Physical Chemistry - Class Contact Number:

11th - Practice MCQs 9667591930 / 8527521718

1
Two students performed the same experiment 6
The molality of a solution containing 18.25 g of
separately, and each of them recorded two readings of HCl gas in 500 g of water is -

mass, which are given below. The correct reading of 1. 0.1 m

mass is 3.0 g. On the basis of the given data, mark the 2. 1 M

correct option out of the following statements. 3. 0.5 m

Students Readings 4. 1 m

(i) (ii)

  A 3.01 2.99

7
The number of molecules of H2SO4 present in 100
  B 3.05 2.95
mL of 0.02 M H2SO4 solution is

1. The results of both the students' are neither accurate 1. 12. 044 × 10  molecules

20

nor precise.
2. 6. 022 × 10  molecules

23

2. The results of student A are both precise and accurate.

3. 1 × 10  molecules

23

3. Student B's results are neither precise nor accurate.

4. 12. 044 × 10  molecules

23

4. The results of student B are both precise and accurate.

8
The mass percent of carbon in carbon dioxide is : 

1.  0.034%

2
The molarity of a solution containing 5.85 g of 2.  27.27%

3.  3.4%

NaCl(s) per 500 mL of solution is -

4.  28.7%

1. 4 mol L-1

2. 20 mol L
-1

3. 0.2 mol L-1

9
The empirical formula and molecular mass of a
4. 2 mol L-1
compound are  CH O  and 180 g, respectively. The
2

molecular formula of the compound is -

1. C H O
9 18 9

3
If 500 mL of a 5 M solution is diluted to 1500 mL, 2. CH O
2

3. C H O

the molarity of the resultant solution is 

6 12 6

4. C H O

1. 1.5 M

2 4 2

2. 1.66 M

3. 0.017 M

10
Which of the following statements is correct about
4. 1.59 M

the reaction is given below?

4 Fe(s) + 3O (g) → 2 Fe O (g)

2 2 3

4
The highest number of atoms is present in
1. Total mass of iron and oxygen in reactants = total
mass of iron and oxygen in product therefore it follows
1. 4 g He

law of conservation of mass

2. 46 g Na

2. Total mass of reactants = total mass of product,

3. 0.40 g Ca

therefore, law of multiple proportions is followed

4. 12 g He

3. Amount of Fe2O3 can be increased by taking any one

of the reactants (iron or oxygen) in excess

5
If the concentration of glucose  (C H O ) in blood 4. Amount of  Fe2O3  produced will decrease if the
6 12 6

amount of any one of the reactants (iron or oxygen) is

is 0.9 g L-1, The molarity of glucose in blood is -

taken in excess

(1) 5 M

(2) 50 M

(3) 0.005 M

(4) 0.05 M

Page: 1
  Physical Chemistry - Class Contact Number:

11th - Practice MCQs 9667591930 / 8527521718

11
Which of the following statement indicates that the 15
Which of the following conclusions could not be
law of multiple proportions is being followed?
derived from Rutherford's  α-particle scattering
1. A sample of carbon dioxide taken from any source experiment?

will always have carbon and oxygen in the ratio of 1:2.

1. Most of the space in the atom is empty

2. Carbon forms two oxides namely, CO2 and CO, where 2. The radius of the atom is about 10-10 m while that of
masses of oxygen that combine with a fixed mass of nucleus is 10-15 m

carbon are in the simple ratio of 2:1.

3. Electrons move in circular path of fixed energy called
3. When magnesium burns in oxygen, the amount of orbits

magnesium used for the reaction is equal to the amount 4. Electrons and the nucleus are held together by
of magnesium  formed in magnesium oxide.
electrostatic forces of attraction

4. At constant temperature and pressure, 200 mL of

hydrogen will combine with 100 mL of oxygen to

produce 200 mL of water vapour.

16
Which of the following options does not represent

ground state electronic configuration of an atom?

1. 1s 2s 2p 3s 3p 3d 4s

2 2 6 2 6 8 2

12
Assertion: The empirical mass of ethene is half of
2. 1s 2s 2p 3s 3p 3d 4s

2 2 6 2 6 9 2

its molecular mass.

3. 1s 2s 2p 3s 3p 3d 4s

2 2 6 2 6 10 1

Reason: The empirical formula represents the simplest

4. 1s 2s 2p 3s 3p 3d 4s

2 2 6 2 6 5 1

whole-number ratio of the various atoms present in a

compound.

1. Both the assertion and the reason are true and the
reason is the correct explanation of the assertion.
17
The probability density plots of 1s and 2s orbitals
2. Both the assertion and the reason are true and the diagrams are given below

reason is not the correct explanation of the assertion.

