SAFETY DATA SHEET (REGULATION (EC) n° 1907/2006 - REACH) Version 8.

3 (22-12-2016) - Page 1/8

STERANIOS 2% - 382000

SAFETY DATA SHEET

(REACH regulation (EC) n° 1907/2006 - n° 2015/830)

1.1. Product identifier

Product name : STERANIOS 2%
Product code : 382000.
1.2. Relevant identified uses of the substance or mixture and uses advised against
Disinfection of medical devices
For further information on product indication, please see the label.
1.3. Details of the supplier of the safety data sheet
Registered company name : Laboratoires ANIOS.
Address : PAVE DU MOULIN .59260.LILLE - HELLEMMES.FRANCE.
Telephone : + 33 (0)3 20 67 67 67. Fax : + 33 (0)3 20 67 67 68.
e:mail : fds@anios.com
www.anios.com
1.4. Emergency telephone number : + 33(0)1 45 42 59 59.
Association/Organisation : INRS.

2.1. Classification of the substance or mixture

In compliance with EC regulation No. 1272/2008 and its amendments.
Skin irritation, Category 2 (Skin Irrit. 2, H315).
Serious eye damage, Category 1 (Eye Dam. 1, H318). Respiratory
sensitisation, Category 1 (Resp. Sens. 1, H334). Skin sensitisation,
Category 1 (Skin Sens. 1, H317).
Specific target organ toxicity (single exposure), Category 3 (STOT SE 3, H335).
This mixture does not present a physical hazard. Refer to the recommendations regarding the other products present on the site.
This mixture does not present an environmental hazard. No known or foreseeable environmental damage under standard conditions of use.
2.2. Label elements
In compliance with EC regulation No. 1272/2008 and its amendments.
Hazard pictograms :

GHS07 GHS05 GHS08

Signal Word :
DANGER
Product identifiers :
EC 203-856-5 GLUTARALDEHYDE
Hazard statements :
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
Precautionary statements - General :
P102 Keep out of reach of children.

Made under licence of European Label System, Software of INFODYNE (http://www.infodyne.fr)

Quick-FDS [17959-11709-17117-019126] - 2017-03-02 - 03:15:10

 Precautionary statements - Prevention :
P260 Do not breathe vapours.
P280 Wear protective gloves and eye protection/face protection.
P284 In case of inadequate ventilation wear respiratory protection.
Precautionary statements - Response :
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician. P333
+ P313 If skin irritation or rash occurs: Get medical advice/attention.
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
Precautionary statements - Storage :
P403 Store in a well-ventilated place.
Precautionary statements - Disposal :
P501 Dispose of unused product and its container as hazardous waste.
2.3. Other hazards
The mixture does not contain substances classified as ‘Substances of Very High Concern' (SVHC) >= 0.1% published by the European CHemicals Agency
(ECHA) under article 57 of REACH: http://echa.europa.eu/fr/candidate-list-table
No other hazard identified in the current state of knowledge.

Title for H and EUH statements: see § 16.

3.2. Mixtures
Composition :
Identification (EC) 1272/2008 Note %
CAS: 111-30-8 GHS06, GHS05, GHS09, GHS08 [1] 0 <= x % < 2.5
EC: 203-856-5 Dgr
REACH: 01-2119455549-26 Met. Corr. 1, H290
Acute Tox. 3, H301
GLUTARALDEHYDE Skin Corr. 1B, H314
Skin Sens. 1, H317
Acute Tox. 3, H331
Resp. Sens. 1, H334
STOT SE 3, H335
Aquatic Chronic 2, H411
Aquatic Acute 1, H400
M Acute = 1

Information on ingredients :
[1] Substance for which maximum workplace exposure limits are available.

As a general rule, in case of doubt or if symptoms persist, always call a doctor.

NEVER induce swallowing by an unconscious person.
Reminder: any unconscious person must be placed in the lateral recovery position.
4.1. Description of first aid measures
In the event of exposure by inhalation :
Move the person away from the place of exposure and take him/her outside.
In the event of respiratory problems (e.g. heavy coughing):
Put the person in a half-seated position, with the torso raised ; keep the person warm and calm. Call a doctor
immediately.
In the event of splashes or contact with eyes :
If applicable, remove contact lenses.
Wash thoroughly with soft clean water for 15 minutes, holding the eyelids open. Take
care not to introduce rinsing water in the undamaged eye.
Additional treatment to be provided immediately in an eye clinic or by an ophthalmologist.
Continue rinsing until medical advice is obtained.
In the event of splashes or contact with skin :
Remove all contaminated or stained clothing immediately. Do not use them again until they have been decontaminated. Rinse
immediately and thoroughly with water.
 In the event of skin irritation, seek medical advice. Show this container or label.
In the event of swallowing :
Rinse out the mouth, do not allow to drink, do not induce vomiting. Calm the person down and transfer immediatly to hospital or doctor. Show the label to the
doctor.
4.2. Most important symptoms and effects, both acute and delayed
Cf. § 11
4.3. Indication of any immediate medical attention and special treatment needed
Refer to the recommendation of the doctor.

5.1. Extinguishing media

Suitable methods of extinction
Any extinguishing agents are authorized: foam, sand, carbon dioxide, water, powder.
5.2. Special hazards arising from the substance or mixture
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health. Do not
breathe in smoke.
5.3. Advice for firefighters
Due to the toxicity of the gas emitted on thermal decomposition of the products, fire-fighting personnel are to be equipped with autonomous insulating breathing
apparatus.
Full protective suit.

6.1. Personal precautions, protective equipment and emergency procedures

Consult the safety measures listed under headings 7 and 8. Keep
away any unprotected person.
Avoid inhaling the fumes.
Avoid all contact with skin or eyes.
6.2. Environmental precautions
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for waste
disposal.
Do not get rid in natural spaces (waterways, ground and vegetations...)
6.3. Methods and material for containment and cleaning up
Absorb any spilled product with absorbent non-combustible materials, and sweep away or remove with a shovel. Put any waste in drums for disposal. Do not
mix with any other waste. Wash the contaminated surface thoroughly with water.
Do not collect the product for re-use.
6.4. Reference to other sections
Disposal considerations: see section 13.

