n

IsomerismflUPACNames.IT#
 Isomerism
✓ →

¢
✓✓1.ChainT
t.MetamerismJL~2.posih.org
5.aestomen.sn#p3.FunctionalJo6.RingchainJ
•

f
<

Isomers M F
•

having same .

but differing in type of G .

different Physical
lsome①
•
Isomers have
& chemical properties are functional
, →
* AFynesdtkadenesl.cn Hzn -
z ] C4H6
* A÷hydes&kebnes [ Cn Hzno ] ancfnetalkadiene
* TEthe [ Cn Han -120 ] Ccs Hg )
* #boxylinds&Este ( Cn Hznoz ]
* tf Ccn Hzh -13N ]
*
tigon [ -
⇐N E -
NEC]

* Titmice [ -
N=o & -
o -

]
N=o

±
lUPACName→&Jpeofisomerism
Aldehydes & ketones ( Cn Hzn
o

ia*o :

* ECHO & }=o ]

i::÷
as two
different
functional groups
Common
group :
-
§ c-
Carbonyl group
-

C I \, @ keto
)
O O

It R-c-R.ly
•
aldehyde . Ketones

i→¥
C3H60 :

z E E ,+o
-
-

→
F. I # -

an
aldehyde a ketone

f ] ¢Hz=§
C4Hso : to

cHzCH3
]
↳ F. If
 IUPAC names in &
ketones
l l .

Family name :
A⑦
9 g p
a
word root G
Ttd word root

( IN) common Name

#
Iupac
2
(TN )
HCHO : Methanol
Diao : Ethanol

IE¥¥I÷ IIE:3 : :
'
:

#⇐¥zqcLto
" chain
→
: 2-
Methyl propanol Isomers .

CC 4480 ]
Note : Do not specify
Locant of G here .
 O

E
'
ketones : R -
-
R
°

Igt 2 2
: Pro pan -
2 -

one

'
Acetone
(Dimethyl ketone
)
T Te te

]¥±⇐°¥T
•

* *

Batan -2 one
ECHO
c- -

← - G
f
chain
ketones
§
:

•
Cs aldehydes I -
C -

C-C

(4 possible ) II Q
↳ acHo c

Ic
-

±,

{ LI ,
H-§-cHzC contd. . ..
 I 04131 X X
I .

atz-d-CHzCHzCHz€ : Pen tan - 2- one

@ µ,
I 2 3 4 5
✓

CHz-d-q+z-atT
3 4
I : 3- Methyl baton -2 one
-

@ n,
.

I 2

T
G o

III . CHzCHz-d-CHzCHs# : Penton -

3- one
@ n,
I 2 3 4 5
T
G

nnaiinsoisnoers.rs/F-If4Y9-atJ
• I & II : chain isomers

.
I & III : Pose
: aces : x

aldehydes
ALcoholsftthers-i.cn/tznt#
• Functional Isomers :

M -
F
TY Ethers
CZHGO
'

CHZCHZOH →←CH3 -
O -

CHS

↳ Hso :

( 'Iz÷t¥HgoH )
ca fats o chats
]
-
-

→ Fa
( 4h00

a.akohds-h.FI#caHs-oIczHs ]
: c
Uts o c c
- -
-
-

[ C4Hq OH
]
-

←
f f y atz o c c
- - -

,
'
 IUPAC Names :

I iY÷9
Jato Ethers

state.d;e D
.me :

.
locant

Eltz It

Ettzditzott
?

:
Methanol
Ethanol
]

yo÷g¥t ]
Pro pan t ol Position Isomers
!
- -

Pro z ol
pan
-
-
CLIHIOO : C4Hg -
OH ( Butyl alcohols
)
.IE#-EoH
]
I : Batan I ol
3%2:3 #
- -

'

± OH : Butane .
. ,
.

) ?%{mI÷÷¥
I ol
HI
.CI#-goH:2-tnethylpropan
- -

tyg methyl propane

z ,
F- i o
,
-
-

't

note :
areas!!:S
 IUPAC names : Et L -

ALalk
' T T
R -

o -

R G word root

let R is the
bigger ( larger)
)
)
' '
& R CR ( is smaller) -

or =
Alkoxy → G
& - R = Alkane

•
cetz-o.CH z :
Methoxy methane ( Cz Hoo) T word root
•

CCHzCHz '
.

Methoxy ethane Ago) (Parent chain

↳ Hyo O
'
.
I 2 3

:np'In:]
Position

I
I Dec
-
: 1- Meth

isomers
: z meth
II.
-

-
cHade±a,# Ethoxy ethane
 )
I 2 3
I .

City
-
O -

cHzCHzCHz
I -

Methoxy propane
→
Position
I CH z -

o
-

IH -
Eltz 2 -

Methoxy propane
CH3
I

II. CH3CHz -

o -

CHzCHz Etboxy ethane ]

• Chain isomer of
I & I
??
⇐ )
& III
& III
)
:

:
Metamer
metamer s
) a
special
isomer →
case

Metamer
of chain

.me/-amerismJ

]
R ,
-
O -

Rz ⇐ +

+ r,
Rs -
o -
re
,
)
R # H
(alcohol)
CarboxylicAcids4EsterCnHzn@Functionalisomevsi.M
- F Acid Esters
CzH40z i
CHZCOOH
]→←µ -

Cy
-

O -

Cltz

]
[ 31+60 : CH3CH2 OH

)
H CzH5
q o
- -

↳ its -0 CHS
-

T
what are these ?
Metamer !H
IUPACName.SI# Acids : £R-%OH
4 3 2 I
- - - -

family
JALKanoica.fi?
• Standard name :

T
word root

0 ( Parent)
11
OH : Metanoia acid
1
O

E
⑦Chez OH : Ethanoic acid
-
-

tBzHzdOH : propanoic acid

contd . . -
 4 2 I

)
3

TzttcooH Butanoic acid

i%%%
•
:

3 2 I

butanoic acid
•

Stott : 2-
Methyl
a⑦ M F:-

C4Hg0z

IUPACNamesofEste.rs#

④
-
3 2 I
y
- -

o -

→ Alkyl
O

family name : F-
AalkanoateJ
n T
1 Parent chain = word root
'
R
ALkylalkanoatef.DE
Methyl
O

L
-
o : methanoale
O

. Sto -

:
Methyl ethanoate
2 I

fcH3CHz_ld-O-CH@iMelhytpropanoate321.JH-cooCzHsIo.E
•

2 1
thylmetbanoate

JCH3coo@tsiEthy1etbanoate.TCHzCQcH3cootzCHzi .p
.

zopyletbanoate
"
It
t
:
) isiosmennxlgthanoate
Metamer 's ! ! !
"
MoreE-ampksn.LI
O
3

Itza -c
z

•
:
Methyl -
2-
methyl pnopanoate
I
Cltz

H3CHz
3 2 I

CHz O
O
-CHzC :
Ethyl propanoate
3 111
-a⑦
21
•

Ttc
-
O
: Methyl
-

2,2 -

dimethyl pnopanoate
CHS

go-cIc methane ate

I
• : Isopropyl
Gt3

÷ :÷:::::÷ .
 -utorialShee
structures
Draw all
possible of organic compounds
with and write their IUPAC names
given rn F
.

.
.

(a) Cotto ( alkynes & alkadienesj

alcohols &
(b) CSHIZO ( Ethers
(c) Co Hizo (ketones & aldehydes)
(d) Ca Hs Oz ( acids & )
esters