fasts Begs BITS PTAT Qualitative Chemistry ‘pfTs (Introduction) 4 fag ope Freres ore yer ASS, AA Id (matter) & feSif “AS (radiant energy) | 74 Tacs A aeaR fafoy sea Te ray | as toes aeace fog yA Se oo tere onfaera, ATE PAT 6 HAMTGCS aera Rar creat aca aR -PaP eT Reels SAS SQ wate PMMA GHYS | aM ACA ACTH aR mi wens Cats Ts eter FAS I eT UAE PN AAAI ‘afty, ara rer Ber Ren BLA tet | TTS MS-wae fice OPT; FRY A SITS-O I AEE PTAA FA ONS PTA STC A age TAF SPH STAT STR; CATA IR aM, UV afu, afes- Chen war | 4 Aa Sam ay OTE fafSqors Tea af | BREN, FEy AMY Cres eat BAe er Ay aera ahh HB BA, U aes QS Tera MATES At FEE RT| Stee STAI ATTA FETs TSA HATTER Core Aes Fa calc Barmais St aseat, Rone eefS IPAS @ ETS afeM OTS FATA TTS | BATH AUT “OTR (Key Words) : STH FT, wis wan fafear, Bera © QE (Hz), CAPA, AeA ater, ce afta, feo aor, aia-fawat aise, RTS Fee, Tafa, ATE (node), “efa aA ANS, weitere fe, acer AS, IR ‘aff, Laser a], UV af, UV- Fluorescent ink, MRI 7411, Flame Test, SVS @ ITOH OH, FAS SIEM, CFA, UVedawear, wea, was Fer, carrera Prerey sa eagTe ad cca Preeatat— ATMA MATCHES ACSA G CATA ACCA GAT FATS AAT | matt Sorarsa “ear o wrglS aa sare aT wise Gata aif re Faw tscs | ae AA cree fafeq Ge Te SACS TACT | CR HRT AOS PATA Horas aera TAM SACS ATCA PEA epsguvy ARTE FeeMnferes fafey Corea e BIA Mat FAST BAT FATS MARTA | STSRAE, BS @ nv aly MS ecm sea ora VTA a AACS AACA |v8 ASE 9a vy, BI TCE BI ee AN TESA UV ah TT SATS MAA | d. fBfeonera IR ay orca aca BaI-caAAT ComreNs GAM SACS ACA do, carn Ficftrs MRI Aha SANS eat Fas TATA | dd, Tees : Frat the gta Sq ewe SIN ATS SACS AAT | D8. OMS Aes TATE, BATE AS 6 BIRT ST OF HMM FATS AACA | Do, WTAE : AAC GAM MATE FATS ATA | 28, HRP aAS HTT FATS ANAL | de, Waals : ear vafere wfeR NaCl cars fee NaCl aefe 28, NSA, SPS SA, a eA, VeoSAy TI ACS MALS | da, Fist care RfSq alt Yatteact ree Menta TaAS aha saw MATS | de, GeaTeBafies eres enact ray FACT AIT de, aertte ; corarcbiatieg (a /ferore corms) ATIC Fela cles AAA AH Bea AACS TAIT Ro, TEACH CIS Acta VY TMI FACT AACA | Rd AAA Towa @ Hes gra Atom Model and Primary Concept ayaa RBH AT GG, CH, AA (Sir J. J. Thomson) Rae ag era sae BeTeTT anferercae 912) Ce STM TSA HATH STAT Gy PRATT al ae-ParTe Aga ANAT CUA] A 1 ea IHOR ‘ire oe fafey fer raga enta fSy Aahe-abea oa ate we cars ama TR ATE @ BfShST = IM Berger Say, Bl AMY TOE ATTN ARES | eter FEAR ee aTy TOCA ACH MITA Fal VT: QOaracenss aI ACB (Rutherford’s Atom Model) —: 1911 Sew Berafers Qarea any WS (Bohr's Atom Model) 21913 Bc Verafas 1 Q ovo wee era HSA (Quantum Mechanical Atom Model) : 1924—1927 Berc4 Gerais | MRS Bre aang AEA Sorgercra Med CUA ICeA ers ra faesTe wren se Fmt TAT SCF | 2.9.9 ACPO SA (a) Set fet whe : BEM Ste Rutherford’s o-Particle Scattering Experiment : Nucleus discovery Reval arfsercaa a asada oe ace feat cap eaifes (1898 B:) plum-pudding aoe ace Poe eratt ates Boao so yy RBH aTACHTS GTR (co) Sat FaeRae she sea | STs ofthe fagiin 9648 wifsew 2H, GENT (ggRa). BOTAN (5U) Tor COBEN Aha cars FOrESEIA corral ot fafefre eT a5) RI.Q AACS HT ACSA Rutherford's Atom Model COTTA ART aa APTA STATS AMTACATS AT NCUA" @ “CAT TT Woe HEC FE ATA CAITR | MAT BOY HAT NOT CAT STAB PCA YHA FACT | 1911 QBrem wreret Set evRhera recA raatieS AR ATA ATTA ATATATATE TS oR Tombs Serr Fae: (2) CHAT HAN HEA AG ears vreHaE STH ay Aare | AE STA ATS aT CH A PROB Fen RT| aM CATS OrTwRAA Wor AB iMIOT STOR we