7.1. Precautions for safe handling

Product for external use - do not swallow. Avoid
all contact with skin, eyes and clothes.
Handle in accordance with user instructions on label
Fire prevention :
Handle in well-ventilated areas.
Prevent access by unauthorised personnel.
Recommended equipment and procedures :
For personal protection, see section 8.
Observe precautions stated on label and also industrial safety regulations. Avoid
eye contact with this mixture at all times.
Safety shower, eye bath and water point nearby.
Change any contaminated or wet work clothes immediately. Ensure
room is well ventilated.
Prohibited equipment and procedures :
No smoking, eating or drinking in areas where the mixture is used.
7.2. Conditions for safe storage, including any incompatibilities
Keep the container tightly closed
 Store ONLY in the original package.
Store between + 5 °C and + 35 °C in a dry, well ventilated place Do not
use after the expiry date mentioned on the packaging.
Keep out of the reach of children
Store away from incompatible materials (see section 10)
7.3. Specific end use(s)
For professional use only
Refer to paragraph 1 for product indication

The information in this chapter refers to the product specifically described in this document. If the product is handled and/or exposed
simultaneously with other chemical agents, these must be taken into consideration when choosing personal safety equipment.
The Exposure Threshold Limit Value and the Average Exposure Value given below are quoted by the CAS number of the substance. Paragraph 3 details the
chemical name corresponding to the CAS number.
Individuals should not be exposed to this product if they have already experienced skin irritation or asthma caused by :
- glutaraldehyde
8.1. Control parameters
Occupational exposure limits :
- Belgium (Order of 19/05/2009, 2010) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
111-30-8 0,05 ppm M
0,21 mg/m3
- France (INRS - ED984 :2012) :
CAS VME-ppm : VME-mg/m3 : VLE-ppm : VLE-mg/m3 : Notes : TMP No :
111-30-8 0.1 0.4 0.2 0.8 - 65.66
- Spain (Instituto Nacional de Seguridad e Higiene en el Trabajo (INSHT), Mayo 2010) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
111-30-8 0,05 ppm Sen
0,2 mg/m3
- Poland (2014) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
111-30-8 0,4 mg/m3 0,6 mg/m3
- Czech Republic (Regulation No. 361/2007) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
111-30-8 0,2 mg/m3 0,4 mg/m3 I, S
- Slovakia (Regulation No. 300/2007) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
111-30-8 0,05 ppm 0,42 mg/m3 S
0,21 mg/m3
- Switzerland (SUVA 2015) :
CAS VME VLE Valeur plafond Notations
111-30-8 0,05 ppm 0,1 ppm S SSC
0,21 mg/m3 0,42 mg/m3
- UK / WEL (Workplace exposure limits, EH40/2005, 2007) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
111-30-8 0,05 ppm 0,05 ppm Sen
0,2 mg/m3 0,2 mg/m3
- Germany - AGW (BAuA - TRGS 900, 21/06/2010) :
CAS VME : VME : Excess Notes
111-30-8 0,05 ppm 2(I)
0,2 mg/m3
8.2. Exposure controls
Suitable technical inspections
Ensure the rooms are well-ventilated. Atmospheric concentrations at the workplace must not exceed the limit values given for normal conditions
of use.
Personal protection measures, such as personal protective equipment
Use personal protective equipment that is clean and has been properly maintained. Store
personal protective equipment in a clean place, away from the work area.
Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using. Ensure that there is adequate ventilation, especially in confined
areas.
- Eye / face protection
 Before handling, wear safety goggles with protective sides accordance with standard EN166. Prescription
glasses are not considered as protection.
Avoid all contact with skin or eyes.
Make gloves and safety goggles with side protection available to the personnel. Provide
eye washes in workshops.
If necessary, the nearest water supply
- Hand protection
Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN374. Gloves must
be selected according to the application and duration of use at the workstation.
Protective gloves need to be selected according to their suitability for the workstation in question : other chemical products that may be handled, necessary
physical protections (cutting, pricking, heat protection), level of dexterity required.
When handling this product, wear suitable gloves. Butyl
or nitrile gloves are recommended.
Gloves must be replaced immediately if they show signs of wear and tear.
- Body protection
Avoid skin contact.
Work clothing worn by personnel shall be laundered regularly.
After contact with the product, all parts of the body that have been soiled must be washed. Change
wet and dirty work clothes immediately.
- Respiratory protection
In case of insufficient ventilation, with the risk of exceeding the TLVs (Treshold Limit Values)/TWA, wear suitable breathing apparatus. Use Type
A1P1 or A2P2 filtres.

9.1. Information on basic physical and chemical properties

General information :
Physical state : Fluid liquid.
Odour: typical
Colour: green
Important health, safety and environmental information
pH : 6.00 .
Neutral.
Boiling point/boiling range : Not specified.
Flash point interval : Not relevant.
Vapour pressure (50°C) : Not relevant.
Density : +/- 1.0
Water solubility : Soluble.
Melting point/melting range : Not specified.
Self-ignition temperature : Not specified.
Decomposition point/decomposition range : Not specified.
9.2. Other information
The pH stated in section 9.1 is an indicative value. Below the minimum and maximum product pH:
pH pure product: 5.5 - 6.5

10.1. Reactivity
No hazardous reaction if the instructions/indications for storage and handling are respected.
10.2. Chemical stability
This mixture is stable under the recommended handling and storage conditions in section 7.
10.3. Possibility of hazardous reactions
Cf. § 10.1 and 10.2
10.4. Conditions to avoid
Avoid :
- frost
Do not mix with other products.
10.5. Incompatible materials
Latex
Refer to the scientific folder*: product/material compatibility table
* available on request
10.6. Hazardous decomposition products
At high temperatures, dangerous decomposition products may be produced, such as fumes, carbon dioxide and carbon monoxide, nitrogen oxide.

