~ POKHARA UNIVERSITY Level: Bachelor Semester Spring Year: 2019, Programme: BE Fall Mas: 100 Cou Chenisey ass Masks 45 Time ahr. Candas are regured fo giveth anewers in thir own words fer ‘x practicable ‘The flgures nthe margin nice full mars Atempt all the questions. 4) Define buer soliton, Explain the mechanism of acidic butler olution. Calculate the pH of 500 ml of Buffer solution coating (0.2M of ammonium sulphate and 03M ammonium hydroxie which 1521196 fnized in late solution, (Ksof ammoniom hydroxide i 18 «10° 1) Deline lecochemia! cell The standart reduction potentials of Guu and AgIAg eleckodes are 034V and O:80V respetvely. Construct a gavanic cell using dhese Evalue. For what ‘Soncenation of Agron wil he emf othe cel at 23°C be 2eo ifthe oncetation of Co" 0018 2) "Define Ionization enery. What ae the factors whieh affect Discs he variation of LE inthe pero tbe, 1) Give reason: TC) is colored bat THC scores. 3) Za ssare white, Ii) Caienot considered as trans met 8) _Traneton elements show varible oxidation ste 4) Define carbocation. How are carbocation sblzed? Write any two ‘methods of het formation 1) What is feliination reaction? Wie the diferences between SN and SN; ration. 2) Wii notes on i Natal Rubber fy T Nylon66 'b) Define the term polymerization. Explifin the fre radical mechanism forthe poiymeration often. ) How is omen manutscrre? Explain in bit 1) Wie principle and Important applications of mas spectrometry in naa ld, Wet the application of FL. 2) What is water plision? Point ou the major causes of water 7 proluion, tee adverse eect and posible emedis, b) Define alain. How is estimated inthe laboratory, explain? 5 ‘Wet shot ots on: (Any two) 2s ') Aromatic elecuopiie station ection 5) Chromatography ©) Sileon polymerPOKHARA UNIVERSITY Level: Bacelor Semester: Fall Yer :2019 Programme: BE all Mars: 100 Course Chemisy ass Maks 45 Time 3h Candidates are reguired tive thet anewers x hit own word for cas proticabe ‘The figure in he margin dicate fll marks Atept all the questions. 2) What is buffer solution? Write the mechanism of buffer sction of acidic buffer with suitable example. Calculate the pH of butler Selution containing 400m of 0.3 M sete eid and 200ml of 0.6 M Sedum ace (K, of ctc acid is 180") 1) Diflereniate between chemical coresion and. clecrocbemial corosio. From the given electrode potential value answer the following: 1. Write th electrode restion, i. Wet the cll ation fi. Calelate the eam ofthe cell at 298K when Both the eleewodes se coupled topetier EZa" fen =-076V EY Ag‘/Ag = +080 V R816) mo" K! F=96500C [Za 001M —— [Ag’]= 0M ®) Explain te flowing for the nston elements: "form colored compounds i, paramagnetic innate 1) What is leeron affinity? Write the factors tat affect electron aff. Between nitogen and oxygen which one has higher Tonization energy give reson? 8) Esplin te mechanism spd sereachemisry’ of SN: reston. 1b) Whit is eleczopilic aromatic subsiution? Write the mechanism of| Halopeaton aking suitable example 8) Differentiate between themepastc and themoseingplsiss, Write 8 ‘the preparation, properties and uses of| Teflon 1, Polyester i. pve )-Whatisa chemical composition of ural ubbe? How sit 7 processed to obtain cepe rubber and smoked mbber? Wit some scdvanages of vlcanized rubber. 8) What explosive describe the diferent types of explosive. Also write 8 ‘he repantion and wes of TNT and TNG 1») Explain brie: 7 Paper cromstogrpty |, Mass Specwoscopy 8) What shard war? Wie is pes and also methods ofremow. = 1) Define alain. How ican be measured inthe Inborton? Desribe 7 ‘Wate short notes on: (Any to) aes ‘Biologia xygen demand > SN ©) NMR SpectroscopyPOKHARA UNIVERSITY Level Bachelor Semester: Spring Year 2018, Programme: BE Fall Maks: 100 (Course: Chemisty Pass Maks: 45 Time Shs Candidates are reuired 0 give ther answers thelr own words far sx practable The figures nthe margin Indicate fll mars Atempt al the questions. |. a) Waite the mecanism of basic bute solution ving suitable example. 