safe working procedures
and guidelines for the operation of
chemical tankers
 Explain the importance of
communicating with the owners or
company and obtain permission.
 Explain Importance of Hot & Cold work
permits
 Complete Hot & Cold work Permits R1, R2, R3, T2, B2, B4, B6,
R7, R8, R9 & B7, B8, B10, B11 A1, A11,
R12 & B12 A13, A14,
.4 Precautions for electrical safety
.5 Use of appropriate Personal Protective

Equipment (PPE).
 Explain that the requirements for and
the standards of protection and
safetyequipment are laid down by
international and national regulations
 Explain that all protection and safety
equipment should be regularly
inspected and kept ready for
immediate use
 Explains the different elements of
Personal Safety Equipment:
1. Protective clothing
2. Breathing apparatus
3. SCBA
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CARGO OPERATIONS
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4. EEBD
5. Filter Mask
 Explains the use of personal safety R1, R2, R3, T2, B2, B4, B6, A1, A11,
equipment: - wearing of clothing - R7, R8, R9 & B7, B8, B10, B11 A13, A14,
donning and use of BA - storage and R12 & B12
maintenance of safety equipment –
precautions
 Lists the items constituting protection
equipment of crew members engaged
in cargo operations
 Lists the respiratory and eye protection
needed for the purpose of an
emergency escape
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CARGO OPERATIONS
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TOPICS 5.1 KNOWLEDGE AND UNDERSTANDING OF CHEMICAL TANKER EMERGENCY

PROCEDURE
5.2 ACTIONS TO BE TAKEN FOLLOWING COLLISION, GROUNDING OR
SPILLAGE
5.3 KNOWLDGE OF MEDICAL EMERGENCY FIRST AID PROCEDURES ON
BOARD CHEMICAL TANKERS, WITH REFERENCE TO THE MEDICAL FIRST
AID GUIDE FOR USE IN ACCIDENTS INVOLVING DANGEROUS GOODS
(MFAG)
COMPETENCE 5: RESPOND TO EMERGENCIES
TRAINING OUTCOMES:
1. Chemical tanker emergency procedures, inluding:

- ship emergency response plan
- cargo operations emergency shutdown
- actions to be taken in the event of failure of systems or services essential to cargo
- fire fighting on chemical tankers
- enclosed space rescue
- cargo reactivity
- jettisoning cargo
- use of Material Safety Data Sheet (MSDS)
2. Action to be taken following collison, garounding or spillage
3. Procedures on board chemical tankers, with reference to Medical First Guide for use in accidents
invloving dangerous hazardous goods (MFAG)
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CARGO OPERATIONS
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COMPETENCE 5:Respond to Emergencies
5.1 Knowledge and understanding of R1, R2, R3, T2, B2, B4, B6, A1, A11,
chemical tanker emergency R7, R8, R9 & B7, B8, B10, B11 A12, V05
procedures, including R12 & B12 A13, VC1,
VC2, VC6
.1 Ship emergency response CBT
 Explain the need for an emergency
organization and lists the main
components of the organization as:
- an emergency command center
- an emergency party
- a break-up emergency part
- a break-up emergency part
- an engineers group
 Explainthat the ship's muster list and
emergency instructions should specify
such details as:
- the assembly point for personnel
and the basic action for each group
in the emergency organization
- -the location of equipment for each
group
 Explain that all personnel should know
their place in the emergency
organization and be familiar with their
duty in case an emergency procedure
is initiated
 Explainthat emergency operations
have to be pre-planned and trained in if
they are to succeed
 Explain that an emergency plan
should be directed to:
- rescue and treatment of casualties -
safeguarding others
- minimizing the damage to the ship,
to property and to the marine
environment
- containing the incident and bringing
it under control
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CARGO OPERATIONS
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.2 Cargo operation emergency shutdown R1, R2, R3, T2, B2, B4, B6, A1, A11,
 Explain that planning and preparation R7, R8, R9 & B7, B8, B10, B11 A12, V05
are essential for dealing successfully R12 & B12 A13, VC1,
with emergencies and lists the VC2, VC6
information which should be readily CBT
available as:
- Type of cargo and its disposition
- Location of other hazardous
substances
- General arrangement plan of the
ship
- Stability information
- Location of fire-fighting equipment
and instructions for its use
 Explain that, in an emergency,
important actions to take would
include:
- Giving audible and visual warnings
that an emergency exists by means
of:
- Bells, whistles, klaxons or other
audible devices
- Flashing lights
- Advising the command center of
the location and nature of the
emergency
- Promptly activating the Emergency
Shutdown Device (ESD) and
stopping any cargo-related
operations, closing valves and
openings in tanks as initiated by the
ESD system
- Ensuring that any craft alongside R1, R2, R3, T2, B2, B4, B6,
are removed R7, R8, R9 & B7, B8, B10, B11
.3 Actions to be taken in the event of R12 & B12 A1, A11,
failure of systems or services essential A12, V05
to cargo A13, VC1,
VC2, VC6
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CARGO OPERATIONS
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 Explain that personnel in the vicinity of CBT