11.1. Information on toxicological effects

11.1.1. Substances
Not specified
11.1.2. Mixture
The toxicological data of the mixture (resulting from studies or in accordance with conventional methods) are outlined below.
Acute toxicity :
Acute toxicity estimate (ATE)* :
Oral ATE : > 2000 mg/kg
* according to the method of calculation describe in the CLP regulation (Classification, Labelling, Packaging) Part 3 Chapter 3.1 based on the data of the
different components present in the product.
Inhalation may lead to irritation of the respiratory tracts.
Sore throat, coughing, shortness of breath, respiratory failure
If swallowed: burns to upper digestive and respiratory tract, abdominal pain, vomiting blood, serious lesions to mucous membranes and risk of perforation.
Skin corrosion/skin irritation :
Skin irritation: itching, light to moderate local redness, burning sensation…
Serious damage to eyes/eye irritation :
Serious eyes damage.
Burns, characterized by discomfort or pain, excessive blinking, lacrimation and redness, swelling of the conjunctiva.
Respiratory or skin sensitisation :
Product not classified in this hazard category.
Germ cell mutagenicity :
Product not classified in this hazard category.
Carcinogenicity :
Product not classified in this hazard category.
Reproductive toxicant :
Product not classified in this hazard category.
Specific target organ systemic toxicity - single exposure :
Product not classified in this hazard category.
Specific target organ systemic toxicity - repeated exposure :
Product not classified in this hazard category.
Aspiration hazard :
Product not classified in this hazard category.
Other information
Repeated or prolonged exposure may lead to sensitization by inhalation (risk of asthma) and by skin contact (risk of eczema).

12.1. Toxicity
12.1.1. Substances
Not specified
12.1.2. Mixtures
The mixture has not been classified as an environmental hazard, in compliance with EC regulation 1272/2008.
12.2. Persistence and degradability
No data available.
12.3. Bioaccumulative potential
No data available.
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
No data available.
12.6. Other adverse effects
No data available.
 Proper waste management of the mixture and/or its container must be determined in accordance with Directive 2008/98/EC.
The packages must not be reused.
Do not pour into waterways.
13.1. Waste treatment methods
Waste :
Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air,
soil, plants or animals.
Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.
Soiled packaging :
Empty container completely. Keep label(s) on container. Give to a
certified disposal contractor.
Codes of wastes (Decision 2001/573/EC, Directive 2006/12/EEC, Directive 94/31/EEC on hazardous waste) :
18 01 06 * chemicals consisting of or containing dangerous substances For
information :
The waste code is given for indicative purposes.
The waste code must be determined by the user, according to the application of the product.
18 = Wastes from human or animal health care and/or related research (except kitchen and restaurant wastes not arising from immediate health care)

Exempt from transport classification and labelling.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
- Classification and labelling information included in section 2:
Regulation (EC) No. 1272/2008 and its amendments.
15.2. Chemical safety assessment
Information from the chemical safety assessment of substances present in the product is included in the appropriate sections of this safety data sheet, whenever
necessary.

Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of
knowledge and on national and community regulations.
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations. The information
in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture.
It is recommended that the information contained in this safety data sheet is provided to the users, if necessary in an appropriate form.
This information relates to the specifically designated product and may not be valid in combination with any another product. The product must not be used for
applications other than those specified in heading 1 without having first obtained written handling instructions.
UPDATES SINCE PREVIOUS VERSION
-§9
- § 11
Wording of the phrases mentioned in section 3 :
H290 May be corrosive to metals.
H301 Toxic if swallowed.
H301 + H331 Toxic if swallowed or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H331 Toxic if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
Abbreviations :
ADR : European agreement concerning the international carriage of dangerous goods by Road. IMDG :
International Maritime Dangerous Goods.
IATA : International Air Transport Association. ICAO :
International Civil Aviation Organisation
RID : Regulations concerning the International carriage of Dangerous goods by rail. GHS05 :
Corrosion
GHS07 : Exclamation mark GHS08
: Health hazard
SAFETY DATA SHEET (REGULATION (EC) n° 1907/2006 - REACH) Version 17.2 (22-12-2016) - Page 1/9
ANIOSYME DD1 - 1200000

SAFETY DATA SHEET

(REACH regulation (EC) n° 1907/2006 - n° 2015/830)

1.1. Product identifier

Product name : ANIOSYME DD1
Product code : 1200000.
1.2. Relevant identified uses of the substance or mixture and uses advised against
Cleaning and pre-disinfection of medical devices
For further information on product indication, please see the label.
1.3. Details of the supplier of the safety data sheet
Registered company name : Laboratoires ANIOS.
Address : PAVE DU MOULIN .59260.LILLE - HELLEMMES.FRANCE.
Telephone : + 33 (0)3 20 67 67 67. Fax : + 33 (0)3 20 67 67 68.
e:mail : fds@anios.com
www.anios.com
1.4. Emergency telephone number : + 33(0)1 45 42 59 59.
Association/Organisation : INRS.
Other emergency numbers
New Zealand: 0800 764 766 (National Poisons centre)
Australia : 13 11 26 (National Poisons centre)

2.1. Classification of the substance or mixture

In compliance with EC regulation No. 1272/2008 and its amendments.
Skin corrosion, Category 1B (Skin Corr. 1B, H314). May
produce an allergic reaction (EUH208).
Hazardous to the aquatic environment - Acute hazard, Category 1 (Aquatic Acute 1, H400). Hazardous to the
aquatic environment - Chronic hazard, Category 1 (Aquatic Chronic 1, H410).
This mixture does not present a physical hazard. Refer to the recommendations regarding the other products present on the site.
2.2. Label elements
Detergent mixture (see section 15).
This mixture being intended for professional use only, the labelling for contents under detergent regulation does not appear on the label but is resumed in section
15
In compliance with EC regulation No. 1272/2008 and its amendments.
Hazard pictograms :

GHS05 GHS09

Signal Word :
DANGER
Product identifiers :
EC 619-057-3 N,N-DIDECYL-N-METHYL-POLY(OXYETHYL)AMMONIUM PROPIONATE
EC 239-032-7 SODIUM N-(2-CARBOXYETHYL)-N-DODECYL-ß-ALANINATE
Additional labeling :
EUH208 Contains POLYHEXAMETHYLENE BIGUANIDE HYDROCHLORIDE. May produce an allergic reaction.
Hazard statements :

Made under licence of European Label System, Software of INFODYNE (http://www.infodyne.fr)

Quick-FDS [17959-11292-12790-010562] - 2017-03-02 - 03:08:12

 H314 Causes severe skin burns and eye damage.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements - General :
P102 Keep out of reach of children.
Precautionary statements - Prevention :
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statements - Response :
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
Precautionary statements - Disposal :
P501 Dispose of unused product and its container as hazardous waste.
2.3. Other hazards
The mixture does not contain substances classified as ‘Substances of Very High Concern' (SVHC) >= 0.1% published by the European CHemicals Agency
(ECHA) under article 57 of REACH: http://echa.europa.eu/fr/candidate-list-table
No other hazard identified in the current state of knowledge.