3. The assertion is true but the reason is false.

4. The assertion is false but the reason is true.

13
Assertion(A):  One atomic mass unit is defined as
one-twelfth of the mass of one carbon-12 atom.

Reason(R): The carbon-12 isotope is the most abundant

isotope of carbon and has been chosen as the standard.

The density of dots in a region represents the probability
1. Both the assertion and the reason are true and the density of finding electrons in the region.

reason is the correct explanation of the assertion.

On the basis of the above diagram which of the
2. Both the assertion and the reason are true and the following statements is incorrect?

1. 1s and 2s orbitals are spherical in shape

reason is not the correct explanation of the assertion.

3. The assertion is true but the reason is false.

2. The probability of finding the electron is maximum
4. The assertion is false but the reason is true.

near the nucleus

3. The probability of finding the electron at a given

distance is equal in all directions

14
Assertion: The combustion of 16 g of methane 4. The probability density of electrons for 2s orbital
gives 18 g of water.
decreases uniformly as the distance from the nucleus
Reason:  In the combustion of methane, water is one of increases

the products.

1. Both the assertion and the reason are true and the
reason is the correct explanation of the assertion. 
18
Which of the following statements about the
2. Both the assertion and the reason are true and the electron is incorrect?

reason is not the correct explanation of the assertion.

1. It is a negatively charged particle

3. The assertion is true but the reason is false.

2. The mass of electron is equal to the mass of neutron

4. The assertion is false but the reason is true.

3. It is a basic constituent of all atoms

4. It is a constituent of cathode rays

Page: 2
  Physical Chemistry - Class Contact Number:

11th - Practice MCQs 9667591930 / 8527521718

19
The number of radial nodes for 3p orbital is 25
Assertion:  The temperature at which the vapor
______.
pressure of a liquid is equal to the external pressure is
1. 3
called boiling temperature.

2. 4
Reason: At high altitudes atmospheric pressure is high.

3. 2
1.  Both assertion and reason are true and the reason is
4. 1
the correct explanation of assertion.

2.  Both assertion and reason are true and the reason is
not the correct explanation of assertion.

20
Total number of orbitals associated with third shell 3.  Assertion is true but the reason is false.

will be _____.
4.  Assertion is false but the reason is true.

1.  2

2.  4

3.  9
26
Match the following:
4.  3
List I List II

A. Adiabatic
i. At constant temperature
Process
21
The pair of ions having the same electronic
B. Isolated System ii. No transfer of heat
configuration is -
C. Isothermal
1.  Cr3+, Fe3+
iii. Heat
Change
2.  Fe3+, Mn2+
iv. No exchange of energy and
D. Path Function
3.  Fe3+, Co3+
matter
4.  Sc3+, Cr3+

                                     

Codes
22
If travelling at same speeds, which of the following
A B C D
matter waves have the shortest wavelength?

(1) ii  iv  i  iii 

1. Electron

(2) iii  iv  i ii

2. Alpha particle (He2+)

3. Neutron
(3) iv iii  i ii
4. Proton
(4)  iv  ii i iii

23
A person living in Shimla observed that cooking
food without using a pressure cooker takes more time. 27
Match the following process with entropy change
The reason for this observation is-
Reaction Entropy change
1. Pressure increases
A. A liquid vaporizes 1. ΔS = 0
2. Temperature decreases
B. Reaction is non-spontaneous at all
3. Pressure decreases
2. ΔS = positive
temperatures and ΔH is positive
4. Temperature increases

C. Reversible expansion of an ideal

3. ΔS = negative
gas
24
Dipole-dipole forces act between the molecules
Codes
possessing permanent dipole. Ends of dipoles possess
'partial charges'. The partial charge will be-
A B C
1. More than unit electronic charge

1. 2 3 1
2. Equal to unit electronic charge

3. Less than unit electronic charge

2. 1 2 3
4. Double the unit electronic charge

3. 1 3 2

4. 3 2 1

Page: 3
  Physical Chemistry - Class Contact Number:

11th - Practice MCQs 9667591930 / 8527521718

28
 Match the following: 31
The correct statement among the following is-

1. The presence of reacting species in a covered beaker

A. Entropy of vaporization 1. Decreases is an example of an open system.

2. There is an exchange of energy as well as matter

between the system and the surroundings in a closed
2. Is always system.

B. K for a spontaneous process

positive 3. The presence of reactants in a closed vessel made up
of copper is an example of a closed system.