the emergency should take appropriate
action to try and control the incident
until the emergency team can take
over

 Explain that all crew members should
know the location of all safety
equipment, such as;
- Breathing apparatus
- Protective clothing
- Approved portable electric lights
- Instruments for measuring oxygen
and other gases
- First-aid kits
- Tank evacuation equipment
- Fire-fighting equipment with
instructions for its use
 Explain that all equipment which may
be needed in an emergency must be
maintained in good order and always
be ready for use, and lists important
items as:
- Fire-fighting equipment
- Breathing apparatus
- Protective clothing
- Alarm systems
- Communication systems
- Arrangement plans
 Explain that a plan for dealing with an
outbreak of fire or an explosion must
be prepared and all crew members
briefed on its operation R1, R2, R3,
R7, R8, R9 &
.4 Fire fighting on chemical tankers R12 T2, B2, B4, B6, A1, A11,
 Describes and explains the water as B7, B8, B10, B11 A12, V05
fire-extinguishing agent & B12 A13, VC1,
 Describes and explains the foam as a VC2, VC6
fire-fighting agent CBT
 Describes and explains the carbon
dioxide as a fire-fighting agent
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by: CAS
Foundation Inc.
 Explains when HALON was used as a

fire extinguishing agent, there were two
types:
- Halon 1211, used in portable
extinguishers
- Halon 1301, used in fixed
extinguishers

 Explains that HALON as a fire-fighting
agent has been decommissioned
under the Montreal Protocol
 Explains that under IMO guidelines, as
of 01.1.1994 HALON has been
prohibited on new ships built after this
date
 Explains that for existing installations
IMO has not set a deadline as all
Halon use on board will eventually be
de commissioned based on the de-
commissioning of Halon plants ashore.
 Explains that there are regulations for
the fire protection of cargo tanks, the
cargo tank deckarea and pump-rooms
 Explains that:
- the protection of cargo tank deck
area shall be achieved by a fixed
deck foam system
- the protection of cargo tanks shall
be achieved
- by a fixed inert gas system
- Explains that protection of the
pump-room shall
- be achieved by:
- a CO2 system, or
- a high-expansion foam system, or
- a fixed pressure water-spraying
system
 Explains that pump-room fire
protection systems must be operated
from a position outside the pump-room
 Explains that some tankers maybe
exempted from the inert gas R1, R2, R3,
Revision Page no.

CARGO OPERATIONS
(MATP-031) Approved
by: CAS
Foundation Inc.
requirements owing to the size or age R7, R8, R9 &

R12
.5 Enclosed space rescue T2, B2, B4, B6, A1, A11,
 Demonstrates an enclosed space B7, B8, B10, B11 A12, V05
rescue, including all relevant rescue & B12 A13, VC1,
equipment. VC2, VC6
CBT

.6 Cargo reactivity
 Explains early indicators of reactivity
and precautions to prevent reactivity
in chemical cargoes.
T2, B2, B4, B6,
.7 Jettisoning cargo R1, R2, R3, A1, A11,
B7, B8, B10, B11
 Explain that the jettisoning of cargo is R7, R8, R9 & A12, V05
& B12
an extreme measure, justified only in R12 A13, VC1,
an emergency as a means of saving VC2, VC6
life at sea or where the integrity of the CBT
ship is at risk.
 Describe the precautions to take when
jettisoning of chemical cargo.
.8 Use of Material Safety Data Sheet

(MSDS)
 Explains with the aid of an SDS the
constituents of the product by chemical
name, name in common usage, UN
number and the maximum
concentration of any toxic components,
expressed as a percentage by volume
or as ppm. T1, B1, B2, B5,
R2,R3,R6,
B7
R8 A1, A11,
5.2 Actions to be taken following
A13, A14
collision, grounding and spillage
 Explains standard initial and follow-up
actions to be taken subsequent to a
collision/grounding or spillage and
activation of the Shipboard Oil
Pollution Emergency Plan (SOPEP) /
Shipboard Marine Pollution Emergency
Revision Page no.