Title for H and EUH statements: see § 16.

3.2. Mixtures
Composition :
Identification (EC) 1272/2008 Note %
CAS: 57-55-6 [1] 10 <= x % < 25
EC: 200-338-0
REACH: 01-2119456809-23

PROPYLENE GLYCOL
CAS: 94667-33-1 GHS07, GHS05, GHS09 2.5 <= x % < 10
EC: 619-057-3 Dgr
REACH: 01-2119950327-36 Acute Tox. 4, H302
Skin Corr. 1B, H314
N,N-DIDECYL-N-METHYL-POLY(OXYET Aquatic Acute 1, H400
HYL)AMMONIUM PROPIONATE M Acute = 10
Aquatic Chronic 1, H410
M Chronic = 10

CAS: 14960-06-6 GHS05 2.5 <= x % < 10

EC: 239-032-7 Dgr
REACH: 01-2119980040-48 Skin Irrit. 2, H315
Eye Dam. 1, H318
SODIUM
N-(2-CARBOXYETHYL)-N-DODECYL-ß-
ALANINATE
CAS: 69011-36-5 GHS07, GHS05 2.5 <= x % < 10
Dgr
ETHOXYLATED ISOTRIDECANOL Acute Tox. 4, H302
Eye Dam. 1, H318

CAS: 7631-99-4 GHS07, GHS03 2.5 <= x % < 10

EC: 231-554-3 Dgr
REACH: 01-2119488221-41 Ox. Liq. 2, H272
Eye Irrit. 2, H319
SODIUM NITRATE
CAS: 75-75-2 GHS05 [1] 0 <= x % < 2.5
EC: 200-898-6 Dgr
REACH: 01-2119491166-34 Met. Corr. 1, H290
Skin Corr. 1B, H314
METHANESULPHONIC ACID
 CAS: 27083-27-8 GHS06, GHS05, GHS09, GHS08 [2] 0 <= x % < 2.5
Dgr
POLYHEXAMETHYLENE BIGUANIDE Acute Tox. 4, H302
HYDROCHLORIDE Skin Sens. 1, H317
Eye Dam. 1, H318
Acute Tox. 2, H330
Carc. 2, H351 STOT
RE 1, H372
Aquatic Acute 1, H400 M
Acute = 10
Aquatic Chronic 1, H410 M
Chronic = 10

Information on ingredients :
[1] Substance for which maximum workplace exposure limits are available.
[2] Carcinogenic, mutagenic or reprotoxic (CMR) substance.
CAS: 107-21-1 REACH: 2119456816-28 GHS07 GHS08 Wng Acute Tox. 4 : H302 ; STOT RE 2 : H373 [1]
x%<1
[1] Substance for which there are exposure limits in the workplace.

As a general rule, in case of doubt or if symptoms persist, always call a doctor.

NEVER induce swallowing by an unconscious person.
Reminder: any unconscious person must be placed in the lateral recovery position.
4.1. Description of first aid measures
In the event of exposure by inhalation :
Move the person away from the place of exposure and take him/her outside.
In the event of respiratory problems (e.g. heavy coughing):
Put the person in a half-seated position, with the torso raised ; keep the person warm and calm. Call a doctor
immediately.
In the event of splashes or contact with eyes :
If applicable, remove contact lenses.
Wash thoroughly with soft clean water for 15 minutes, holding the eyelids open. Take
care not to introduce rinsing water in the undamaged eye.
Additional treatment to be provided immediately in an eye clinic or by an ophthalmologist. Show this container or label. Continue rinsing
until medical advice is obtained.
In the event of splashes or contact with skin :
If possible, wear rubber gloves when giving first aid.
Remove all contaminated or stained clothing immediately. Do not use them again until they have been decontaminated. Rinse thoroughly
with water during 15 minutes.
If the contaminated area is widespread and/or there is damage to the skin, call the service N°100, an hospitalisation is required. Show the label to the doctor.
In the event of swallowing :
Rinse out the mouth, do not allow to drink, do not induce vomiting. Calm the person down and transfer immediatly to hospital or doctor. Show the label to the
doctor.
4.2. Most important symptoms and effects, both acute and delayed
Cf. § 11
4.3. Indication of any immediate medical attention and special treatment needed
Refer to the recommendation of the doctor.

5.1. Extinguishing media

Suitable methods of extinction
Any extinguishing agents are authorized: foam, sand, carbon dioxide, water, powder.
5.2. Special hazards arising from the substance or mixture
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.
 Do not breathe in smoke.
5.3. Advice for firefighters
Use autonomous insulating breathing apparatus and a full protective suit.

6.1. Personal precautions, protective equipment and emergency procedures

Consult the safety measures listed under headings 7 and 8. Avoid
all contact with skin or eyes.
Keep away any unprotected person.
6.2. Environmental precautions
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for waste
disposal.
Do not get rid in natural spaces (waterways, ground and vegetations...)
6.3. Methods and material for containment and cleaning up
Absorb any spilled product with absorbent non-combustible materials, and sweep away or remove with a shovel. Put any waste in drums for disposal. Do not
mix with any other waste. Wash the contaminated surface thoroughly with water.
Do not put any spilt product back into its original container with the intention of re-use. Do not
get rid in natural spaces.
6.4. Reference to other sections
Disposal considerations: see section 13.