Ate | ACERT TAMIA AAT PATS OIF 6 ats HAG SH ATGT | (a) samy Range Pacers 1 iS MORTON GIS Gre HATTA HT Meas es OrehS BATA CTvy PAT Hh (9) Arreete 3cis vafire YAR sOTTe WO Mya AeraAOTM aa aay ABER vaice Re fe ward aoe YT Urs | MATS DRAAE ABM @ wes TRAE Tao fae fee Capes SRE RET TH oa CST Berar eR I A IG HMAC TAPAS AI, HAG WA (counter-balanced) | AMPS EMG NCTA BARRIOS eae Ae ACH ace ra FAVEFAA TEMS ace | TrEICER FM fer RA se CH RAMTEC ACS CHTATA PACER ABA ATER (Solar system atom model)-¢ we — - +— oa et & torts [MCQ-2.1 : arr =) oon Te aN (Fagan ahem arin Fiera ote lect fee fot at. x03] fee (® fepa —(@) AgCl (@) Zn (@)PbS (8) NiS wet foa-2.g : TATRTTER ora ACER | RUATACRS aM ACETAA ATATAWET (Limitations of Rutherford’s Atom Model) AMIRCRTS NY AOSTA AT Fre GH RATT COE REIT « AEA sade Bere we TRS StS HAETASS 6 PH aa erly | fey alba eters AarewTt Ro ARE: * © cherwea seng ateore MAE, crap samngee rasta RoraE ATTe HITS ee, carta Pe Caapfoe am wtat Faas aca | Setar spoT mere ae al PHATE GTM ea | SATE ROCHA He Resraera Were HSS ahs & Oi wrscce ore are Vike yeas STEIN CoAT Drea ag LFA CHT FOTHIA ACA TACHI GHATS TUICA TS fafa Sas ae STI staeaoae fea Bra ware aiece | FER aC PHN SSAA ‘wears Drege Sora PTR ga AAS Race Bares AVEEMCT aw =r | die aTATACRTCE amg ROEM FY FoI eat era GIR Ba ES AU Re arate Ae Fea ReratoryceR BLE To SHEAR a x He xf ACR CI BY TNT a wwe FACS trea A OTA rhacal | UO, OR aT PF GRR SPE REM fox .o ; eracaitm ora areite | Fag ates 3 corm Peg o Ge Seam aT sy faa © He en AQ srréatte Boras PHAR TET 6 Ih AACR CRT MAT TAT EGTA FAT SAT | a (@) ete Resa ame Rovencce MOGI Hei REN wre, COT BON oR RAETCS fea tery cara a CUT fy aA RECT Bea ABA ACER eter CHA | f AS Hea OSH FSS: SREORRS OSS,CANS TAT be © Gm oer SCE ART hv = (E)—E)) ace Mite feat wes Ry a MH RA 109739 em-!, 31 APR AF 109678 cm! aH eR AAA | [NALPRH-2.¢.0 4 () @ (8) CATR rae hee (y) Gla rag Woaers Fra GS ae UATE cl, 6 WeAM “al tage TEAM, TAS atc fae Feta aca | CATA era, NTCTHTR BS stars fareN RCA (9) stamTcw AfSq Awa ee ae (2) aafeamnes weg Boralicrs Braces ory iby AfacrTa YR ea, OTA RT eT v= (E)-E,hh a ete wR, a AG fae GE aeETStOSICS eS 1 oom BALM CATR ATE HOUTA RAAT FP COTRTR | * 2.5.8 MACE laa AUS @ ATA eat ACOA ATT Comparison between Rutherford’s Atom Model and Bohr’s Atom Model (#) Ben srry Bower Corgeicrs aT aTATTAR 25 Q) orang woocrs PAB: araTaceST emg CeCe FEY RT TINTS avg Fee ser (a) eon Fegas abers onfcares fsa PrereryR | aMACHTS ANY ALOT ANY AT MATTE BITS: CEPI ACH aaa AIS DICE TMS VTS Laas AVIS wy Sea HSS SSAA ANCE | RIMTACRTE WCET ACHR CTTECOR FATT eta | Goals, Cara fat wewcera PEAS eco aATATHTS TAT ACTA ATTA CoE CHA o MBIT eae RT Bae HC ATH AE @ STRATE TCTs aera N FaaaCa CHOTA WORT TE | %Q) orawates Seralicra See Mae: aMTACESa TY WSC AA PHT OTT S AROS ME Sal TA | Cw Ge Aer RATE PACLRICH Cry Ms I INA TPM GUIS HHH RAATACT MRA ACT STEN FATS TS | MFT, é Gr ANS efS RereiA eras AME aT OPM Geer Ah ws MBPS orawA sea Ae | 4 7a ME QR SHI ARB fey aad ETS vee are AW Sere SST * Berane oefereny eo ace x) saan scoera gfty : sacees AAA AUC UIfCgA SIRs CHAIR KATE MATES DTS ray MUIM o sore DIeAS eralira Ty ee Cafes orate cea aa eae HASTA Berar eae EN seracsa ferret (resultant) | HratAce, Gis RAT AOSTA AIAORA FIAT CAAITAT BUICK TIS BPA eer FB AME ReaTe faa Rear IA ae MS fae IGT 2 ia Pea mfeA HOY MOU MASTS STAT | (8) Ben sere wtecra AarTeoI aT Serie wiry : D1 AMTACRITEA