Scribd Logo
Upload

Welcome to Scribd!

  • Chapter 6

    Uploaded by

    Quỳnh Anh Trần
    7 views17 pages
    The document discusses 1,3-dienes, including their nomenclature and common reactions. It describes how 1,3-dienes undergo electrophilic additions, producing two isomers from 1,2- or 1,4-addition of hydrogen halides. The ratio of products depends on reaction temperature. It also explains the Diels-Alder reaction between a diene and alkene to form a cyclohexene product, and how diene conformation influences this reaction.

    Original Description:

    Original Title

    chapter 6

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    The document discusses 1,3-dienes, including their nomenclature and common reactions. It describes how 1,3-dienes undergo electrophilic additions, producing two isomers from 1,2- or 1,4-addition of hydrogen halides. The ratio of products depends on reaction temperature. It also explains the Diels-Alder reaction between a diene and alkene to form a cyclohexene product, and how diene conformation influences this reaction.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as pdf or txt
    7 views17 pages

    Chapter 6

    Uploaded by

    Quỳnh Anh Trần
    The document discusses 1,3-dienes, including their nomenclature and common reactions. It describes how 1,3-dienes undergo electrophilic additions, producing two isomers from 1,2- or 1,4-addition of hydrogen halides. The ratio of products depends on reaction temperature. It also explains the Diels-Alder reaction between a diene and alkene to form a cyclohexene product, and how diene conformation influences this reaction.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as pdf or txt
    of 17

    1,3-DIENES

    1
    DIENES
    Cumulated double bonds

    Conjugated double bonds

    2
    NOMENCLATURE OF DIENES

    3
    NOMENCLATURE OF 1,3-DIENES

    4
    NOMENCLATURE OF 1,3-DIENES

    5
    REACTIONS OF 1,3-DIENES

    The most common reactions of 1,3-dienes are


    electrophilic additions.

    6
    ADDITION OF HYDROGEN HALIDES
    TO 1,3-DIENES

    Products are two isomers formed


    through 1,2-addition or 1,4-addition.

    7
    ADDITION OF HYDROGEN HALIDES
    TO 1,3-DIENES

    8
    ADDITION OF HYDROGEN HALIDES
    TO 1,3-DIENES
    Ratio of products depends on the reaction temperature.

    9
    ADDITION OF HYDROGEN HALIDES
    TO 1,3-DIENES

    10
    DIELS-ALDER REACTION

    Pushing arrows to draw the product

    11
    DIELS-ALDER REACTION

    12
    DIELS-ALDER REACTION

    13
    DIELS-ALDER REACTION

    14
    DIELS-ALDER REACTION
    Diene conformations

    15
    DIELS-ALDER REACTION
    Diene conformations

    16
    SYNTHESIS OF 1,3-DIENES

    17

    You might also like