www.AhaGuru.

com
Class 12 Chemistry Test Consolidated Test -1 S. Santhanam
TS21.C12.CT01
Solutions
24-04-2021
2021-22
Name: Write your answer in the boxes provided.
Test Time: 3 Hrs
Mobile No:

1. ______ when added to toluene would form a solution without an azeotrope

(A) Methanol (B) Ethanol (C) o-Xylene (D) l-Propanol

2. Which is false regarding Solution (P) HNO3 + H 2 O ; Solution (Q) : benzene + ethanol.

(A) solution (P) forms an azeotrope with maximum vapour pressure, (Q) forms
an azeotrope with minimum vapour pressure
(B) both the solutions do not obey Raoult’s law
(C) For solution (Q) ΔH mix > 0, ΔVmix >0
(D) For solution (P) ΔH mix < 0, ΔVmix <0

3. The cooling system of a car contains 6×10-3 m3 of water (density: 1g/cc). _____ kg
of ethylene glycol must be added nearly to produce
ΔTf = 12 degrees  k f =1.8K/molal 

(A) 1.2 (B) 1.86 (C) 2.5 (D) 0.25

4. Isotonic solutions at the same temperature will have the same

(A) concentration (B) osmotic pressure

(C) ΔTb (D) ΔTf

5. 0.05 mol of a non-volatile solute lowers the freezing point of pure water by an
amount of KCl in moles equal to _______  k f =1.86 K/molal 

(A) 0.0125 (B) 0.05 (C) 0.1 (D) 0.025

6. At 20o C the vapour pressure of two liquids (P) and (Q) that form an ideal solution
are 70 torr and 20 torr respectively. The molefraction of (P) in solution is 0.5.
The ratio of molefraction of (P) in the liquid phase to that in the vapour phase in
equilibrium with this solution is _____.

9 7 7 14
(A) (B) (C) (D)
14 2 9 9
 www.AhaGuru.com
Class 12 Chemistry Test
S. Santhanam
TS21.C12.CT01

7. The total vapour pressure of a 4 mol % solution of NH 3 in a solvent is 6500 Pa at

20°C. The vapour pressure of the pure solvent at 20°C is 2200 Pa.
Which is true?

(A) K H of NH 3 is nearly 1.1105 Pa.

(B) K H is independant of temperature for a gas in a solvent.
(C) the partial pressure of NH 3 in 5 mol % solution of the solvent is nearly 5500 Pa
(D) Henry's law is valid for high concentration of solute in a solvent

8. A Solution of 40.7g of HgCl2  s  in 100g water freezes at – 2.83o C on adding it to

aq. KCl  HgCl4  is formed. Which is true?
2-

(A) the freezing point of the final solution is lower than that of aq. KCl.
(B) complex formation is similar to association and it leads to reduction in the number of
particles in the solution
(C) the oxidation state of mercury in K 2  Hg I4  is + 1

(D) the freezing point of the final solution is equal to – 2.83o C

9. For a solution of (A) and (B) that forms an ideal solution ( PA , PB are the vapour
o o

pressures of pure (A) and (B) x B is the molefraction of (B) in the liquid phase, y B is
that in the vapour phase in equilibrium) Which is true?

(A) A graph of Ptotal vs x B will give a curve.

(B) A graph of Ptotal vs y B will give a curve.
1
(C) A graph of vs y B will give a curve.
pt
PAo PBo
(D) Ptotal =
PBo  yA  PBo  PAo 
 www.AhaGuru.com
Class 12 Chemistry Test
S. Santhanam
TS21.C12.CT01

10. The relative lowering of vapour pressure of a solution of a non-volatile solute in

benzene is 0.0156 at 25o C. The molality of the solution is nearly = ______ 102

(A) 1.56 (B) 4 (C) 2 (D) 3

11. The normal bp of n-pentane is 36o C. Its molar enthalpy of vaporisation is

nearly _____ cals/mol

(A) 21 (B) 6.5 (C) 8314 (D) 6500

12. Which among the following is incorrect

dlnp ΔH Vap
o
PAo XA
(A) = (B) yA  vapour  =
dT RT 2 PBo +  PAo  PBo  XA

for an ideal solution with y A , x A are the molefractions in the vapour phase and in the liquid
phase respectively.

