allowed: 3 hours

Time
Maximum marks: 70

SECTION-A
Theallowing questions
are multnple-choice
questions with one correct answer. Each question carries
There is no internal choice in this section.
I mark.
1The boiling points of alcohols are
higher than those of hydrocarbons of
due to:
comparable masses
(a) Hydrogen bonding (b) lon - dipole interaction

Dipole- dipole interaction (d) Van der Waal's forces.

2. Which of the following isomer has the highest melting point?
(a) 1,2-dichlorobenzene
b) 1.3 -dichlorobenzene
c) 1,4-dichlorobenzene
(d) All isomers have same melting points.
3. Which one of the following does not correctly represent the correct order of the property
indicated against it?
(a) Ti<V<Cr< Mn, increasing number of oxidation states
(b) Ti<V<Mn < Cr, increasing second ionisation enthalpy
(c) Ti<V< Cr< Mn, increasing melting point
(d) Ti<y3<C3 < Mns*, increasing magnetic moment
order of the reaction is
4. The rate constant of reaction is 2.0x 10 molL' s.The
(a) 0 (b) 2

(c) 1 (d) 3

Which of the statements about solutions of electrolytes is not correct?

size of ions.
a)Conductivity of solution depends upon
b) Conductivity depends upon viscosity of solution.
solution.
solvation ofions presentin
Conductivity does not depend upon
onductivity of solution increases with temperature
6. For the reaction,
H)+Br,(g) 2HBr(g)
The experimental data suggests,
1
Rate k[H,J[Br,]2
reaction is
The molecularity and order for the
(b) 2 and 1
(a) 2 and 2

(d) 1 and 1
(c) 1 and 2

7. The IUPAC name of the organic compound which gives

propanamine by Hoffmann
degradation reaction is
(b) butanamide
(a) butanoic acid
c) butanamine (d) ethylbutanoate
8. Ambidentate ligands like N0, and SCN are:
(a)unidentate (b) didentate

(c) polydentate (d) has variable denticity

9. Mark the correct increasing order of reactivity of the following compounds with HBr/HCI.

CH OH CH,OH CHOH

NO2 Cl
II III
(a) I<II < III (b) Il<I < III|
(c) Il<III<I (d)II<II<I
10. A compound with molecular formula C3H,N reacts with CH SO,CI to give precipitate
which is insoluble in aqueous solution. The
compound is
(a) CH,tCHzNH2 (b) CHs-NH-CH
(c) (CHzN (d) (CHCH-NH,
11. The correct sequence of steps involved in the
mechanism of Cannizzaro's reaction is
(a) transfer of H", transfer of H" and
nucleophilic attack
(b) nucleophilic attack, transfer of Hand transfer of H
(c) electrophilic attack by OH , transfer
of H" and transfer of H
d) transfer of H', nucleophilic attack and transfer
of H
12. Rate law can be determined from balanced chemical
(a) reverse reaction is involved equation if
(b) it is an elementary reaction
(c) it is a sequence of
elementary reactions
(d) any of the reactants is in excess
 ahsorption maNima of several octahedral
13 complex ions are as follows:
S.No Compound
max (1nm)
Co(NH)* 475
2 ICo(CN),] 310
3 ICo(H,0),* 490
The crystal field splitting is maximum for:
a) [Co(H0),*
(b) [Co(CN),
c)[Co(NH)3
d All the complex ions have the same splitting,
A.
14. What the correct 1UPAC name of the given
is
compound?
CH3
CH-CCH2-CH3
COOH
(a) 2,2-Dimethylbutanoic acid (b) 2-Carboxyl-2-methylbutane
c)2-Ethyl-2-methylpropanoic acid (a) 3-Methylbutane carboxylic acid

In these questions (Q. No. 15 to 18), two statements are given - one labelled as Assertion (4) and the
other labelled Reason (R). Select the most appropriate answer from the options given below:
(a) Both A and R are true and R is the correct explanation ofA.
6) Both A and R are true but R is not the correct explanation ofA.
(c) A is true but R is false.
(d) Ais false but R is true.
15. Assertion (A) p-nitrophenol is more acidic than phenol.
ion by dispersal of
Reason (R): Nitro group helps in the stabilisation of the phenoxide
negative charge due to resonance.
16. Assertion (A) :The two strands of DNA are complementary.