7.1. Precautions for safe handling Product

for external use - do not swallow. Avoid all
contact with skin or eyes.
Handle in accordance with user instructions on label
Fire prevention :
Prevent access by unauthorised personnel.
Recommended equipment and procedures :
For personal protection, see section 8.
Observe precautions stated on label and also industrial safety regulations. Water
source nearby.
Change any contaminated or wet work clothes immediately.
Prohibited equipment and procedures :
No smoking, eating or drinking in areas where the mixture is used.
7.2. Conditions for safe storage, including any incompatibilities
Keep the container tightly closed Store
ONLY in the original package.
Store between + 5 °C and + 35 °C in a dry, well ventilated place Do not
use after the expiry date mentioned on the packaging.
Keep out of the reach of children
7.3. Specific end use(s)
For professional use only
Refer to paragraph 1 for product indication

The information in this chapter refers to the product specifically described in this document. If the product is handled and/or exposed
simultaneously with other chemical agents, these must be taken into consideration when choosing personal safety equipment.
The Exposure Threshold Limit Value and the Average Exposure Value given below are quoted by the CAS number of the substance. Paragraph 3 details the
chemical name corresponding to the CAS number.
8.1. Control parameters
Occupational exposure limits :
- Switzerland (SUVA 2015) :
CAS VME VLE Valeur plafond Notations
107-21-1 26 10 52 20 4x15 R
- Germany - AGW (BAuA - TRGS 900, 21/06/2010) :
CAS VME : VME : Excess Notes
75-75-2 0,7 mg/m3 1(I)
107-21-1 10 ml/m3 26 mg/m3 2(I) DFG, H, Y
- Slovakia (Regulation No. 300/2007) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
107-21-1 20 ppm 52 mg/m3 104 mg/m3
- Czech Republic (Regulation No. 361/2007) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
107-21-1 50 mg/m3 100 mg/m3 - - -
- Spain (Instituto Nacional de Seguridad e Higiene en el Trabajo (INSHT), Mayo 2010) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
107-21-1 20 ppm 40 ppm - - -
- Poland (2014) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
107-21-1 15 mg/m3 50 mg/m3 - - -
- Belgium (Order of 19/05/2009, 2010) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
107-21-1 - - 101 - -
- European Union (2009/161/EU, 2006/15/EC, 2000/39/EC, 98/24/EC)
CAS VME-mg/m3 : VME-ppm : VLE-mg/m3 : VLE-ppm : Notes :
107-21-1 52 20 104 40 Peau
- France (INRS - ED984 :2012) :
CAS VME-ppm : VME-mg/m3 : VLE-ppm : VLE-mg/m3 : Notes : TMP No :
107-21-1 20 52 40 104 * 84 -
- UK / WEL (Workplace exposure limits, EH40/2005, 2007) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
57-55-6 150 ppm
474 mg/m3
8.2. Exposure controls
Suitable technical inspections
Ensure the rooms are well-ventilated. Atmospheric concentrations at the workplace must not exceed the limit values given for normal conditions
of use.
Personal protection measures, such as personal protective equipment
Use personal protective equipment that is clean and has been properly maintained. Store
personal protective equipment in a clean place, away from the work area.
Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using. Ensure that there is adequate ventilation, especially in confined
areas.
- Eye / face protection
Before handling, wear safety goggles with protective sides accordance with standard EN166. Prescription
glasses are not considered as protection.
Avoid all contact with skin or eyes.
Make safety goggles with side protection available to the personnel.
Provide eye washes in workshops.
If necessary, the nearest water supply
- Hand protection
Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN374. Gloves must
be selected according to the application and duration of use at the workstation.
Protective gloves need to be selected according to their suitability for the workstation in question : other chemical products that may be handled, necessary
physical protections (cutting, pricking, heat protection), level of dexterity required.
When handling this product, suitable gloves have to be worn.
Neoprene or nitrile gloves are particularly recommended.
Gloves must be replaced immediately if they show signs of wear and tear.
- Body protection
Avoid skin contact.
Work clothing worn by personnel shall be laundered regularly.
After contact with the product, all parts of the body that have been soiled must be washed. Change
wet and dirty work clothes immediately.
HEALTH MEASURES:
Do not eat, drink or smoke during use.
Wash hands each time after handling.
After each use, systematically wash all personal protective equipment.
- Respiratory protection
In case of insufficient ventilation, with the risk of exceeding the TLVs (Threshold Limit values)/TWA, wear suitable breathing apparatus (mask
 which filters organic vapours - type A protection)

9.1. Information on basic physical and chemical properties

General information :
Physical state : Fluid liquid.
Odour: sweet-smelling
Colour: blue
Important health, safety and environmental information
pH : 6.00 .
Neutral.
Boiling point/boiling range : Not specified.
Flash point interval : Not relevant.
Vapour pressure (50°C) : Not relevant.
Density : +/- 1.1
Water solubility : Soluble.
Melting point/melting range : Not specified.
Self-ignition temperature : Not specified.
Decomposition point/decomposition range : Not specified.
9.2. Other information
The pH stated in section 9.1 is an indicative value. Below the minimum and maximum product pH:
pH pure product: 5,7 - 6,3

10.1. Reactivity
No hazardous reaction if the instructions/indications for storage and handling are respected.
10.2. Chemical stability
This mixture is stable under the recommended handling and storage conditions in section 7.
10.3. Possibility of hazardous reactions
Cf. § 10.1 and 10.2
10.4. Conditions to avoid
Avoid :
- frost
Do not mix with other products.
10.5. Incompatible materials
Refer to the scientific folder*: product/material compatibility table
* available on request
10.6. Hazardous decomposition products
At high temperatures, dangerous decomposition products may be produced, such as fumes, carbon dioxide and carbon monoxide, nitrogen oxide.

11.1. Information on toxicological effects

11.1.1. Substances
Not specified
11.1.2. Mixture
The toxicological data of the mixture (resulting from studies or in accordance with conventional methods) are outlined below.
Acute toxicity :
Acute toxicity estimate (ATE)* :
Oral ATE : > 2000 mg/kg
* according to the method of calculation describe in the CLP regulation (Classification, Labelling, Packaging) Part 3 Chapter 3.1 based on the data of the
different components present in the product.
If swallowed: burns to upper digestive and respiratory tract, abdominal pain, vomiting blood, serious lesions to mucous membranes and risk of perforation.
Skin corrosion/skin irritation :
Severe skin irritation, burns, redness, dermatitis, necrosis of tissue.
Serious damage to eyes/eye irritation :
 Serious eyes damage.
Burns, characterized by discomfort or pain, excessive blinking, lacrimation and redness, swelling of the conjunctiva.
Respiratory or skin sensitisation :
Contains at least one sensitising substance. May cause an allergic reaction.
Germ cell mutagenicity :
Product not classified in this hazard category.
Carcinogenicity :
Product not classified in this hazard category.
Reproductive toxicant :
Product not classified in this hazard category.
Specific target organ systemic toxicity - single exposure :
Product not classified in this hazard category.
Specific target organ systemic toxicity - repeated exposure :
Product not classified in this hazard category.
Aspiration hazard :
Product not classified in this hazard category.