AAT TOUTS OTARTOA AMC GANT Fa ATE | CHASICH atrOTIR WaIAL A TT ATE OEE ora; fy VereTs vTeTS Vera vars Reals wea | Home aeoTATs Bera ee OTT HH MAT RAR | AT MAT ACL A CICA THAD CAE | 2 WRC SOPH TMCS aT AOC SITS Bera Sawer MS afar sacs SR a TASH Das ica Fea ATS tas | WA BEAL Ge AS ase MEHMET afeS zee | TE ATTRTCOS HANY ACOA BANG ees AT ia rang weer Serabera fea fea SHAT MTA TS ara a OB aA aa ZCATe | ACEO Pebou ya PRIA AAG, 1 = 0.529 x 10-8 cm | AAA BA COTA PHY Al Tea Boras CTT AOS RENT CHAT ABTA AR | GH CATs aATY ACEC BMY SYS | © | STATES A TAT NCSC mT WraT Bee ACH TAT MTA CTT ATA | Fe CATA era, ewe eile HABA BKB era CAAT ATR | GAM ANT NCUTATA art Urw, BeeragA wre wife caret sea ‘Safe cre Fee Ga (E,) Ae Bo fours (Ep) amfoea wr aR oa 2 cons me Fafa ara CEEBo PAG -IAH Fa fers afiece pes CIC | wate fA cotrae @ FAfeacea wo weTERCR STAT Tea Cara VAM s bee aca firma achat AB Fca | om fafette “fe M4, AE = (E) - E)) | aeea Witead we, i fafearca re AeA v A, SLA Ey — Ey) = hy @ 1 Behe 3B sramratse ] fafsq ete ATAPI H-aa cael aeifera Fifer crate eet: ny = 1 a fears orca aos Fifer AB ea | = 2 fa sfeeea SPA arate fafa AB a ny =3 fe “ears Ore onToDA Fifer afB ea | fra sfeura OP arcet fafa 4f2 =| fre sioraca orem HE Pre AB eae ara arg rae TR eran emT oraaTC aD ee Seer CaM aiea oes ROT AIC ‘Preras FTe-2.g : HATS ATOMS ASS : HRS: cava rt a Fe eta wa Bl cara cs Rea Pee we a ote : Bera aS Ridad aa Re “Sart ere tae AUB ae mace H-R.U() 5 STR HA ATA HTRTCAT MAAC CLT MAAC AT OT ote ACEC Oro ea . fb. i. 2034] RUC): Hormaga ahfet ABs art tise meaty AcwaTS waicetoAt at | Tt. Gt. 2034] QPH-RU(M) : THIS eae ACERT @ Ts PEOTIS, NOSES WHAT Sa [ol Gt. 2094] OH: ATA TAM ACCC eQIATTOTA AAT AS GTATS | (ot at, sode]COTS TIA >> FATAPS TPTI-R. : RITE rT on feaTH mea Rema AVA SHAN FE NAY WRU! (Strategy) : Gx HCOA HTS, vmvr = 3 22 = 3.1624 x wor s PRAT-R.S : HAT HAMA M PHA TAOS IG AeTRaCTA TS SALA CA TA | 2 eRe THY 3.6 x 10-8 cm Wa VAs sera Fer Res SA m, = 9.11 x 1028 g} WOT : mv = 32 areas RCE hw AH BR OTe Rn RNR SH kg Care cae MUTA oPng FABIA (m) aCe XA sates: Ge waa, mur =P acwca “feoR, n= M =3 a ‘AICHA EFS, h = 6.626 x 104.5 . X 6.626 x 10-34 J. 8x7 22 . mvr TxD $F, w= 7 = 3.1624 x 10-#J.s Bees GF, m, = 9.11 x 108g Rerralicra afecat fea : =911 x 10% kg myr = 3.1624 x 10-4 J. s ~feurra Png, r= 3.6 x 10-%cm 3.1624 x 10-4. s = 3.6.x 10m mr Re ware, mvr =? 3.1624 x 10-34 (kgm?s-? aera A, v=? 10m 11x 103tkg X 3.6 x I .64267 x 105ms-! FAMMAPFS WHT-Lo ; HAGA Geo wHacra TNL 8.5 x 10-8 cm aa Bearers afetat 5.4452 x 107 cms-! wr Rare cam wrod oer aay) Rete a, me = 9.11 x 108 g] San GA ATR, mv cs mvnx 28 wre TPG, 1 = 8.5 x 10-8 em = Sse = 85x 10-10 m DLL X 1034p x $4452 x 105 ms-l x 8.5 x 101m x2x 22 sferast, v = 5.4452 x 107 cms-! 6.626 10° kem’s x7 = 5.4452 x 105 ms! = 399,99 x 10-2 RANA GA, me = 9.11 x 10-8 g _ =9.11X 103 kg 99 = 4 (AF HTT) TF, h = 6.626 x 10.5 2. Baraat ogd ered (n= 4) Steere fet) hh = 6.626 x 10-4 kgm?s-! PHA, n=? FARAFS FTL. : TAC HAAN AACA OF SHIA TPN 8.45 x 10-10 m wa a PH VATS AT AAA Sa | (RTBU GA, me = 9.109 x 10-3! kg) WHO | GIA WA WS, mvr = nh/2n; 1, v= nb/2n mrBR PARAS FE son 3, h = 6.626 x 10 Js (@1, ke m?s"!) ("LJ = kg ms 7] 3x 6.626 x 10-4 kg = 2x 22/7 x 9.109 x 107! 