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KVPY [HINTS & SOLUTION] - 2009

ANSWER KEY
Ques. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. D A A A C C B D D B D B D B C
Ques. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. C B C B A A D A D C D C B D B
Ques. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. D C A D B C A C D B C B A B C
Ques. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. D C C B A B A A D B B A A C C
Ques. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans. A B B C D C A D D A A C D B C
Ques. 76 77 78 79 80
Ans. C D A A B

x3 + 3x + 2 = 0
PART-I no solution
One Mark Questions x = 1 only one solution

MATHEMATICS 5. (1 + 2x)20 = a0 + a1x + a2x2 + ------- + a20x20

put x = 1 320 = a0 + a1 + a2 + ------- + a20
1. x5 0  1– x  0 x = –1 1 = a0 – a1 + a2 – a3 ------- + a20
x<1 ...(i) subtract 320– 1 = 2(a1 + a3 + -------- + a19]
add 320 + 1 = 2 (a0 + a2 + -------- +a20]
x5 > 1 – x 2 (a1 + a3 + ----- + a19)
x + 5 > 1 + x2 – 2x + 3 [a0 + a2 + --------- + a20]
x2 – 3x – 4 < 0 3 20
(x – 4) (x +1) < 0 = (320–1) + (3 + 1)
2
x  (–1, 4) ....(ii)
Using (i) & (ii) x  (–1, 1) 5.320  1
=
2
3. x = x2 + y2 & y = 2 xy
6. Points which are equidistant from O and P1 lies on
 when y = 0
perpendicular bisector of OP1
 x = x2
P5
 x = 0, x = 1
 solutions are (0,0) (1,0) P1
1 P4
 when x =
2 O
1 1 1 1 P3 P2
 – = y2  = y2  y=±
2 4 4 2 Similarly for others
 1 1  1 1  In figure points on pentagon are equdistant from points
 solutions  ,   ,–  P1, P2, ...... and O
2 2 2 2
 interior region of pentagon is closed to ‘O’
4. x3 – 3 |x| + 2 = 0 [Let x > 0]
7. Let (x, y) be any point
x3 – 3x + 2 = 0
Using given condition
(x – 1) (x2 + x – 2) = 0
2 ( x  2) 2  y 2 < 3 ( x  0) 2  ( y  3) 2
– 1 9
x = 1, x = =1 5x2 + 5y2 – 54y + 16x + 65 > 0
2
Now, let x < 0 x2 + y2– 10.8y + 3.2x + 13 > 0

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It is a circle, radius = 18.72 d25

x=
Centre (– 1.6, 5.4) 37.27
Hence region is exterior of 25
(x + 1.6)2 + (y – 5.4)2 = 18.72. take d = 9 then x =
27
8. (r + 3)2 + (r + 10)2 = (13)2 d = 9 n = 25
d + n = 34
C
3 12.  Let at x minute past 10 o’clock they
3 D become symmetric
10 We know the speed of hour hand and minute
r hand is 1 : 12
B A  When minute hand moves x mimute distance
r 10
x
 r2 + 9 + 6r + r2 + 100 + 20r = 169 then hour hand moves minute distance
 2r2 + 26r – 60 = 0 12
x x1
 r2 + 13r – 30 = 0 x 12
 (r + 15) (r –2) = 0  = 10 – x 11
12
 r=2
13 x 10 – x 2
 = 10 10
9. To find possible intergal value of 4th sier minimum 12
possible value of 4th side greater than 0 is 1.
120
For maximum possible value.  x=
13
D  x = 9 minute 13.8 second therefore required
time is 10h 9m 13.8 sec.
20
C 13. P = LLLLLL W
A
B 9 8 7 6 5 4 1
P=  ×  ×  ×
let angle ,  are slightly smaller than 180º 10 9 8 7 6 5 4
if ,  = 180º 1
AD = 35 P=
10
 maximum value of 4th side is 34
 1, 2, 3, ------------- 34 are possible value of 4th side
14. Let x student like all three games.
 34 values are possible.
4 p q
R' 3 Cricket a Football
V' 172 .8 3
10. = = x
V 100 4 c
R 3 b
3
r
R'
= 1.2 Tennis
R
Now, ratio of surface area  If x minimum then a + b + c will be maximum
and p + q + r should be minimum.
S' 4 R' 2 S'  p+q+r=0
= = 3 = = 1.44
S 4 R S a + b + x = 74 ..... (i)
Hence surface area increased by 44% a + c + x = 76 ......(ii)
b + c + x = 82 ......(iii)
11. x = 0.d25 d25d25 ------ and a + b + c + x = 100
a + b + c = 100 – x
x = 0. d25
Add (i), (ii) & (iii)
1000 x = d25. d25 2 (a + b + c) + 3x = 232
999x = d25 2 (100 – x) + 3x = 232
200 – 2x + 3x = 232
d25
x= x = 32.
999