Following information is based on data from the compounds.

Avoid any product release into waterways.
12.1. Toxicity
12.1.1. Substances
Not specified
12.1.2. Mixtures
Acute toxicity:
Very toxic to aquatic organisms.
Chronic toxicity:
Very toxic to aquatic life with long lasting effects.
12.2. Persistence and degradability
The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents.
Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct
request or at the request of a detergent manufacturer.
12.3. Bioaccumulative potential
No data available.
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
No data available.
12.6. Other adverse effects
No data available.

Proper waste management of the mixture and/or its container must be determined in accordance with Directive 2008/98/EC.
The packages must not be reused.
Do not pour into waterways.
13.1. Waste treatment methods
Waste :
Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air,
soil, plants or animals.
Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.
Soiled packaging :
Empty container completely. Keep label(s) on container. Give to a
certified disposal contractor.
Codes of wastes (Decision 2001/573/EC, Directive 2006/12/EEC, Directive 94/31/EEC on hazardous waste) :
18 01 06 * chemicals consisting of or containing dangerous substances For
information :
 The waste code is given for indicative purposes.
The waste code must be determined by the user, according to the application of the product.
18 = Wastes from human or animal health care and/or related research (except kitchen and restaurant wastes not arising from immediate health care)

Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and ICAO/IATA for air transport (ADR 2015 -
IMDG 2014 - ICAO/IATA 2016).
14.1. UN number
1903
14.2. UN proper shipping name
UN1903=DISINFECTANT, LIQUID, CORROSIVE, N.O.S.
(n,n-didecyl-n-methyl-poly(oxyethyl)ammonium propionate, sodium n-(2-carboxyethyl)-n-dodecyl-ß-alaninate)
14.3. Transport hazard class(es)
- Classification :

8
14.4. Packing group
III
14.5. Environmental hazards
- Environmentally hazardous material :

14.6. Special precautions for user

ADR/RID Class Code Pack gr. Label Ident. LQ Provis. EQ Cat. Tunnel
8 C9 III 8 80 5L 274 E1 3 E
IMDG Class 2°Label Pack gr. LQ EMS Provis. EQ
8 - III 5L F-A,S-B 223 274 E1
IATA Class 2°Label Pack gr. Passager Passager Cargo Cargo note EQ
8 - III 852 5L 856 60 L A3 A803 E1
8 - III Y841 1L - - A3 A803 E1
For limited quantities, see part 2.7 of the OACI/IATA and chapter 3.4 of the ADR and IMDG. For
excepted quantities, see part 2.6 of the OACI/IATA and chapter 3.5 of the ADR and IMDG.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
- Classification and labelling information included in section 2:
The following regulations have been used:
Regulation (EC) No. 1272/2008 and its amendments.
- Labelling for detergents (EC Regulation No. 648/2004,907/2006) :
- 5 % or over but less than 15 % : amphoteric surfactants
- 5 % or over but less than 15 % : nonionic surfactants
- enzymes
- disinfectants
- perfumes
15.2. Chemical safety assessment
Information from the chemical safety assessment of substances present in the product is included in the appropriate sections of this safety data sheet, whenever
necessary.
 Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of
knowledge and on national and community regulations.
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations.
It is recommended that the information contained in this safety data sheet is provided to the users, if necessary in an appropriate form.
This information relates to the specifically designated product and may not be valid in combination with any another product. The product must not be used for
applications other than those specified in heading 1 without having first obtained written handling instructions.
The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture. UPDATES SINCE
PREVIOUS VERSION
- § 11
-§9
- § 15
Wording of the phrases mentioned in section 3 :
H272 May intensify fire; oxidiser.
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H351 Suspected of causing cancer .
H372 Causes damage to organs through prolonged or repeated exposure .
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Abbreviations :
CMR: Carcinogenic, mutagenic or reprotoxic.
ADR : European agreement concerning the international carriage of dangerous goods by Road. IMDG :
International Maritime Dangerous Goods.
IATA : International Air Transport Association. ICAO :
International Civil Aviation Organisation
RID : Regulations concerning the International carriage of Dangerous goods by rail. GHS05 :
Corrosion
GHS09 : Environment
Safety data sheet

Page: 1/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 15.12.2015 Version: 6.0
Product: PVP-Iodine 30/06
(ID no. 30034963/SDS_GEN_EU/EN)
Date of print 16.12.2015

SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier

PVP-Iodine 30/06
Chemical name: 2-Pyrrolidinone, 1-ethenyl-, homopolymer, compd. with iodine CAS
Number: 25655-41-8

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: Pharmaceutical agent

1.3. Details of the supplier of the safety data sheet

Company:
BASF SE
67056 Ludwigshafen
GERMANY
Operating Division Nutrition and Health

Telephone: +49 621 60-48434

E-mail address: EN-global-safety-data@basf.com

1.4. Emergency telephone number

International emergency number:

Telephone: +49 180 2273-112

SECTION 2: Hazards Identification

2.1. Classification of the substance or mixture

According to Regulation (EC) No 1272/2008 [CLP]

 Page: 2/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time. Date /
Revised: 15.12.2015 Version: 6.0
Product: PVP-Iodine 30/06
(ID no. 30034963/SDS_GEN_EU/EN)
Date of print 16.12.2015
Skin Corr./Irrit. 2
Eye Dam./Irrit. 1
Aquatic Chronic 2 H318,

H315, H411

For the classifications not written out in full in this section the full text can be found in section 16.

2.2. Label elements

Globally Harmonized System, EU (GHS)

Pictogram:

Signal Word:
Danger

Hazard Statement:
H318 Causes serious eye damage.
H315 Causes skin irritation.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements (Prevention):

P280 Wear eye/face protection.
P280 Wear protective gloves.
P273 Avoid release to the environment.
P264 Wash with plenty of water and soap thoroughly after handling.

Precautionary Statements (Response):

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
P391 Collect spillage.
P362 + P364 Take off contaminated clothing and wash it before reuse.

Precautionary Statements (Disposal):

P501 Dispose of contents/container to hazardous or special waste collection
point.