CARGO OPERATIONS
(MATP-031) Approved
by: CAS
Foundation Inc.
Plan (SMPEP).
 Explains the importance of evidence R2, R5,
collection and emergency reporting R6, R8 T1, B1, B2, B6
requirements.
A1, A2, A3,
5.3 Knowledge of Medical First Aid A11, A13
procedures on board chemical
tankers, with reference to the
Medical First Aid Guide for Use in
Accidents Involving Dangerous
Goods (MFAG)
 Explains the actions taken in a medical R2, R5, T1, B1, B2, B6 A1, A2, A3,
emergency in line with current R6, R8 A11, A13
recognized first aid practice and
international guidelines
Revision Page no.

CARGO OPERATIONS
(MATP-031) Approved
by: CAS
Foundation Inc.
TOPICS 6.1 UNDERSTANDING OF PROCEDURES TO PREVENT POLLUTION OF

THE ATMOSPHERE AND THE ENVIRONMENT
COMPETENCE 6: TAKE PRECAUTIONS TO PREVENT POLLUTION OF THE ENVIRONMENT
TRAINING OUTCOMES:
1. Proceduresto prevent pollution of the atmosphere and the environment.

Revision Page no.

CARGO OPERATIONS
(MATP-031) Approved
by: CAS
Foundation Inc.

COMPETENCE 6:Take precautions to prevent
pollution of the environment
6.1 Understanding of procedures to R1, R2, R3, T2, R7, R8, R9, A1, A11,
prevent pollution of the atmosphere R7, R8, R9 & B2, B4, B6, B7, A11, A13,
of the environment. R12 B8, B10, B11 & A14, R12,
 Explains that an oil tanker comply with B12 V05, VC1,
constructional requirements with VC2, VC6,
respect to: CBT
- Segregated ballast capacity
- Slop-tank capacity
- Limitation of tank size
- Survival capability in case of damage
- Overboard piping arrangements
- Emergency towing arrangements
 Explains that an oil tanker must have
approved equipment for:
- Monitoring and controlling discharges
of oil and oil/water mixtures into the
sea
- Establishing the oil/water interface in
slop-tanks
 Explains that ODME must be approved
for Bio-Fuel Blends when used for
oil/water mixtures contains bio-fuel
Revision Page no.

CARGO OPERATIONS
(MATP-031) Approved
by: CAS
Foundation Inc.
blends (Please see Part D).

 Explains that the ship and its
equipment shall be maintained in
satisfactory condition
 Explains that different requirements
may apply to certain oil tankers such
as:
- Oil tankers engaged in specific
trades
- Oil tankers have special ballast
arrangements
- Oil tankers carrying asphalt or
similar cargoes

- Oil tankers trading within special
areas or within 50 miles of the
nearest land
- Vessels engaged in alternate crude
oil/product transport A1, A11,
 Explains that compliance with such R1, R2, R3, T2, R7, R8, R9, A11, A13,
different requirements are reflected in R7, R8, R9 & B2, B4, B6, B7, A14, R12,
the IOPP Certificate R12 B8, B10, B11 & V05, VC1,
 Explains that load-on-top (LOT) B12 VC2, VC6,
procedures are normally allowed on oil CBT
tankers
 Explains that the discharge provisions
applicable to oil must be complied with
 Explains the control of discharge of oil
into sea procedures as applicable to oil
tankers outside special areas.
 Explains that, when discharge into the
sea in compliance with the discharge
provisions is not possible, oil and oil
mixtures should be discharged to
shore reception facilities
 Explains that reception facilities require
notice, including information on
Revision Page no.

