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HALL fy;tpg; nghJj;juhju ( caHju)g; khjpupg; guPl;ir ) - 2021

General Certificate of Education (Adv. Level) Model Examination -2021

xU kzpj;jpahyk;
,urhadtpay; - II STRUCTURE -03
One hour
Chemistry - II

ftdpf;f :

 ,t;tpdhj;jhs; 08 gf;fq;fisf; nfhz;lJ

 vy;yhtpdhf;fSf;Fk; tpil vOJf
 fzpg;ghidg; gad;gLj;jf; $lhJ
 tpilj;jhspy; jug;gl;Ls;s ,lj;jpy; ckJ mDkjp ml;il ,yf;fj;ij vOJf

mfpy thAkhwpyp – R = 8.314Jmol-1K-1


mtfhjNuh khwpyp – NA = 6.022x 1023 mol-1
gpshq;fpd; khwpyp (h) = 6.62 x 10-34 Js
xspapd; Ntfk; (c) = 3 x 108 ms-1 BY- DIAS B.Sc.(Hons)Spl in chem

Full Name:…………………………………………………………………………………………………………………….…..

Index No:……………………………………. School:…………………………………………………………………..

1)
a) fPOs;s tpdhf;fSf;fhd tpilfisj; jug;gl;l ,ilntspfspDs; vOJf.
i) Mg , P , C vDk; %yfq;fspy; kpff; $ba cUFepiyAilaJ vJ?
………………………………………………………………………………………………………

ii) P3- , S2- , Cl- Mfpa rk ,yj;jpudikg;Gf;Fupa md;dad;fspy; kpfr;rpwpa madhiu

cilaJ vJ?
………………………………………………………………………………………………………..

iii) Cr , Mn , V Mfpa %d;W 3d %yfq;fspy; vjdJ cah; xl;rpNaw;w vz; Cl ,d; mjpAah;
xl;rpNaw;w epiyf;F rkdhdJ?
………………………………………………………………………………………………………

iv) Hg , Cs , Ca , Br Mfpa %yfq;fspy; vJ / vit 25oC ,Yk; tspkz;ly mKf;fj;jpYk;

jputepiyapy; fhzg;glyhk;?
………………………………………………………………………………………………………..

v) F , Cl , Mg Mfpa %yfq;fspy; $ba kiwg; ngWkhdj;Jf;Fupa ,yj;jpud; ehl;lj;ijf;

nfhz;lJ vJ?
………………………………………………………………………………………………………..

vi) NH3 , NO3- , NO2- Mfpa $Wfspy; vjpy; N mZ $ba kpd;ndjph;jj

; d;ikiaf;
nfhz;bUf;Fk;?
………………………………………………………………………………………………………..
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b) nkjapy; INrhraNdw; (CH3NCO) vDk; er;Rj;jd;ikAs;s thAtpd; %yf;$Wf;fhd rl;lf

mikg;G fPNo jug;gl;Ls;sJ.

H
│
H–C–N–C–O
│
H

i) ,k; %yf;$w;wpd; kpfTk; Vw;fj;jf;f Yhap fl;likg;ig tiuf.

ii) ,jd; gupTf; fl;likg;Gf;fis tiue;J mtw;wpd; rhh; cWjpepiy gw;wpf; fUj;Jj; njuptpf;Ff.

iii) H cld; ,ize;j C, O cld; ,ize;j C , N Mfpa mZf;fspd; fyg;G epiyfisf;

Fwpg;gpLf.

……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………

iv) VSERP nfhs;ifia gad;gLj;jp H cld; ,ize;j C, O cld; ,ize;j C , N Mfpa

mZf;fisr; #oTs;s tbtq;fis ca;jj; wpf.

……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
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c) i) fPNo jug;gl;l gl;baypUe;J Kidtw;w $Wfis njupT nra;f.

PCl5 , SF4 , CH3CHO , MgO , ICl4-

……………………………………………………………………………………………………………..

ii) kpd;fhe;jf; fjph;tPry; xd;wpd; miyePsk; 750nm MFk;.

a) mjd; kPbwidf; fzpf;f.

……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………

b) NkYs;s fjph;tPrYf;Fupa 1mol Nghl;ld;fspd; rf;jp ahJ?

……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………

(gpshq;fpd; khwpyp h = 6.626 × 10-34 Js, tspapy; xspapd; Ntfk; = 3 × 108 ms-1)

2)
(a) i) gpd;tUk; %yfq;fspdhy; mtw;wpd; mjpcah; xl;rpNaw;w epiyapy; Njhw;Wtpf;fg;gLk;
xl;irl;Lf;fspd; #j;jpuq;fis vOjp mtw;wpd; mkpy / %y / <upay;Gj; jd;ikfis gpd;tUk;
nrhw;fisg; gad;gLj;jp tpgupf;Ff.

(td;dkpyk; , nkd;dkpyk; , <upay;G , td;%yk;> nkd;%yk;)

xl;irl;bd; #j;jpuk; mkpy / %y/ <upay;G ,ay;G

Cl ………………………… ………………………….