RTfo 2 M1 P0  P 1000
(C) k f = (D) 0
× molality
1000ΔH fusion P Mwt of solute

for a solution of a non-volatile solute in a volatile solvent

13. An azeotropic solution of two liquids has a bp lower than either of them when
it shows _____ from Raoult's law

(A) -ve deviation (B) +ve deviation

(C) no deviation (D) either +ve or-ve deviation

14. Among N, M, m, χ , ppm, wt%, v/v for liquids, v/v for gases, F the total number
of conc. units that are independant of temperature is _____ .

(A) 5 (B) 6 (C) 4 (D) 7

 www.AhaGuru.com
Class 12 Chemistry Test
S. Santhanam
TS21.C12.CT01

15. 6.24 g I 2 (normal solute) in 200g of an organic solvent freezes at 0.85 degrees
lower than that of the pure solvent 1.04 g of another normal solute (X) in 50g of
the same solvent shows. ( ΔTf = 0.51 degrees)
Which is correct?

(A) The Van't Hoff factor i=1 in both the cases

(B) k f is characteristic of solute only
(C) The molecular mass of (X) is 564 g/mol
(D) Freezing point of a solution is a colligative property

16. Methanol (A) and ethanol (B) form an ideal solution  PA =11.82 kpa, P 0 =5.93 kpa  .
0

If equal masses of both are mixed which is false?

( X A : molefraction in the liquid phase, YB : molefraction of (B) in the vapour phase)
y A | yB PA0
(A) x A = 0.59 (B) yB  0.26 (C) x A + y A =1 (D) 
xA | xB PB0

17. If T1 and T2 are the bp and the freezing points of the same solvent and k1 , k 2 are
k1
their ebullioscopic and cryoscopic constants respectively then = _____.
k2
( ΔH1 , ΔH 2 are their molar enthalpies of vapourisation and fusion)

2
T 2 ΔH1 T 2 ΔH 2 T ΔH1 T  ΔH1 
(A) 22 × (B) 1 2 × (C) 1 (D) 1  
T1 ΔH2 T2 ΔH1 T2 ΔH 2 T2  ΔH 2 

18. W gram of C6 H 5COOH (Mwt 122g/mol) dissolved in 30g. benzene shows a

ΔTf = 2 degrees. If the % dimerisation is 80 then W =_____ g. ( k f = 5k/molal)

(A) 1.8 (B) 2.44 (C) 1 (D) 1.5

19. Which is / are false ?

(i) A liquid with low vapour pressure will have high bp and high  H vap
(ii) Water vapour approaches ideal behaviour at low P and hight T
(iii) Trouton's law is not valid for ethanol, H 2 O, CH 3COOH
(iv) Azeotropes are only mixtures of liquids since azeotropic composition varies with
external pressure

(A) (i), (iii) (B) (ii) only (C) all four (D) none of these
 www.AhaGuru.com
Class 12 Chemistry Test
S. Santhanam
TS21.C12.CT01

20. The vapour pressure is expected to be the lowest for ____ and highest for _____
(all are at the same T) among 1-pentanol, 1-butanol, ethanol, methanol

(A) 1-pentanol, methanol (B) 1-butanol, ethanol

(C) methanol, 1-pentanol (D) 1-butanol, 1-pentanol

21. During depression of freezing point of a solution which of the following are
in equilibrium?

(A) Frozen solvent and the solution containing a non-volatile solute in a

volatile (liquid) solvent
(B) Liquid solute & solid solute
(C) Liquid solute & solid solvent
(D) Liquid solvent & solid solute

22. Which of the following mixtures would be nearer to an ideal solution

(A) NaCl + H 2 O (B) ethanol + benzene

(C) heptane +H 2 O (D) heptane + octane

23. CHCl3 + ethanol system

(A) shows - ve deviation from Raoult's law

(B) forms an azeotrope with minimum bp
(C) obeys Raoult's law
(D) ΔH mix is  ve, ΔVmix is  ve

24. The relation between  and i for an electrolyte Ax By is  = _____

i 1 i 1 i 1 i 1
(A) (B) (C) (D)
x 1 x  y 1 x 1 y x 1 y

25. A solution of benzoic acid in C 6 H 6 is 84% dimerised. The value of i = _____

(A) 0.42 (B) 0.58 (C) 0.84 (D) 0.98

 www.AhaGuru.com
Class 12 Chemistry Test
S. Santhanam
TS21.C12.CT01

26. An ideal solution of two liquids A & B have equal molefractions in the liquid phase
with different vapour pressure in the pure state. X A is the molefraction in the liquid
phase and YA is that in the vapour phase in equilibrium with this. Which is true?

