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Tot) : Tw. tv (at) Llu Cy is hint cobacity ab constant Volitroe, AT 4s Change in Loner abun _ ae oe ic pO a Aystern - ee | con : 2 ‘ . occu g JO “FCO bie > Changs Sas wri 5 ikbowk px “(game wystine » Oo 7 a a = O+p 'Matusnaaticalty Ypst= OI Py x Enthalpy Change (AH) = It tet nto f | 7 u Lk Cosgey ] lout “ota conbonr pymunte- IE iW an i | entberns ivi prep ccty [eta givin toy 2 I AH = AUdt PAV | gox On ideal oa PV= nRT iz I DH: AU+Anp (2S Atl= AOFRTAN L furan An= non G-Gorcciis Poroddurt, | = KOO) moles 5 GOs GUS ~yeortoanty - L Abe tn,-5,? © El Exotturmio tortion. A AtOcben In LOKich Jawok ib Libexotiol isnun Ot rnt, se Lewort trol into Produ ts Paco th umic LOL On Exovaple = Cec, +23 9) & Krew On SCOsgy i At. ja5c KImol 7 Sox i : ae STi Tice A agate ] | £; z nA ‘ e daclicctttinay ato chen LOChies in os ——_—___|I & Cusre : A Qywertol into Pe divcts - | Exornble:- No co) + O2¢95 = INO J See Page No. aa Javunochamica! Qusotion :- It BO bas x anc Tf chasenicndecpusction 2hach jrckicatis ty th ~emcthalpy Change tue pluysical status i= Ilr t ; — Entonnple:— SD tta (4) + 02 1) 2 Dh, O ro AH 2-570. OF Fred | | re Dini = * Sfinitions ~Dhteot a A FtaAckien ak Contant RTA AH a Due Smounr 7 int absoxbul DY two veo Lat @Gp is LOUGd link Da rtartion- ji Reachien Enthalpy:- AW le i oy Chovac to writnalpy hat bears “the Wo. mols 3) vtoctants jncicatio by the alokred clunidal e2uctinn have completely wearkiol unde pho Given coach tiers» Ex. Cfo we) £O2(4) > COxq): OH s = 343-SK Tmal, it) | Stanclercol Enthalpy (AH) Jt uw dibinzol os the uathe |puy Chang Oa. uattion that OCLs ps Ohio tHuriy Abonolond Abate Wl Stancdasud Entholpy Oo fsssi on( Cage: Ces tthe Change itn a , lraple Da _A tance vin its Senda Ode bts ot ith milking point & andox primure(/). - . a HyO to <> taogy | Ap: 6.0 Tnse ‘| ee | 2 —«t ; He Boul i rh In ‘ie Antic Aub ins ot an wotuxte ond Abondard pruguste- Beer => “2 +69-4 KImo? Sule ien (AgH)— Jen ty Change -ip_tnthalpy Cte ts Cluscin pensation LD. a cempeund! born it elimenta “anole t HE given Condens tump exasuse G pristine. a Standard sinthatpy Dan eliment KO. fey +a 20 ance? GH" == O99. 9K Trl ga t 2zO ¥ || Standand cndholpy O fowoahan Ais Iba a Chonan in WAthalm Ores j i saoot6e nice a comborimds in it 4 : Baap Ha (q)_ + a Oa tg) —> Hr0(%2): i i i HP oito San und ceand ard ny Libs ey ~ r . o | fq eudlah P yo Combustend 4 Gluecne . Biya @o ath —= 6 + y SHO ca (ey 7% a : lL ee AH®. — 2805%oimol. et Ethalo, Bakes ation du erthaley ang ¢ pceumba ying tak disacuce ~ Lote OL a giver Substao Lito gosccus agus i