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15. Number of integers between 2n and 2n + 1 is 30. As masses are equal for cude and sphere
2n + 1 – 2n – 1 So, ms = vs × density
and  term = 2n + 1 me = ve × density
last term = 2n+1 – 1 as ms = me  vs × density  ve × density

 Sn =
2 n1
 2n  1 n 
[2 + 1 + 2n + 1 – 1]
 vs = ve
4 3
2  r  s3
3
=
2 n1
 2n  1 n 
(2 )(1 + 2)
surface area comparison 6s2 > 4r2
2
CHEMISTRY
= (2n – 1)
2 .3 n
31. Silicon is tetravalent, so it forms SiCl4 .
2
Sn = 9 ;    32. NH4Cl undergoes sublimation while NaCl does not.
 3 × 2n – 1 × (2n – 1) = 9
2n – 1 × (2n – 1) = 3 Oxidation
2n(2n – 1) = 6
It is possble when n is even. 34. SO2 + 2H2S 3S + 2H2O
Reduction
PHYSICS
17. Given mass of planet A = mA 36. As per Boyle’s law
and mass of planet B = mB PV = constant
mB = 8 mA 1
and P 
Gm A GmB V
gA = r 2 and gB = r 2
A B
38. CaC2 + 2H2O  Ca(OH)2 + C2 H2
2 Calcium Water Calcium Ethyne
gA mA  rB 
or    .......(i) carbide hydroxide (acetylene)
gB mB  rA 
 mB = 8 mA 39. As we move downwards in a group, atomic radii in-
creases. So the order will be Li < Na < K < Cs.
4 3 4  rB
rB d  8  rA3 d   r = 2
3 3  A
40. CH3 – C  CH (Propyne) and (cyclo propene)
gA 1 1 are two possible structural isomers of C3H4 .
 4 
gB 8 2
41. Propionic acid and methyl acetate both have same
gB = 2gA molecular formula (C3H6O2) but different functional
groups, so they are isomers.
25. A = r2
A A 42. N2 + 3H2 2NH3
2
A r Initial
no. of
A  A  moles 1 0.5 0
%  2   100
A  r  After
reaction 1 – 0.167 0.5 – 0.5
A 0.334 mole
%  2  0.15 = 0.30%
A 0.334 moles of NH3 = 2.0 × 1023 molecules
43.
235 207
27. 92 U 82 Pb  724 He  4 1e 0
CH2OCOR CH2 – OH
so, n = 4 ( particles)
–1
Alkaline
CHOCOR + 3NaOH CH – OH + 3RCOONa
Hydrolysis
Soap
29 . Bulbs are connected in series and resistance of 100W CH2OCOR CH2 – OH
is greater then that of 200 watt. Triester Glycerol
In series, P = I2 R (Here I is constant)
So, PR 44. Copper cannot displace lead from its solution as it is
So, power of 100W will be greater in the combination. less reactive than lead..