(A) y A = y B (B) x A + y A  1 (C) y A  y B (D) y A  0.5

27. Two liquids A & B are mixed at a given T in a certain ratio to form an ideal solution
and it is found that PA  PB . The expression for Ptotal in terms of PA and PB only
is Pt = ______

PA0 PB0 2 PA0 PB0

(A) (B)
2  PA0  PB0  PA0  PB0

PA0 PB0 3PA0 PB0

(C) (D)
PA0  PB0 PA0  PB0

28. K H at 25C for H 2 , N 2 , O 2 and CO in H 2 O in kbar are 71.7, 86.4, 44.1 and
58.8. ______ gas has the least solubility and ______ has the highest solubility in H 2 O .

(A) H 2 ,O 2 (B) N 2 ,CO (C) N 2 ,O 2 (D) O 2 , H 2

29. On adding Hg I2  s  to aq KI  fpt.T1 o C  K 2  Hg I 4  is formed.  fpt.T2 o C 

Which is true?

(A) T1 = T2 (B) T1 > T2 (C) T2 > T1

(D) there is increase in effective number of particles in solution in the formation of the
complex species.

30. An aq solution of fructose freezes at - 0.180°C. The molality of aq BaCl2

solution having the vapour pressure is ______.

1 1
(A) 0.1 (B) 0.186 (C) (D)
2 30
 www.AhaGuru.com
Class 12 Chemistry Test
S. Santhanam
TS21.C12.CT01

31. The freezing point of 0.1m Pt  NH3 2  Cl 2 is  0.186C. in H 2 O k f =1.86.

Which is true?

(A) i=2
(B) the formula of the complex is  Pt  NH3 2  Cl 2 

(C) the complex is expected to react with aq. AgNO3 to form a curdy white
precipitate of AgCl
(D) the oxidation state of the metal in the complex +4

32. Among benzene + toluene, HCl + H 2 O,CHCl3 + acetone HNO3 + H 2 O , ethanol +

cyclohexane, n-hexane + n-heptane the total number showing -ve deviation
from Raoult's laws is _____.

(A) 4 (B) 6 C) 3 (D) 5

33. The Henrys law constant for two gases A and B in water are x and y. The ratio
of the pressure of A to B is 0.2:1 The ratio of molefraction of B to A in H 2 O is ______.

2x y 0.2x 5x
(A) (B) (C) (D)
y 0.2 x y y

34. Which is false?

(A) k b value for a given solvent depends an barometric pressure

(B) For a normal liquid k b 10-4 M1 T10 where M1 is its molecular mass, T10 its bp
(C) 100% ethanol can be got by repeated fraction of rectified spirt
(D) azeotropes are not compounds

35. For a solution of acetone in CHCl3 K H =150 tor at 308K. The vapour pressure of
acetone when it is 12 mole percent is ______ torr

(A) 30.8 (B) 12 (C) 17.5 (D) 18

36. Among the following ______ is dimensionless

(A) k b (B) k f (C) K H (D) molefraction

 www.AhaGuru.com
Class 12 Chemistry Test
S. Santhanam
TS21.C12.CT01

37. For an abnormal solute (B) i = ____.

(A: solvent)

kf m CRT nA kb m
(A) (B) C) P0  P / P 0  (D)
T f  nB Tb

38. The limitting value of i for Al2 SO4 3 is equal to that for

(A) K 4  Fe  CN 6  (B) K 3  Fe  CN 6 

(C) BaCl2 (D) Ca  NO3 2

39. A solute dimerises in H 2 O. The bp of a 2 molar solution of A is 100.52C.

The freezing point of the solution is ______ C k b = 0.52, k f = 1.86 k/molal.