4. The presence of reactants in a thermos flask or any

3. Lowest other closed insulated vessel is an example of a closed
C. Crystalline solid state
entropy system.

D. ΔU in an adiabatic expansion of

32
The state of a gas can be described by quoting the
ΔHvap
4. 
ideal gas Tb

relationship between-

1.  Pressure, volume, temperature

Codes
2.  Temperature, amount, pressure

           A            B          C           D
3.  Amount, volume, temperature

1.       2, 4         2           3            1

4.  Pressure, volume, temperature, amount

2.        1            2           3            4

3.        1           4, 3        3            2

4.       4             3          3, 1         2 33

If the volume of a gas is reduced to half from its
original volume, then the specific heat will-

1.  Reduce to half

2.  Be Doubled

3.  Remain constant

29
Assertion: Combustion of all organic compounds is 4.  Increase four times

an exothermic reaction.

Reason: The enthalpies of all elements in their standard

state are zero.
34
In an adiabatic process, no transfer of heat takes
1.  Both assertion and reason are true and the reason is place between the system and its surroundings. The
the correct explanation of assertion.
correct option for free expansion of an ideal gas under
2.  Both assertion and reason are true and the reason is adiabatic condition from the following is -

not the correct explanation of assertion.

1. q = 0,   Δ T ≠ 0,  W = 0

3.  Assertion is true but the reason is false.

2. q ≠ 0,   Δ T = 0,  W = 0

4.  Assertion is false but the reason is true.

3. q = 0,   Δ T = 0,  W = 0

4. q = 0,   Δ T = 0,  W ≠ 0

30
Assertion: A liquid crystallises into a solid and is

accompanied by a decrease in entropy.

35
On the basis of thermochemical equations (1), (2),
Reason:  In crystals, molecules organise in an ordered and (3), find out which of the algebraic relationships
manner.
given in options (a) to (d) is correct

1.  Both assertion and reason are true and the reason is (i) 
the correct explanation of assertion.
−1

2.  Both assertion and reason are true but the reason is C (graphite) + O2 (g) → CO2 (g);   Δr H = x  kJ   mol

not the correct explanation of assertion.

(ii) 
3.  Assertion is true but the reason is false.
1 −1
C (graphite) + O2 (g) → CO(g);   Δr H = y  kJ   mol
4.  Assertion is false but the reason is true.

(iii) 
1 −1
CO(g) + O2 (g) → CO2 (g);   Δr H = z  kJ   mol
2

1. z=x+y

2. x=y-z

3. x=y+z

4. y=2z-x

Page: 4
  Physical Chemistry - Class Contact Number:

11th - Practice MCQs 9667591930 / 8527521718

36
The enthalpies of elements in their standard states 39
For the reaction : N2(g) + 3H2(g) →2NH3(g)

are taken as zero. The enthalpy of formation of a [NH3 ]

2

​ Equilibrium constant K = ​

compound is -
 
c
[ N ][H2 ]
2
3

1. Generally negative
Some reactions are written below in Column I and their
2. Always positive
equilibrium constants in terms of Kc  are written in
3. Zero
Column II. Match the following reactions with the
4. Never negative
corresponding equilibrium constant.

Column II
Column I (Reaction) (Equilibrium
37
Which of the following is not correct?
constant)
1. ΔG is zero for a reversible reaction.
A. 2N (g) + 6H (g) ⇌ 4 NH (g) 1. 2K
2. ΔG is positive for a spontaneous reaction.

2 2 3 c

3. ΔG is negative for a spontaneous reaction.

B. 2 NH (g) ⇌ N (g) + 3H (g)
3 2 2. K 2
1/2
c

4. ΔG is positive for a non-spontaneous reaction.

C.  N (g) + H (g) ⇌ NH (g) 3. 
1 3 1

2 2 3
2 2 Kc

4. K 2
c

38
Match the following equilibria with the
corresponding condition. Codes
A. Liquid⇌Vapour 1. Saturated solution
A B C
B. Solid⇌Liquid 2. Boiling point
1. 4 3 2
C. Solid⇌Vapour 3. Sublimation point
2. 1 2 3
D. Solute (s)⇌Solute (solution) 4. Melting point
3. 1 4 3
5. Unsaturated solution
4. 4 1 3
Codes

A B C D
1. 2 4 3 1 40
Match the standard free energy of the reaction with
2. 1 2 3 5 the corresponding equilibrium constant.
3. 5 4 3 2 A. ΔG > 0 ⊝
1. K>1
4. 4 5 3 2 B. ΔG < 0 ⊝
2. K=1

C. ΔG = 0 ⊝
3. K=0

4. K<1

Codes

A B C
1. 4 1 2
2. 1 2 3
3. 2 4 3
4. 4 1 3

Page: 5
  Physical Chemistry - Class Contact Number:

11th - Practice MCQs 9667591930 / 8527521718

41
Match the following species with the corresponding 43
Assertion:  The increasing order or acidity of
conjugate acid. hydrogen halides is HF<HCI<HBr<HI.