Cr ………………………….. …………………………

P …………………………… ………………………….

Al ……………………………. …………………………..

Cs …………………………….. …………………………….

Si ……………………………. ………………………………..

NEW SCIENCE WORLD ,JAFFNA Dias BSc(Hons)Spl inChem

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ii) fPOs;s gjhh;j;jq;fspypUe;J fPNo jug;gl;l tpdhf;fSf;F tpilaspf;Ff.

K2Cr2O7 , NH4SCN , H2O2 , Na2S2O3 , NaOH , K2SO3

a) Ma;T$lj;jpy; ,Uz;l Nghj;jy;fspy; Nrkpf;fg;gLtJ?

………………………………………………………………………………………………………….

b) FeCl3 cld; Nrh;f;fg;gLifapy; FUjpr; rptg;G epwj;ijf; nfhLg;gJ?

………………………………………………………………………………………………………….

c) GNshuPDldhd jhf;fj;jpy; xl;rprd; Neh; xl;rpNaw;w epiyapy; cs;s Nrh;itiaj;

Njhw;Wtpg;gJ?

………………………………………………………………………………………………………….

d) Kjdpankhd;whfg; gad;gLj;jf;$baJ?

………………………………………………………………………………………………………….

e) HCl Ir; Nrh;f;Fk; NghJ fyq;fy; jd;ikahtJld; thAnthd;iwAk; nfhLf;ff;$baJ?

………………………………………………………………………………………………………….

(b) A,B vd;gd mZntz; 20 ,w;Fl;gl;l xNu Mtu;jj

; dj;jpd; mLj;jLj;Js;s %yfq;fshFk;.
,it KiwNa AB , AB2 Mfpa Nrh;itfis cUthf;Ffpd;wd.

i. %yfq;fs; A,B I ,dq;fhz;f?

A - ……………………………….. B - ……………………………………

ii. AB , AB2 vd;gtw;wpy; vJ NaOH(aq) cld; jhf;fkilAk;. mt;thW jhf;fkilAk;

Nru;itapd; cz;ikahd #j;jpuj;ij vOjp mJ NaOH cld; GupAk; jhf;fq;fSf;fhd
<Lnra;j rkd;ghl;il vOJf?

…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………

jho; ntg;gepiyapy; Nrh;it AB MdJ AB2 cld; jhf;fkile;J NtNwhU Nrh;itia

cUthf;Ffpd;wJ.

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iii. NkNy ngwg;gLk; Nrh;itapd; #j;jpuj;ij vOJf?

…………………………………………………………………………………………………..

iv. NkNy gFjp (iii) ePh; Fwpg;gpl;l Nrh;itapd; fl;likg;ig tiue;J mr;Nrh;itapy; A
,d; xl;rpNaw;w epiyiaf; Fwpg;gpLf?

…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………

v. AB , AB2 vd;gd jk;kpilNa jhf;fkiltjw;fhd fhuzj;ijf; Fwpg;gpLf?

………………………………………………………………………..………………………………

vi. AB2 ,d; ePUldhd X , Y Mfpa ,U xl;rpakpyq;fs; ngwg;gLtJld; X ,y; A ,d;

xl;rpNaw;w epiy Y ,Ys;sij tpl FiwT. X, Y Ij; jUtJld; mtw;wpd; mkpy
typikf;Nfw;g VWtupirg;gLj;Jf.
…………………………………………………………………………………………………............
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3)
a) mkpy Clfj;jpy; MnO4- ,dhy; C2O42- mad;fs; xl;rpNaw;wg;gLk; jhf;fj;ijf; fUJf.
i) nghUj;jkhd rkg;gLj;jpa xl;rpNaw;w Miu mad; rkd;ghl;ilj; jUf.
..............................................................................................................................................................
ii) nghUj;jkhd rkg;gLj;jpa jho;j;jy; miu mad;rkd;ghl;ilj; jUf.
..............................................................................................................................................................
iii) rkg;gLj;jpamad;rkd;ghl;ilvOJf.
..............................................................................................................................................................
iv) C2O42-kiwAk; tPjj;jpw;fhd Nfhitiaj; jUf.
..............................................................................................................................................................
v) Mn2+ cUthFk; tPjj;jpw;fhd Nfhitiaj; jUf.
.............................................................................................................................................................
vi) jhf;fj;jpd; jhf;f tPjj;jpw;fhd Nfhitia ntt;NtW $Wfs; rhh;ghf vOJf.
............................................................................................................................. ................................
vii) jug;gl;l epge;jidfspd; fPo; MnO4- kiwAk; tPjk; 0.01moldm-3s-1 vdpy;
I. H+kiwAk; tPjk; ahJ?
............................................................................................................................. ................................
.............................................................................................................................................................
II. CO2 cUthFk; tPjk; ahJ?
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viii) ,j;jhf;fk; xU Kjd;ikj;jhf;fkhf mika KbAkh? tpilf;fhd fhuzj;ijj; jUf.?