(A) – 0.52 (B)  1.86 (C) +1.86 (D) 0.86

40. The osmotic pressure of an aq. solution of a normal solute is 83.14 kPa at 300K.
The concentration of the solution is _____ mol/l

(A) 33.3 (B) 0.033 (C) 0.09 D) 0.8314

41. Ethylene glycol (fpt 13C ) is used as an antifreeze. Which of the following
would represent the freezing points of various mixtures of water and ethylene
glycol. In each graph the y-axis the fpt  C  and the x-axis is molefraction of water
added to pure glycol
(A) (B)

fpt O
fp
-13
-13
 C O
o
o
( C)
1
X H2O
 x H2O

(C) (D) O
O
fpt -13
fp
-13
 C
o
(o C)

X H2O
 x H2O
 www.AhaGuru.com
Class 12 Chemistry Test
S. Santhanam
TS21.C12.CT01

42. The osmotic pressure of an aq. solution of sucrose at 300K is 101.3 Kpa. The
freezing point of the solution is ____ C k f = 2 K/ molal

(A) – 1.86 (B) –1.2 (C) 0.09 (D) –0.08

43. An aq. solution of maltose freezes at -0.21o C  k b =0.52, k f =1.86K/molalfor water 

Which is / are true?

(i) the bp of the solution is 100.06C

(ii) the molality of sugar solution is nearly 0.11
(iii) the molality of aq. KNO3 having the same vapour pressure as aq. maltose is 0.056
(iv) k b is characteristic of solute only

(A) (i), (iv) (B) (ii), (iii)

(C) (i), (ii), (iii) (D) all four

44. 0.1M K 4  Fe  CN 6  is 45% dissociated at 27C. Its osmotic pressure is

_____(assume M m )

(A) 6.9 atm (B) 6.9 pascal (C) 2.46 atm (D) 590 torr

45. 1.33kg of an aq. solution containing 0.33kg of ethylene glycol (62 g/mol) is
cooled to 18.6 C. k f  1.86 K/molal for water _____ g of ice will separate
outnearly

(A) 0.4677 (B) 532 (C) 468 (D) 0.532

 www.AhaGuru.com
Class 12 Chemistry Test
S. Santhanam
TS21.C12.CT01

Numerical Answer Type:

46. A 6.5m KOH (aq) has a density of 1.89g/cc. The molarity of the solution
is ______ mol/l (nearest integer)

47. AB 2 is dissociated in water to form ions. The bp of a 10molal solution of AB 2

is ____ C (integer) kb  0.5K/molal.

48. At 363K the vapour pressure of pure A is 21 kPa and that of B is 18 kPa.
1000 mmoles of H and 2000 mmoles of B are mixed. the total vapor pressure of the
solution (ideal) is ______ kPa (integer)

49. 2molal solution of a weak acid HA has a freezing point of 3.885 C . The 3.885 C
degree of dissociation of this acid is ______ 103 (integer) k f  1.85 K / molal.

50. The molefraction of a solute in 100 molal aq. solution is _____ 103 (integer)

51. The partial pressure of O 2 in H 2 O is 20 kPa. ( K H =8×104 kPa kg mol-1 , ) density

of water with dissolved oxygen is 1kg/lit the molar solubility of oxygen
= ______ 105 mol/l (integer)

52. 19.45g of monochloro acetic acid (94.5 g/mol: Mwt) is added to 500 ml water
and the freezing point of the solution is  0.5 C.  k f =1.86 K/molalfor H 2 O  .
The dissociation constant of the acid is x  103. The value of x is ______. (integer)

53. 250ml of 0.2M solution of P (Mwt 90) is to be prepared ______10g P is

needed. (integer)

54. 12.2 g of benzoic acid is dissolved in 100g H 2 O the freezing point of the solution
is 0.93C. k f =1.86 K/molal. The number of moles of the solute associated is _____
(100% association)

55. The freezing point of 10-3 m K x  Fe  CN 6  aq is 7.44 103 C. k f = 1.86 K/molal x =