Catitecd cuthalpy O abowualtion Hala)? Otay Ad” =u 45:0 Tmol" «lLNa rey —> Na (9) 3 Aa HH” =108- tr xTenol = || Bound Missamio clisAoctahen enthoU py. Tt the Cha Ww _enthad py Loin lL mney a covalunk howd’ 7 a Gast ois "compound _w ‘brotiun to Jorre ae io “be Gad proc’ 2 ng & — DH pay 5 Arete uss. OkKTmol™ | Putoolpy OL solubion: Hu dilined asttu beak cotin! mole Do lite Change udldith Occurs ie dulsoluinl in a Lose ref gowent yp AH + 5: Ox5~o! foe Nach gp tog = Wa Cag pep Te, { Lolo Dp | . L bbb bohid” “10 WLC me © Waar Oris Nee i Br x | Bown - Hotout Cyc | catentortien 3) lathe. eugy Ty igiug [coma b | fuser oa a one £6 Te ib vA for go Mae +O, AH 2 UIS:2 KImol” tp I Clegr te —9 ( oT , AH. -3ug-4 KT mol"! Not. +cpn7 9 Noack : Agi = —39g KT mol" ta TH ty | Nees tL Chaee Noth, Au, = Ons [44s Jb 2 Aug Na (4) Chigy | oHt | J Nati + Cn = ry 4 ad, OeTSH — Ay — ¥ z Atpet Atty — Ay BH, Entinolpy DO) lor wali Hi. &utholod a! Winouation Aits . Latah Sublimation oe Bata lay OD). LOW afew JAH, = ition 7 eo, ple aS rate dg i ( “| Hess's Sow 5) cowstont buat sao Page No ture. ma Liew [be aAtatu that te total iviitolinu Changs, 6) a. | otOChier semnains the Jame uahitlust Cu daitien Jeay ox plate ina Ainal sb er Acues st Ooh i Lips - Exowat bei- den casoon is | oe (0 eke 2 emygen canhen Atowids ts Posed & buatis 8 aleascd Shen mole rf a Coton Coy t Orgs = yh Att: - 399-5 K Tol! The_obeve reortien can also be canned gut in | dive Aba Stebel Cees Orgs 9 Cig) s Ad s 110-5 KSmol! - > 4 “ a =2 + bbad CA.» 10s f5) — COs ay 3 Atl= - oo PS > £3 =a : 7 Nsecatl reaction: Ce, FOrgy 9 CO. Adis 393514) e Spontan ontk £ Nien - Spenktanugu drocus t= | > A procew wlth occu 806 U4 Quon 121 Hour ag ottomal agoh undit corcboin conditions uv Co {Lind Apoukavicus prncen - Se roayhe 7. 7 ] pout ox AOL a £xcamble. few ii) Neurttrotisa hen af do acd by on bone Sa A_procen wWith takis place rm rd Hue, Span Don whemal ys cotid. pdakancous pois ~|eyanhyt Onabrniod ¥. ox gs FPL Achiever f eee das ao a) cee! clipe nls Can ae Z fH éurropy a Aclich cil opy ——— oe a Abas — Abake+ lo m— - lav di vol’ az Se Lye! small, tind pt 4 - + £ eae ts ¢ 2£ =943 Ky — Sntropy ts Wighut wo Ugquids Jor a cive, ubsfone, ‘twtropy incrteasts prero’ solid 2 Liquid & Meiuol to gas =a g ancthy = & 7 la ues tbhes to the ODI Db. tus auyakinn bome Prom initial Abobky bo tia. Li Akoke - S+ Se-Sr. whe, Se = kop yY, Jus stake & Sa is wbropu Of initial avead = sevensible a Eabropy Choanmec is usd tp prulick as poukbinily Bea Proc, - A PYOCHAK iW 2 wkaniods oben Su +ve- eS Eker ecco cee Gibbs dou route 3— Sh Meadinoure available Kuna WW