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Applications of Chemistry
Applications of Chemistry
21BC052
BS-III Chemistry
Assignment # 02
Department of Chemistry
Chemicals used in industry have a direct impact on our daily life, including what we eat, wear,
travel, technology, how we treat illnesses, how we receive electricity, and many more.
Many future concerns, such as sustainable energy and food production, environmental
management, supplying safe drinking water, and improving human and environmental
health, will be solved with chemistry. There are several times in our daily life where
chemistry, its applications, and its principles are involved. Let’s take a look at each one
separately.
Since ancient civilizations, chemistry has been related to metals, mining, the production of
colors, medicine, and some technical industries like tanning, dyeing clothes and the production
of glass, the ancient Egyptians used some chemicals in mummifying their dead.
The pharmacological industry is one of the most important applications of chemistry, All food
consist of chemicals even if they are organically grown, Fuel and all parts of the car are made up
of chemicals. The dyeing of fabrics is a chemical process, Chemical reactions can be used to
produce the electricity, the water treatment and purification is an important chemical method.
A dye is a colored compounds, normally used in solution, which is capable of being fixed to a
fabrics. The dye must be ‘fast’ or chemically stable so that the color will not wash with soap and
water, or fade on exposure to sunlight (ultraviolet light). A dyes owes its color to the presence of
a chromophores and its fixing property to the acidic or basic auxochromic groups such as OH,
SO3H, NH2, NR2, etc.
Coloring materials have been used for many thousands of years by man. Leather, cloth, food,
pottery and housing have all been modified in this way. Some of our most common dyes are still
derived from natural sources. These are termed natural dyes. The Color Index uses this as a
classification and naming system.
Synthetic dye:
Dyes derived from organic or inorganic compound are known as synthetic dyes. Examples of
this class of dyes are Direct, Acid, Basic, Reactive dye, Mordant, Metal complex, Vat, Sulfur,
Disperse dye etc. Synthetic dyes quickly replaced the traditional natural dyes.
They cost less, they offered a vast range of new colors, and they imparted better properties to the
dyed materials dyes are now classified according to how they are used in the dyeing process.
Acid dye:
Acid dyes are water-soluble anionic dyes, containing one or more sulfonic acid substituents or
other acidic groups. An example of the class is Acid Yellow 36.
Acid dyes are water-soluble anionic dyes that are applied to fibers such as silk, wool, nylon and
modified acrylic fibers using neutral to acid dye baths. Acid dyes are not substantive to cellulosic
fibers. Most synthetic food colors fall in this category. The dyeing process is reversible and may
be described as follows:
Basic Brown 1 is an example of a cationic dye that is readily protonated under the pH 2 to 5
conditions of dyeing.
Direct-Dye:
These are the dyes which can be applied directly to the fabrics from an aqueous solution. These
are most useful for fabrics which can form hydrogen bonds with the Dyeing of Fabrics. The
direct dyes mainly the basic dyes and were widely hailed because they made it unnecessary to
use a mordant or binder in dyeing cotton. The colors are not as brilliant as those in the basic dyes
but they have better fastness to light and washing, and such fastness can be measurably improved
by after treatments (diazotized and developed.) Direct dyes can be used on cotton, linen, rayon,
wool, silk and nylon. These dyes usually have azo linkage –N=N- and high molecular weight.
They are water soluble because of sulfonic acid groups.
Azoic-Dye:
Azo dyes contain at least one azo group (-N=N-) attached to one or often two aromatic rings.
These dyes are used primarily for bright red shades in dyeing and printing since most other
classes of fast dyes are lacking in good red dyes. Azoic dyes, called Naphtha’s in the industry,
are actually manufactured in the fabric by applying one half of the dye. The other half is then put
on and they combine to form the finished color. Unless they are carefully applied and well
washed, they have poor fastness to rubbing or crocking.
The production of bluish red azoic dye from the following two components is an example.
Nitro-Dye:
Nitro dyes are pollinator derivatives of phenols containing at least one nitro group ortho or para
to the hydroxyl group. It is used to dye wool. It Consist of two or more aromatic rings (benzene,
naphthalene).
Example:
Disperse-Dye:
Disperse dyes were originally developed for dyeing secondary cellulose acetate fibers. These
dyes are relatively insoluble in water and are prepared for dyeing by being ground into relatively
fine powder in the presence of dispersing agents. In the dye bath, a suspension of the dye particle
dispersion produces a very dilute solution of the dyes, which are then absorbed by the fibers.
This dye class is used to dye polyester, nylon, acetate and triacetate fibers.
Disperse yellow 3, Disperse Red 4, and Disperse Blue 27 are good examples of disperse dye.
