n

:E::m:÷÷±÷÷:mes
Functionalism .

Alkynes & Alka dienes

&
.
Aldehydes ketones

• 10
,
2930 Amines ( Cn Hantz N) .
Alcohols & Ethers

•
Acids & Esters
•

fyqqtionallsomen.sn#o zoo 30
↳ Han

¥3,121.IE?uHz)EH5NH-czH5 fats Enya ] 's

]
-

A- ->

ME
(4
10 t
Hit N
Cq Hq -
N Hz zo 30

n .
.

# 1. Iii I ] Ignition
"

Sec Bu Tert By

④-¥②
-

iso Bu
1upACNamesofArmneIfRJ-NHz@gIA.m
✓ tParen (
ines :
word Root)
standard family
hame :

ALKan-L-amine.FI Locant

£HzNHz : Methenamine

EHzCftzNHz : Ethan amine

]
Position
&t3£tzcHzNHz : Pro
pan
- l -
amine isomers

amine
Mk :
psopan z
- -

C
3 2 I
I
3 C c
-
C

d- Nitz
-

J¥§tVHz
'
E- E- E- d- Nitz
1
{ Nitz

Batan I -
-
amine
G- Methyl
Buton -
2- amine
amine
poopan I
)
-
-
IUPAC Name

N
'

Famines ⑦ let R is
'
smaller
group

§
-

NH -
R EG

family name : and R E Parent chain

TWit ( word root

amine
bigger group
or N -

Alkyl alkan - L -

at Hs N Methyl methenamine
÷
-

N Methyl etbanamine
CHZNHCHZCHZ
-

N Ethyl etbanamine
Cttzcttzlvttcctzcttz
-
,

I 2 3

€3 NH-cia-caps-N-meitxipnpanamindfg.gs
Gt3 NH -CHzatzCH3T N Methyl pro pan l amine

!
y;
-
- - -

1GB
(
N -
Methyl propane
-

amine
'm :}
(2 - N
methyl psopanamine )
-
Famines
' "

Family name : let R > R & R > R

↳ Parent ( word root

alkyl alkan amine [ R is biggest group ]
L N
Alkyl , N the
-
- -

)
' "
L N N Diatkylalkanamine ( R R
-

=
=
-

Gt3
'
Gt3 -
N -

cttz : N
,
N -
Dimethyl methenamine
N
Gt3 Cltz ethan amine
-

Dimethyl
-

: N, N -

gig
CHS -
N -
cuts : N -

Ethyl ,
N -

methyl ethanol mine

I 2
1

CHzC
 CH 3
'
2 2 3 ⑤ ⑤ Gt3 z 3
Gt3 Itza oh
-g,Ij-cHT#
-
N
CHS
-

1
2- N N
Dimethyl propane mine
-

or N, N -

Dimethyl propane -
I -

amine 2 -
N
, Dimethyl propanamine
N -

I III : Position isomers or N

,
N -

Dimethyl propane 2 amine - -

Utz
(I) l l 2 3 4
-CHzCHzCHzCHzJ batan I amine
CH3CHz- N : N -

Ethyl ,
N -

methyl -
-

(II ) Gt3 z 3 4
Ctbcttz N butan
N
Ethyl N
methyl 2-amine

gigahertz
- - -
-

:
-

1 II. II : position isomers

£+3
cH3CHzI¥z-CHz-It7cH3 NYI
'

Et -

city

CH3
3
Metamensmcnzyzotminesn.TO Metamerism is not
in 10
possible amines

④ R -
Nit -
R
'
(Position)
Catti , N :
[ Hz
-
NH -

Cltzcitzcttz
-
& the NH
- -
isopr
]
↳ [CzHs -
NH -

GHS
]→ £
Metamer
;Bs4oBu
GHB H :

[ Me -
NH -

GHG
Sec-

By
] Types of isomers ?

fEeEIIit7i9.oprin?IIFsfposi.mIanmens4.
onT7neteiYane-imergsoPrH.sIP@Iosi.Inon-T-
Tert Bu
IUPAC ④
 Jinns
R - N=° R -
O -
N - O
functionalism
Xo
L Nitro alkanes
-
Alkyl nitrites ← INITN Game)

( R Noz)
-
(RONO)
•
Gt3
-

NOZ
•
Cttzcttz NOZ

'
]
. -

niinpnpane
:
z Nitro
propane
-
cyanidesllsocyanide.si#i9soacyniadm.dses7E.&
-
CIN

N
-

RIN
NZ C

Alkane nitrile Alkan isonitrile

2 L
CH3C=_ N : Ethane nitrile

EHzcftz.CN :
Propane nitrile
4 3 2 I
Butane nitrile

)
CH3cttzcltz.CN

[Latta
:
chain
: 2- Methyl propane nitrile isomers

Gt3 C
'
* C-C C-C CN c c c j c-
; q g
c
- - - - -
-

CN CN
A. w .
Bondline(dash)representatior
#
A dHzEHz8Hz 1 3

c9bEHzEHzEHz
-
C Hz -

•
n -
Pentane :
5
3
-
C
Hz

• iso Pentane : i
-¥4
pentane
µ
•
Neo -
:
④ Draw all bond line structures of C6Hi4( Hexanes)
or

ALkenes =\
C3H6 : Eltz - EH Eltz , z
or
-
cents : .