3 x 6.626 x 10-4 x 7 ms! = 2x DX IAOIR BAS TOT = 40199 x 105 mst FANTTPS AUHTT-R : Heels Berar YP Sy viforee wfkew only 245.9 kJ mol"! | SHea ~efteea care Pasa “ara Breda afta ters Saw ores ahs wate « fare aw Rar west (Strategy) : AE = hv =hx 5 ERAS | FR ATR MER PH BA) FRIAR ; MTFTA, AE = 245.9 kJ mol! h = 6.626 x 10-4 J.s x 6.022 x 102? mol"! = 3.99 x 10°19 kI.s. mol! AE 245.9 kJ mol"! 2 BVA, V="h = 3.99% 10 KT s, molt = 61629 x 10M st , ¢ 3x 108x 10? nm s"! A 2. Bae, A= = egg oly P= 4867 X10? nm Preaia se-2.0 : SA PTT : ata ATI ATEMTSISS : FAPMR.S | GT a ACUAT ATS, SH TA H-tatga SrASaAT Bera AA aca Fae az) IB: 1.054136 x 10-4 J.s} [b. @t. 2038] FATA. : GICAL aD cater AS (E) = LeV A, 1.602 x 10-195 Rea & CHIT war wy ata 1 (E = hv =h x c/a}; [S: 1241 nm] FAT-S.9(H) + Cent Beeracaa WD sweat stay 399.1 kJ molt, @ Bemaliena Piehte ses joaatady e Regret ee Rar (h = 6.626 x 10-4 J.s) 18: 4 = 300 nm; v = 1.0% 10! Hz} FATA : Aerehrrs afb sear ay 35.64 x 10-13 erg. Aa 4 Bera Ooniewa calc Femifeara fos =a faleftw “fea Great to war (h = 6.626 x 10-2? erg.s; 1 erg = 10-7 J) (Ey -E)) = hv} [B: 5.3788 x 10! 5] WPT-L.0(F) | STA AAAS US Baca wold Berar “AS Aatercy 6.3 x 10-19 J aay) 19.8 x 10-19) 1 aft Be Mfewa care fre fara Berea Baieaw aa, wre Afatte afi ems | wamtads B Rar [h = 6.626 x 10-345. 8; ¢ = 3.0.x 108m sl] ie 5.282 x 10! s-! Hz; 4 = 5.679 x 10-7) FAPT-NB : TECH aA ATR Bed HRCA TING 8.5 x 10-10 m Re erento Sarat hs GaN Fer (m_ = 9.109 x 10-3! kg) | [B: 4.96 x 10-25 kgms-1; v = 5.445 x 105 ms!) HST-2.8(F) : GH AAAS wa “eraa TINY 3.6 x 10-8 cm WI 2 mfoara orasaAe eet] Reece fete waren o afecet cas sa (Reraiera Ga, m, = 9.11 x 10-78 g] [S: ie wacatt = 3.1624 x 104 Ls. y = 9.642667 x 10° ms} WAPT-2.8(2) : ARE TATA N SAA TPM 8.5 x 10-8 cm BA cae waa a iferat +e Rar ea SA, m, = 9.11 x 10-82] (8: ceifts ware = 4.2165 x 10-4 J.s Scat v = 5.4452 x 105 ms] FAPT-8.8(1) : TECHS AAMT CHT alate @woTA eel *Hferat 9.64 x 107 cms! 444) emnaiba rnd-ecn 3.6 x 108m 1 oy eRe SeraaAT aaweT Ae fer OT AT a Reeralicaa Sa, m= 9.11 x 10-3! kg) (8: Ber fees, n= 3)81S TIAA de | Sfte coca ate RD.¢ ATH ANY Sosa CATT Application of Bohr's Atom Theory UGH RTI ACUTE Tee AES, mania fe mea HRB w fAfey aca “STS (quantization of energy) sae 74 BH Seed SrasaAla Berane MS ag ace |e eras ee omePaRTTA agree FOS TR AEH Fea Cala MRTEA HAI @ HT FIP TTS wicte ELEM SAE aT ReaD TS A GO He* A, Li2+ a ry caTeT cae one aeae aT sea | (0) n-OR FHC DPN (1) FA, (2) n-WA SHA BEA CI (Vq) FRG (9) nea SRY erates Grid iB (E,) feta (3) neem SRE PTE (rq) FAR: HCA A, H TAT @ a ORE COTTA SHA FICE GUD STR DIRE ANN AT Z x e [fBa-2.U()] WATE Z = aaMIAe Fe aT cada aeaT aay e = ASE RTOS ANTS OTe | Horry 6 Oa OB Reval TS On Was Ree a Die = ¢ (HTTS COTA @ Woe Reval ores afar AIT, BIC sepfe Sq) | oRTE m Safa RoUAE ABLES CoM Bear TRIE AE que SRC v ROT GAA Bay | OTR BIS TS Sata ORTH FAC EM Ae, (2) Reem oes SreSaai Beebe ore ors wa EET Zexe Ze? wma Sx. & (2) Sista Fara SHA, y cae STATA m walae Serer For Advanced Students | my? fPa-2.4(%) = AT Fa wRPTE Oma RET TH == | Reralira S485 | are RE woe STASI Teoralaa BARA oT CeRAA we aT aera a ra FA BS A | Te, Ze? _ my? 2 Zet Wa Ave ~ / ‘SIRT CAT A NTH SH SFUTIAT HO, FAY ww TaN Rear CAR Sac TH GF FIA WATS AeA | Be, vr = 83h (acca n = 1, 2,3 Bent atiean] nh neh? =". a ye NY = Ome Sh ¥? = gett »@ Ze? nth? nth? FEM (1) 6 (2) HeATeAI WE, T= goes A, Ze = Far 2y2 = woe 5 Sdie Z ones RMA sage n-oH RET TENE, wg | -(_) fa = apeimZeds m= (atime) x38 FARAH H Sama CAM, Z = 1, SA H FAA NOT SHCA TPA, 2h? m= ane [SPHLL, (i) PHA GPG T ABP YG, rq A VTA CCRT |] . . 