Vat-Dye:
The vat dyes are insoluble complex polycyclic molecules based on the Quinone structure
(ketoforms). The term vat comes from the old indigo method dyeing in a vat: indigo had to be
reduced to light form. Vat dyes are made from indigo, anthraquinone and carbazole. They are
successfully used on cotton, linen, rayon, wool, silk, and sometimes nylon. Vat dyes are also
used in the continuous piece of dyeing process sometimes called the pigment application process.
The dyeings produced in this way have high wash and light fastness.
Mordant-Dye:
These Dyeing of Fabrics do not dye the fabric directly but require a binding agent known as
mordant. The mordant acts as a binding agent between the fiber and the dye. Some dyes combine
with metal salts (mordanting) to form insoluble colored complexes (lakes). These materials are
usually used for the dyeing of cotton, wool or other protein fiber. The metallic precipitate is
formed in the fiber producing very fast colors highly resistant to both light and washing.
Example:
Reactive-Dye:
These dyes react with the cellulosic fiber to form a covalent bond. This produces dyed fiber with
extremely high wash fastness properties. These are the dyeing of fabrics which contain a
reactive group which combines directly with the hydroxyl or the amino group of the fiber.
Because of the chemical reaction the color is fast and has a very long life. Cotton, wool or silk
can be dyed with this type of dyeing of Fabrics. There are various types of reactive dyes used in
dyeing industry.
Solvent-Dye:
These dyes are water-insoluble but soluble in alcohols, chlorinated hydrocarbons, or liquid
ammonia. These colors are applied by dissolving in the target, which is invariably a lipid or non-
polar solvent. The Color Index uses this as a classification and naming system. Each dye is
named according to the pattern: – solvent + base color + number they are used for coloring
synthetics, plastics, gasoline, oils and waxes.
Example:
Sulfur-Dye:
The Sulphur dyes provide very deep shades, which have excellent resistance to washing but poor
resistance to sunlight. They will dye cotton, linen, and rayon, but not brightly. A problem with
Sulphur dyes especially the black colors is that they make the fabric tender, or weaken its
structure, so that it breaks easily. Sulfur dyes are applied to cotton from an alkaline reducing bath
with sodium sulfide as the reducing agent. They are low cost and have good fastness to light,
washings and acids.
1. Analgesics are pain relievers that are used to treat a variety of ailments.
2. Tranquilizers are medications that are used to treat mental illnesses. Take, for instance,
tension.
3. Antiseptics are used to destroy or prevent the growth of microorganisms on the skin,
wounds, and cuts.
4. Disinfectants are chemicals that kill microorganisms but are not suitable for human
consumption.
5. Antibiotics are chemical molecules produced by some microorganisms that can be employed
to kill infection-causing microorganisms.
6. Antacids are substances used to eliminate excess acid from the stomach and increase the pH
to a healthy level.
The pharmaceutical industry develops, produces, and markets drugs used as medications for humans
or animals.
Some pharmaceutical companies deal in brand-name (i.e., has a trade name and can be produced and
sold only by the company holding the patent) and/or generic (i.e., chemically equivalent, lower-cost
version of a brand-name drug) medications and medical devices (agents that act on diseases without
chemical interaction with the body).
Pharmaceuticals (brand name and generic) and medical devices are subject to many country-
specific laws and regulations regarding patenting, testing, safety assurance, efficacy, monitoring,
and marketing.
Polystyrene Is used for the production of caps of bottles of acid, in making the body of the
accumulator cells etc.
Ethyl bromine It is for making local anesthesia.
Chloroform In surgical operation as anesthesia, in form of a solvent of rubber, fat, lac etc.,
as insecticide etc.
Methyl alcohol In making methylated spirit, artificial color, varnish and polish, mixing with
petrol and utilized as a fuel of engines etc.
Ethyl alcohol It is used for making wine and other alcoholic drinking stuff, tincture, varnish
and polish, in the form of solvents, in methylated spirit, in artificial colors in
perfumes and scent of fruits, in transparent soaps, in spirit lamps and stoves, in
the form of fuel of motor vehicle in cleaning the wound, in the form of
insecticide etc.
Acetone In making varnish, cordite, clod Ian cellulose, artificial silk, synthetic rubber,
sulphone, chloretone, chloroform, iodoform etc. as medicines etc.
Acetic acid As laboratory’s reagent, in the form of vinegar, in making sauces and jelly etc.
Acetic anhydride In the color industry, in the manufacturing of medicine like aspirin, in making
artificial or synthetic silk from cellulose etc.