2.3. Other hazards

According to Regulation (EC) No 1272/2008 [CLP]

 Page: 3/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time. Date /
Revised: 15.12.2015 Version: 6.0
Product: PVP-Iodine 30/06
(ID no. 30034963/SDS_GEN_EU/EN)
Date of print 16.12.2015
The product is under certain conditions capable of dust explosion.

SECTION 3: Composition/Information on Ingredients

3.1. Substances

Chemical nature

Complex of polyvinylpyrrolidinone and iodine

CAS Number: 25655-41-8

For the classifications not written out in full in this section, including the hazard classes and the hazard
statements, the full text is listed in section 16.

3.2. Mixtures

Not applicable

SECTION 4: First-Aid Measures

4.1. Description of first aid measures
Remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Wash thoroughly with soap and water.

On contact with eyes:

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult
an eye specialist.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section
2) and/or in section 11.

4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Symptomatic treatment (decontamination, vital functions).
 Page: 4/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time. Date /
Revised: 15.12.2015 Version: 6.0
Product: PVP-Iodine 30/06
(ID no. 30034963/SDS_GEN_EU/EN)
Date of print 16.12.2015
SECTION 5: Fire-Fighting Measures
5.1. Extinguishing media
Suitable extinguishing media:
water spray, carbon dioxide, dry powder, Dry sand, foam

Unsuitable extinguishing media for safety reasons:

water jet

5.2. Special hazards arising from the substance or mixture

Hydrogen cyanide, iodine, Carbon dioxide, nitrogen oxides

5.3. Advice for fire-fighters

Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

SECTION 6: Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures
Use breathing apparatus if exposed to vapours/dust/aerosol. Ensure adequate ventilation. Avoid contact
with the skin, eyes and clothing.

6.2. Environmental precautions

Do not discharge into drains/surface waters/groundwater.

6.3. Methods and material for containment and cleaning up

For large amounts: Sweep/shovel up. Dispose of absorbed material in accordance with regulations. For
residues: Sweep/shovel up. Dispose of absorbed material in accordance with regulations.
Avoid raising dust. Ensure adequate ventilation.

6.4. Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be found in
section 8 and 13.

SECTION 7: Handling and Storage

7.1. Precautions for safe handling
Provide good ventilation when handling large quantities. Use only nitrogen for pneumatic conveying. Avoid
contact with the skin, eyes and clothing.

Protection against fire and explosion:

Avoid dust formation. Prevent electrostatic charge - sources of ignition should be kept well clear - fire
extinguishers should be kept handy.
 Page: 5/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time. Date /
Revised: 15.12.2015 Version: 6.0
Product: PVP-Iodine 30/06
(ID no. 30034963/SDS_GEN_EU/EN)
Date of print 16.12.2015
7.2. Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep container tightly closed and dry; store in a cool place.

7.3. Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.

SECTION 8: Exposure Controls/Personal Protection

8.1. Control parameters

Components with occupational exposure limits

64-18-6: formic acid...%

TWA value 9 mg/m3 ; 5 ppm (OEL (EU))
indicative

8.2. Exposure controls

Personal protective equipment
Respiratory protection:
Breathing protection if breathable aerosols/dust are formed. Particle filter with low efficiency for solid
particles (e.g. EN 143 or 149, Type P1or FFP1)

Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended:
Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile
rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) etc.
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature)
it must be considered, that the practical usage of a chemical-protective glove in practice may be much
shorter than the permeation time determined through testing.

Eye protection:
Tightly fitting safety goggles (splash goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots,
chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Remove contaminated clothing.
Hands and/or face should be washed before breaks and at the end of the shift. Preventive skin protection by
use of skin-protecting agents is recommended.
 Page: 6/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time. Date /
Revised: 15.12.2015 Version: 6.0
Product: PVP-Iodine 30/06
(ID no. 30034963/SDS_GEN_EU/EN)
Date of print 16.12.2015

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Form: amorphous powder

Colour: brown
Odour: faint specific odour, characteristic
Odour threshold:
not determined
pH value: 1.5 - 2.5
(100 g/l, 20 °C)
melting point (decomposition): > 350 °C
Boiling point:
dropped
Flash point:
not applicable
Evaporation rate:
negligible
Flammability: not applicable
Lower explosion limit:
For solids not relevant for
classification and labelling.
Upper explosion limit:
For solids not relevant for
classification and labelling.
Ignition temperature:
not determined
Vapour pressure: < 0.1 hPa
(approx. 20 °C)
Relative vapour density (air):
not relevant
Solubility in water: readily soluble
200 g/l
(20 °C)
Solubility (qualitative) solvent(s): ethanol; ethyl alcohol
soluble
Partitioning coefficient n-octanol/water (log Kow): 0.81
Self ignition: Based on its structural properties the
product is not classified as self- igniting.

Thermal decomposition: > 350 °C

Viscosity, dynamic:
not relevant
Explosion hazard: not explosive
Fire promoting properties: not fire-propagating

9.2. Other information

 Page: 7/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time. Date /
Revised: 15.12.2015 Version: 6.0
Product: PVP-Iodine 30/06
(ID no. 30034963/SDS_GEN_EU/EN)
Date of print 16.12.2015
Bulk density: 450 kg/m3

SECTION 10: Stability and Reactivity

10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals: Corrosive effects to metal are not anticipated.

10.2. Chemical stability

The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions

Dust explosion hazard.

10.4. Conditions to avoid

Avoid dust formation. Avoid electro-static charge. Avoid all sources of ignition: heat, sparks, open flame.

10.5. Incompatible materials

Substances to avoid:
reducing agents, metal

10.6. Hazardous decomposition products

Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.

SECTION 11: Toxicological Information

11.1. Information on toxicological effects

Acute toxicity

Assessment of acute toxicity:

Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact.

Experimental/calculated data:
LD50 rat (oral): > 4,640 mg/kg

LD50 rat (dermal): > 2,500 mg/kg (BASF-Test)

Irritation

Assessment of irritating effects:

Irritating to skin. Risk of serious damage to eyes.
 Page: 8/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time. Date /
Revised: 15.12.2015 Version: 6.0
Product: PVP-Iodine 30/06
(ID no. 30034963/SDS_GEN_EU/EN)
Date of print 16.12.2015

Experimental/calculated data:
Skin corrosion/irritation rabbit: Irritant. (OECD Guideline 404)

Serious eye damage/irritation rabbit: Risk of serious damage to eyes. (OECD Guideline 405)

Respiratory/Skin sensitization

Assessment of sensitization:
Skin sensitizing effects were not observed in animal studies.