I-8¥ , :X
N
or I

•
C -
@ = c -
c

=E
• E -

g- :
ly or

I
CSHO :

ftp.#i)Pentenes
ALkyNES
C3H4 :
HE E- c'Hz # t wrong
↳
3

# z
or

Cqttg : • I -

Butyne or
,

]
z

¥5 ,

• z -

Butene ex

¥54
cEn¥ En
44
re
I ,
the 2
'

-1¥
¥-
Peistyne
-
⇐I 1
4
2 I

2-
Pentyne

fvnctionalgnups.it#-g
/
'

having No c -
atoms

e.g
OH OR
@ther)
- -

.
'
' ,

G C atoms
having Nitz NH
,N
-
-
- -
-

, ,

e.g COOH COOR NO z

- -
. -

-
CHO , -4=0
-
X ( halogens)
--
CN
 O
11
txyhcaa.de R C OH
-
-

- . . - 4 3 2 I
2
OH
Propanol'c acid
3 2 I
•
CHZCHZCOOH
3 #✓
"
o

4 3 2 I
Butanoic acid
C -
C -
C -
COOH
•
on,

3 2 I /
C COOH # OH
g
- -
•

11
o O
11
*
cftzc - OH

can visualise its

you
bond line
representation ?
AbdeYzdeso stig Nig
ldwon.ie?tHgCH3CHzC
, !
"
or

d4tzEHzEHzdH0 :

3 2 I
it
¥70
git

Agr
Gt3 -

CHO :

to
-

't
's
• Y
Cltzctto :

or 1=0
Est o

methyl methanoate
it in
'

Itza
O -

, H Ethyl ethanoate
.

HM @ ✓
Esters - - - -

z OW = Ethyl propanoate
H
O
O

↳
¥↳ -
= Methyl
-
3-
methyl butanoate

Propyl -3,3 dimethyl pentanoate

5 3
=
-

nyt -2,3 dimethyl butanoate

-

\
kes@niIasg.e.s a'Entire 'i
'

: :

Cttzcocttzcttz
.
:
idndnsfnnaamle
CSHIOO : #
¥
CGHIZO : -
all possible ketones
-

IUPAC names
Isocyanide
cyanide
+2¥ ¥ aztsaztznc

( (
,
atsatzcn z
,

N C

4¥= "
3- Methyl butane nitrile
 tGwthoWcan .
-
OH
,
-

NHZ ,
-0 -

,
-
X
. .
-
etc .

E- E- '
c G :
ha G
-

3 z I
c- C -

G : 3h21 G
{1 3

• Give common Name

) Iupac name to
following .
Tefft
'LL'T
'

#
3
3
1- OH I

#ae÷Bguty1 #
2
z
It
# a 3
,

isoatsuoehylog
2
alcohol
n -

Butyl OH
3 I
OH

,
I
H
PETTEY ¥4 # OH
iso -

Pentyl
4 z

↳
OH
neo
pentyl 1 OH

alcohol 2,3 Dimethyl butane ol

-
-

OH
2,33 -

Trimethylbatan -2-01 contd . . .

€4¥ .az#yDipmenehham.neZ-o-2-EthoxypropaneI
tame NO -

MethoxyethaneJ
n#z

I
20

!
4¥
L

2-Ethoxy-3-methy-y~NH-fNThypwpan-z.am
l

€
butane

3
on
zo I

ftp.a.me#y.o
.
.

3
3

30€N-Etnyl.N-methylpropan-2-amine.IS
propane
NFthybutan.am
I
 -utorialSheet

Also draw their Bond line representation .

of each of structures
2 .
Write IUPAC names
following .

cis TTY dis ¥y ciii, TE

liv ) Cv ,
1,1kt evi,
#
C"
Lviii
riff Xiii ) Mor
N Hz

rfoyrcx.sn/n1cxisnyovcxisnHIo-*cxi s#o/cxirvsJ-N~
Lix,

'

cxv )
.¥ (xvi )
II