Toluene In the dry cleaning, in the form of solvent, in the production of medicines, in
making of explosives etc.
Benzene Sulphonic In the production of saccharin, in the production of solute color, in making
acid sulpha drugs etc.
1- C-1 Chemistry (Syn Gas) : Many important organic chemicals can be produced from the
CO and H2 mixture known as syn gas. They range from simple molecules, such as
methanol, to high-grade synthetic crude oil.
The basic reaction for conversion of syn gas to mixtures of hydrocarbons is called the Fischer–
Tropsch reaction, used in Germany during World War II to produce fuel mixtures for diesel and
gasoline engines. Since the 1950s South Africa has also used this reaction, and currently there is
much interest in using it to convert natural gas (methane) to more easily transported liquids.
Ammonia (NH3), although it is not an organic compound, is often considered as part of C-1
chemistry, since it is produced via a reaction that uses hydrogen gas obtained from methane. It is
made by the Haber process
Ammonia and its derivatives, HNO3, NH4NO3, and CO(NH2)2, are key fertilizers and ingredients
for explosives, and their production consumes nearly 5 percent of the world.
2- C-2 Chemistry (Ethylene or Ethene). With annual worldwide capacity running over 100
million tons, ethylene is the world's largest volume organic compound. Most of it (almost
60%) is used to make polyethylene, the world's highest poundage plastic.
Polyethylene comes in two basic types: high density and low density. The original polymer was a
highly flexible branched product, first prepared in 1932 by a process that required high
temperatures and ultrahigh pressures. It is now known as low-density polyethylene (LDPE), to
differentiate it from a linear polymer discovered later and known as high-density polyethylene
(HDPE). For many applications the original branched LDPE has now been replaced by linear
low-density polyethylene (LLDPE). HDPE is more rigid and less translucent than LDPE or
LLDPE, and it has a higher softening point and tensile strength. HDPE is used to make bottles,
toys, kitchenware, and so on, whereas LDPE and LLDPE are mainly used for film used in
packaging (e.g., plastic bags).
Ethylene oxide is made by air oxidation of ethylene. Most ethylene oxide (about 60%) is
converted to ethylene glycol via acid catalyzed hydrolysis.
Acrylonitrile (CH2=CH−CN) was made from acetylene and HCN until the 1960s. Today it is
made by direct ammoxidation of propylene. Its major use is in making polyacrylonitrile, which is
mainly converted to fibers (Orlon). It is also copolymerized with butadiene and styrene to
produce high impact plastics.
Propylene oxide is made via several methods. The classical one involves treating propylene with
chlorine water to produce propylene chlorohydrin, and then using base to split out HCl. The
primary use for propylene oxide is its oligomerization (to polypropylene glycols). These
products combine with diisocyanates to produce high molecular weight polyurethane foams,
which make very good padding for furniture and vehicle seats.
Phenol and acetone each have a number of important commercial uses, but they also have an
important use together. Phenol and acetone can be condensed to form bisphenol A, which is used
in the production of poly-carbonate and epoxy resins.
Methyl-tertiary-butyl ether (MTBE) is one of the leading chemicals currently being made from
isobutylene (methyl propene) via the acid-catalyzed addition of methyl alcohol. MTBE has been
added to gasoline as a required "oxygenate." However, it is under attack as a groundwater
contaminant and is being phased out.
Polyisobutylenes are easily made via the acid-catalyzed polymerization of isobutylene. The
low molecular weight polymers are used as additives for gasoline and lubricating oils, whereas
higher molecular weight polymers are used as adhesives, sealants, caulks, and protective
insulation.
Butyl rubber is made by polymerizing isobutylene with a small quantity of isoprene. Its main
uses are in the making of truck tire inner tubes, inner coatings for tubeless tires, and automobile
motor mounts.
ABS resin (acrylonitrile-butadiene-styrene) is a widely used terpolymer that accounts for about 8
percent of the butadiene market.
Cumene, discussed under C-3 chemistry, is the second-largest-volume chemical product made
from benzene. About 25 percent of manufactured benzene is alkylated with propylene to form
cumene. Although its high octane number makes it desirable in gasoline, most cumene is
oxidized to the hydroperoxide, which is readily cleaved to phenol and acetone
Caprolactam (C6H11NO) is also used to make nylon. Nylon-6 is made by direct polymerization of
caprolactam, often obtained by reaction of cyclohexanone with hydroxylamine, followed by
rearrangement of the oxime. Although nylon-6,6 is the dominant nylon produced in the United
States, nylon-6 is the leading nylon product in Europe.