2h? pn orga su wre are PA | TT, HL n- RCEA TAG, to = Gr CGS *afeTs, h = 6.626069 x 10-27 erg.s; m = 9.109382 x 10-8g; 7 = 4.803 x 10-10 esu; m= 3.141593; 94 WRC BT, n= 1 APTA TR — (6.626069 x 10-7 erg.s? x (1)? GX G14TS9B)Ex 9.109382 x 10% g) x (4.803 x 10M esu)™ _ 43,90479039 x 10-54 cm = "8296.098891 x 10-8 + ry 30.5292 x 10-8 cm; I, 0.5292 A [areg 10-8 em =1 Aj Tees H aaa ON SRT apnaes Art WAN (ap) TH Bohr radius 4 ‘quae cata BNE (ap) = 0.5292 x 10-8 cm? : 2 ovasnece Rene ra REM, ry = 0.5292 x 10-¥ em xy n ~ 1 3 CRA Ate : 1 erg = 1g cm?.s-; | esu=g2cm2s! 4421 em 3.x 10! esu | ORNS SA SHH @ n-wT SHC BATA Te : GINA STAY H NTA n-SI FHACLA nh? gy, lex he 2 DG, tq = Gar ig? TR IH PHM TMG, 1 = Gee MeT = Heme} ino ye ame? _ ae oq Gatmee = 9 ABA ry = ry XM? = (0.5292 x 10-8 cm) x n? + RAGA ye PHA CHS OT FHA OF OF SHAT TPM BW, 15 = 1 x (3)? = 911 adie wl SEKI TPM (15) 98 PHAULA TPS (1}) 4 9 OF BW! (a) n-Se SRA TASTY VOTH SM (Vn) FAT; AIA TAM ATCT 2H AGIA! ATS, orasaate Rearend Ae ACA, mv =" 22 avast we Q) SR nN PRY HASTA Ror HCA TANG, @ ae (3) Fe Ma (4) A AeA HTS 1 AN SBCA TR, nh 1 nh. 4n’mZe? _ 2nZe? Y= 2mm % 1 = 2nm™~ neh? ahets TT 4 FAMTAGS AAHGT-R90 | AO CA PHILA HAS — 13.5815 eV VA OF ais eros He ET GETS VS RAP —2ntmet rat | HR no wee BoiCTa ow oA, By =~ AT . —2n?me* | — 2n?me* FRNA 2 99 a wet MR, Ei = 7) PHT SROT PHA MAS, Ey = GP HE | Ey_(¢2n?met) he 1 xh? * Con? me) ~9* ES =gx E 23 (- 13.5815 eV) =~ 1.50906 eV ‘sata, 1 eV = 1.602176 x 10-19 J; i Ey =~ 1.50906 x 1,602176 x 10-19 J = - 2.4177 x 10-0 F x tame ta ete war TePAMTT 6 GIifwercaR Say AAT Wave Mechanical Model of Atom and Schrodinger Wave Equation reo Fey cara ore ram wee Sern APART AAT CT TANT ACTH SAA AT FER ethers eae hore Bra come FR core Sra RAN TET ReoTAC FROTA a wraren | fay 1924 Grew eth gz fe anf (Lous de Broglie) WS 44M FA 4, BROS Fe way Bou cara of Bee | BE AS gniara 4 Teas 1926 BIH faci 2, @ifGerra (Erwin Schrodinger) ema FCT @ AAMT WAR | Gena OAR Rema FHAMB wane AAAE wa Rea TH FTA wore Rees Fare a wearer StraehS GHrRLTA TAR, MT CHTATSTA SARHN a HEUTE FCT Cea a ort | (@) DATTA AEF fo wa acta ers : anita wheat ara a CST Ren i et AA aT LHR | pags WTeH aA 2B FE ath (Louis de Broglie) 1S ert FR CH, AHP FH © Say Cor of GE HTT STG ACER carpiea y (RB) Brera HS aalt cerbera MAB, E = hw | WHRRITE WEAR TERATE SH SER BETO Sepia 1, B= me?, aaa m BM Sls SA B= croc 1S; ¢ = rears FE | Be ers Cees GTA AR, FET © |< Reralient me? = hv =hx 43 Sc=UA wr wen fe cece cat eH mR, me =f HERE CBT BA = m AR A MARTA = CE FHaN 8: FAITH Hee ROTM SATA STATS creme TORI FUERA COST, ATA p = mv: sone 3e Cerri ac#)ab PAR a ea aowea Soars (1) Ae AateaeS rere awe: m=}; 3, Rebx Ho; aeits, k= DR aRRAIA a Berar waa v h i, Da ARSE wa Ae, (9) = EE) << ater fe gifts aiteat arm afeioe | tars, eae cee scant ara A SRR caRcaI' Cf Sat RATE, aT ACTA aoa eo reo ees a (9) Reralirs one ec aren © Reralicaa ce Sara, mur = 22 a era Sarita roar sepren, Reval waa HGH Dice area oe pee 1c Sera CaM Ie SREY SAC CATA AT | A x OPTRA Tor SHELA RTA RemratiCTE waR LAG (A) a aeoReRTA (n) offer ae He | Td, 2nr= ny = 2Xh, wash, (fS antra seas 305) me * nxh mers STE mer = AOR Rea CAR SAM, Tk a EAT (a) WAITS | ARS Tara afeeat (v) Stra sfScaH (c) aa Tere; WR c= v IA! ce mur = 5 ferme] 2 AR erEOrO® cata TeRTEAT TATET Tose; Wea RoraATH CATAL ey Fal BL Bers aa AT ONT FM FHWA