Known as Gibbs fry wuroy (id w The Jute’ cst y oy | mob oh E puted! ce its “Aboble Jorn at O96 jy lotmesprere Prsediet b&b Collichh AEan hard Gibb. rusensen q). Toy Standand bue erty fox thecnta ta Laven ano, Achie ev ER Bou Page No: TT Tattunatscaiig “Gg a t Gibbs pose ergy pag -Att~ Taks D A G.uoTs vidi bardandh cond ton, Ac’ d SAtu"-TAS° pectainicey LO bums Tu emoy. i JAS: +ve AG = =e =) SBerwtones, fess Sey Ac arene New ~ penton ps Serres: AG :O, the ytartion KH os Cus it briure lAs =o G=O > Spontancuoun PRO isd» [AS<0 Ag vo > Nan- Sponkonenis Lerocs. is HM Thy Suond bh au Of Thx WUlcn = (6 statu oe one Ape bon Dees iyawwoetyble § tu to attain equi burn XM duird Sous DL Hiwsmody omits s~ it gto Hur entropy 0) ony Buse uc i G (2 he J fi Ubstance Ohryaparchu exo ON Hier kre —fune abbroclus absolute ©. Lenuioy Cla w (ag74 @ Lit box? AG": 2+ 3038 T log K ~ yy vwlwe P= univoudl gos Comstont f Equiiliow nes Te bendy, of en fp &. (UbruUre Comte || Codusate tu cwkholpy y Pricer tos, Lotiowing dlord: aaaHOn B bin sre Ee Soe —— —— al +r £19 Orgy 5 CO +S 183 C AH=s — > eye KE i) Gen +Oatgy —> COzees 5 At = -393- 5x5 Wil Hara Ff Oz — 2 HaO AH = ~285-9kKT . | =u = sd] | Sotution = Reg tredl tg poe ! 6C+an, —> Cathey A? CG Hef tis Or cos OOO a 3H,Or ; AH: —36u-6 eT 2 Cosy tOregs =? CO , Atl: -393-SKT —@ Hacayt | © 2 H20/,); AH: ~ogs- ays @ Rusewe ean, vu bply eqn@x6 Multpy 2on @x3- oe ee ECeyt 60, — COO Bue ese 3 Hagt 3 0, > 3H,0 oe Cuadding @ O4 © & Ce TBH 6a => CoH Atle Tus ayet eee Page No: f - AS) Colaslate tha Loy 2} fornattiow Dp roithane is | nS | : ay ces +t Dag, 3 COag) 5 AH’: = 39 3-545 ~~ Hey + 1 Oa tg > HaOyy; AH'=- 986-8 FKT ia oO oO. +4 sAH= 890K Solution: Requirrdol quation Cpep FQ 2 tgy => CH, py SAH "= Cyst Orgs 2 COasgy Hi2-343-5Ks —©@ Haig) ty Orpg) > HaD py j AM ones tks a) [CHy fg) + 20,19 > COs (9) F2H2O fy AH ~RIOKTS fan @ %Q), Ribaio EgrO Rusorae eo G) Wl Cry + Dapg) 2 €Os(g) : OH" =-393-SkT —_V)) tia yay tig) =) BHO, AM = Fl -9UeT Vil Cos cq) + OHS .gy —CHucgy HAE BH; = I89085 a 4 | Ceey FQH 2 fq) 3 CH4(g) 5 AH = -9S QUT a j Te oT PECs 4 6HaDyy iveon AH, pyr Oatley fr HQe, ~~ | Ant. —152:6, =39>- ~ 985° ST mot OPE C.5 + Stay, 2 Gta sAHs se C+Os9y > COacg) Bus 393-5 ke 5 em ad - Teeis + ~ Hoty O> Ha Op, 5 Dit QSS~ PK T wot | Roe grO, Ox6, @ XE. Cee atime alee DLE Hata iAH 4153-653 BL GOs 66 ECOacg7 AW = - 2361 T mas~) Sua + 302 9 Et+hOwsAH' = 49lueeT mad GH atk 2D-—) = E.COs 193+ CHO; SAH" E73 Q3- Qi Tmo Ci y thee ion which = thr v 2 1SX1O Pat Bong " AG = -0-303 RT tog K 30 4-303 RT ing XI: XID "

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