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Tugas Analitik Makalah
Tugas Analitik Makalah
2022
SAY INTRODUCTION
Assalamu'alaikum Wr. Wb.
Praise be to Allah SWT who has given His mercy and grace, so that the
author can complete his final project entitled "Qualitative examination of borax in
suggestions. Hopefully this final project can be useful for all of us and achieve its
goals.
Serang, 16 june
2022 Author
ABSTRACT
Borax is one of the dangerous chemicals that is prohibited from being used
in food. However, it is still often found in certain foods such as meatballs and rice
cake which acts as a chewing agent. The purpose of this final project is to
qualitatively determine the presence of borax in meatballs and rice cakes
circulating on Jalan Pancing.
The samples used were meatballs and rice cake. Two meatballs with
sample codes A and B and three lontong with sample codes C, D, and E. The
sampling locations for meatballs and lontong that were examined were on the
fishing street. Samples are prepared through the ashing process. Qualitative
examination of borax was carried out by a flame reaction test using concentrated
H 2 SO 4 and methanol and a reaction test for curcumin paper using 2 N HCl, then
dipped in curcumin paper.
The results obtained from the qualitative examination of borax in
meatballs and rice cakes circulating on the fishing trail are sample codes A and C
which were tested with a flame reaction containing borax because a green flame
was formed on the fire. Sample codes B, D, and E which were tested by the flame
reaction did not contain borax because they did not form a green flame in the
flame. While the sample codes A and C in the curcumin paper reaction test
contain borax because a brownish red color is formed on the curcumin paper.
Sample codes B, D, and E which were tested with the reaction of curcumin paper
did not contain borax because there was no red-brown color on the curcumin
paper.
Keywords: borax, meatballs and rice cake, flame reaction test, curcumin paper
reaction test
TABLE OF CONTENTS
ABSTRACT .......................................................................................................iii
5.2. 18 suggestion....................................................................................................
Table
Attachment
5. Pictures of Positive Curcumin Paper Reaction Results and Negative Borax ...25
CHAPTER I
INTRODUCTION
1.1 Background
Food has a very important role in public health. Therefore, all members of
society, without exception, are food consumers. In Indonesia, most of the people
still have relatively low incomes and education levels. Therefore, their awareness
and ability as consumers are also still very lacking, and in choosing food, they
often ignore the quality. Because food has a very important role in public health, it
is necessary to avoid using food additives that can harm or endanger consumers
(Cahyadi, 2009).
There are so many dangerous chemicals that are prohibited by traders from
being added to food. This of course is very dangerous for consumers. Many things
want to be achieved, including traders want their food to be durable and attract
consumers. One of the dangerous chemicals that are prohibited from being used in
food is borax. Borax is often used as a food preservative. Apart from being a
preservative, this ingredient also serves to thicken food. Foods that are often
added to borax include meatballs, rice cakes, noodles, and crackers (Yuliarti,
2007).
Indonesia. Borax is also known as boric acid, sodium tetra borax or sodium
borate is actually a cleaner, fungicide, herbicide, and insecticide that is toxic or
toxic to humans. The characteristics of foods containing borax are very chewy,
durable, the meatballs are whiter in color, will turn dark gray if excessive borax is
chemicals, the food is no longer eligible. The qualitative test aims to determine
borax qualitatively with a flame reaction and curcumin reaction (Sumantri, 2007).
1.2 Destination
1.3 Benefit
circulating.
CHAPTER II
LITERATURE REVIEW
2.1.1 Definition
Food additives are materials that are not normally used as food and are
usually not a typical food ingredient, have or have no nutritional value, which are
RI, 1988).
Food additives are materials added to food to affect the nature or shape of
the food. Everyone who produces food for distribution is prohibited from using
any materials as food additives that are declared prohibited. Everyone who
produces food using food additives for distribution is obliged to use permitted
in general is an ingredient that is not usually used as food and is usually not a
typical component of food, has or does not have nutritional value, which is
Food additives or often called food additives are materials added to food to
affect the nature or shape of the food. These food additives may have nutritional
additives are ingredients that are added and mixed during food processing to
value and shelf-life quality, make food items easier to serve, and facilitate food
preparation. In general, food additives can be divided into two major groups,
namely as follows:
2. Food additives that are accidentally added, namely materials that do not
have a function in the food, are found accidentally, either in small amounts
them that are still being carried into the food to be consumed (Cahyadi,
2009).
be added and those which are prohibited (called Chemical Additives) have been
additives that are prohibited from being used in food are as follows: Sodium
above, there are still prohibited chemical additives, such as rhodamine B (red
2.2.1 Definition
Preservatives are food additives that can prevent or inhibit the process of
foods that are preferred as a medium for the growth of bacteria or fungi, for
are compounds or materials that are able to inhibit, restrain or stop, and provide
protection for food ingredients from the spoilage process (Cahyadi, 2009).
can defend food against attack by bacteria, yeast or molds. For example, sodium
prevent mold in breads and pastries, sorbic acid is used in in cheese for prevent
1. Inhibits the growth of spoilage microbes in food, both pathogenic and non-
pathogenic pathogens.