RAY | STFS AAT-39 | CAR ALON TANTITS ATS cara Borat GE ee a Rea wee at af eres Face aH of wan A saa OI aaa | nh FIAT : GA ASAT ATS, mye = 57 Iman xh Cre osm wa) sec) re Bann fhene w= P (sere 2 ager (2) ae CS 1, aH a, Mc 2m=nxd OR PHL CT, ACRE IT CTS ACH, n= 3 =H, o 2m =A, s a) CUPRA HY = 37. coats 3 a weer ae TORR Rea OH (A) oF OOH BI | ASA Om PHY ATES BERUAP of 94 wae ae ea TERR. RR Fey Ste STURT RA a CORTON TUITE HATE fore Ae a) sero care cD,CoS FAR Be (a) aRcerratefa afrorst AS (Heisenberg’s Uncertainty Principle) afta Wereacr Fa 6 way Bey of crory aereranf nAfSeers ems aca A, A Cor TA waa wera Pgererca FAH a ATH, wee aa aT Aa APS WA AUB Tata a wa wary GTO ida Fat es RH, UA as OTE Fa GAPS Rea Cw | a Hee Vera BHAT A ace | OTT : ask A RTA STAR CHR ACR cars ARE Haga SHAE AEA @ Bea carat feta SACS CT CAA BOTA OTSA 9 water Berra aera Tg FSET! EAT PETE! HAT ORL sdQ9 Riry acerat Bera aforera Aha wes cals Ars Bar Sear | «UOTE AS eRpia A Ax ae Ap ae2 TAA Rafe eopalicrs VISTA SBN GINS © warts HaUTCTA Bera ATT BH, Sa BEN Heoia Mla TPT ICRA LEAH Fe NCA AT FTA BA | SS Axx Ap 2 (e7@), Ap =m x Au, “Gk, m = S48 G4, u = Sera HSA wea AS TAN ATH, Ax ae Ap after ames TUMSs | areca Verses at ABST Fda BATS CUM OHA TACT (Ap) A QM AR FAST AS AI A TTT Ax a TTA CAG ATH aS Reraliera wag Refers Berra Wal UG UH | IA BA, Brac CH (wa of) wre eta SATE OTH eT AO OMY ACH A | HT VTA ITE (SA end) afd wers Fete SATS ote aa wae eR RTT OHH MIC AT | (8) qqfeencaa war Alsat (Schrodinger Wave Mechanics Equation) Gia srg WEE (i) VRcoratefs Boe! MS, (ii) Saha Serica sateef @ Car aot fey arpfoa aerg wae (iii) RerateTs Pea ~afeeraa eran aa aifers aren Pwers few andar) 4 Feats ‘FRITS 9 BTA Qu Bem afSera raiga way TAIT AcwA aera BAT | a ATU TSA (9) Raed war 6 et Bou at fag aghoqS erera ara | (a) a SATA VAP MATS pretge Meirarora vratace fienfrcsrca PATNA aCe | SATAN Berelers BOK TI SAT STfSsra aes farms (x, y, 2) SH TE AAteae Bergers Tea, UT Aieorcaa ware Aras ACH AS : ty BR 2, we +8 = orem x E-Vyy=0 <9 RAB ER staACA (i) m = Reeralieyy ea, (ji) E = RoraaAR GAS mA, (iii) V = Faas (xy, 2) cae Png Remar Poms (= 2S), civ) h = BTewa Se, (v) y (psi, MR) = ROMO peice firanfire fafa wen Beaters wares FaAS aI wet CATATE, (vi) x, y, z= FAFA (0, 0, 0) sarcore Famrtire enifitea Feat era AACR ES OF | y (psi) ¢ y2 aa CaPMBT : (2) Gafeercaa FAST GRE aTleAt (second order differential equation) A144 Fea E ana aaa AME STA onemT aH, aca wTRTET ATA (Eigen values) 727 a Qa TR WAT FANIICE FOC AME MTA aT AAAS cavaTH | () TART Cae E at seen way DARA CAC he ABT che FOOT CAR AA ate UK| eB Rea A oR FEM, y- MAA Fe [Eigen function] #1 = REE A ARGC SRC A FT A | y (psi) eH Corea TW THEE GR, AS Reraiena aca FAS (amplitude ear AR on Sra Face eed exer a |? IB Te Rematna ac SETA TATIMAE | CHT Sarees vere wears RSAC oP COTA ATR HEA CL PN IN CTH TAT TH | (@) STE _—_ rate oars an ore fie ios RTE Sra CAA em 90 — 95% A, oo eee eee cay Sen wet UT | TEAR wy? it AFAR RTS FER MSHdoo PARR oan AA sacta AM (solve) TR RA wave functions A aeora | Fae wave solve, [wave function rpeniiy of finding electron] equation] —— Lor, orbital (y)] —> Lin a region of space (y2) SRST gS Ply waAd a “Sars Reralicrs fafSq Cortidea © wake org, wt ye TOT By FER RTCA HA HT STS ATA RET A A, CHATS ATTA CHT ANT SE BE | RWS HAT SAT AAT TSA Quantum Mechanical Atom Model CORON ena aa NOU A yf ererty ACUTTS FSS ea CRIS HOA aa OTA