n

a
 n

• Isomerism &
IUPAC Nomenclature -
I

• Answers to Tutorial sheet

 Tetorialshe.ee#Answe@
Write the Trivial
the
Names of following :

: :÷÷÷:: ÷ f
1 .
CCCH 3) 4
Me -

f -
me 7 .

Cltzcocl Acetyl chloride

me
Neo pentane

2 Chez at =
Cltz
Propylene 8 CHS COO Gt3
Methyl
acetate
. .

: :c:c:::÷÷¥÷¥: .

5.
Htat§Ha , coho ,
11 .

HzMethyl-a⑦ -
O

vinyl ether
" Me
smile
• ' 2-

n'yicmon.de
'

> contd . . .

Methylene .

Isopropyl methyl ether -

 cetate

.e /. . i:. . . :. .a
O

'3 . cH3coNHz Acetamide zo .

tpeHny9t2afHohg
CH3
14 .
CHz-c.it COOH tsobutyric 21 -

CHS acid

alcohol

::÷÷÷
HzC=CH0H vinyl
÷
÷
" 22 .

:*
17 .
OH
teayteohboetyl 24 .

CHcN Ats
Isopropyl
cyanide
nzopr
18 .
Mez.CH O Me - -
25 . Etz
ether
isopropyl Methyl / amine

19 .

H-NHz CHS
amine
Diethyl -
n -

propyl amine
contd . -

butyl
-

Sec -
Fill in the blanks .

I .
Total number of structures ( isomers) with ME

of C4Hs Clz is - .

2 .
The smallest
'
alkyne having 10,20 ,
30 It atoms -

has c' atom & H' atoms

'

- - .

3 .
The total number of Pentyl radical that can be

formed from CSHI , -

is - .

4 .
The total number of alkanes that can be

formed with ME : C6HI4 is -

.

Contd . - .
' : ace

acidic ③

c -
c -
c- c C c c c
c
- - -

did , di di c -
E c
③

d:
-

c-c-c-cc-c-c.ec
l l
eds ki
l l
Cl Cl Cl C, C -
d -
C ③
l l
Total isomers =
@ Cl Cl

&jo
Z H H
-

"

Hzc
-

÷ 'q--
It
it

cttz
5 I
3 .
4 3 2 I 5 4 3 2 5 4 3 2 I
-

C
'
C C C ca C c C C C C c C-C
-

C
- -
- - - - -
- - -

' l
p l
4 3 2 I 4 3 4
$2 I 4 3 A 2 I 3 2 I
c c c ;
c-I-c-c.c-g-c-c.GE
- -
- -

c -
- c- c
l ' s

C
z CZ I

⑧
'
c- c .
g
- -
 4
64
I 2 Z 5

Coffee
.

c-c-c-c-c-c.FI , 2 3 4 5 I 2 3 4 5

Lecce ; c-c-c-c-#
l l
C C C

⑤
l 2 3 4 I 2 3 4

Sis
' l l
C C C

5 5
34 1 2 5 I 2 3 4
CSHIO

jc-c-c-C-ck-q-E-Ed-E-E-EE-g-E-d.co
.
C=C : -
C-C -
C

. CSHS : alkadienes c' EE

⇐
- E E -
⑤
I 2 3 4 5
-

'
e - E -3=9
£
isolated 2*2=2-3*5

⑥
 of possible alkenes
5 .
The number
having M F
-
=

↳ Ito is - .

6 .
The number of alkadienes (all types with
ME : CS Hg is - .

7 .
The number of possible tri -
chloro structures
F C3H5U3
possible with M . .
= is -
.

8 .
The number of 4014 -
atoms in neo -

pentane
is - .
 Cl CI

7
.
Czttsclz : C -
C -
d -

Cl ; c -
c -
d -
ol
l l
Cl Cl Cl

④
'
c-
g-
c- a

E II
s
-

Cl . ,

pentane
49
g .
Neo -
:

cuz atz No -
of

Thanks !
!
Isomerism organic compounds having same

formula ( M F
)

I :÷÷÷÷÷:÷¥÷÷÷÷s
molecular .
.
but

Tiffing at least one or

--

-1
Tutu's
or constitutionalism
stereoisomerism
conformah.to#GeImerts&/
• will cover in
PART II
-
opti
stnecturalcconstitutionablsomersJ.io
organic compounds having same M - F but

having different relative arrangement

atomic

Ituano or
DDplane( plane of paper) .

Basically ,
having different structural
formula ( s F.)
.
.

- "

a.rnetamerism.TT#TPosihon/!5.TautomerismT-3.Fonc
↳Tf ↳

6.Ringchai#
wPACName.sn# Basic Rules for writing Names : -

Identify
the toga.tn?dca97bIPnlGdhain ]
g .

*
) alkenes) alkynes/ alka dienes alkenynes
Alkanes

nota ¥4 to to =

pair
( ) of

z.si#nu:nbe:esn4sa:aenntfcn'ain] # =]
How ?? →
cont. . .
 -
G should -

get

tyg
lowest
/ 3 4 Parentcaba.ca
99%37
2

-
- - - .
Longest & continuous
I 2 3 C - C
- C Charis

Decc .
inclusive of G ??
X 2x X 123£ idea
wrong ?
Iso butene c-c-⑦

i
or
y,
It does not include
C

function
c -
C -
c
- # group

it does not
2 3 4
includes

-§-c⑦
c -
c

it 1
4C -

parent ( itiischndes G)
 locants ( 1,33

(
2 .
: . Give Number .