CARGO OPERATIONS
(MATP-031) Approved
by: CAS
Foundation Inc.
procedure and quantity

 Explains that the Masters must send a
report to the Flag State in case of any
inadequacies observed regarding
reception facilities
 Explains that sea surface and
discharge outlets must be observed
when discharging ballast or decanting
slop-tanks
 Explains that the surface of clean or
segregated ballast must be observed
prior to discharge
 Explains that when commencing
ballasting, the pumps must be running

before opening sea inlets to prevent
pipeline contents polluting the sea
 Explains that the loading arms have a R1, R2, R3, A1, A11,
T2, R7, R8, R9,
very small operating envelope R7, R8, R9 & A11, A13,
B2, B4, B6, B7,
 Explains that moorings must be kept R12 A14, R12,
B8, B10, B11 &
adjusted when a ship is aloingside to V05, VC1,
B12
prevent the ship from ranging VC2, VC6,
CBT
 Explains that oil/water levels must be
watched in cargo and slop-tanks when
handling ballast or cargo
 Explains over side discharge scuppers
must be plugged when handling cargo
or ballast, or when bunkering
 Explains that sea valves must be
closed and secured during cargo work
 Explains that a watch must be kept
both at the manifold and when
patrolling the deck
 Explains that hoses and loading arms
must be drained before disconnecting
 Explains that after tank and pipe
stripping, the residues should be
Revision Page no.

CARGO OPERATIONS
(MATP-031) Approved
by: CAS
Foundation Inc.
discharged by means of the small-

diameter line (if fitted)
 Explains that the ship is provided with
an ORB
 Explains that the format of ORB is
uniform and that all operations
involving oil and oily mixtures should
be recorded, where possible in coded
entries
 Explains that, where the use of coded
entries is not possible, entries should
be recorded at least in English, French
or Spanish.

 Explains that foreign authorizes may R1, R2, R3, T2, R7, R8, R9, A1, A11,
ask to inspect the book and have R7, R8, R9 & B2, B4, B6, B7, A11, A13,
copies of entries certified as true R12 B8, B10, B11 & A14, R12,
B12 V05, VC1,
entries by the master, and the ship is
VC2, VC6,
required to co-operate in these Matters CBT
 Explains that ORB must be kept on
board in a readily available location
and must be preserved for a period of
three years following the date of last
entry
Revision Page no.

CARGO OPERATIONS
(MATP-031) Approved
by: CAS
Foundation Inc.
TOPICS 7.1 KNOWLEDGE AND UNDERSTANDING OF RELEVANT PROVISIONS

OF THE INTERNATIONAL CONVENTION FOR THE PREVENTION OF
POLLUTION FROM SHIPS (MARPOL) AND OTHER RELEVANT IMO
INSTRUMENTS, INDUSTRY GUIDELINES AND PORT REGULATIONS
AS COMMONLY APPLIED
7.2 PROFICIENCY IN THE USE OF THE IBC CODE AND RELATED
DOCUMENTS
COMPETENCE 7: TAKE PRECAUTIONS TO PREVENT POLLUTION OF THE ENVIRONMENT
TRAINING OUTCOMES:
1. Relevant provisions of the International Convention for the Prevention of Pollution from ships
(MARPOL) and other relevant IMO instruments, industry guidelines and port regulations as commonly
applied.
2. The use of IBC Code and related documents
Revision Page no.

CARGO OPERATIONS
(MATP-031) Approved
by: CAS
Foundation Inc.

COMPETENCE 7:Monitor and control
compliance with legislative requirements
7.1 Knowledge and understanding of R1, R2, R3, T2, R7, R8, R9, A1, A11,
relevant provisions of the International R7, R8, R9 & B2, B4, B6, B7, A11, A13,
Convention for the Prevention of R12 B8, B10, B11 & A14, R12,
Pollution from Ships (Marpol) and other B12 V05, VC1,
relevant IMO instruments, industry VC2, VC6,
guidelines and port regulations as CBT
commonly applied
 Explains that the International
Convention for the Prevention of
Pollution from Ships (MARPOL) is the
main international convention covering
prevention of pollution of the marine
environment by ships from operational
or accidental causes.
 Explains that the Convention includes
regulations aimed at preventing and
minimizing pollution from ships – both
accidental pollution and that from
routine operations – and currently
includes six technical Annexes. Special
Areas with strict controls on
operational discharges are included in
most Annexes.
 Lists and Explains the MARPOL
Annexes as:
 Annex I Regulations for the Prevention
of Pollution by Oil (entered into force 2
October 1983)
 Annex II Regulations for the Control of
Pollution by Noxious Liquid
Substances in Bulk (entered into force
2 October 1983
 Annex III Prevention of Pollution by
Harmful Substances Carried by Sea in
Revision Page no.

