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Class 4: Chemical Kinetics
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1) A graph between t1/2 and conc. for nth order reaction is a straight line. Reaction
of this nature is completed 50% in 10 minutes when the conc. in 2 molL−1. This
is decomposed 50% in t minutes at 4 molL−1, n and t are respectively: t½
(min)
(A) 0, 20 min (B) 1, 10 min (C) 1, 20 min (D) 0, 5 min
conc. (M)

1) n tJ tif tpidf;fhd 𝑡1/2 > nrwpT Mfpatw;Wf;fpilNaahd tiuglk;

xU Neh;NfhL MFk;. ,j;jd;ikAila tpidahdJ nrwpT 2 molL−1 Mf
,Uf;Fk; NghJ 10 epkplq;fspy; 50% epiwtilfpwJ. 4 molL−1 ,y; t
t½
epkplq;fspy; 50% rpijfpwJ vdpy; n kw;Wk; t Mfpait KiwNa: (min)
(A) 0> 20 epkplq;fs; (B) 1> 10 epkplq;fs; conc. (M)
(C) 1> 20 epkplq;fs; (D) 0> 5 epkplq;fs;

2) Following is the graph between log t1/2 and log Ao (Ao = initial concentration)
for a given reaction at 27℃. The order of the reaction is ________. log t ½ 45°
(A) 0 (B) 1 (C) 2 (D) 3

log A0

2) 27℃ -,y; nfhLf;fg;gl;l xU tpidf;fhd log 𝑡1/2 kw;Wk;

log 𝐴𝑜 (𝐴𝑜 = Muk;gr; nrwpT) Mfpatw;Wf;fpilNaahd tiuglk;
fPNo nfhLf;fg;gl;Ls;sJ. ,e;j tpidtif__________. log t ½ 45°
(A) 0 (B) 1 (C) 2 (D) 3

log A0

3) A graph between log t1/2 and log a (abscissa), ‘a’ is the initial concentration
of A in the reaction, is given. For the reaction A → product, the order of the log t ½ slope = −1
reaction is:
(A) 0 (B) 1 (C) 2 (D) 3
log a

3) log 𝑡1/2 > log a (fpil mr;R) Mfpatw;Wf;fpilNaahd tiuglk;

nfhLf;fg;gl;Ls;sJ. |a| vd;gJ tpidapy; A ,d; Muk;gr; nrwpthFk;. log t ½ slope = −1
tpid 𝐴 → tpisnghUl;fs; vd;Dk; tpidf;fhd tpid tif:
(A) 0 (B) 1 (C) 2 (D) 3
log a
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4) The time for half-life period of a certain reaction A→ Products is 1 hour. When the initial
concentration of the reactant A is 2.0 molL−1, how much time does it take for its concentration to
come from 0.50 to 0.25 molL−1 if it is a zero-order reaction?
(A) 1 h (B) 4 h (C) 0.5 h (D) 0.25 h

4) 𝐴 → tpisnghUl;fs; vd;Dk; xU Fwpg;gpl;l tpidapd; miu tho; fhyk; 1 kzpNeuk;.

tpidgLnghUs; A -,d; Muk;gr; nrwpT 2.0 molL−1 -Mf ,Uf;Fk; NghJ> mJ g+[;a tif
tpidahf ,Ue;jhy;> mjd; nrwpT 0.50 ,ypUe;J 0.25 molL−1 -Mf vt;tsT Neuk; MFk;?
(A) 1 h (B) 4 h (C) 0.5 h (D) 0.25 h

5) The time for half-life period of a certain reaction A→ Products is 2 hour. When the initial
concentration of the reactant A is 8 molL−1, how much time does it take for its concentration to
come from 6 to 2 molL−1 if it is a zero-order reaction?
(A) 1 h (B) 4 h (C) 2 h (D) 6 h

5) 𝐴 → tpisnghUl;fs; vd;Dk; xU Fwpg;gpl;l tpidapd; miu tho; fhyk; 2 kzpNeuk;.

tpidgLnghUs; A ,d; Muk;gr; nrwpT 8 molL−1 -Mf ,Uf;Fk; NghJ> mJ g+[;a tif
tpidahf ,Ue;jhy;> mjd; nrwpT 6 ,ypUe;J 2 molL−1 -Mf vt;tsT Neuk; MFk;?
(A) 1 h (B) 4 h (C) 2 h (D) 6 h

6) The time for half-life period of a certain reaction A→ Products is 4 hour. When the initial
concentration of the reactant A is 1.6 molL−1, how much time does it take for its concentration to
come from 0.05 to 0.03 molL−1 if it is a zero-order reaction?
(A) 0.1 h (B) 0.4 h (C) 0.5 h (D) 0.3 h

