GALAXONIA CLASSES, NOIDA

CHEMISTRY TEST -01

Name: TIME: 2hrs

Date: MM: 50

INSTRUCTIONS:
 Attempt all questions.
 Q1-Q5 carry 1 mark each, Q6-10 carry 2 marks each, Q11-Q15 carry 3 marks
each, Q16-Q19 carry 5 marks each.

Q1. What happens if Eext is more than 1.1 volt in Daniell Cell?
Q2. Differentiate between a colloid and a solution on the basis of optical phenomena.
Q3. EDTA is used in the treatment of lead poisoning. What is its denticity?
Q4.Cyclohexanone forms cyanohydrin in good yield but 2,2,6-trimethylcyclohexanone does
not. Give plausible explanation.
Q5. What is cell constant? Write its SI unit.
Q6. Draw the graph which shows the variation of molar conductivity of the following
electrolytes with the concentration of their aqueous solution.
(a) KCl (b) CH3COOH
Q7.(a) Give an example of 2-2 electrolytes.
(b) Relate the following terms in the form an expression
Molar conductivity, Limiting molar conductivity and degree of dissociation
Q8. Define the following terms:
(a) Craft Temperature (b) Critical micelle concentration
Q9. Complete each synthesis by giving missing starting material, reagent or products
(a) (b)

Q10. Explain the term synergic bonding in the metal carbonyls with an example.
Q11. The molar conductivity of 0.025 mol L–1 methanoic acid is 46.1 S cm2 mol–1. Calculate
its degree of dissociation and dissociation constant.
Given λ0 (H+ ) = 349.6 S cm2 mol–1 and λ0 (HCOO– ) = 54.6 S cm2 mol–1
Or
Calculate the emf of the cell in which the following reaction takes place Ni(s) + Ag+ (0.002
M) → Ni2+ (0.160 M) + Ag(s)
Given that E0(cell) = 1.05 V
Q12. (a)Explain on the basis of valence bond theory that [Ni(CN)4] 2– ion is diamagnetic and
the [NiCl4] 2– ion is paramagnetic.
(b) State the type of hybridization and geometry of each ion.
Q13. How will you bring about the following conversions in not more than two steps?
(a) Propanone to Propane (b) Benzoic acid to Benzaldehyde
(c) Benazaldehyde to α-Hydroxyphenylacetic acid
Q14. (a) Which of the following ion coagulates the positive sol easily.
[Fe(CN)6] 4– , PO4 3– ,SO4 2– , Cl–
(b) Which rule is used to explain the answer of (a).
(c) Define electro kinetic potential.
Q15. An organic compound with the molecular formula C9H10O forms 2,4-DNP derivative,
reduces Tollens’ reagent and undergoes Cannizzaro reaction. On vigorous oxidation, it gives
1,2- condensation (ii) Cannizzaro reaction (iii) Hell Volhard Zeilinsky(HVZ) reaction
(b) Mention the test to distinguish between
(a) Pentan-2-one and Pentanal (b) Acetophenone and Benzaldehyde
benzenedicarboxylic acid. Identify the compound.
Q16.(a) Predict the products of electrolysis of an aqueous solution of AgNO3 with silver
electrodes.
(b) A solution of Ni(NO3) 2 is electrolysed between platinum electrodes using a current of 5
amperes for 20 minutes. What mass of Ni is deposited at the cathode?
(c) Suggest the type of cell used in hearing aids.
Q17.(a) Arrange the following compounds in increasing order of their property as indicated:
(i) Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl ketone (reactivity towards
HCN) (ii) CH3CH2CH(Br)COOH, CH3CH(Br)CH2COOH, (CH3)2CHCOOH,
CH3CH2CH2COOH (acid strength)
(b) What is meant by the following terms ? Give an example of the reaction in each case.
(i)Hemiacetal (ii) Schiff’s base (iii) Semicarbazone
Q18.(a) What is the difference between multimolecular and macromolecular colloids? Give
one example of each. How are associated colloids different from these two types of colloids?
(b) Explain what is observed when an electric current is passed through a colloidal sol?
Q19. (a) Explain the following reactions
(i) Aldol condensation (ii) Cannizzaro reaction (iii) Hell Volhard Zeilinsky (HVZ)
reaction
(b) Give a test to distinguish between
(i) Acetophenone and Benzaldehyde (b) Pentan-3-one and Ethanal

-oOo-
Q1. A 10% aqueous solution of cane sugar ( mol wt. 342) is isotonic with 1.754% aqueous
solution of urea. Find the molecular mass of urea.
Q2. The molecular weight of an organic compound is 58 g/mol. What will be the boiling
point of a solution containing 48 grams of the solute in 1200 grams of water?
(Kb=0.513 Ckg/mol ; Boiling point of water= 100 C )
Q3.