Professional Documents
Culture Documents
Nano Technology
Nano Technology
Introduction
Composite formation with nanofibers
Carbon nanofiber (CNF) fabrication and preparation of CNF and polymer composites
Polymer nanofiber preparation and formation of nanofiber composites
Strengths and weaknesses of nanofibers in composites
Applications of nanofiber composites
Future trends
References
Abstract:
Nanofibers have emerged as important fibrous materials for reinforcing or modifying polymer matrices.
Carbon nanofibers (CNFs) and polymer nanofibers in composites have been critically reviewed in this
chapter. The concept, methodology, potential applications, advantages and limitations of utilizing
nanofibers in composite materials are discussed. The important application examples reviewed include
carbon and polymer nanofibers in structural carbon fiber reinforced polymer (CFRP) matrix composites,
polymer nanofiber-reinforced nanocomposites for medical use and modification of thermosetting
polymer by polymer/CNF composite nanofibers. A brief account is also given of the future trends in this
area.
Acknowledgement
VISION
To provide an enabling environment to nurture critical and creative
minds and to propel them to greater heights of excellence in their
pursuits for acquiring knowledge in chemical engineering in particular
and life skills in general.
MISSION
WHY ARE WE USING IT
Nanomaterials can occur naturally, be created as the by-products of co
mbustionreactions, or be produced purposefully through engineering
to perform a specialized function. Nanotechnology can provide high
durability for fabrics, because nano-particles have a large surface area-
to-volume ratio and high surface energy, thus presenting
better affinity for fabrics and leading to an increase in durability of the f
unction. Nanotechnology can reduce the use of water as the nanostruct
ure and surfacefunctionality can be imparted using dry techniques on
fabric. It has a great effect on environment and the process is also eco-
friendly. Nanotechnology has the potential
to being revolution in the field of technical textiles for the benefit of hu
manity. In today’s performance market, microencapsulation in textiles i
ncludes the application of fragrances, skin softeners, insect repellent,
and antimicrobial agents. It is used to develop desired textile
characteristics, such as high tensile strength, unique surface structure,
soft hand, durability, water repellency, fire retardancy, antimicrobial
properties, and the like. The unique and new properties of nano
materials have attracted not only scientists
andresearchers but also businesses, due to their huge economical pote
ntial. A super hydrophobic surface is the one that can bead off water
droplets completely; such surfaces exhibit water droplet advancing
angles of 150o degree or higher. They also showed that such an
alteration in the fabric’s surface properties is capable of exhibiting the
―Lotus-Effect, which demonstrates the natural hydrophobic behavior
of a leaf surface. Due to the ability to generate the materials in a
particular way to play a specific role, the use of nanomaterials spans
across a wide variety of industries, from healthcare and cosmetics to
environmental preservation and air purification. Elsewhere,
environmental preservation processes make use of nanomaterials too -
in this case, nanowires. Applications are being developed to use the
nanowires - zinc oxide nanowires - in flexible solar cells as well as to
play a role in the treatment of polluted water. Nanotechnology is
growing by leaps and bounds and it has been introduced in many fields
including the textile industries. There isa considerable potential for
profitable applications of nanotechnology in cotton and other textile
industries. Its application can economically extend the properties and
values of textile processing and products. By deploying
nanotechnology, ultra strong, durable andspecific function oriented
fabrics can be efficiently produced for a number of
applicationsincluding medical, military and industrial apparels etc.
NANOFIBERS
Nanofibers are fibers with diameters in the nanometer range.
Nanofibers can be generated from different polymers and hence
have different physical properties and application potentials.
Nanofibers
have attracted a great deal of attention due to their remarkable proper
ties. Compared to conventional fibrous structures, nanofibers
are lightweight with small diameters, controllable pore structures and
high surface-to-volume ratio, making them ideal for use in applications
as varied as filtration, sensors, protective clothing, tissue engineering,
functional materials and energy storage.
