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Thermodynamics
Thermodynamics
• Nonflow work
𝟐
𝑾𝒏 = න 𝑷𝒅𝑽 𝑾𝒏 = 𝟎
𝟏
• Steady flow work
𝟐
𝑾𝑺 = − න 𝑽𝒅𝑷 = 𝑽 𝑷𝟏 − 𝑷𝟐
𝟏
• Change in internal energy
∆𝑼 = 𝒎𝑪𝒗 ∆𝑻
• Change in enthalpy
∆𝑯 = 𝒎𝑪𝒑 ∆𝑻
• Heat transferred
𝑸 = ∆𝑼 + 𝑾𝒏 𝑾𝒏 = 𝟎 𝑸 = ∆𝑼
• Change in Entropy
𝒅𝑸 𝑻𝟐
𝒇𝒓𝒐𝒎: 𝒅𝑺 = ∆𝑺 = 𝒎𝑪𝒗 𝑰𝒏
𝑻 𝑻𝟏
• P, V and T relation (P = C)
𝑽𝟏 𝑽𝟐
= (Charles Law)
𝑻𝟏 𝑻𝟐
• PV and TS diagram
• Nonflow work
𝟐
𝑾𝒏 = න 𝑷𝒅𝑽 𝑾 𝒏 = 𝑷 𝑽𝟐 − 𝑽𝟏
𝟏
• Steady flow work
𝟐
𝑾𝑺 = − න 𝑽𝒅𝑷 = 𝟎
𝟏
• Change in internal energy
∆𝑼 = 𝒎𝑪𝒗 ∆𝑻
• Change in enthalpy
∆𝑯 = 𝒎𝑪𝒑 ∆𝑻
• Heat transferred
𝑸 = ∆𝑼 + 𝑾𝒏 𝑸 = ∆𝑼 + 𝑷∆𝑽 𝑸 = ∆𝑯
• Change in Entropy
𝒅𝑸 𝑻𝟐
𝒅𝑺 = ∆𝑺 = 𝒎𝑪𝒑 𝑰𝒏
𝑻 𝑻𝟏
• P, V and T relation (T = C)
𝑷𝟏 𝑽𝟏 = 𝑷𝟐 𝑽𝟐 (Boyle’s Law)
• PV and TS diagram
• Nonflow work
𝟐
𝑪
𝑾𝒏 = න 𝑷𝒅𝑽 𝒘𝒉𝒆𝒓𝒆: 𝑷 =
𝟏 𝑽
𝑽𝟐 𝑽𝟐
𝑾𝒏 = 𝑷𝟏 𝑽𝟏 𝑰𝒏 = 𝒎𝑹𝑻 𝑰𝒏
𝑽𝟏 𝑽𝟏
• Steady flow work
𝟐
𝑪
𝑾𝑺 = − න 𝑽𝒅𝑷 𝒘𝒉𝒆𝒓𝒆: 𝑽 =
𝟏 𝑷
𝑽𝟐 𝑽𝟐
𝑾𝒔 = 𝑷𝟏 𝑽𝟏 𝑰𝒏 = 𝒎𝑹𝑻 𝑰𝒏 = 𝑾𝒏
𝑽𝟏 𝑽𝟏
• Change in internal energy
∆𝑼 = 𝟎
• Change in enthalpy
∆𝑯 = 𝟎
• Heat transferred
𝑸 = ∆𝑼 + 𝑾𝒏 𝑸 = 𝑾𝒏
• Change in Entropy
𝒅𝑸 𝑽𝟐
𝒇𝒓𝒐𝒎: 𝒅𝑺 = ∆𝑺 = 𝒎𝑹 𝑰𝒏
𝑻 𝑽𝟏
• P, V and T relation (S = C or PV k = C)
𝑷𝟏 𝑽𝒌𝟏 = 𝑷𝟐 𝑽𝒌𝟐 𝒑𝒓𝒆𝒔𝒔𝒖𝒓𝒆 − 𝒗𝒐𝒍𝒖𝒎𝒆
𝒌−𝟏
𝑻𝟏 𝑽𝟐
= 𝒕𝒆𝒎𝒑𝒆𝒓𝒂𝒕𝒖𝒓𝒆 𝒗𝒐𝒍𝒖𝒎𝒆
𝑻𝟐 𝑽𝟏
𝒌−𝟏
𝑻𝟏 𝑷𝟏 𝒌
= (𝒑𝒓𝒆𝒔𝒔𝒖𝒓𝒆 𝒕𝒆𝒎𝒑𝒆𝒓𝒂𝒕𝒖𝒓𝒆)
𝑻𝟐 𝑷𝟐
• PV and TS diagram
• Nonflow work
𝟐
𝑪
𝑾𝒏 = න 𝑷𝒅𝑽 𝒘𝒉𝒆𝒓𝒆: 𝑷 = 𝒌
𝟏 𝑽
𝑷𝟐 𝑽𝟐 − 𝑷𝟏 𝑽𝟏 𝒎𝑹(𝑻𝟐 − 𝑻𝟏 )
𝑾𝒏 = =
𝟏−𝒌 𝟏−𝒌
• Steady flow work
𝟐
𝑪
𝑾𝑺 = − න 𝑽𝒅𝑷 𝒘𝒉𝒆𝒓𝒆: 𝑽 = 𝒌
𝟏 𝑷
𝒌(𝑷𝟐 𝑽𝟐 − 𝑷𝟏 𝑽𝟏 ) 𝒌𝒎𝑹 𝑻𝟐 − 𝑻𝟏
𝑾𝒔 = =
𝟏−𝒌 𝟏−𝒌
𝑾𝒔 = 𝒌 𝑾 𝒏
• Change in internal energy
∆𝑼 = 𝒎𝑪𝒗 ∆𝑻 = −𝑾𝒏
• Change in enthalpy
∆𝑯 = 𝒎𝑪𝒑 ∆𝑻
• Heat transferred
𝑸 = ∆𝑼 + 𝑾𝒏 𝑸=𝟎 ∆𝑼 = −𝑾𝒏
• Change in Entropy
∆𝑺 = 𝟎
• P, V and T relation (PVn = C)
𝑷𝟏 𝑽𝒏𝟏 = 𝑷𝟐 𝑽𝒏𝟐 𝒑𝒓𝒆𝒔𝒔𝒖𝒓𝒆 − 𝒗𝒐𝒍𝒖𝒎𝒆
𝒏−𝟏
𝑻𝟏 𝑽𝟐
= 𝒕𝒆𝒎𝒑𝒆𝒓𝒂𝒕𝒖𝒓𝒆 𝒗𝒐𝒍𝒖𝒎𝒆
𝑻𝟐 𝑽𝟏
𝒏−𝟏
𝑻𝟏 𝑷𝟏 𝒏
= (𝒑𝒓𝒆𝒔𝒔𝒖𝒓𝒆 𝒕𝒆𝒎𝒑𝒆𝒓𝒂𝒕𝒖𝒓𝒆)
𝑻𝟐 𝑷𝟐
• PV and TS diagram
• Nonflow work
𝟐
𝑪
𝑾𝒏 = න 𝑷𝒅𝑽 𝒘𝒉𝒆𝒓𝒆: 𝑷 = 𝒏
