ASSignment

4. In electrochemical cells, the cathode is always the

SECTION-A
electrode where

objective Type Questions (One option is 1) Oxidation occurs

correct)
(2) Reduction occurs
1. Conside he following redox reaction:
(3) Positive ions are fomed

aSn"(ag)+ bMno, (aq)+ cH (ag)- xSn" (ag) (4) Negative ions are formed

+y Mn (aq)+ zH,o(0) 5. Consider the following standard electrode potential

a, b, c, x. y and z are stoichiometric co-efficients data of redox couples

in the balanced reaction. The

value ofis FFe
+ 0.77 V

h i o r +0.54 V
(2) 1

+ 0.34 V
EG
(3) 2 (4)
2 A'IAg+0.84 V

2 In which of the following change, nitrogen The strongest oxidising agent is

undergoes oxidation?
Cu 2
(1)
(1) N2NH, (2) 2NON,O,
(2) Ag

(3) NONO (4) N,O2NO, (3) Fe3

(4) 2 (S)
Consider the reaction of ethanol with
oxygen 6. In which of following compounds, an element
CH,OH (9) O, (9) Co,(9)+ H,O (9) exhibits two different oxidation states?

In the balanced reaction number of moles of (1) NHOH

gaseous products formed per mole of ethanolis 2) H,0
(1) 2 (2) 5 (3) NH,NO,
(3) 4
(4) 6 (4) NH
Puen
 eOx Hoactions ve
12. Oxidation state of nitrogen in its
7. Consider the following species
from ompounds
MnO Cr,O CIO (1)-5to +5

(2)-3 to +3
order of oxidation
Select the correct increasing
(3)-3to +5
number of underlined atoms

(1) I< < 4)-1 to +3

(2) 1l<I<I
(3) l <
SECTION-B

4) 11 l< Objective Type Questions (More than

options are correct):
elements, jdentify the one
8. From the following given
which does not show disproportionation tendency. 1. Which of the following can act as a reducino .
well as an oxidising agent?
(1) C
(2) B (1) N,Os
(3) F (2) H,SO
4) (3) HO
9 Forthe balanced reaction: (4) HNO

8H (aq)+5Fe"(ag) + MnO.(aq)-> 5Fe" (aq) 2. Which of the following is/are disproportionater

+Mn2 (aq)+ 4H,0 () reactions?

Which statement is incorrect? (1) 6NaOH+ 3Cl2 NaCIo, 5NaCl+3H,0

+

(1) Fe (aq) undergoes oxidation (2) 2NaOH +Cl2NaOCI+ NaCI+ H0

(2) MnO (aq) is the oxidising agent
(3) HO H,07
(3) H' (ag) is the oxidising agent

(4) Fe" (aq) is the reducing agent (4) 2KCIO 2KCI+ 302
3. Which of the
10. MnO +
NO, + H° Mn +
NO, + H,O () following can act as an oxidisi;
When this reaction agent?
is balanced correctly witn the
smallest integer coefficients, the coefficient of H* is (1) HSO
(1) 6 (2) 3 2) HNO,
8 (4) 4
(3) KMnO
11. From the
following given electrodes,select the one
which will act as
(4) KCrO,
anode when connected to
standard hydrogen electrode.
4 The average oxidation number of carbon is ze
(1) F2 (9) 2F (aq): E = +
2.87 V (1) HCHO
(2) Fes (aq)I Fe2*; E' +0.77 V =

2) CHC
(3) A (aq)Al(s): E° z -

1.66 V
(4)
3) CH0
Ag(s)/ Ag" (aq): E° =
-0.80 VN
(4) CHCI
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For the reaction
ds vary Redox Reactions49
GIO *H,SO, > C + HsO
Which of the
following is an example of redox

The
correCl statement(s) i thee
balanced equation
reaction?

is/are (1) 2NON,O

stoichiometrc coemcient of Hso, is 6 (2) NH,OH NH,+OH
is Oxidized
(2) lodide 13) 2NO,+ H,O HNO,+ HNO
Sulphur is reduced
(3) (4) N,O, +
H,O2HNO,
(4) H,O is one of the products
Comprehension
Consider the following redox reaction
one
SECTION-C
CIo, +Br C+B,
ing as nked Comprehension Type Questions
1. Which is the reducing agent?
his section contains paragraphs. Based upon
raaraphs, each paragrapns nave two/three multiple
nave to De
(1) CIO
choice questions answered. Each question
choices (1), (4). ( ) and (4). Out of which ONLY Br
has 4
ONE IS COmect.
(3) Both (1) and (2)
Comprehension-

(4) Neither (1) nor (2)

is a reacton in Wnich botn oxidation and reduction
Redox 2. When this equation is balanced, what is the

nation wil take place simultaneOusly. It is obvious that if one

electron there must be another Br7Cio coefficientratio?

substance gives
these electrons. In s o m e reactions
substance to accept
3H,0 is reduced as well as oxidised, these (1)
same substance
reactions.
are temed as disproportonation
reactions
answer:
Choose the correct
(4)
of
1. Given reaction is an example
Br
Brog+ HO
+
Br+OH
SECTION-D
dising Oxidation reaction only
(1)
Matrix-Match Type Questions

(2) Reduction reaction only oxidation

Column-ll for the
1. Match Column-l with
(3) Neutralization reaction
central atoms.
states of the
4) Disproportionation reaction Column-ll
Column-
NaoH, the
reacts with +3
When phosphorus (P)
and NaHPO,,
which of the (a) CrO
products are PH, +4
(i)
statement is correct? (6) MnO
ro in following
P is oxidised only (i)+5
(1) (c) VO,
)
(2) P is reduced only d) FeF
duced ) +7
well as
(3) P is oxidised as Ph.011-47623456

oxidised Delhi-110005
4) Pis neither
reduced nor
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2. Match the items in Column-I with relevant items in SECTION-E
Column-Il.

Column Column- Integer Answer Type

Questions:

(a) lons having positive 6) Anion 1. Corsider the following species: Clo, CIO,.c
charge and CIO. The sum of oxidation states of Cl
(6) The sum of oxidation (i) -1 species which cannot undergo disproportiona
number of all atoms
reaction iS
in a neutral molecule
(c) Oxidation number of (ii) 1 2. Consider the following half reaction:
hydrogen ion (H') (aq)+ H,O)
Cr,0 (aq) +H
(aq) Cr
(d) Oxidation number of () 0
The number of electrons lost or gained per molesi
fluorine in NaF
of Cr,0,ion is
(e) lons having negative Cation
3. Oxidation state of chromium in CrOg is
charge