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PART-II 65. Case - I

Two Marks Questions

MATHEMATICS
61. loga b = 4 & logcd = 2
b = a4 d =c2
a –c =7
4 2 a r
(a2 – c) (a2 + c) = 7
a2 – c = 7 & a2 + c =1 not possible
or a2 – c = 1 & a2 + c = 7
2a2 = 8
a = ±2 A1 =
a=2 c=3
 c–a=1
Case-II
62. P(x) = 1 + x + x + x + x + x
2 3 4 5

1 x6 r
=
1 x
a/2 a/2
It has 5 roots let 1, 2, 3, 4, 5 they are 6th roots of
unity except unity
Now, P(x12) =1 + x12 + x24 + x36 + x48 + x60
= P(x)  Q(x) + R(x)
Here R(x) is a polynomial of maximum degree 4
Put x = 1, 2, .......5
we get Case-III
R(1) = 6, R(2) = 6, R(3) = 6, R(4) = 6, R(5) = 6
i.e. R(x) – 6 = 0 has 6 roots
Which contradict that R(x) is maximum of degree 4 r – a/4
So, it is an identity
 R(x) = 6 a/2

30º
r
63. BD  b and CE  c a/4
A a/2

c D
E a/2
b
k r + a/4
h
B C
a
c sin A  b ...(i)
and b sin A  c ...(ii)
(i) + (ii)
(c + b) sin A  b + c  a a
sin A  1 A3 =  a  r   r   = 2ra
 4 4
 A = 90º
Now from (i) and (ii) Hence A1 = A2 = A3
c  b and b  c
 c=b Hence angles are 45º, 45º, 90º PHYSICS
C
u=0
(37 )2  (7)2 – (33 )2 (37 )2  x 2 – (33 )2 h=?
64. cos  = =
2.37.7 2.37.x
A 67.
d
37 33 37
Time taken by the photon, t = d/c

B 7 D x C
1 2
h=0×t+ gt
[(37)2 + (7)2 – (33)2] x = 7(31)2 + 7x2 – 7(33)2 2
x = 40

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72. Initially concentration of salt in solution

1 d2
h= g 2 222  10 –3
2 c
= = 0.2M
111  10  10 – 3
2
gd On dilution the final concentration of CaCl2 will be
h=
2c 2 M1V1 = M2V2
0.2 × 10 = M2 × 100
69. For lens L1, M2 = 0.02 M
u = –0.40 m CaCl2  Ca2+ + 2Cl–
f = 0.20 m 0.02 M 0.02 M 2 × 0.02
1 1 1 [Cl–] = 0.04M = 0.04 mole/L
 
v f u 73. 4Al + 3MnO2  3Mn + 2Al2O3
1 1  1  To reduce 3 moles of MnO2 required moles of Al = 4
   So, for one mole of MnO2 required moles of Al will be
v 0.20  0.40 
= 4/3
1 2 1
  v = 0.40 m Alkaline
v 0.40 74. CH3 – CH2 – OH   CH3COOH
KMnO 4
 for lens L2 , u = 0.1 m Ethanol Acetic acid
f = – 0.1 m (X)
1 1 1 CH3COOH + CH3OH  H 
 CH3COOCH3 + H2O
 
v 0.1 0.1 Acetic acid Methanol Methyl acetate
v=  (Y)

70. After removing charge from P, net force on central 75. On dilution, mili equivalent of the solute remains con-
charge will be : stant.
Initially pH of HCl = 4
Kq1q2 9  10 9  10 5  5  10 5 so normality of HCl = 10–4 N
F= 
r2 12 after dilution pH of HCl = 5
F = 4.5 N so normality of HCl will be = 10–5 N
m = 0.5 kg N1V1 = N2V2
so, acceleration, 10–4 × 10 = 10–5 × V
V = 100 mL
F 4.5
a=  = 9 m/s2 upwards So, 90 mL of water should be added for this pH change
M 0.5

CHEMISTRY
71. 2NaCl + H2SO4  Na2SO4 + 2HCl(g)
(X)
2HCl + CaCO3  CaCl2 + H2O + CO2
(X) (Y)

Ca(OH)2 + CO2  CaCO3 + H2O

lime water (Y) Milky
Suspension

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