6) 𝐴 → tpisnghUl;fs; vd;Dk; xU Fwpg;gpl;l tpidapd; miu tho; fhyk; 4 kzpNeuk;.

tpidgLnghUs; A ,d; Muk;gr; nrwpT 1.6 molL−1 -Mf ,Uf;Fk; NghJ> mJ g+[;a tif
tpidahf ,Ue;jhy;> mjd; nrwpT 0.05 ,ypUe;J 0.03 molL−1 -Mf vt;tsT Neuk; MFk;?
(A) 0.1 h (B) 0.4 h (C) 0.5 h (D) 0.3 h

7) The rate law for inversion of cane sugar is R = k′ [C12 H22 O11 ][H2 O]. Find the concentration of
sucrose if the rate of the reaction is 0.032 Ms−1 and rate constant k=0.005 s −1.
(A) 8.8 M (B) 9 M (C) 10.2 M (D) 6.4 M

7) fUk;Gr; rh;f;fiuapd; Neh;khw;w Ntf tpjp R = k′ [C12 H22 O11 ][H2 O]. tpidNtfk; 0.032
Ms−1 kw;Wk; tpidNtf khwpyp k=0.005 s−1 vdpy; Rf;Nuh]pd; nrwpitf; fz;Lgpb.
(A) 8.8 M (B) 9 M (C) 10.2 M (D) 6.4 M
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8) The rate law for inversion of cane sugar is R = k′ [C12 H22 O11 ][H2 O]. Find the concentration of
sucrose if the rate of the reaction is 1.6 Ms −1 and rate constant k=0.4 s −1.
(A) 50 M (B) 4 M (C) 10 M (D) 20 M

8) fUk;Gr; rh;f;fiuapd; Neh;khw;w Ntf tpjp R = k′ [C12 H22 O11 ][H2 O]. tpidNtfk; 1.6
Ms−1 kw;Wk; tpidNtf khwpyp k=0.4 s −1 vdpy; Rf;Nuh]pd; nrwpitf; fz;Lgpb.
(A) 50 M (B) 4 M (C) 10 M (D) 20 M

9) The rate law for inversion of cane sugar is R = k′ [C12 H22 O11 ][H2 O]. Find the concentration of
sucrose if the rate of the reaction is 5.40 Ms−1 and rate constant k=5.0 s −1 .
(A) 1.08 M (B) 7.40 M (C) 6.09 M (D) 8.05 M

9) fUk;Gr; rh;f;fiuapd; Neh;khw;w Ntf tpjp R = k′ [C12 H22 O11 ][H2 O]. tpidNtfk; 5.40
Ms−1 kw;Wk; tpidNtf khwpyp k=5.0 s −1 vdpy; Rf;Nuh]pd; nrwpitf; fz;Lgpb.

10) During the kinetic study of the reaction, 2A+B → Products , following results were obtained;

Ex. No. [A]molL−1 [B] molL−1 Initial rate of formation (molL−1 )

I 0.2 0.02 0.3
II 0.4 0.02 0.6
III 0.4 0.08 2.4
Based on the above data which one of the following is correct?
(A) rate = k[A]2 [B]2 (B) rate = k[A]0 [B]
(C) rate = k[A]2 [B] (D) rate = k[A][B]

10) 2A+B→ tpisnghUl;fs; vd;w tpidapd; Ntftpay; Ma;tpd;NghJ gpd;tUk; KbTfs;

ngwg;gl;ld : tpisnghUl;fs;

Nrhjid vz; [𝐴]𝑚𝑜𝑙𝐿−1 [𝐵]𝑚𝑜𝑙𝐿−1 Muk;gj;jpy; cUthFk; Ntfk;

−1
(𝑚𝑜𝑙𝐿 )
I 0.2 0.02 0.3
II 0.4 0.02 0.6
III 0.4 0.08 2.4

NkNy cs;s juTfspd; mbg;gilapy; gpd;tUtdtw;wpy; vJ rhp?