Experimental/calculated data:
Guinea pig maximization test guinea pig: Non-sensitizing. (OECD Guideline 406) Germ

cell mutagenicity

Assessment of mutagenicity:
Most of the results from the available studies show no evidence of a mutagenic effect.

Carcinogenicity

Assessment of carcinogenicity:
No data available concerning carcinogenic effects.

Reproductive toxicity

Assessment of reproduction toxicity:

No data available.

Developmental toxicity

Assessment of teratogenicity:
No indications of a developmental toxic / teratogenic effect were seen in animal studies.

Aspiration hazard

No data available.

SECTION 12: Ecological Information

12.1. Toxicity

Assessment of aquatic toxicity:

Acutely toxic for aquatic organisms. The inhibition of the degradation activity of activated sludge is not
anticipated when introduced to biological treatment plants in appropriate low concentrations.

Toxicity to fish:
LC50 (96 h) > 4.6 - 10 mg/l, Leuciscus idus (DIN 38412 Part 15, static)
 Page: 9/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time. Date /
Revised: 15.12.2015 Version: 6.0
Product: PVP-Iodine 30/06
(ID no. 30034963/SDS_GEN_EU/EN)
Date of print 16.12.2015
The details of the toxic effect relate to the nominal concentration.

Aquatic invertebrates:
EC50 (48 h) 2.79 mg/l, Daphnia magna (OECD Guideline 202, part 1, static) The
details of the toxic effect relate to the nominal concentration.

Aquatic plants:
EC50 (72 h) 4.91 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static) The
statement of the toxic effect relates to the analytically determined concentration.

Microorganisms/Effect on activated sludge:

EC10 (17 h) 270 mg/l, Pseudomonas putida (DIN 38412 Part 8, aerobic) The
details of the toxic effect relate to the nominal concentration.

12.2. Persistence and degradability

Assessment biodegradation and elimination (H2O):

Not readily biodegradable (by OECD criteria). Poorly biodegradable. Poorly eliminated from water.

Elimination information:
< 20 % DOC reduction (3 h) (OECD Guideline 302 B) (aerobic, activated sludge, domestic, adapted)

< 10 % (28 d) (ISO 14593) (aerobic, activated sludge, domestic)

12.3. Bioaccumulative potential

Assessment bioaccumulation potential:

The product has not been tested.

12.4. Mobility in soil

Assessment transport between environmental compartments:

Adsorption in soil: Adsorption to solid soil phase is not expected.

12.5. Results of PBT and vPvB assessment

According to Annex XIV of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance fulfilling
the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/very bioaccumulative)
criteria. Self classification

12.6. Other adverse effects

The substance is not listed in Regulation (EC) 1005/2009 on substances that deplete the ozone layer.

SECTION 13: Disposal Considerations

13.1. Waste treatment methods

 Page: 10/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time. Date /
Revised: 15.12.2015 Version: 6.0
Product: PVP-Iodine 30/06
(ID no. 30034963/SDS_GEN_EU/EN)
Date of print 16.12.2015

Observe national and local legal requirements.

SECTION 14: Transport Information

Land transport

ADR
UN number UN3077
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(contains POLYVINYLPYRROLIDONE IODINE COMPLEX)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for Tunnel code: E
user:

RID
UN number UN3077
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(contains POLYVINYLPYRROLIDONE IODINE COMPLEX)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for None known
user:

Inland waterway transport

ADN
UN number UN3077
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(contains POLYVINYLPYRROLIDONE IODINE COMPLEX)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for None known
user:

Transport in inland waterway vessel

Not evaluated

Sea transport
 Page: 11/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time. Date /
Revised: 15.12.2015 Version: 6.0
Product: PVP-Iodine 30/06
(ID no. 30034963/SDS_GEN_EU/EN)
Date of print 16.12.2015
IMDG
UN number: UN 3077
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(contains POLYVINYLPYRROLIDONE IODINE COMPLEX)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Marine pollutant: YES
Special precautions for None known
user:

Air transport

IATA/ICAO
UN number: UN 3077
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(contains POLYVINYLPYRROLIDONE IODINE COMPLEX)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for None known
user:

14.1. UN number
See corresponding entries for “UN number” for the respective regulations in the tables above.

14.2. UN proper shipping name

See corresponding entries for “UN proper shipping name” for the respective regulations in the tables above.

14.3. Transport hazard class(es)

See corresponding entries for “Transport hazard class(es)” for the respective regulations in the tables
above.

14.4. Packing group

See corresponding entries for “Packing group” for the respective regulations in the tables above.

14.5. Environmental hazards

See corresponding entries for “Environmental hazards” for the respective regulations in the tables above.

14.6. Special precautions for user

See corresponding entries for “Special precautions for user” for the respective regulations in the tables
above.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
 Page: 12/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time. Date /
Revised: 15.12.2015 Version: 6.0
Product: PVP-Iodine 30/06
(ID no. 30034963/SDS_GEN_EU/EN)
Date of print 16.12.2015
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated

SECTION 15: Regulatory Information

15.1. Safety, health and environmental regulations/legislation specific for
the substance or mixture

If other regulatory information applies that is not already provided elsewhere in this safety data sheet,
then it is described in this subsection.

15.2. Chemical Safety Assessment

Chemical Safety Assessment not required

SECTION 16: Other Information

Any other intended applications should be discussed with the manufacturer. Corresponding
occupational protection measurements must be followed.

Full text of the classifications, including the hazard classes and the hazard statements, if mentioned in section
2 or 3:
Skin Corr./Irrit. Skin corrosion/irritation
Eye Dam./Irrit. Serious eye damage/eye irritation
Aquatic Chronic Hazardous to the aquatic environment - chronic
H318 Causes serious eye damage.
H315 Causes skin irritation.
H411 Toxic to aquatic life with long lasting effects.

The data contained in this safety data sheet are based on our current knowledge and experience and describe the
product only with regard to safety requirements. The data do not describe the product's properties (product
specification). Neither should any agreed property nor the suitability of the product for any specific purpose be
deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to
ensure any proprietary rights and existing laws and legislation are observed.

Vertical lines in the left hand margin indicate an amendment from the previous version.