200m of 01M calc acd i mined with 400ml of 02M sodiom ‘sett solution, calla the p of resulting mixture (™*4.74) 1) What do you mean by standar hydrogen electrode? How can we determine te standard electrode potential of ze electrode by using SHE? From the given elect potential values answer the following |. White the electrode reaction. Witte cll reaction. i, Calelat the eam of thecal at 27°C when bth the electrodes se coupled togetier EMg/Mg™ =42370V B Fee" =+048V R814) mot K? F=96s00¢ Me" 01M 2.) Give easons forthe followings: ‘TiCh is coloured but TCL, is colouess {i Tranton element show variable cndstion state. (re }=001m |v. Zn snot considered as anton element. | ‘ik Zn ate are white 1) Define ionization energy. Explain the factors acting negativity How electron afin of chlorine higher tan Florine, 3. @) Define carbocations. How carbocations are stabilizes”? Wit any two 7 7 » a » 9 9 » “bel smebode fii formation ‘What ae elmion rescions? Wits he rechasism and sti} henley ofan seston. ‘Wie te mest of eisionplyeraton ‘Wits condenestion plymeration? Write preparation, propeis sd wa of Non, 6. y Compare he proper ora aber an cinder Witte ripe and apeaons ofa spestosoy. ‘What re bias? How re they classed? What re the apples 7, of besos? ai, PR ©) What is water palon? Discs ts aes, eso human eth and waysto cool it. 3 1b) What shad wate? How can tbe measured in boron? 1 ‘Wate bot notes on: Amy two) 2s 8) Mechanism of rsing of ron é ») Nizaton 0 Ozone layer depletionPOKHARA UNIVERSITY Level Bachelor Semester: Fal Year :2018, Programme: BE all Mars: 100| (Coane! Chemisy Pass Marks 45 Time he. Candidates are required to give thelr nsrers iter own words a for x prateabl ‘he figures in he mara indict full mars. tempt al the questions. : 1) What do. you mean by acidic buler? Deve Henderson Hassell equation for sce buffer. Caleta the of 100 mt ‘of O4NH soltion in which 2m. of 05M Helis added. (PKs = 474) ') What do you mean by standard hydrogen electrode (SHE)? Calculate the eff the eal at 25. Elena 7104 Eran” 2009 trees] =05M, tnetytoam 2) Give reasons 3) Second ionization energy is greater than rst ionization eniny i) Elen ffinty of rine i es than chlorine Ii) loianton energy of galium is highe thn alumiium 1b) vpltin why zine sulphate satis oles whereas copper sulphate salt is ble colored. Translon metal compounds are generally parsnaget in ate, explin ©) Whats elimination reaction? Write the mechanism of E and Es reaction with one pope example of ech 1) Define fe al, Witte rsction mechanism of fee radical dion ecto, 1) What i condenestion polmesiation? Write the prepartion, propeies and uses of Nson--6, 6. 1b) Write shor nto: 1) "Processing of natural rubber 1) Siiones 1 2) Whats he principle of TLC? Menton its appiatins in nay fil 1) Define explosive. Give the methods of preparation of TNT and its important uses. ©) What ae three important raw teas used in the manuf of cement? Explain ection mechanism of sting of een. 1) What soi polaon? Discuss its effects on agriculture and ving beings. How ean tbe contra? 1) What are parculates? Clasiy particulates, and discuss in rie its effets on human. How can ane contol global warming, and paroles? We short ots on: (Any evo) 2) Steroisomersn ) Ozone ayer Depletion ©) Masespecroseopy s 2s\s ’ oxtank unWversity Let Bacon Semester Spring Year :2017 Proganme BE Full Mas 100 Cone: Chemiey brs Mas 43 Tine i Candidates are required to sve her answer in thelr own word as far ts practicable ‘The fgures in the margin indicat fl marks. Attempt al the questions : 12) What sbufer solution? Define sid and basi buffer. How do you alculate the pH vale of offer mintre? Give your answer ‘lustacing, Hendersa’s Equation. Calle the pH of rested solution sien 100ml of SM HCL is added t0 100 ml of 01M ammoniigkb 4.74) by Define elcromechanical series with application. What i the ‘concentration of Nin the cel at 25%, ithe emf 0.601? Nu(INl2*(a =2)|1Cu2(O7Smeuls) Given E®nilnit* = 0250 BE°Cu*ICu = 0247 1) Define elestzonalfnity- Explain the factors affecting eleewon afin ow electron fit of Chlorine is igher than Florine. 