3. Does not reduce the nutritional quality, color, taste, and odor of food
ingredients preserved.
requirements.
longer shelf life. Preservatives used must be preservatives that are permitted for
food and added at levels that are safe for consumption. Preservatives commonly
used in food processing are sulfites and sulfur dioxide, nitrite salts, sorbic acid,
propionic acid, acetic acid, benzoic acid, and antibiotics (Estiasih and Ahmadi,
2009).
organic preservatives are easier to make and can be degraded so that they are
easily excreted. Organic preservatives that are often used are sorbic acid,
propianic acid, and benzoic acid. Meanwhile, inorganic preservatives that are still
2.3 Borax
In West Java it is also known as "bleng", in Central Java and East Java it is known
properties. It causes indigestion in humans, and is not considered suitable for use
slightly soluble in water. Frequent consumption of borax foods will cause brain,
liver, fat, and kidney disorders. In large quantities, borax causes fever, anuria (no
pressure, kidney damage, fainting, and even death (Widyaningsih and Murtini,
2006).
sodium tetraborate contains not less than 99.0% and not more than 105.0% Na 2 B
odorless , salty and alkaline taste. In dry air brittle. Solubility soluble in 0.5 parts
which is equivalent to not less than 99.0% and not more than 105.0% Na 2 B 4 O 7
warm air, crystals are often coated with a white powder. Solubility soluble in
form of powder, liquid, and ointment (in the form of boric acid). Borax is also
increase the elasticity of meatballs and noodles. Consumption of borax can cause
abnormalities in the nervous system, digestive tract, kidneys, liver, and skin. In
the nervous system, borax can cause depression and mental disorders (Budiyanto,
2010). 2001).
2.4 Use of Borax in Meatballs and Rice cake
a dry product (rough and not sticky). However, in the Regulation of the Minister
prohibited from being used in food products. Borax is not a food preservative, but
some food manufacturers still use borax as a food preservative. Borax is often
misused to preserve various foods such as meatballs, wet noodles, banana molen,
dumplings, rice cake, ketupat, and dumplings. Besides aiming to preserve, borax
can also make food texture more chewy and improve the appearance of food.
However, borax has been declared as an ingredient that is prohibited from being
used in food according to the Regulation of the Minister of Health of the Republic
With borax the dough can be more elastic and elastic so that it remains attractive.
Meatballs that use borax tend to have a more chewy texture, when you bite
them they will return to their original shape. Another characteristic of meatballs
that use borax is that the color looks whiter. This is different from good meatballs,
which are usually fresh gray in color evenly in all parts, both on the edges and in
In the process of making rice cake, the addition of borax is done in two
ways, namely sprinkled on cooking water or added to rice cake dough, it aims to
more profitable for the seller. The physical characteristics of rice cake containing
borax can be identified by looking at the shape of the rice cake which is dense and
chewy, the color is clean, and can be stored for more than 5 days. In the cooking
process, rice cake that does not contain borax takes more than 4 hours, but if
borax is added it only takes 2 hours to cook so it is more profitable for traders in
terms of fuel. This is what encourages traders to add borax to the rice cake
(Anisyah, 2009).
it was found that there was a preservative suspected to be borax in a snack in the
form of rice cake made from rice. According to the Head of the Food and Drug
Supervisory Section (POM) of the Depok City Health Office, borax is used as a
mixture to make lontong so that it is more durable, has a dense texture, is more
noodles, rice cake, meatballs, pempek, and shrimp crackers taken randomly at
84% were positive for borax. Of the 9 samples of lontong, 11.1% contained borax,
and of the 13 samples of pempek, 85% were also positive for borax. And what
was even worse were 12 samples of meatballs, 7 samples of black grass jelly, and
This test is often called the flame test. The use of methanol or ethanol (the
former is preferred because it is more volatile) in a small porcelain dish, and this
alcohol is ignited and the alcohol will burn with a flame with a green rim.
acidified with dilute hydrochloric acid, then dried at 100 0 C, the paper becomes
reddish brown. The paper is dried most simply by wrapping it around the outer
edge near the mouth of a test tube containing water, and boiling the water for 2-3
minutes. After the paper is moistened with dilute sodium hydroxide solution, the
powder added, heated over a Bunsen flame, ashed in an electric furnace, and cooled.