Species Conjugate acid Reason: While comparing acids formed by the elements

A.  N H  1. CO 2− belonging to the same group of the periodic table, H-A
bond strength is a more important factor in determining
3 3

B. H CO −

3
2. N H +

4 the acidity of an acid than the polar nature of the bond.

C. H O 2 3.H O 3
+
1.  Both the assertion and the reason are true and the
D. H SO −
 4. H CO 2 3
reason is the correct explanation of assertion.

2.  Both the assertion and the reason are true and the
4

5. H 2 SO4
reason is not the correct explanation of assertion.

3.  Assertion is true but the reason is false.

Codes
4.  Assertion is false but the reason is true.

A B C D

1. 2 5 1 5
2. 2 4 3 5 44
Assertion:  A solution containing a mixture of
3. 5 4 3 2 acetic acid and sodium acetate maintains a constant
4. 4 5 3 2 value of pH on the addition of small amounts of acid or

alkali.

Reason: A solution containing a mixture of acetic acid

and sodium acetate acts as a buffer solution. 

42
Match the Column I with Column II 1.  Both the assertion and the reason are true and the
reason is the correct explanation of assertion.

Column I Column II 2.  Both the assertion and the reason are true and the
reason is not the correct explanation of assertion.

3. The assertion is true but the reason is false.

A. Equilibrium 1. ΔG > 0,  K < 1 4.  The assertion is false but the reason is true.

B. Spontaneous  reaction 2. ΔG = 0 45

Assertion: The ionisation of hydrogen sulphide in
water is low in the presence of hydrochloric acid

Reason: Hydrogen sulphide is a weak acid.

C. Non-spontaneous reaction 3. ΔG < 0,  K > 1 1.  Both the assertion and the reason are true and the
reason is the correct explanation of assertion.

2.  Both the assertion and the reason are true and the
 
reason is not the correct explanation of assertion.

Codes
3.  The assertion is true but the reason is false.

          A           B          C         
4.  The assertion is false but the reason is true.

1.       2           3          1           

2.       1           2          3           

3.       2           1          3       

46
Assertion: 
An aqueous solution of ammonium
4.       3          1           2       
carbonate is basic.

Reason: The acidic or basic nature of a salt solution of a

salt of a weak acid and a weak base depends on the Ka

and Kb values of the acid and the base forming it.

1.  Both the assertion and the reason are  true and the
reason is the correct explanation of assertion.

2.  Both the assertion and the reason are true and the
reason is not the correct explanation of assertion.

3.  Assertion is true but the reason is false.

4.  Assertion is false but the reason is true.

Page: 6
  Physical Chemistry - Class Contact Number:

11th - Practice MCQs 9667591930 / 8527521718

47
Assertion:  An aqueous solution of ammonium 51
When hydrochloric acid is added to cobalt nitrate
acetate can act as a buffer.
solution at room temperature, following reaction takes
Reason:  Acetic acid is a weak acid and  NH OH  is a
4 place and the reaction mixture becomes blue. On cooling
weak base.
the mixture it becomes pink

1.  Both the assertion and the reason are true and the [Co(H2O)6]3+(Pink)(aq)+4Cl-(aq)⇌[CoCl4]2-(Blue)
reason is the correct explanation of the assertion.

(aq)+6H2O(l)

2.  Both the assertion and the reason are true and the
reason is not the correct explanation of the assertion.
On the basis of information given above, mark the
3.  Assertion is true but the reason is false.
correct answer

4.  Assertion is false but the reason is true.

1. ΔH > 0 for the reaction

2, ΔH < 0 for the reaction

3. ΔH = 0 for the reaction

4. The sign of  ΔH  cannot be predicted on the basis of

48
The value of Δn for the following reaction will be :
the given information.

NH Cl(s) ⇌ NH (g) + HCl(g)