However, the
developmentof new composite nanofibers holds even greater potential
and investigation of new polymer composite nanofibers aimed at furthe
r developing their multifunctional possibilities and enhancing both their
physical and chemical properties has gainedextensive interest. All
polymer nanofibers are unique for their large surface area-to-
volume ratio, high porosity, appreciable mechanical strength, and flexib
ility infunctionalization compared to the rmicrofiber counter
parts. Among various forms thatnanomaterials can take such as
nanorods, nanospheres, and so on, the fiber form comes
tothe forefront due to its superior characteristics. The advantageous pr
operties of thismaterial form include flexibility, high specific
surface area, and superior directional performance. These merits allow
many uses from conventional clothing to reinforcementapplications in
aerospace vehicles. Nanofibers refer to solid state linear
nanomaterials,which are flexible and have aspect ratios exceeding 1000
:1. Nanomaterials arecharacterized by their dimensions at least one of
which should be equal to or less than100 nm. A million times increase
in flexibility can be achieved via reduction of the fiber diameter from 10
μm to 10 nm, which also leads to increases in specific surface area,
andin turn surface reactivity. As mentioned before, nanofibers present
very importantadvantages based on their high specific surface area. The
re are
various methods to produce nanofibers. Electrostatic spinning, which is
generally referred to aselectrospinning, is the most commonly used
nanofiber production method. Other thanelectrospinning, there are a
number of other techniques including force spinning, phaseseparation,
melt blowing, bicomponent spinning, flash spinning, and so on.
NANOWHISKERS
Nano whiskers form a cushion of air around each cotton fiber and
when something is spilled onthe surface of the fabric, the miniature
whiskers actually cohesively prop up the liquid drops,allowing the liquid
drops to roll off and this is how they can repel stains. This treatment
lasts for about 50 home wash cycles before its effectiveness is lost. A
corollary finish is that of using Nano particles to provide a ―lotus
plant effect which causes dirt to rinse off easily, such as inthe
rain. Nanowhiskers are utilized for the water repellent characteristics,
and titanium dioxide isused for the ultraviolet shielding. Nano-silica and
Nano-titanium dioxide improve the creasedefiance of silk and cotton.
Carbon nanotubes CNTs are essential substances owing to their
highstrength and greater electrical conductivity. CNTs could be utilized
in the cloth making thatincludes wearable computers or electronic
appliances. CNTs offers electro-conductivity, fireresistance, self-
cleaning, antistatic, water repellent, and high toughness for fiber.
Highly durable,reliable and necessary tasks-related nano fabrics are
proficiently manufactured for many usages,e.g., sports, medical and
industrial purposes, and military. Nanotechnology has a bright
futurewith its excellent characteristics and the marvelous outcomes.
Nano whiskers are hydro-carbonsand one-thousandth of the dimension
of a conventional fiber made of cotton which is adjoined tothe fabric.
Gaps inside the cotton whiskers are lesser compared to regular water
drop yet moresignificant than molecules of water. Therefore water
stays over the hairs or whiskers and top of the fabric exterior. Nano-
whiskers, each of which is just 10 nanometres long (a grain of sand is
1lakh nanometres in comparison). Basically, nano whiskers, 1/1000 the
size of a typical
cottonfibre are attached to the individual, constituent fibres of the fabri
c. The whiskers arehydrocarbons added by dipping in an aqueous
solution 8. The whiskers modify water-resistanceof fabric due to
surface tension that causes water to form into drops or spheres. The
spaces between the whiskers on the fabric are smaller
than a typical drop of water while the whiskersare hydrophobic and do
not absorb water. As a result, water remains on top of the whiskers
andabove the surface of the fabric. Nano-whiskers are wonder
molecules, which can impart variousfunctional properties not only to
the textiles but also contribute significantly in the field of electronics
and medicine. Recently several works has been reported, where nano-
whiskers have been synthesised from a variety of materials by using
some new and improved techniques.