Reason (R): Cytosine always pairs with guanine

and thymine pairs with adenine.
Assertion (A) :Cu salts are green in colour.
electron which cause d-d transition.
Reason (R) :Cu has one unpaired
Gabriel Phthalimide Synthesis.
Assertion (A) Aromatic 1° amines can not be prepared by
0
Reason (R) halides do not undergo nucleophilic substitution with the anion formed
Aryl
by phthalimide.

SECTION-B
The following questions are
This section contquestions with internal
ntains 7
choice in two questions.

type and carry 2 marks each.

Short answer
9. Calculate the time for 80% completion of the
reaction is 50% complete in 25 minutes.
order
reactíon.
 20. Define the following terms:
(b) Invert sugar
(a) Oligosaccharides
OR

(a) What is meantby the secondary structure of proteins?

(b) Write the products of hydrolysis of lactose.
chloride and chlorobenzene?
21. (a) How will you distinguish between benzyl
(b) Convert: Benzene to 4-bromonitrobenzene.
OR
(a) What are enantiomers? Draw the structures of the possible enantiomers of 3-methylpent-1.an.
ene.
(b) In the pair, (CH,),C-Br and CH-CH-Br, which one is more reactive towards S2 reaction
and why?
22. (a) Using crystal field theory,write the electronic configuration of iron ion in the following complex
ion. Also predict its magnetic behaviour:

Fe(H,01
(b) Write the IUPAC name of the coordination complex:
[COClen),]NO,
23. Calculate e.m.f and AG for the following cell at 298 K:
Mg(s) | Mg (0.01 M)||Ag* (0.0001 M) | Ag()
Given:
[ EMs/Mg-2.37 V, EAs'/Ag = + 0.80 V]
24. Define order of reaction. Write the condition under which a bimolecular reaction follows first order
kinetics.
25. (a) Arrange the following in the increasing order of their reactivity towards nucleophilic addition
reaction:
CH,COCHg, HCHO, CHCHO, -coCH
(b) Draw the structure of 2, 4 DNP derivative of
acetaldehyde.
SECTION-C
This section contains 5 questions with internal choice in two
questions. The following questions are
short answer type and carry 3 marks each.

26. Give the structures of final products of any three expected from the following reactie
(a) Hydroboration of propene followed by oxidation with
H,0, in alkaline medium.
(b) Dehydration of (CH,),C-OH by heating it with 20%
HPO at 358 K.
(c)Heatingof CH-0- with HI.
(d) Anisole is treated with CH Cl/anhydrous AICl2,
(e) Phenol is treated with Zn dust?
27. (a) Why a solution of [Ni(H,0),1*" is green while a solution of
(At. no. of Ni = 28)
[Ni(CN),.1 is colourless?
(b) Explain the hybridisation and shape of complex ion [Fe(CN),J.
 K 30 g Of
28. At300 glucose present in a litre of its solution
notic p r e s s u r e .of a
has an osmotic
t h e osmotic
pressure glucose solution is 1.52 bar at the pressure of 4.98 bar.
same
concentration? temperature, what would be its

Arange following in increasing order of

the
29. property specified:
Aniline, ethanamine, 2-ethylethanamine
(a)
(solubility in water)
Ethanoic acid. ethanamine, ethanol
(b)
(boiling point)
Methanamine,
(c) N,
N-dimethylmethanamine and N-methylmethanamine
aqueous phase) (basic strength in

OR
(alGive chemical
a test to
distinguish between N-methylethanamine and
N,N-dimethyl ethanamine.
(b)Write the reaction for catalytic reduction of nitrobenzene followed by reaction of product so
formed with bromine water.

c)Out of butan-1-ol and butan-1-amine, which will be more soluble in water and
why?
30. Among all the isomers of molecular formula
C4H,Br, identify
(a) the one isomer which is optically active.

(b) the one isomer which is highly reactive towards Sy2.

(c) the two isomers which give same product on
dehydrohalogenation with alcoholic KOH.
OR
What happens when
(a) n-butyl chloride is treated with alcoholic KOH,
(b) methyl bromide is treated with sodium in the presence of dry ether,
(c) methyl chloride is treated with KCN?