1) What ae tansiton elements? Zine and caémium are aot considered es tans etal give reasons Explain the characteristics properties ‘of wanton clement with regard 0 complex formation i oxidation ste 4) Describe the sracure,sublity and resctions of etocaton, 1) Deseibe Se and EI rection wih mechanism 48) Write the preparation, properties and uses of Teflon and Poiyvinyt chloride 1) What are the demerits of satura rubber? How the prope fit can ‘be improved, explain it 4) Give the principle of mass specossopy. Write the application of| Te. | — 1) What are essential requirements of an explosive? Compare the 7 property of slid and lil propels. 16, 9) What is green hotse effect? Describe the photochemistry of enone 7g layer depletion. ‘ 1) Define seid ai and alkalinity. Discuss biefy about source of water 8 F pollo, is effects and contol measures, 71. Write sr notes on (Any 0) 2s 48) lectonic configuration 1) Cogoton and its mechanism and contol ©) Principle of paper chromatography~ POKHARA UNIVERSITY Level: Bachelor Semeser: Fall, Year :2017 Progamme: BE all Macs: 100 Course: Chemisty Pass Masks 5 Time: 3h Candidates ae requ give thelr answers in theron words afar ‘as practical ‘The figures inthe margin indicate fall marks. Autempt all the questions 1) Desive Hendrso-Hase Bach equation for Acidic buffer. What is the pl of 050M aqucous NACN? PD for Cyne ion is 4:70. Define electrochemical series with applications. Also explain rsting ‘of on with mechanism 1) Define ionization energy. Why second ionization energy is always reer tan fs onston energy? Explain with ube reason and cxamples 1b) Give reasons i. Tranion elements sow paramagnetsm ii MOHD is pale pink, Mas is black and MNO¥ is intensely purple colour 4) Define fee adc with formation structure and stability. 1) Diflrentite SNI reaction and SN2 reaction in terms of thee mechan 4) Write noes on veaization, Nyon and Teflon 1b) Desetibe the mechanism of coadessaton and dion polymerization 1) Desetiethe principle of Nuclear Magnetic spectroscopy 15). Draw a aat nd labled diagram of Mas Spectrometer )Deseibe the chemi of cement 2) Define Ozone layer with its importance 1) Show youragutance with global warming and green hous effet ©) Writ various case of wate polaon. How ian be conto ‘Write short noes om (Any 0) 8) Cxomatography 1) Chemica oxygen demand ©) Optical activity \ asPOKHARA UNIVERSITY Level: Bachelor SemeserSpring - Yea 2016 Progamne Be Fl Mais: 100 ‘Course Chemistry Pas Marks: 45 Time Shes Condes ave ruired to hve teranewersin ther own words for os practicable he figures the margin indicate fl marks, Atemp al he questions 3) Define Bur soliton wit pes and mechani of working. 1) Define standard electrode potential. The standard reduction poeta of Cu"iCu and NI“ cleceodes are 4034V" and 0250 respectively Conse galvanic ceil using these electrodes, Wate the tell action and caleulte the standard emf ofthe eel For wat sonceniaion of Cu", the emf will be zero at 25 if the someentation ofthe Nis 001M 4) Difeeniate between ionization energy nd elect affinity. Why and in what ways does itis resembelmagnesm, 2) Givereasone {Zinc i mot considera ate tanston element. fi PMgOHn,T is pale pink, My is Back and MNOY is imensly pple colour, 8) Difeeminte carbocation and carhanon in terms of framton, structure and sabi, 1) Show th detail mechanism and role of solvent of SN1 reaction and SN2 eatin, 8) Write notes on Bakalite, Nylon an poyurtelene 5) Deserve the metal of processing of Natupl rubber and 8) Describe the principle of mass spectroscopy. Give reason wy °C sarbon dean show NMR phenomenon wile "C shows NMR Phenomenon though the relave abundances of "C and "C carbonate 98.9% and 1.1% respectively. 1) Define bras and cement with examples Descibehow coment manufactured in industry. 8) Define Ozone lye with is impontace,Desctbe How does it firms 7 and delete. 1) Show your aguance with ease of water polation and is eet in § ‘naman eat, What ae the contol measures of water polation, ‘testo notes on (Any two) » ©) Thin Layer eromatogapy ©) Polymerization ©) Opin activiPOKHARA UNIVERSITY Level: Bacelor Semester Fall Year :2016 Progammne: BE all Maks: 100 (Course! Chemisty ass Maks 45 Time Shr Candidates are required gibt anowers i the own words 2 far ax procicable The flgres nthe margin ncte fal marks Atop ll the questions. 