4 3

1. 1

2. 0.5

52
The ionisation constant of an acid, Ka  , is the
3. 1.5
measure of the strength of an acid. The Ka  values of
4. 2

acetic acid, hypochlorous acid and formic acid are 

1. 74 × 10
−5
,  3. 0 × 10   and  −8
1. 8 × 10   , −4

respectively. The  correct order of pH value of 0.1 mol

49
An incorrect statement about equilibrium among the dm-3 solutions of these acids is -

following is:
1. Acetic acid > hypochlorous acid > formic acid

1. Equilibrium is possible only in a closed system at a 2. Hypochlorous acid < acetic acid > formic acid

given temperature
3. Formic acid > hypochlorous acid > acetic acid

2. All measurable properties of the system remain 4. Formic acid < acetic acid < hypochlorous acid

constant

3. All the physical processes stop at equilibrium

4. The opposing processes occur at the same rate and 53

Acidity of BF3 can be explained on the basis of 

there is a dynamic but stable condition.

1. Arrhenius concept

2. Bronsted Lowry concept 

3. Lewis concept

50
An incorrect statement about equilibrium among the 4. Bronsted Lowry as well as Lewis concept

following is:

1. In equilibrium mixture of ice and water kept in

perfectly insulated flask, the mass of ice and water does 54
The value of pH of 0. 01  mol   dm −3
  CH3 COOH  
not change with time.
(Ka = 1. 74 × 10
−5
)  is-

2. The intensity of the red colour increases when oxalic

1. 3.4

acid is added to a solution containing iron (III) nitrate

2. 3.6

and potassium thiocyanate.

3. 3.9

3. On the addition of a catalyst, the equilibrium constant

4. 3.0

value is not affected.

4. The equilibrium constant for a reaction with a

negative  ΔH  value decreases as the temperature
55
K   for  CH   is  1. 8 × 10   and Kb  for 
−5
COOH
increases.

a 3

NH4 OH   is  1. 8 × 10 . The pH of ammonium acetate

−5

will be 

1. 7.005

2. 4.75

3. 7.0

4. Between 6 and 7

Page: 7
  Physical Chemistry - Class Contact Number:

11th - Practice MCQs 9667591930 / 8527521718

56
On increasing the pressure, the direction in which 60
Assertion:  In the presentation  E
⊝

Fe
3+
/ Fe
2+
  and 

gas phase reaction proceeds to re-establish equilibrium is E

⊝
2+
,  Fe
3+
/ Fe
2+
  and  Cu
2+
/ Cu   are redox
predicted by applying the Le-Chatelier's principle. Cu / Cu

Consider the reaction,

couples.

N (g) + 3H (g) ⇌ 2 NH (g)

Reason:  A redox couple is the combination of the

2 2 3
oxidised and reduced forms of a substance involved in
If the total pressure at which the equilibrium is
an oxidation or reduction half cell.

established is increased without changing the

1.  Both the assertion and the reason are true and the
temperature, then the correct option is:

reason is the correct explanation of the assertion.

1. K will remain same.

2.  Both the assertion and the reason are true, but the
2. K will decrease.

reason is not the correct explanation of the assertion.

3. K will increase.

3.  The assertion is true but the reason is false.

4. K will increase initially and decrease when pressure is

4.  The assertion is false but the reason is true.

very high.

57
  Among water, ether, and acetone, water has the 61
Assertion:  The decomposition of hydrogen
peroxide to form water and oxygen is an example of a
maximum boiling point and ether has the minimum
disproportionation reaction.

boiling point. The correct order of vapour pressure of

Reason: The oxygen of peroxide is in –1 oxidation state
water, acetone and ether at 30°C is-

and it is converted to zero oxidation state in O2

1. Water<ether<acetone

2. Water<acetone<ether
and –2 oxidation state in H2O.

3. Ether<acetone<water
1. Both assertion and reason are true and the reason is
4. Acetone<ether<water

the correct explanation of assertion.

2. Both assertion and reason are true and the reason is

not the correct explanation of assertion.

58
The addition of a small amount of argon at a 3. Assertion is true but the reason is false.

constant volume will not affect the equilibrium in which 4. Assertion is false but the reason is true.

of the following reactions?

1. H (g) + I (g) ⇌ 2 HI(g)

62
The more positive the value of E , the greater is the
2 2
⊝

2. PCl (g) ⇌ PCl (g) + Cl (g)

5 3 2

3. N (g) + 3H (g) ⇌ 2 NH (g)

2 2 3
tendency of the species to get reduced. Using the
4. The equilibrium will remain unaffected in all the three standard electrode potential of redox couples given
cases

below find out which of the following is the strongest

oxidising agent.