ANTS wees Q AMCRTE SS TAN NOES coary AUB RIOTE BFE | @ Aer cas (s990 B.) oe rang Wears Breas fs SHrie a Gala a xfer eat; © asl ewe (sae (.) ReredA HP [PH FaI-aBA Sarenf (mass property) ae SIF of (wave property) S28 saa eae wave duality) | aia ater, = 1! _ weed, Ir =n A=T, 2 GOS ater, mye = ® Fem ae one) em et Oe 8 Oe BEM EV) y=; ety (si) = RORYCTE GTR ETA, ms = ROAR ©, b= SORE FE, = Roa ‘wera CatD oR, V = fitfice (x, y, 2) Goren Fre Rema wea oats = 2 @ Ree RIAA AS (3280.88.) Serene NAT SATION, GAR ere aL cote a beatee (x, y, 2) fears eam FRteaafeSe raga FB Delice Bera GRA SAE HS ATA HATE VT ENTS ATT stanly WENA afer AeA TH te fantre eae ete ates see mata te aig font af TS Ipeameie Gal Reraera Aer Adee WTA (Bo—De%) 6) <1 saree “ental (energy. level) aay 1% faratfires SPR OIP ee ert Sat UE Bere Sass ere w feat Hers qe a a omanfrace ORTABTONE CHAPOT FEAT eT | RAR SPT HIP, Say Corsa 6 Bera aa Quantum Numbers, Different Sub-orbits and their Electron Capacities CARTON eT: CoB aeaaT EPC AMS Lora SEIg a Secs ore (size), atala STBfS (shape) 6 PEAceH fnnfae fre aA (orientation) OTe ama HAS fea ahh ART | ORIG state 31 QO COMTBT ACI, nA AT TEM eepta tatia Bore MEBs re Bem FAME GUTH SAAD TT SUC TATA FER | AAA CARTON ART BaleD I Mfoataa Slate era BA FaeaIA ATA RUS HART TA COTRTFUT FCN (1m) A MTA BTA FCA | ATA ATTN ARITA FHF 1, 2, 3, 4. 1pFS ef eT | nae A A sho ATCA ATC TAS Rea ABMS ATH ae GH ane ABM CH GTA PHL TABS CAG Un = 1 RAL OH SGA I K-Cte; n= 2 A OH ooo a Lom; n= 3 A oF SEs Tt M-otet | waactera of MiSaa TN Ota Sere A AT aA Safeacaa acd Sera Mat TOT RM Qn? | TAS ATA CHAO HAH n Bla Coat Seraera FAB feece ara Wa AT SETAC TS @ MOEA Cae ATGTS CATA | [fBal-2.d CAAT] ‘ 2 + (yeas Pnea HOMER A, 1 = (Galina?) «2 GF 2 TENT TRIS AI HOTA COA 1, mn 8 e- GA ATA AHA NON HACC AHA CGS srafeTs, h = 6.626069 x 10-27 erg.s; m = 9.109382 x 10-*8g; e- = 4.803 x 10-19 esu; m = 3.141593 arc 8 it (6.626069 x 10-27 erg.s)? et Ta = 4X (B.141593)2 x (9.109382 x 10-78) x (4,803 x 10-1 esuy? * Z 2 Ay ty = 0.5292 x 10-8 em x5 ty hn? 4e2me?Z _ SIA, ot = Galme2Z * 2 x (12 = ™ rq = Ty XN? = ay X n? = 0.5292 x 10-8 cm x n? 5292 x n2 x 10-8 cm (or, A, or 104 pm) ['" LA = 10 cm) FEB RORGATS ACSA ATA co. Haas OM TETAS FATT, ORAS PT: Za1, a: m= 5.292 xx 10m fy = 5.292 x 101m xn? | BET : ARE ry oa ASA *Z’ (ote een) BABE ITE; SHR AOE Tera TANT TCA CAT 8 tg I HRT GAT FY RCA | GHMTCTEA Ey, 8 ves A CTS TT HCA | _ ont met. Z2 _ + Gi) wHora Berea *e, E,=(— me me) x Sy; aor h, m, mee a h = 6.626069 x 10-27 erg.s; 1 = 3.141593; m = 9.109382 x 10-28 g; e~ = 4.803 x 10-10 esu aia nom Sreicers AS SE: 2x (3.141593)? x 9.109382 x 10-2 g x (4.803 x 10-10 esuyt 2 a (6.626069 x 1077 ergs az — 95690.56038 x 10-6 g.(esu)* , Z* \ ee . “7390479039 x 10° (erg. xat facrca fae rer “ 3 e-1yt Ze esu)’ _ g-(e2.cm? sy 2 (2179.5 x 10-14) x 10-7 x Gz (ergs)? = (g.cm?s? xs? 7 x 2.cmo.s~4 2.572 aS XE SMS = gomts gzcmts* xs’ 10-3 kg (10-%m)?.s-* = 10-7 kg m2? = 10°73) Zo ay eer eee ee Be 21K 10°83 (a *s(2) Kip = C28 = 1008 9 FE 2 = (2.18 x 10°18 I) x ae308 Taher tat HVT OA PR Borsa AS, E) = - 2.18 x 10-18 J aa ae CA TNT TAT E, =~ 2.18 x 10-18 J x 6.022 x 1023 mol-! = E, = ~ 1312 kJ mol-!, 1312 Sw HAT CH, n= 2, Ey = (—L) id molt 3, Ea= [G7] Hd mot! =~ 328 kd mot! * Fea 2H 6 OF eH MSA eT, (Ey -E)) = (-328 kJ mol!) ~ (-1312 kJ mol-!) = 984 kJ mol-! rade 25 PRI cre HTT Berea 2a SETS WAIST (984 kJ mol! + 6.022 x 10? mol-!) = 1.634 x 10-18 J ~fa cored Bea @ sofeyers a see com Fe, 1: NTT RoR Sra wa aS ets noua FMB mere Bomfsare few are wel BoralT ae “fect cH Brees ACHE UT SATO SS RST CHET HT ATES RH) aASCe wa CaTATBTA TeTT @ sATAfS CoTTRTH AeeT LFA araraew Fe cao Hea (1 HATH AACN TAT CTA | HEMT GPA ARTIC LTR PM SAY A 1 TCA RTA AAT! A Wal Reais ce ware FRR TO Ce (n— 1) ene RE a I Wa BoroMERA ae ARC RE 6a 0,1, 2, 3 atm Semifoware UTE s, p, d, FAM hee Fal ka) ara Boriieara aaa SOTAICe 8, Pod f ROTO GT 1 MTA CHATS AAT n Re RHA CHTMTBT Fee s CAA wore FASa eR Ficare Borieaa Tt SABI HaNGTS aI | aa fea, n= 1H, = 0 wehe sa fara BoraE 91, 1s Say *ASeA, n = 2B, 1=0,1 Saigon “fara SomfseT VfB, 2s Ip Seta AGES, n= 3 VM, 1=0, 1,2 ‘wets on fara EorntBea of, 3s 3p 3d SAF OWA, n= 4H, 1= 0,1,2,3 wei ad afate Boren at, 4s dp 4d AF SE n GH A TS Sormforacaa Heals BE | ( Semtfeacas areata Bey : ako] GATE MTR rami 1 2 1 2 FERH oreo RAT (NO 0 is 0 i RR Mo RT (m) +0 1 + Adana nee + angen 4 im Nie ST Ni 4 ae a a Welt, Tal eed 11 i Pence (> 13-37-72 22223 eS tg ate scat Rema = 216 = ot = 188 FATATAPS ATR. : STH. AUST ATE Bd mifeeaea (N-Cicel) CORT BT HA |e mm A ATA fare ea CHO HARADA FeaTT 6 ROTA tat TTT TT! Fa (ay Cars (#-C4B) 2090; AMA GI. 2094] a ne ok Gre aN cote cate tet CMRI HEMT n= A BAL GEA, FER SAR OL Ee ST SNE SOA NTSdou PARA a TOR DA TIA Bert rate; OR ve mivars fafSy Crea a walabrt ae Bra tars; AAA 4s, 4p, 4d, 4f | SIT CRIS aT AAA ICH ATS ALA OWA CMV HIT tm’ a ATER Gora See aE ‘a TAT SR ATCA GR FER SEF | ORR Sm" GA ATT CHD AIR CALS QTOTS erates WafaoTA meat farae fee Sat: 1=0 8, m=08 1. 4s Corafrara 116 wrafsbre 7a 1=1 A, m=-1,0,418 1. 4p Boptfteaca 316 walabre ea | 1= 2&4, m=-2,-1,0,+ 1,42 2. 4d Boptfeaca Sf crafebt Fes | 1=3 BA, m=-3,-2,-1,0,41,+2,439 «of Sortfears 716 safest es | 2. A orate 8g “fears a, N-crer yaniaw cis oafetre Het = (1434547) = 168) sre sf “Sara cd VATA Mat AUT : ASE oafiora te Pye yd ca Boras URS Mca; WR od mfSaraa 16 sate cS Borsa Mat ACL WH = 16 x 2 = 32/81 CTIA 4s? 4p8 4d!0 4fl4, L200 Die CORTE Fete Breerh ificance of four Quantum numbers CORTE SRAM TTY ATER PATA aMTICS AME ROR at wah MATA eft Berets “AS, TEA eA ere CY Hama TSS Bra CORT ea AME ATA SCAT eA | COTA 31 Se CARTS era PETS eo AP: ety COMB HIT BTS Ve n eA n= 1, 2,3, 4,5, 6, 7 oS FT Be | CAPES: naa A aI Gafed a1 efSeraA STATA (Size) HCH BTA UI) ae SeraaAfatAe tary (H) 6 STATA CATT & ax * i) n-Oa SHEA TPG, ry = (h2/42me2) x n7/Z = ag x n2/Z; AATA- ara Teng 4H AMIS BENE, ay = 5.292 x 10-1! m. * Gi) n-Oa Peed Reraera Bea, vq = (2ne2/h) x Zin; H ANT CAR, Z = 1, vq = 2me%/nh | * (ii) n-OR WR Aor ~AS, Ey = (— 2.18 x 10-18 J) x Zn? | oe cat Beara AS, Eq = (— 1312 x (Z2/n2)) kJ mol! | Z = VAFAICT ve meAT, n= PHA AE HUT | Hoots GAM, Z = 1, n= 1 WA, Ey =~ 1312 KI mol-! Be) wa SAM + 1312 kT mol! wfS arcmin ear H ora RIA PRG case |S WT! OH AeNlga Teas He, Ej = + 1312 KJ mol, oe SCRTOATTET 2 4 CORTON MTs eICRTeR RAH ora aif NCHS eter at Cae TEN Sar cal 1 eer coterie mesota ete we ate : FRR COMPO ea nets ROM | wae = 0 cae (a= 1) SIF se Ba CaS we Rema AR rary caUM eccarey BomfeataA SIGE (Shape) cATAITATA BA 1a FT FAQS A | MCR | = 0, 1, 2, 3 wea Bortfeey S, p, d, f Ba | Cofeacaa zee 0 Ga Wa FA BH | s-Borifows RT CTs UTETA, p-Comfea Crew area eae d-Bomifeea rae * STAT SISTA BE) CHTOATTCT : TA COTMTDTA Fei (I) aa ATMO BU TRA AAS AB TR Gaeta Bets cases BT | -