4) Write the mechanism of bufer dct of a solution conaiing a 4 rine of mthanoc aiden slum methancat ‘bute soliton consning 04 mo "of moni soln ard 0.6 ‘m0 L of ammonium chloride has prepared. What wil be the pH of thissoltion ater 0.075 M HCI hasbeen aed othe bur (ssune ‘ta volume is uncharged Ky for NH solutions 18 x10” Nils HfO=NHOH ) What do you mean by standart hydrogen elcode? Calculate heemf 43, ofthe following ea 2ai5y20(0.MYICO"CTSMYCus at 25°C Ea O76 Eon OV Ref314Inet'K" ss00 € 8) Define lization Energy. Why second loization Energy Is greater 1424 than fit lonzaton Energy’? Explain it Discuss the general ed of ite value nthe perio and group nthe perioci tbl ») Givereason 4 it Transition elements orm significant numberof emplees {ie block elements are eduing in rature fi, Transition elemens show variable valency is, Za ale re white ') What are reaction intermediates? Expl the setae and sali of 22264 aieren types of earbocation 1) Poin ou the difereces between SN and SN resctons wih suitable 7 ~ “amples 1) What is pobmeriation reaction? Write the lifernt types of lpm with suitable examples foreach 1) White shor nots on pve fi Vueaizaton of uber 1) Wit the procedure involved in mass spectroscopy. How many NMR signals would we expect in compound ames of CHO. 1) Whit the fintion of brea How cement canbe manufacture, 2} *Kathmanda considered as one of he very pollu ces in Asa. Diseases estes, fet fo human alt and ways to contol 1b) What are he cases of Hardness of water How it an be measured in ‘he Iaboratory. Deseibe ‘write shart tes on (Any 69) 8) Oro ayer dpltion 1b) Markownikor' rule ©) Themaplastis and Themaseting plastics 25 oe sa 26 246 ms9 » » » » » POKHARA UNIVERSITY Level: Baeelor Semester:Sping Year 2015 Programme: BE all Marks: 100 (Coun: Chemisty ass Maria 43 Tine! Shs, Candidates are required ove their answers inter own words far ‘3 proticale The igre inthe margin indict fl mars Atempt all the questions ‘What is buffer solution? Wete mechani to show acd bute solution of benzoic acid and sodium benzoate mantis its P* onstat even aeration of few drop of srg aid or base. Find ‘he P* of bur solution which consis 0.1M potassium acette and 02M of sete aed wih2 % degree of dsociation What willbe changed in PH afer addon of2%10°M KOH soltion(Ky of acetic ci. fx10°) How does zine metal produce single electode potential? Use SHE to etermine single electrode potential copper. Callie the emf of the ‘ll at 300K fom given pas of halal, Zn(s) > Zn*(0.1M) + 20° BF 0.76 vols Ag()—> Ag" (01M) +e Bt -0.84,ols ‘Give reasons fo the fllowings: i. Tics is coloured ba TiC is colourless. ii, Transit elements show variable ondstion stats iit Za" sals are wate iv. Cu isnot considered ae anton clement. Define ionization energy. Explain the factors afecting neg. How eleconafityof cries highe han Fine ‘What is Elimination reaction? Diferenote between Ey and Ey reaton with suitable reason mechs, ow carbocation are produced? Explain thir types along. wih stably orer, ~ 8) What is polymerization reaction? Write the diferent ypes of 8 polymerizton with utable examples for ac, i 1) Esplin bit 3) PVC 1) Voleaizatonofrabber 5) Whats the peineple factional dstlaion? Write its appietons. 1) Wht proper, prepanin and uses of TNT and TNG. ©) Menton chemisey aud sting mechanism of cement. |) Whats oonne ayer depletion? Mention causes, hazardous ats and ctrl measures of global warming. Defoe atin oat Howistmeauvin teary? ‘te shor notes on: (Any Evo) 2) Coresion 1) Niwaion : ©) Thermoplastic and Themosting plasticsPOKHARA UNIVERSITY Love: Bachelor Semester Fall Year 2015 Programa: BE ull Mars: 100 (Course: Chemistry Pass Make 45 Time = 3h. Candidates are rue give ther answers in tir own words far ‘arproticable Th figs in the margin indicat fall marks Atop the questions. 