3+ 2+

⊝
E  values :   Fe / Fe = +0. 77

59
Which of the following elements does not show a I2 (s)/I
−
= +0. 54;
disproportionation tendency?

1. Cl
Cu
2+
/Cu = +0. 34;  

2. Br
+
Ag /Ag = 0. 80 V
3. F

4. I

1. Fe3+

2. I2(s)

3. Cu2+

4. Ag+

Page: 8
  Physical Chemistry - Class Contact Number:

11th - Practice MCQs 9667591930 / 8527521718

63
E  values of some redox couples are given below.
Θ
67
Which of the following solutions have the same
On the basis of these values choose the correct option.
concentration?

(a) 20 g of NaOH in 200 mL of solution

Θ −
E  values :   Br2 / Br = +1. 90

+
(b) 0.5 mol of KCl in 200 mL of solution

Ag / Ag(s) = +0. 80
(c) 40 g of NaOH in 100 mL of solution

2+
(d) 20 g of KOH in 200 mL of solution

Cu / Cu(s) = +0. 34;  

 

1. (a), (b)

−
I2 (s)/I = +0. 54
2. (b), (c)

3. (c), (d)

1. Cu will reduce Br-

4. (b), (d)

2. Cu will reduce Ag

3. Cu will reduce I-

4. Cu will reduce Br2

68
16 g of oxygen has the same number of molecules

as in-
(a) 16 g of CO

64
In the reactions given below, thiosulphate reacts (b) 28 g of N2

differently with iodine than with bromine.

(c) 14 g of N2

+ 2I

2− 2− −
2S O 2 + I → S O
3 2 4 6 (d) 1.0 g of H2

+ 10H

2− 2− − +
S O
2 + 2 Br + 5H O → 2 SO
3
2 + 2 Br2
 
4

Which of the following statements best describes the 1. (a), (b)

above dual behaviour of thiosulphate?

2. (b), (c)

1. Bromine is a stronger oxidant than iodine

3. (c), (d)

2. Bromine is a weaker oxidant than iodine

4. (b), (d)

3. Thiosulphate undergoes oxidation by bromine and

reduction by iodine in these reactions

4. Bromine undergoes oxidation and iodine undergoes 69

Unitless term among the following is/are-

reduction in these reactions

(a) Molality

(b) Molarity

(c) Mole fraction

65
One mole of oxygen gas at STP is equal to -
(d) Mass per cent

(a). 6. 022 × 10  molecules of oxygen

23
 

(b). 6. 022 × 10  atoms of oxygen

23
1. (a), (b)

(c). 16 g of oxygen molecule

2. (b), (c)

(d). 32 g of oxygen 
3. (c), (d)

1. (a), (b)
4. (b), (d)

2. (a), (c)

3. (a), (d)

4. (c), (d)

70
The correct statement among the following

regarding gaseous state is -

(a) Complete order of molecules

66
Which of the following pairs have the same number (b) Complete disorder of molecules

of atoms?
(c) Random motion of molecules

(a) 16 g of O2(g) and 4 g of H2(g)

(d) Fixed position of molecules

(b) 16 g of O2 and 44 g of CO2

 

(c) 28 g of N2 and 32 g of O2
1. (a, b)

2. (b, c)

(d) 12 g of C(s) and 23 g of Na(s)

3. (c, d)

 
4. (a, d)

1. (a), (b)

2. (b), (c)

3. (c), (d)

4. (b), (d)

Page: 9
  Physical Chemistry - Class Contact Number:

11th - Practice MCQs 9667591930 / 8527521718

71
Which of the following figures does not represent 1 74
A sample containing 1.0 mol of an ideal gas is
mole of dioxygen gas at STP?
expanded isothermally and reversible to ten times of its
(a) 16 g of gas
original volume, in two separate experiments. The
(b) 22.7 L of gas
expansion is carried out at 300 K and at 600 K
(c) 6. 022 × 10  dioxygen molecules

23
respectively. 

(d) 11.2 L of gas

The correct statements among the following are-

The correct choice among the above is -

(a) Work done at 600 K is 20 times the work done at 300
1. (a, b, c)
K

2. (a, b, d)
(b) Work done at 300 K is twice the work done at 600 K

3. (b, c, d)
(c) Work done at 600 K is twice the work done at 300 K

4. (a, c, d)

(d) ΔU = 0 in both cases

1. (a, b)

72
Thermodynamics mainly deals with-
2. (b, c)

(a) Interrelation of various forms of energy and their 3. (c, d)

transformation from one form to another.

4. (a, d)

(b) Energy changes in the processes which depend only

on initial and final states of the microscopic systems

containing a few molecules.
75
For the reaction N O (g) ⇌ 2 NO (g), the value of
2 4 2

(c) How and at what rate these energy transformations K is 50 to 400 K and 1700 at 500 K. Which of the
are carried out.
following option(s) is/are correct?

