n

alka dienes
* Alkenes ; alkynes ;

*
vinyl ; allyl
 Pentyl (Cs Hii ) Radicals & limitation of Trivial
system
( 5h12 Cs Hii -

( Pentyl) : Visualise all possible

structures & Name them !!
z° 20 I
Cttzcttzcltzcttzcttz , n -
pentane
CH3CHzCHzCHzc°Hz-:n-Penty
•

/ ↳
| 39,12GHz 919+3
20

] pentyl
aoiygemeT
see

¥
-

20

Ets 9+3
>

3-
Pentyl
EH citadels isoatttnaeheedd
pentyl
, : iso

City
1- @
at5fHCcHz Hein

L
,

Utz 1so-pen
it
at.

attached .pe#r
so

Recall : isas o

CHA
CHI
" -

⑨
J G is
end
attached to the
of chain

III. IH -

cuz -

⑨
 0

I÷cH2_¥i3Tert.Pen
I 20 go
at

\
"
"
10 .
. . .
-
'

CH3

#HIT
-

.
at
I

€④Hzt¥tz No name is

Gt3 Trivial
system
E Methyl ±
-
-
-

beefy ,
Neo -
pentane :

Neo-pent
Tts go
CHS CH Chez
q Gt3 C
- -
- -

3 →
-

l
-

H
C.
Hz CHS
 HomologousSeries@M.fi.Cn
Alkenes :

'

have
'
-
Azn * one
pair of sp hybrid
C- atom

=L
•
Cz Hq : Ethene T T
•
Cz Hs :
Propene spa spa
Cats Butene ! !
) ( double bond
)
.
: one -c=c -

.
Cgtho : Pent ene
! ! - will have isomers .
Czltg : Hzc =
cttz : Ethene ( Ethylene)
( IN ) (TN)
IUPAC name
T
Trivial
name

↳ Hs : Hzc = CH -

GHz : Propene [ Propylene]

TN
4

{
3
Had
2

C4Hg : = CH -

CHzCHz : But -
I -

ene
G- Butene)
IN

Hz 's - EH = EH -
Eltz : But -2 -
ene
G- Butene
IN

)
Note Butene
: I = 2-
Butylene
-

2- Butene Z B -

Butylene TN

contd . - - -
Isomers of Butene contd . - - -

Iso butene
Hf c =cHz :
-

* branched 1 (TN )
alkene - - e .
CH3

Isomers of Pentane ( CSHIO)

• Hz 's = EH 8HzEHzc%z : I -

Pentene
I 2 3 4 s
( IN )
•
Utz CH = CH
CHzCHz : 2 - Pentene
( IN)
•

Sci ;
Sci Eg-c
C
Basic Parent carbon chain : ( From alkenes )
2 I

• Hzc = CH
z → Hz- :
vinylg.ro#
Ethene ↳ -

H
(radical)
•
Hzc = CH Cl

vinyl chloride
CPK) CTN )
T gs the + oh,

•
Propene : Hzc = CHCH
,
vinyl alcohol
CTN)
↳ 3 2 I

H
HzC=CHCHz#
(TN)
-

• Hzc -_
CHCHZCI - Allyl chloride
Hzc =
CHCHZOH
Any , alcohol
•

→
 Hz C = CH -

CHZ Hec = CH CH
Ty
z
-

T T
sp2:Vi
(allyl)

\ a

.
Hzc

"
so
=
zo

q
-

sea
C

" 3)
Hz
vinylic (NO TN )

a
F not of
,
•
CHzCHzCH=CHz much
importance
\!
:÷!!
vinylic Csp)
x is and
n
a. .
20
C
Hz H CH =CHz
q
-

contd
⇐ allylic )
. . . .
 Butene
CH=CH3ballistic
•
2 -
:

,
f a tic
/
X
20
( same)

CHZ CH
=cHCH3
-

CHzg=CHCHz
-

@ allylic)
@vinylicJ.iso.s
:
"" i .
A :
ltomologoussen.es
'
Cnttzn
having of
'
M F
. : -
z . a
pair
Sp hybridise d
C -
atoms
OR -
CE C (A -

⇐ c-

Czttz :
Ethyne Triple bond ]
CzH4 :
Propyne
) isomers
Catto Butyne will have
!!
: .

Csltg :
Pentyne
contd - -
-
GHz : H CECH :
Ethyne Acetylene
IN

↳ Hq : HC E C -

CHZ :
Propyne NO TN

IN

Catto Itc EE 8HzEHz : 2

Butyne [But zyne)
-

:
- -

( IN)
ditz -2=8 Eltz Butynq
-
: 2 -

, ,w,
C5H8 : I 2 3 4 5
HC EC CHzCHrCHz : I
Pentyne (in,
-
-
•

CHZCEC
i 2 3
-

cHzCHz
4 5
:
2-
Pentane GN)

• ⇐"

pentane
iso -

,
Basic parent chain from alkynes :

sp sp
HC CH HC C -

Ethyne Ethynyl radical

(IN)

eg
.

HC
He C- Cl

c- OH
] ?
not important
at all
Note :

Ford root ↳ Two

families ?
having both
spYsp3
c=C CEC hybrid
-
.

Butenyne
:
atoms
(first alkenyne ) C -
 A-
Some more
Lkehynes
C C =C Cz c G- C C
's ⇐ c
- - - -

Ips Isps Tsp

C -
C IC -
CEC . Can we have a

branched one ?
(having 5C atoms)
⇐c
g
-
C -

C
ALKAD@ENESQyczcgHomologousSeriesJt.T
no Pairs of Sph hybrid carbons

( -

g
=

g
-
double
bonded
• Cummulated ( Allen es
)
*

Conjugated
• Isolated

MF : CnHzn z Observe that these are

Isomeric to
Alkynes
Cn Han -
2 : M F
-
: C3H4 - Propyne
f Can isomer
,
alkadienes
c c '

-2
'
'
when a diene has successive c -
c double
bonds ( as shown above
) : Cam mutated Dienes

tone
ttzq-c-CHZJPNpaq.ee
' '
have
.

sp
( T -
hybridized carbon
sp
Spz sp atom
sp2 sp2
1 t 7
(Butadiene
.

GHG
,

C
c=q=c
-

: -
:
2 I

sp t.2-Butadiene.TV
 Conjugated Dienes :
having alternate =/ -/=
carbon -
carbon bonds

C4H6 !
4 3 2 I

C. = C -
C =C

If ← conjugated system
( 1,3 -
Butadiene ) isomerism ?
conjugated I z 3 4
C=C= C -
C

4,2 -
Butadiene )
Cummulated
[ 5H8 : Cummulated dienes

I 2 3 4 5
c=C=C -
C -

C : 1,2 - Penta diene ( IN)

I 2 3 4 5
c -
C=C=C -

c : 2,3 -
Penta diene ( IN)
4 3 2 I

#q=C=C : 3- Methyl -1,2 fbutadienef

-

⑦ Branch
Cstts :
conjugated dienes

I 2 3 4 5

c=c -
c=c -
c :
1,3 -

Penfadiene

#=§-⇐£
¥
: 2-
Methyl -1,3-1 butadiene

Isoprene (TN )
Note :

{⇐ - E -
E :
1,4 Penta diene
-

cummulated
• which is neither nor
conjugated
is Isolated .

dienes with
* visualise all possible
M F -

: coho : classify them

!!)