....................................................................................................................................................................
....................................................................................................................................................................

ix) ,j;jhf;fj;ij epfo;j;Jtjw;F muk;gj;jpy; jhf;ff;fyit Vwj;jho 500 C apw;F

ntg;gg;gLj;j Ntz;bapUg;gjw;fhd fhuzj;ijf; Fwpg;gpLf.
....................................................................................................................................................................
....................................................................................................................................................................

x) vdpDk; jhf;fk; njhlh;e;J eilngWtjw;F jhf;fj;njhFjp njhlh;e;J ntg;gg;gLj;jy;

mtrpakpy;iy. ,jw;fhd fhuzj;ijf; Fwpg;gpLf.
....................................................................................................................................................................
....................................................................................................................................................................

b) 1 mol H2,1 mol I2 vd;gd TK ,y; 1dm3 fdtsTila FLitfspy; jdpj;jdpahf cz;L.
,t;tpU FLitfSk; Gwf;fzf;fj;jf;f fdtsTila Fohapdhy; ,izf;fg;gl;L jhf;fk; epfo
mDkjpf;fg;gl;lJ. 10 epkplj;jpy; 20% H2(g) jhf;fkile;jJ.

,j;jhf;fj;jpd; nghwpKiw
K1
gb 1 I2(g) 2I(g)
K2
gb 2 H2(g) + 2I(g) 2HI(g)

I. ghj;jpuq;fs; ,izj;j fzj;jpy; H2(g) ,d; nrwpT ahJ?

....................................................................................................................................................................
....................................................................................................................................................................
II. 10 epkplj;jpy; H2(g) I2(g) ,d; nrwpTfisf; fzpf;Ff.
....................................................................................................................................................................
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III gb 1 ,d; rkepiyaf; fUj;jpw; nfhz;L rdepykhwpyp KC ,w;fhd Nfhitia Kw;jhf;f
tPjkhwpyp K1 gpw;jhf;f khwpyp K2 ngWf.
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iv Nkw;gb nghwpKiwiaf; fUj;jpw; nfhz;L jhf;fj;jpd; Ntf tpjpf;fhd Nfhitiag; ngWf.

....................................................................................................................................................................
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V ,j;jhf;fj;jpd; tPj khawpypia ntg;gepiy TK ,y; fzpf;Ff.

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4)
Nrh;it A (%yf;$w;Wr; #j;jpuk; C6H14O) xspapay; rkgFjpaj; jd;ikiaf; fhl;Lfpd;wJ. A MdJ
Na cld; jhf;fKw;W H2 thAit tpLtpf;fpd;wJ. vdpDk; ePuw;w ZnCl2 / nrwp HCl cld; fyq;fy;
jd;ikiaf; nfhLf;ftpy;iy.

i) A ,w;F rhj;jpakhd fl;likg;Gf;fis fPOs;s ngl;bfspy; tiuf?

ii) A MdJ nrwpe;j H2SO4 cld; #lhf;fpa NghJ Nrh;it %yf;$w;Wr; #j;jpuk; C6H12 cila B
iaf; nfhLj;jJ. Nrh;it B ck; xspapay; rkgFjpaj; jd;ikiaf; fhl;baJ. A,B ,w;Fupa
fl;likg;Gf;fis fPOs;s ngl;bfspy; tiuf?

A B
iii) B MdJ HBr cld; jhf;fk; Gupe;j NghJ gpujhd tpisthf Nrh;it B ngwg;gl;lJ. Nrh;it
C MdJ alcohol / KOH cld; gupfupf;fg;gl;l NghJ D,E Mfpa Nrh;it ngwg;gl;ld. D ck;
E ck; fl;likg;Gr; rkgFjpaq;fshFk;. C,D,E vd;gtw;wpd; fl;likg;Gf;fis fPOs;s
ngl;bfspy; tiuf?

C D E

a)
i) CH3COCl cld; NH3 milAk; jhf;fj;jpd; Nrjd tpisnghUspd; fl;likg;ig vOJf?

………………………………………………………………………………………………………..

ii) NkYs;s jhf;fj;jpw;fhd nghwpKiwiaj; jUf?

iii) Nkw;gb nghwpKiw vt;thW miof;fg;gLk;?

………………………………………………………………………………………………………

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b)
i) CH3CONH2 , CH3COONH4 , CH3CH2NH2 Mfpa %d;W Nrh;itfisAk; vt;thW xNu
Nrhjidiag; gad;gLj;jp NtWgLj;jpawpayhk; vd tpsf;Ff.

……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
…………………………………………………………………………………………..

ii) gpd;tUk; jhf;fj;jpl;lq;fis vq;qdk; Nkw;nfhs;tPu;?

CH3 CH3 OH
a) C CH3
COOH

NO2 NO2
b)

NH- C-CH3
O

NEW SCIENCE WORLD ,JAFFNA Dias BSc(Hons)Spl inChem