(d) The system in equilibrium state or moving from one (a) The reaction is endothermic

equilibrium state to another equilibrium state.

(b) The reaction is exothermic

The correct choice among the above is -

(c) If NO (g) and N O (g) are mixed at 400 K at partial
2 2 4

1. (a, b)
pressures 20 bar and 2 bar respectively, more  N O (g)
2 4

2. (b, c)
 will be formed.

3. (c, d)
(d) The entropy of the system increases

4. (a, d)
1. (a, b, d)

2. (b, c, d)

3. (b, d, a)

73
The processes among the following that occur 4. (a, c, d)

spontaneously are -

(a) The flow of heat from colder to a warmer body

(b) Gas in a container contracting into one corner

76
At a particular temperature and atmospheric
(c) Gas expanding to fill the available volume
pressure, the solid and liquid phases of a pure substance
(d) Burning carbon in oxygen to give carbon dioxide
can exist in equilibrium. Which of the following term
 
defines this temperature?

1. (a, b)
(a) Normal melting point

2. (b, c)
(b) Equilibrium temperature

3. (c, d)
(c) Boiling point

4. (a, d)
(d) Freezing point

1. (a, b)

2. (b, c)

3. (c, d)

4. (a, d)

77
In the reaction

xBrO3- + yCr+3 + zH2O →Br2 + CrO4-2 + H+

the coefficients x,y,z are respectively ?

1. 6, 10, 11

2. 6, 10, 20

3. 6, 8, 22

Page: 10
  Physical Chemistry - Class Contact Number:

11th - Practice MCQs 9667591930 / 8527521718

78
According to Born-Haber's cycle, the enthalpy of 82
If 0.01 M acetic acid solution is 1% ionised, then
formation of ionic compounds can be determined. The pH of this acetic acid solution is :

formation of NaCl involves following steps :

1.  3

S
(I) Na(s)−−−−−−−−−−−−−→ Na(g)       
2.  2

Energy   of   sublimation 3.  4

4.  1

(II) Na(g)−−−−−−−−−−−→ Na+(g) + e–

I onisation potential

D
(III) Cl2(g) −−−−−−−−−−−−−−→2Cl(g)

Bond dissociation energy 83
One mole of an ideal gas at 300 K is expanded
(IV) Cl(g) + e– −−−−−−−−−→Cl–(g)

E
isothermally from 1 L to 10 L volume. Δ U for this
Electron−affinity
process is (Use R = 8.314 J K–1 mol–1)

 (V) Cl–(g) + Na+(g)−−−−−−−−→ NaCl(S)

1.  1260 J

Lattice energy
2.  2520 J

The enthalpy of formation of NaCl will be :

3.  5040 J

1. ΔH = S + I − − E − U

f
D

2
4.  0 J

2. ΔH = S + I +
D
− E − U

f
2

3. ΔH f
= −S − I − D +
E

2
+ U
84
Real gases show nearly ideal behaviour at:

4. ΔH f
= −S − I − D −
E

2
− U

1. low pressure and low temperature 

2. high pressure and low temperature 

3. high pressure and high temperature 

79
Which of the following is not correct about 4. low pressure and high temperature 

postulates of kinetic molecular theory of gases?

1. Pressure of the gas is due to the collision of molecules

against the walls of the container. 85
For the reaction of cyanamide  N H 2 CN (g)     with 
2. Volume of the gas is due to the large number of   in a bomb calorimeter,  ΔU   was found to be -740
O2

molecules of the gas.

kJ/mol at 300 K. The enthalpy change for the reaction 

3. Average kinetic energy of molecules is directly NH CN (g) + 2 O  (g) → N  (g) + CO  (g) + H O (l)
3
2 2 2 2
2
proportional to the absolute temperature of the gas.
will be 

4. The molecules move randomly with different speeds 1.  -507.1 kJ /mol 

in different directions.