SECTION-D
he following questions are case-based questions. Each question has an internal choice and ecarries
+ 2 ) marks each. Read the passage carefully and answer the questions that follow.
n e spontaneous flow of the solvent through a semipermeable membrane from a pure solvent to a

solution or from a dilute solution to a concentrated solution is called osmosis. The phenomenon of
OSmosis can be demonstrated by taking two eggs of the same size. In an egg, the membrane below the
e l and around the egg material is semi-permeable. The outer hard shell can be removed by putting
tne egg in dilute hydrochloric acid. After removing the hard shell, one egg is placed in distilled water
and the other in a saturated salt solution. AfRer some time, the egg placed in distilled water swels-up
While the
egg placed in salt solution shrinks.
The pressure applied to stop the osmosis is termed as osmotic pressure (a Colligative
osmosis takes place when the applied external pressure becomes larger than the
Keverse
Osmotic pressure.
Answer the
following questions:
What happens when RBC's are placed in 0.5% NaCI solution.
b hi 1 M KCl or IM urea?
o n e of the following has higher osmotic pressure
c) What
"at 1s
is reverse
rever
osmosis? Name one SPM which can be used in this plant.
 OR
How the molecular mass of a substance can be determined by a method based on measuremen
measurement of
osmotie pressure
32. The most abundant biomolecules of the living system are proteins. They are polymers of a-amine
acids connected to each other by peptide linkage. Amino acids contain amino (-NH2) and carbovul
-COOH) group. Amino acids are classified as acidic, basic or neutral depending upon the relative
number of amino and carboxyl groups in their molecule. They behave like salts rather than simnle
amines or carboxylic acids. In aqueous solution, the carboxyl group can lose a proton and amino
as zwitter ion.
group can accept a proton, giving rise to a dipolar ion known
The amino acids, which can be synthesised in the body, are known as non-essential amino acids, On
the other hand, those which cannot be synthesised in the body and must be obtained through diet, are
known as essential amino acids.
Answer the following questions:
(a) Name the alpha amino acid which is optically inactive.
(b) Name two essential amino acids.
(c) The K, and K, values of a-amino acid are very low. Why?

OR
Draw the structure of zwitter ion.

SECTION-E
The following questions are long answer type and carry 5 marks each. Two questions have an internal
choice.
33. (a) Fora weak electrolyte, molar conductance in dilute solution increases sharply as its concentration
in solution is decreased. Give reason.
(b) At 291 K, the molar conductivities at infinite dilution of NH,C1, NaOH and NaCl are 129.8,
217.4 and 108.9 S cm mol respectively. If the molar conductivity of a centinormal solution
of NH,OH is 9.33 S cm* mol", what is the percentage dissociation of NH,OH at this dilution?
Also calculate the dissociation constant of NH,OH.
OR
(a) Calculate the standard free energy change for the following reaction at 25°C.

Au(s)Ca2"(1 M) Au(1M) +Ca(s)

Au/Au+1.50 V, EC2/c-2.87 V
Predict whether the reaction will be spontaneous or not at 25°C. Which of the above two halr
cells will act as an oxidising agent and which one will be a
reducing agent?
(b) Tarnished silver contains Ag2S. Can this tarnish be removed by placing tarnished silver warc
an aluminium pan containing an inert electrolytic solution such as NaC1? The standard elecuo
potential for half reaction:
Ag2S(s) + 2e 2Ag(s) + S is -0.71 V

and for A" + 3e 2A1(s) is -1.66 V

(a) An aldehyde. (A) (CH100) which does not
undergo self-aldol condensation but gives
henzaldehyde and two moles of (B) reductive ozonolysis. The
on
ions compound (B) on oxidation
ith silver gives oxalic acid. Identify compounds (A) and (B) and write down the reaction
involved.

hHow will you bring about the following conversions?

)Benzaldehyde to benzophenone

(i7) Acetaldehyde to lactic acid

OR
(a)Write the products formed when ethanal reacts with the following reagents:
() CH3MgBr and then H0*
(i) Zn-Hg/conc. HCI

(ii) C,H,CHO in the presence of dilute NaOH

() Give simple chemical tests to distinguish between the following pairs of compounds:
() Benzoic acid and Ethyl benzoate
(ii) Propanal and Propanone
35. (a) Account for the following:
() Zn, Cd and Hg are soft metals.
with the d-orbital configuration (d") Mn°* is an

(i) Cr* is reducing in nature while

same

oxidising agent.
Zn negative than expected.
(iüi) E values of Mn, Ni and
are more
different from that of non-
in oxidation number of transition elements
(b) () Is the variability
with examples.
transition elements? Illustrate
salts are coloured. Why?
(i) Zn* salts are white while Cu