J
- to the
.

chosen ?) parent carbon chain

Such that

E'those.is?:stFoses::uPoms:Yhge:sI:tn,
'

I
'

* After , give second preference to

parent 3 2 2
branch ( if present)
3 2
of
I
alkyl ( usually)

G
c-c- c- Parent carbon

xxx
q ( 577210ms)
4 3 2 I
I 2 3 4
C-c-c-e.CI
* →
e- ac
3 .
Write IUPAC name .
How to proceed .

④ observe word root .

(No .
of c- atoms in
chosen
parent chain
② follow standard
lUP family name .

Aek'e
' '

ene e
g
= :
* -

T "
¥ Diane family name
wood root
of
word root

'
Aek'
'

* = yne e.g
n
.

2
9 family
word not name

④ Mention ↳ cant of g
& of branch (side chain
)
 • IUPAC Names
Alkanes :
¢nHzn+z) .
Isomerism

( type
Cgttio : (Batanes) 4 3 2 I

)
c-c- Butane

3 2 I
aims
CIN
I
2- Methyl propane ?
.

⑤ Branch
Gide chain
toners
M F
Isomers having same .
.

but differing in type of

parent chain ( having different
word root)
 Isomers
of Pentane (Csttiz)

)
•
c-c-←c Pentane
3 4
'%÷
2. 2

c-# 2- Methyl butane "

"
C

•
i- a. .me#*...e
Methyl pentane
C
3-

46¥14}
Isomers of Hexane (
q s
It , 2 3 45

Ttc Sgt ←c-c-c

I I Hexane
methyl pentane
C C
CZ 2
-

l 3 4 1 2 3 4
I
Tv Sect Ic-c-c-cJ
- l l l
C C C
contd
Dimethyl butane 2,3 Dimethyl butane
. - -

2,2 - -
 4C
-

• I, HI, II. I : are chain isomers of I

÷
• II
-
& I : are chain isomers of I
,
II , II
- -
" "

4cm
6C 5C
are chain
& likewise
4C
trap :
CI ,
IT ) ; (I ,
I ) : are not chain isomers

←✓ Then what are IT & I

]
I & II

positionlsomers.TW
Isomers
having same M F
-
t
but
' '
differing position of
in posting
branch if
present) along
contd
G or a .

the same
parent chain .
 Isomerism
) IUPAC names in Alkenes ( Cn Azn)
2 3 4 I 2 3 4
I II
c-c=←J
.

Colts
.

But - I -
ene But-2 -
ene
It .

c={-c£3 2-
Methyl prop
-
l -
ene

{ .
I & II : Position Isomer
Csttlo :
z z q s
. III is chain isomer of
I .

Fit 1
Pent c-E=c-E#
2
-
I -

3
ene
4
.
I III.

IT
Scientia ene
-

c-ETQi-Inthyibut-z.ee )
.

Methyl but I 2- - -

ene I
,
I : Position
I III II : Position
II. I : Position
I
E-E-c# 3-
methyl but I ene
- -
contd - - -
 II II Position ( in position of I '
w.at
* :
change
& branch
)
* (III) & ( II
,
II ,
I ] are chain isomers of
5C 4C each other

TsminAye( Cn Han -

2)
I 2 3 4 , z z ¢
GHG : tcc ←czc-J
But But -2
tyne \ -yne
-

/
I
3 45 Position Isomers
C←c
2
↳ Hs : I

Pent Kyne c-c=cI#

↳
-

*
-
4 3 I / Pent 2-
2
yne
-

Position
#qzzc
position . I & II :

Methyl 3- but l yne

- -

.
III is chain
isomer of III
 Alkadienes ( Cnltzn ) -
z : Isomeric to alkenes
( what type of Isomers)
Ca Hs : ftp.utat.2-diene ? ??

c=c-E£ Buta -1,3 -

diene
) Pi%ihs
C=E=5 Penta-1,2

}
Cs Hs : I. -

diene

II.
g-e=c=gT#t Penta -33 diene
-
] 9%1%7 ,

II .
c=E-c=c# q
Penta 1,3 diene
- -

I 3
47
2

•
.

II is chain
nyibuta-i.rs ) oYs -
diene
.

isomer of I, I &# .
Alkenyne : Focus on
only IUPAC names

£ [ -
' I 2 3 4

Cee ]
,
-
z 't
,

But-l-en-3-yneJ22.rs
4 5

c=c-c-c=#

3-ynefpositioni-IF.me#.u+.. en.. . g.tn!in

2 2 3 4 5 Pent -
I -

en
-

Kyne
C=c-c=←€
pent I -
-

en -
 TtorialSheets(HT#
1 .
Write all possible structures having M F -
:

Ca ) CG Hiz (b) Colt , o

and give their IUPAC names

only .

2 .
How
many
30 amines can be drawn
having 59 f
-
:

structures)
CSHBN ? (only

3 .
Write IUPAC names for following .

(i ) HC E C -
CH = CH - CH
=CHz ( ID HCE C- CH - CH kHz
iiis Hsc " ""
Ifc
't
2*3
I
-
-