MAINLY USED NANOPARTICLES
Nanosized particles can exhibit unexpected properties different from t
hose of the original bulk material. The basic premise is that properties
can dramatically change when a substance's size isreduced to the
nanometre range. The applications of nanoparticles, e.g. carbon black
or
somefinishing agents in the textile industry, have a long tradition but ar
e in fact not part of nanotechnology. A typical feature of
nanotechnology in textiles is to use nanoparticles with somesystematic
arrangements. Nanomaterials, when engineered at the atomic and
molecular level andintegrated into fabrics, can exhibit properties which
alter the physical properties of textiles. Nanotechnology also has
commercial potential for the textile industry, mainly due to the fact
thatconventional methods used to impart different properties to fabrics
often do not lead to permanent effects, and may lose their functional e
ffects after laundering or wearing. Nanotechnology is able to
provide high durability for fabrics because nanoparticles have
a largesurface area-to-volume ratio and high surface energy, thus
presenting better attraction to fabricsand, therefore, increased
durability of the functionality. Nanoparticles have versatile
applicationsin the textile industry. They can beneficially replace the
classical micron-sized particles used
infinishing for obtaining soil release, stain resistance, flame retardation,
wrinkle resistance,moisture management, antibacterial and antistatic e
ffects, UV protection, improvement of dyeability, etc. Nanoparticles
such as metal oxides and ceramics are also used in textile finishingto
alter surface properties and impart desirable textile functions.
Nanosized particles have alarger surface area and their use can
therefore result in higher efficiency of the treatment agentthan larger
size particles. Besides, nanosized particles are transparent, and do not
affect thecolour and brightness of the textile substrates.FEW TYPES OF
NANOPARTICLEs :1.CLAY
NANOPARTICLE2.ANTIMONY PENTOXIDE NANOPARTICLE3.CARBON NA
NOPARTICLE4.ZnO NANOPARTICLE5.TiO
2 NANOPARTICLE
6.MgO NANOPARTICLE
7.SILVER NANOPARTICLE
location of youngsters. Gloves that have heaters or radiating light from
LED are used for visualizing a cyclist in the darkness.
CONCLUSION
Nanotechnology is growing by leaps and bounds and it has been introd
uced in manyfields including the textile industries. There is a
considerable potential for profitableapplications of nanotechnology in
cotton and other textile industries. Its application caneconomically
extend the properties and values of textile processing and products.
Bydeploying nanotechnology, ultra strong, durable and specific function
oriented fabrics
can be efficiently produced for a number of applications including medi
cal, military andindustrial apparels etc. As mentioned, nanotechnology
overcomes the limitations of applying conventional methods to impart
certain properties to textile materials. There isno doubt that in the next
few years, nanotechnology will penetrate into every area of textile
industry.Furthermore, there are special nonwoven micro and nano
textiles which can be obtainedusing the electrospinning technique.
Their ultrathin diameter and the good control of
their internal structure, density, and porosity make them ideal for very
specific hightechnology applications. Their controllable composition an
d hosting properties for different nanoparticles allow to create
breathable fiber mats with antibacterial propertieswhich can help in
the healing of wounded skin. But such porous membranes have
beenalso investigated for filters and water treatment applications and
other kinds of tunablemembranes. The apparition of all these
functional artificial fibers and smart fabrics meanundoubtedly the new
revolution for the textile industry.
20
REFRENCES
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Institute of textile and clothing, The Hong Kong Polytechnic University,
Hong Kong, March
20062.Rezwan Mahmud, Farhatun Nabi, Department of Textile Enginee
ring, B.U.B.T.,Bangladesh, January 20173.Khushboo Shrimali and Ela
Manoj Dedhia, S.N.D.T. Women’s University, Mumbai,20174.J.K. Patra
and S. Gouda, Department of Biotechnology, N.I.T., Odisha, May
20135.Martínez Stagnaro, S.*a; Volzone, C.b & Huck, L, Nanoclay
as Adsorbent: Evaluationfor Removing Dyes Used in the Textile
Industry,20136.A.P.S. Sawhney, B. Condon, K.V. Singh, S.S. Pang, G. Li
and David Hui, ModernApplications of Nanotechnology in Textiles