The ash was added to water and a few drops of 5 N HCl was added and then
filtered, then added 4 drops of saturated oxalic acid, and 1 mL of turmeric ethanol
extract. The solution was evaporated on a water bath to dry. If a red color (cherry
red) is formed, it is positive that it contains borax, which when dilute NH4 OH-
NaOH is added to the rest of the precipitation, a green color will be formed. black.
CHAPTER III
EXPERIMENTAL METHOD
3.1 Tool
The tools used are stirring rods, porcelain dishes, matches, mortar and
pestle, dropper pipettes, volume pipettes, test tubes, spot plates, and furnaces.
3.2 Ingredient
methanol, samples of two meatballs and three rice cakes circulating on the fishing
road.
The sample was weighed as much as 50 grams and then put into a
porcelain cup. Put in a furnace, then ash (in a fume hood). After turning into
ashes, then the ash is divided into two (2) and an identification reaction is carried
out, namely:
3.3.1 paper reaction curcumin
Some of the ash was dissolved in 2 N HCl, then dipped in curcumin paper.
If the borax is positive (+) there will be a color change on the curcumin paper
Another portion of the ash in the porcelain cup was added with
4.1 Results
and B) and three lontong (sample codes C, D, and E) circulating on the fishing
Table 4.1 The results of qualitative examination of borax in meatballs and rice
method was carried out. The qualitative test was carried out to determine the
presence or absence of borax in the meatballs and rice cakes being tested. The
sampling site for meatballs and rice cakes that were examined was on Jalan
Pancing. Borax examination was carried out on two meatballs with sample codes
A and B and three lontong with sample codes C, D, and E qualitatively circulating
The qualitative test used in this examination is the flame reaction test and
the curcumin paper reaction test. In the flame reaction test using H 2 SO 4 (P)
reagents and methanol then burned to form a green flame on the fire. So that the
results obtained that the meatball with sample code A tested with a flame reaction
gave a positive result of borax because a green flame was formed on the fire.
Meatballs with sample code B which were tested with a flame reaction gave a
negative result of borax because there was no green flame formed on the fire.
Meanwhile, rice cake with sample code C, which was tested with a flame reaction,
gave a positive result of borax because a green flame was formed in the fire.
Lontong with sample codes D and E which were tested with a flame reaction gave
a negative result of borax because no green flame was formed on the fire.
In the curcumin paper reaction test using 2N HCl reagent will give a
brownish red color on curcumin paper. So that the results obtained that the
meatball with sample code A tested with the reaction of curcumin paper gave a
positive result of borax because a brownish red color was formed on the curcumin
paper. Meatballs with sample code B which were tested with curcumin paper
sample code C which was tested with the reaction of curcumin paper gave a
positive result of borax because a red-brown color was formed on the curcumin
paper. Lontong with sample codes D and E which were tested with the reaction of
curcumin paper gave a negative result of borax because it did not form a brownish
prohibited from being used in food in accordance with the Minister of Health of
for health. However, based on the results of the inspection, borax was still found
in the meatballs and rice cakes circulating on Jalan Pancing. This research is
similar to the examination conducted by the Food and Drug Supervisory Agency
(BPOM) in a number of schools in Depok, West Java, which found the presence
of a preservative, namely borax, in snacks such as rice cake made from rice.
in the form of wet noodles, rice cake, meatballs, pempek, and prawn crackers
were positive for borax. Of the 9 samples of lontong, 11.1% contained borax, and
of the 13 samples of pempek, 85% were also positive for borax. And which more
12 samples of law crackers, 100% positive for borax. This shows that the use of
borax by traders or sellers is still often used in food, especially in meatballs and
5.1 Conclusion
meatballs and rice cakes circulating on the fishing trail are sample codes A and C
which were tested with a flame reaction containing borax because a green flame
was formed on the fire. Sample codes B, D, and E which were tested by the flame
reaction did not contain borax because they did not form a green flame in the
flame. While the sample codes A and C in the curcumin paper reaction test
contain borax because a red-brown color is formed on the curcumin paper. Sample
codes B, D, and E which were tested with the reaction of curcumin paper did not
contain borax because a red-brown color did not form on the paper. curcumin.
5.2 Suggestion
other than meatballs and rice cake such as noodles and rice cakes shrimp
crisp.
tests are carried out in addition to qualitative tests such as quantitative tests
Yuliarti, N. (2007). Watch out! The Danger Behind the Delicious Food .
Yogyakarta: ANDI. page. 7-10, 49-51.
Appendix 1. Tool Drawing
Picture 3. Methanol
Appendix 4. The results of the flame reaction (ash+ H2SO4 (P)+methanol) are positive
and negative for borax
Figure 6. The result of the flame reaction (ash+ H2SO4 ( P )+methanol) which is positive for
borax
Figure 7. The result of the flame reaction (ash+ H2SO4 ( P )+methanol) which is
negative for borax