CARGO OPERATIONS
(MATP-031) Approved
by: CAS
Foundation Inc.
Packaged Form (entered into force 1

July 1992)

 Annex IV Prevention of Pollution by
Sewage from Ships (entered into force
27 September 2003)
7.2 Proficiency in the use of the IBC Code R1, R2, T1, B1, B2, B4, A1, A2,
and related documents R3, R8 B5, B6, B7 A11, A12
 Explains the purpose and
demonstrates the use of the IBC Code.
 States that chapter 17 of the IBC Code
and the current IMO MEPC.2/Circular
lists the cargoes to which the Code is
applicable.
 Explain that specific additional
requirements are referenced in column
"o" in the table of chapter 17 of the IBC
Code.
 Explain the importance of thorough
knowledge of the IBC Code and its
different chapters, and describes the
content of the most important chapters.
 Explains chapter 19 and how index
names are provided in the Code.
 Explains the purpose and use of the
ICS Tanker Safety Guide for
Chemicals.

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no.: FEMFI-A-TD-SY096 Issued Date: 1 of 65

ADVANCED TRAINING FOR CHEMICAL TANKER

TOPICS 1.1 KNOWLEDGE OF CHEMICAL TANKER DESIGN, SYSTEM AND

COMPETENCE 1: ABILITY TO SAFELY PERFORM ABD MONITORS ALL CARGO

Demonstrates a knowledge and understanding of:

1. Chemical tanker designs, systems and equipment, including:

ADVANCED TRAINING FOR CHEMICAL TANKER

4. Monitoring and safety systems, including the emergency shutdown

- loading and unloading plans

10. Manage and supervise personnel with cargo-related responsibilities

ADVANCED TRAINING FOR CHEMICAL TANKER

IMO Textbooks, Teaching

ADVANCED TRAINING FOR CHEMICAL TANKER

COMPETENCE 1: Ability to safety perform and

Design and characteristics of a chemical tanker

1.1 Knowledge of chemical tanker, designs,

IMO Textbooks, Teaching

ADVANCED TRAINING FOR CHEMICAL TANKER

Intended Learning Outcomes Reference Bibliography Aid

ADVANCED TRAINING FOR CHEMICAL TANKER

IMO Textbooks, Teaching

 Explain that there are several types of

ADVANCED TRAINING FOR CHEMICAL TANKER

IMO Textbooks, Teaching

ADVANCED TRAINING FOR CHEMICAL TANKER

IMO Textbooks, Teaching

ADVANCED TRAINING FOR CHEMICAL TANKER

machines are either portable or fixed

IMO Textbooks, Teaching

.10 Cargo tank environmental control

ADVANCED TRAINING FOR CHEMICAL TANKER

IMO Textbooks, Teaching

ADVANCED TRAINING FOR CHEMICAL TANKER

accommodation are closed when cargo VC2, VC6,

IMO Textbooks, Teaching

ADVANCED TRAINING FOR CHEMICAL TANKER

VOC management plan and shore

IMO Textbooks, Teaching

ADVANCED TRAINING FOR CHEMICAL TANKER

- the flame of a match = 1100°C

ADVANCED TRAINING FOR CHEMICAL TANKER

IMO Textbooks, Teaching

ADVANCED TRAINING FOR CHEMICAL TANKER

IMO Textbooks, Teaching

ADVANCED TRAINING FOR CHEMICAL TANKER

suitable for pumping.

IMO Textbooks, Teaching

ADVANCED TRAINING FOR CHEMICAL TANKER

into the system;

1.2 Knowledge of Pump theory and R2 B2, B7 A1, A11,

IMO Textbooks, Teaching

ADVANCED TRAINING FOR CHEMICAL TANKER

segregated from the main venting

IMO Textbooks, Teaching

ADVANCED TRAINING FOR CHEMICAL TANKER

hydrocarbon gas in air must be checked

ADVANCED TRAINING FOR CHEMICAL TANKER