Toluene disocyanate (TDI) is polymerized with diols to produce polyurethanes, which are used
to make flexible foam for furniture cushions, mattresses, and carpet pads.Trinitrotoluene (TNT)
is made via a stepwise nitration of toluene in the 2, 4, and 6 positions. TNT is a high explosive
and missile propellant.Phthalic anhydride is made by air oxidation of ortho-xylene. About half of
phthalic anhydride is used to make plasticizers, especially the compound dioctyl phthalate, for
softening polyvinyl chloride plastic. Phthalic anhydride is also used to make unsaturated
polyester resins.
A cosmetic is defined under the Industrial Chemical (Notification and Assessment) Act 1989 as
‘a substance or preparation intended for placement in contact with any external part of the human
body' (this includes the mouth and teeth). We use cosmetics to cleanse, perfume, protect and
change the appearance of our bodies or to alter its odours. In contrast, products that claim to
‘modify a bodily process or prevent, diagnose, cure or alleviate any disease, ailment or defect’
are called therapeutics. This distinction means that shampoos and deodorants are placed in the
cosmetics category, whilst anti-dandruff shampoos and antiperspirants are considered to be
therapeutics.
Emulsifiers
The term emulsifiers refers to any ingredient that helps to keep unlike substances (such as oil and
water) from separating. Many cosmetic products are based on emulsions—small droplets of oil
dispersed in water or small droplets of water dispersed in oil. Since oil and water don't mix no
matter how much you shake, blend or stir, emulsifiers are added to change the surface tension
between the water and the oil, producing a homogeneous and well-mixed product with an even
texture. Examples of emulsifiers used in cosmetics include polysorbates, laureth-4, and
potassium cetyl sulfate.
Colouring agents/pigments
Ruby lips, smoky eyes and rosy cheeks; it is the purpose of many cosmetics to accentuate or alter
a person’s natural colouring. A huge range of substances are used to provide the rainbow of
appealing colors you find in the makeup stand. Mineral ingredients can include iron oxide, mica
flakes, manganese, chromium oxide and coal tar. Natural colors can come from plants, such as
beet powder, or from animals, like the cochineal insect. The latter is often used in red lipsticks
and referred to on your ingredient list as carmine, cochineal extract or natural red 4. Pigments
can be split into two main categories: organic, which are carbon-based molecules (i.e. organic in
the chemistry context, not to be confused with the use of the word to promote ‘natural’ or ‘non-
synthetic’ or ‘chemical-free’ products) and inorganic which are generally metal oxides (metal +
oxygen and often some other elements too). Inorganic should not be confused with ‘synthetic’ or
‘unnatural’ as most of the inorganic metal oxide pigments do occur naturally as mineral
compounds.
The two most common organic pigments are lakes and toners. The lake pigments are made by
combining a dye color with an insoluble substance like alumina hydrate. This causes the dye to
become insoluble in water, making it suitable for cosmetics where water-resistant or waterproof
properties are desired.A toner pigment is an organic pigment that has not been combined with
any other substance.The inorganic metal oxide pigments are usually duller than the organic
pigments, but are more resistant to heat and light, providing a longer-lasting color.
Fragrances
No matter how effective a cosmetic may be, no one will want to use it if it smells unpleasant.
Consumer research indicates that smell is one of the key factors in a consumer’s decision to
purchase and/or use a product.Chemicals, both natural and synthetic, are added to cosmetics to
provide an appealing fragrance. Even ‘unscented’ products may contain masking fragrances to
mask the smell of other chemicals.
The term ‘fragrance’ is often a generic term used by manufacturers. A single listing of fragrance
on your product’s ingredient list could represent dozens or even hundreds of unlisted chemical
compounds which were used to create the final individual fragrance. Manufacturers do not have
to list these individual ingredients as fragrance is considered to be a trade secret. There are over
3,000 chemicals used to formulate the huge range of fragrances used in consumer products
worldwide. A comprehensive list has been published by the fragrance industry. All the
ingredients on this list have passed the International Fragrance Association (IFRA) safety
standards for use in commercial products. However, without knowing which individual
ingredients went in to making up the fragrance of a product, consumers can find it difficult to
make informed choices. If consumers are concerned they should look for fragrance free products
and buy from companies that label their products more comprehensively.
There are various of organic chemicals used in the preparation of cosmetics which should be
used cautiously and appropriately, or else they can have harmful effects to our body. The table
below shows the use of organic chemicals in the manufacturing of cosmetic products and the
effect that caused by it.
Some other uses of organic compound are given in the table
Lead acetate - to be used as a colour additive in men’s hair dye products
- a naturally-occuring organic - can be found in nail polishes,hair dye, soaps, shampoo, lotions and so
compound with the formula CH2O on