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VERACRUZ,JOHN LESTER M.

BS CRIM

Thomas Graham developed Graham's Law, also known as Graham's Law of Effusion,
in the year 1848. The effusion process has an important characteristic that Thomas
Graham discovered through experimentation: lighter gas molecules will move more
quickly than heavier ones.

At constant pressure and temperature, Graham's Law states that lower molecular mass
molecules or atoms will effuse more quickly than higher molecular mass counterparts.
Even the rate of their diffusional egress was discovered by Thomas. It means that a
gas's rate of effusion is inversely proportional to the square root of its molecular mass.
Typically, this equation is applied when comparing the rates of two different gases at
equivalent pressures and temperatures.

The kinetic energy of gas particles is high. Since they can move quickly, there is a high
rate of diffusion. Large interparticle distances are essential for diffusion because they
enable the other gas's particles to fill the space between them.

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