(A) Ntfk; = k[A]2 [B]2 (B) Ntfk; = k[A]0 [B]
(C) Ntfk; = k[A]2 [B] (D) Ntfk; = k[A][B]
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11) During the kinetic study of the reaction, 2A+B → products, following results were obtained;
Ex. No. [A]molL−1 [B] molL−1 Initial rate of formation
(molL−1 s−1 )
I 0.3 0.05 0.15
II 0.6 0.05 0.30
III 0.6 0.2 1.20
Based on the above data which one of the following is correct?
(A) rate = k[A]2 [B]2 (B) rate = k[A]0 [B]
(C) rate = k[A][B] (D) rate = k[A]2 [B]

11) 2A+B→ tpisnghUl;fs; vd;w tpidapd; Ntftpay; Ma;tpd; NghJ gpd;tUk; KbTfs;
ngwg;gl;ld:
Nrhjid vz; [𝐴]𝑚𝑜𝑙𝐿−1 [𝐵]𝑚𝑜𝑙𝐿−1 Muk;gj;jpy; cUthFk; Ntfk;
−1
(𝑚𝑜𝑙𝐿 𝑠−1 )
I 0.3 0.05 0.15
II 0.6 0.05 0.30
III 0.6 0.2 1.20
NkNy cs;s juTfspd; mbg;gilapy; gpd;tUtdtw;wpy; vJ rhp?
(A) Ntfk; = 𝑘[𝐴]2 [𝐵]2 (B) Ntfk; = 𝑘[𝐴]0 [𝐵]
(C) Ntfk; = 𝑘[𝐴][𝐵] (D) Ntfk; = 𝑘[𝐴]2 [𝐵]

12) During the kinetic study of the reaction, 2A+B → C+D , following results were obtained;

Ex. No. [A]molL−1 [B] molL−1 Initial rate of formation

(molL−1 s−1 )
I 0.10 0.10 1.5 × 10−3
II 0.20 0.20 3.0 × 10−3
III 0.20 0.40 6.0 × 10−3

Based on the above data which one of the following is correct?

(A) rate = k[A]2 [B]2 (B) rate = k[A]0 [B]

(C) rate = k[A][B] (D) rate = k[A]2 [B]

12) 2A+B→C+D vd;w tpidapd; Ntftpay; Ma;tpd; NghJ gpd;tUk; KbTfs; ngwg;gl;ld:
Nrhjid [𝐴]𝑚𝑜𝑙𝐿−1 [𝐵]𝑚𝑜𝑙𝐿−1 Muk;gj;jpy; cUthFk; Ntfk;
vz; −1 −1
(𝑚𝑜𝑙𝐿 𝑠 )
I 0.10 0.10 1.5 × 10−3
II 0.20 0.20 3.0 × 10−3
III 0.20 0.40 6.0 × 10−3

NkNy cs;s juTfspd; mbg;gilapy; gpd;tUtdtw;wpy; vJ rhp?

(A) Ntfk; = k[A]2 [B]2 (B) Ntfk; = k[A]0 [B]
(C) Ntfk; = k[A][B] (D) Ntfk; = k[A]2 [B]
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13) Calculate the order of the reaction A→ product, from the following data:
[A] molL−1 d(product)
(molL−1 s−1 )
dt
0.003 5 × 10−5
0.006 40 × 10−5
(A)1 (B) -2 (C) 3 (D) 2

13) A→ tpisnghUl;fs; vd;w tpidapd; tpidtifia gpd;tUk; juTfspypUe;J

fzf;fpL:

[A]molL−1 d (tpisnghUs;fs;)
(molL−1 s−1 )
dt
0.003 5 × 10−5
0.006 40 × 10−5
(A)1 (B) -2 (C) 3 (D) 2

14) Calculate the order of the reaction A→ product, from the following data:
[A] molL−1 d(product)
(molL−1 s−1 )
dt
1.5 60 × 10−6
0.5 20 × 10−6
(A)1 (B) -2 (C)-1 (D) 2

14) A→ tpisnghUl;fs; vd;w tpidapd; tpidtifia gpd;tUk; juTfspypUe;J

fzf;fpL:
[𝐴]𝑚𝑜𝑙𝐿−1 d (tpisnghUs;fs;)
(molL−1 s−1 )
dt
1.5 60 × 10−6
0.5 20 × 10−6
(A)1 (B) -2 (C)-1 (D) 2

15) Calculate the order of the reaction A→ product, from the following data:
[A] molL−1 d(product)
(molL−1 s−1 )
dt
0.4 32 × 10−4
0.2 8 × 10−4
(A)1 (B) -2 (C)-1 (D) 2

15) A→ tpisnghUl;fs; vd;w tpidapd; tpidtifia gpd;tUk; juTfspypUe;J

fzf;fpL:
[𝐴]𝑚𝑜𝑙𝐿−1 d (tpisnghUs;fs;)
(molL−1 s−1 )
dt
0.4 32 × 10−4
0.2 8 × 10−4

(A)1 (B) -2 (C)-1 (D) 2