2. -1987.1 kJ/mol 

3. -738.75 kJ/mol 

4. -741.2 kJ/mol 

80
The solubility product of  BaSO   in water is 

1.5 × 10 . The molar solubility of  BaSO   in 0.1 M

−9
4

solution of Ba(NO3)2 in- 

1. 2.0 × 10 M
−8 86
The correct expression out of the following is 

2. 0.5 × 10 M
−8
1. ΔU = ΔH + Δn RT
g

3. 1.5 × 10 M
−8
2. C − C = R for 1 mole of a non-ideal gas 

p V

4. 1.0 × 10 M

−8
3. ΔS > 0 for a spontaneous process 

total

4. In K = ( )

Δr G

RT

81
At 300 K, 250 mL of gas A at 1 bar pressure is
mixed with 500 mL of a gas B at 2 Bar pressure in a 1.0 87
If the equilibrium constant for a reaction 
L flask. Gas A does not react with gas B. The final aA + bB ⇌ cC + dD  is K   , then the equilibrium
c
pressure of the mixture is-
constant for the reaction  naA + nbB ⇌ ncC + ndD
1. 1.00 bar 
 will be equal to-

2. 2.15 bar 
1. n√K

3. 2.50 bar 

2. (K )
n

4. 1.25 bar 

3. 

Kc

4. nK
c

Page: 11
  Physical Chemistry - Class Contact Number:

11th - Practice MCQs 9667591930 / 8527521718

88
The pH of a buffer solution formed by mixing 25 94
Assuming the water vapor to be a perfect gas, find
mL of 0.2 M NH4Cl and 50 mL of 0.1M of NH3 the internal energy change when 1 mole of water at
solution at 25°C is 
100°C and 1 bar pressure is converted to the ice at 0°C.

(Given pK (N H ) = 4.75)

b 3 (Given the enthalpy of fusion of ice =6.0 kJ mol-1, the

1. 4.75 
Heat capacity of water = 4.2 J/g°C)

2. 4.45 
1. -13.56 J mol-1

3. 5.05 
2. -13.56 kJ mol-1

4. 9.25 

3. -1.356 kJ mol-1

4. -1.356 J mol-1

89
Which one of the following salts will not give rise

to an acidic solution when dissolved in water? 

1. H COON a
95
Which of the following pairs is incorrect? 

2. N H Cl
4
     A                                                         B 

3. N H N O

4 3
1. Snowfall                                           Exothermic
4. (N H ) SO
4 2 4
process

2. Expansion of an ideal gas                 ΔU = 0

 at constant temperature 

90
In the reaction  3. State of equilibrium                          ΔG = 0
T ,P

2Cu O(s) + Cu S(s) → 6Cu(s) + SO (g)  , species

4. Entropy change of a reaction at      Third law of
thermodynamics

2 2 2

that acts as an oxidant is 

0 K is equal to zero 

1. O (-II)

2. S(-II)
3. Cu(I) 

4. Cu(0)

96

[H2 ]
K = C is written for a particular reaction. The
[H2 O]
4

corresponding reaction is: 

91
The energy of radiation in eV for    1.  3Fe(s) + 4H O(g) ⇌ Fe O4 (s) + 4H2 (g)

2 3
I = 300 nm (1eV = 1.6020 × 10
−19
J) is-
2.  H O(l) ⇌ H (g) + 1/2O (g)

2 2 2
1. 3.98 eV 
3.  4H O(l) ⇌ 4H (g) + 2O (g)

2. 3.25 eV 

2 2 2

4.  4H (g) + 2O (g) ⇌ 4H O(l)

3. 2.68 eV 
2 2 2

4. 4.14 eV 

97

92
The value of angular momentum for 'f' orbital is: 
Find the percentage of ionization of Pyridinium ion,
1.  0
when Pyridine is present in 0.1 M aqueous pyridine
2.  h
π
solution (Kb = 1.6 × 10-8)

√2

√3h
1. 0.01%

3.  π

2. 0.04%

4. 
√3h

3. 4%

√2π 4. 10%

93
The compressibility factor (Z) for an ideal gas is-
98
10 mL of a strong acid of pH = 2 is mixed with 10
1. 1
mL of another strong acid of pH = 3. The pH of the
2. 0
resulting mixture is: 

3. >1
1.  1.98

4. <1
2.  2.26

3.  3.0

4.  2.8

Page: 12
  Physical Chemistry - Class Contact Number:

11th - Practice MCQs 9667591930 / 8527521718

99
In which of the following compounds, an element
exhibits two oxidation states in the same compound?

1.  NH2OH

2.  NH4NO3

3.  N2H4

4.  N3H

100
Among the following an example of a
disproportion reaction is: 

1.  2Na CrO + 2H → Na Cr O + 2Na + 2H

2 4
+
2 2 7
+
2O

2.  Na CrO + 2KCl → K Cr O + 2NaCl

2 7 2 2 7

3.  3MnO + 4H → 2MnO + MnO + 2H O

2−

4
+ −

4
2 2

4.  2KMnO → K MnO + MnO + O

4 2 4 2 2

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