𝟏 𝑽
𝑷𝟐 𝑽𝟐 − 𝑷𝟏 𝑽𝟏 𝒎𝑹(𝑻𝟐 − 𝑻𝟏 )
𝑾𝒏 = =
𝟏−𝒏 𝟏−𝒏
• Steady flow work
𝟐
𝑪
𝑾𝑺 = − න 𝑽𝒅𝑷 𝒘𝒉𝒆𝒓𝒆: 𝑽 = 𝒏
𝟏 𝑷
𝒏(𝑷𝟐 𝑽𝟐 − 𝑷𝟏 𝑽𝟏 ) 𝒏𝒎𝑹 𝑻𝟐 − 𝑻𝟏
𝑾𝒔 = =
𝟏−𝒏 𝟏−𝒏
𝑾𝒔 = 𝒏 𝑾 𝒏
• Change in internal energy
∆𝑼 = 𝒎𝑪𝒗 ∆𝑻 = −𝑾𝒏
• Change in enthalpy
∆𝑯 = 𝒎𝑪𝒑 ∆𝑻
• Heat transferred
𝒌−𝒏
𝑸 = 𝒎𝑪𝒏 ∆𝑻 𝒘𝒉𝒆𝒓𝒆: 𝑪𝒏 = 𝑪𝒗
𝟏−𝒏
• Change in Entropy
𝒅𝑸 𝑻𝟐
𝒇𝒓𝒐𝒎: 𝒅𝑺 = ∆𝑺 = 𝒎 𝑪𝒏 𝑰𝒏
𝑻 𝑻𝟏
The general equation of any process is:
𝑷𝑽𝒏 = 𝑪
• n = 0 (isobaric process)
• n = 1 (isothermal process)
• n = k ( isentropic process)
• n = ∞ (isometric process)
Carnot Cycle is the most efficient thermodynamic cycle. It consists of
two isothermal and two isentropic processes.
• Process 1 -2: isothermal expansion
• Process 2 – 3: isentropic expansion
• Process 3 – 4: isothermal compression
• Process 4 – 1: isentropic compression
Analysis of Carnot Cycle:
• Heat added (QA)
𝑸𝑨 = 𝑻𝒉 (𝑺𝟐 − 𝑺𝟏 )
• Heat rejected (QR)
𝑸𝑹 = 𝑻𝑳 𝑺𝟑 − 𝑺𝟒 𝑸𝑹 = −𝑻𝑳 (𝑺𝟐 − 𝑺𝟏 )
• Net work or work done
𝑾𝒏𝒆𝒕 = 𝑸𝑨 − 𝑸𝑹 𝑾𝒏𝒆𝒕 = 𝑻𝑯 − 𝑻𝑳 (𝑺𝟐 − 𝑺𝟏 )
Where: TH = higher temperature, TL = lower temperature
• Cycle Efficiency
𝑾𝒏𝒆𝒕 𝑻𝑯 − 𝑻𝑳
𝒆= 𝒆=
𝑸𝑨 𝑻𝑯
Remember Carnot Cycle efficiency can be increased by increasing
higher temperature and lowering the lower temperature.
Refrigeration is the process of transferring heat from a low-
temperature area to a high-temperature area. Since heat flows
spontaneously only from high to low temperature areas according to
the second law of thermodynamics, refrigeration needs an external
energy source to force the heat transfer to occur. This energy source
is a pump or compressor that does work in compressing the
refrigerant. It is necessary to perform this work on the refrigerant in
order to get it to discharge energy to the high-temperature area.
Coefficient of Performance
𝑸𝑨 𝑻𝑳 𝟏
𝑪𝑶𝑷 = = = −𝟏
𝑸𝑹 − 𝑸𝑨 𝑻𝑯 − 𝑻𝑳 𝒆
𝑾𝒏𝒆𝒕 = 𝑸𝑹 − 𝑸𝑨
SUCCESS occurs