2) Define Single electrode petal. How do you determine the single 233 lestrode potential of Ag — clcrode experimentally? Expsin CCalelate the emf of the cell at 27°C when given electodes are coupled ogee. Zn-+Znt* + 22069 ‘Ag Ag’ + 2098" R= 8314) Imol [En] 1b) Define bute soliton. How does basic br resist the change np on ein few dope of acd ad bse? The pH ofa bute sltion ating 0 molitCH,COOH and 0.5 wollit CH,COONa sound tobe 476. What willbe the pH ofthis solution afer ading 0.1 molt FHL Assume that he volume is unchanged Ka. 75410°) 8) Give reasons forthe followings: {L Titi cooured but TCs colours. Ji Tramion elements show variable extn sate fi Zo" sls re whit jv. Cie mt considered as wanstion element 1) Diferetate between Elton fity and Elecronegtvy. Explain ‘he factor afeting te lonizton poeta ~ OR ‘What are representative elements? Write thelr popes 13) What are enantiomers and diseviomers? We the characteristics of| cmanomes, What are fre ria? Explain the factors th tabilze thee radials, » » » » 9 » “What are Elecuopile and Nuceopiles? Wite the prodvt and 7 mechanism ofthe following chemical rats. i Cliy—CH = Cli, + HBr S008 fi (Clip CBr + NaOH(aq) > i CilerCone HNO} _ ones What is polymerization Testo? Wee the diferent types of 8 polymerization with site examples foreach, Wat short ots on: 7 i PVC fi Vuleanizaton of aber What isthe priaiple Behind mass spectroscopy? Show your 8 scqutnance parent peak and bse peak, ‘What ae hbricans? Explain different kinds of Ibrcans with 7 example . ‘What ae the causes of water polluion? Menton its eet on human lth and nz explain its eonoling measures Define ai politon, What re the factors responsible for ozone ayer 7 depletion and what re ts baradous eft? 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IE TE CC “soba o}a “$Y SNSURLEOAD on aH GOON pug sate i Soa [Hg JERABIOHY WHEWAA MTHS 40. “INLJ0 pos pe powou uouerdand ayt ax suoNDuRG my nes cSHHEHGR AE EHA @ yh ouch sped oye te 3 uossenI0D, ued) oat 5 pba 5079 OFF sume evraup a8 spuog AEN oun pt vs Jo aoionpon poo ave spuog ayeiou Survey punodues oy, suo amp wee yyy woe UaBaupH Jo UoUPo|D Jo NFO 2M 0 IPE 9 oso jo sina yep Jo aiioung soup neds yo gun sSgqna jo wonemuesay 1 wo sou uoKE UA @ geeutcod oqespion Hou) Siajyp 1} OH -voneaoujod aa @OWWARA UIE sk oe Somos Fall Yew 22013 rate Te Falla: 108 ours Chey Poss Marks Tae 3b Conta er rea gv Deemer tae om yor fae cs poecticab he gore the margin inate al cs Asp al the gress” ‘eke the bufer mocha of bist buer soliton giving sues 8 cexanple, Cael he pl of te slit fad by ein $00 ml of (0.2 M acetic sid to $00 mt of @ sm sodium alas. Also caeulte ‘he pH of resulting softion when 1 ml of EAL HC is eld to the love solution, ps fo ost eal 4.1, ¥) How i single elecbode potetial of Ca electode memwed 7 ‘experimentally? From the given eleewoe potntil values answer the follwing: iL Write fe closed resstios ii, Write the et restion, Ti, Cileuate he emt of the cell at 27% when both the loot re coupled tage E'Mg/Mg"* —#2.370v. Wrete” sow | Kees Jagl! x | F=96500C | [Mg"0.1M, [Fe] =001M 8) Give reasons iL onisation energy ofniitogen i greater than oxygen, li, Boctronalfnity of chlrine is higher than fuoin, Ti, Eleewo negativity ofa" is higher than “AP. in. Atomic digo a increasing while moving top to bottom in gro. 1) Explain why zinc sulphate sal is colorless whereas copper sulphate 7 salt is colorful in nature. Why are tanstion elements mostly| | I | | » a » 8 am Behiven emstiomess st sta oie stable tha 2 un scans? Wits Wallets ntechanism fen pansion with example, Cis the propor, poporite ad wes of uylon 6b Stow your aequsatanse om - ‘Valeaiation fier Nylon 66. ‘Weis the procedure involved in T.C. How anany NMR signs would you expect in allan compan i, Cthy~0~ City i CHCH.ON How cepient ean be mimfeetwed? Write th stepse chemical reaction involved during sang of eu, Dine wer polation. Mention aad expaia the eases and effets of| we pall, What ca Be doae to eanol i? What ace green house gases? How are theso eases responsible for lob warning? Explsia tho eects of global wacsing snl how ea it becontaied? Writs short nots on: (Any to) 2 » ° lectrochesicn sues PPeternivtion of bardhess of water Price.gan naj ssa ay nd 0000596 = 4 108 sof s0 10H uo semicon, ALisuaAINA WeWIDIOg « © @