Hybridization

1.In which of the hybridisation sate different quantum No. are used -
(A) sp3d3 (B) sp3d (C) d2sp3 (D) sp
2.The d-orbital involved in sp3d hybridisation in trigonal bipyramidal geometry:
(A) 𝑑! ! "# ! (B) 𝑑$ ! (C) 𝑑!# (D) 𝑑#$
3 2
3.The orbital involved in case of sp d hybridisation is
(A) s + px + py + dxy + pz + 𝑑$ ! (B) s + px + py + 𝑑!# + pz + dyz
(C) s + px + py + pz + 𝑑! ! "# ! + 𝑑$ ! (D) s + px + py + pz + dyz + dxz
4.The d-orbital which is not involved in sp3d3 hybridisation in pentagonal bipyramidal
geometry is:
(A) dxy (B) 𝑑! ! "# ! (C) 𝑑$ ! (D) dyz
5.Trigonal bi pyramidal geometry has
(A) 90°, 120° (B) 90°, 72° (C) 90° only (D) 72° only
6.Statement-1: All adjacent bond angles are equal in sp3d2 hybridisation.
Statement-2: All bond angles are equal in sp3d2 hybridisation.
(A) Statement-1 is true, statement-2 is true, and statement-2 is correct explanation for
statement-1.
(B) Statement-1 is true, statement-2 is true, and statement-2 is NOT the correct explanation
for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
7.A sp3 hybrid orbital contains: -
(A) ¾ s- character (B) ¼ p - character (C) ¾ p - character (D) ½ s - character
8. 𝑑$ ! orbital is present in which of the following hybridisation.
(A) dsp2 (B) sp3 (C) sp3d2 (D) None of these
3
9.Which of the following d-orbitals is involved in dsp hybridisation leading to square
pyramidal geometry?
(A) 𝑑$ ! (B) 𝑑! ! "# ! (C) dxy (D) dyz
10.The trigonal bipyramidal geometry results from the hybridisation
(A) dsp3 or sp3d (B) dsp2 or sp2d (C) d2sp3 or sp3d2 (D) d3sp3 or sp3d3
11.In an octahedral structure, the pair of d orbitals involved in d2sp3 hybridization is
(A) dxy, 𝑑! ! "# ! (B) dxz , 𝑑$ ! (C) 𝑑! ! "# ! , 𝑑$ ! (D) dyz, dxz
12.A square planar complex is formed by hybridisation of which atomic orbitals
(A) s,px,py, dxz (B) s,px,py, 𝑑! ! "# ! (C) s,px,py, 𝑑$ ! (D) s,px,py, dxy
13. sp3d2 hybrid orbitals are
(A) Linear bipyramidal (B) Pentagonal
(C) Trigonal bipyramidal (D) Octahedral
3 2
14.The geometry of the molecule with sp d hybridised central atom is
(A) Square planar (B) Trigonal bipyramidal
(C) Octahedral (D) Square pyramidal
15.In sp hybridisation, shape is
(A) Angular (B) Tetrahedral (C) Bipyramidal (D) Linear
16.The bond angle in sp2 hybridisation is
(A) 1800 (B) 1200 (C) 900 (D) 109028’
17.sp3 hybridization leads to which shape of the molecule
(A) Tetrahedron (B) Octahedron (C) Linear (D) Plane triangle
18.Out of the following hybrid orbitals, the one which forms the bond at angle, 1800 is
(A) d2sp3 (B) sp3 (C) sp2 (D) sp
19.Octahedral molecular shape exists in .......... hybridisation
(A) sp3d (B) sp3d2 (C) sp3d3 (D) None of these
20.Which of the following hybridisation results in non-planar orbitals
(A) sp3 (B) dsp2 (C) sp2 (D) sp
21.Which of the following statement is not correct
(A) Hybridization is the mixing of atomic orbitals prior to their combining into molecular
orbitals
(B) sp2 hybrid orbitals are formed from two p atomic orbitals and one’s atomic orbital
(C) sp3d2 hybrid orbitals are directed towards the corners of a regular octahedron
(D) dsp3 hybrid orbitals are all at 900 to one another
22.Compound formed by hybridization sp3d2 will have structure
(A) trigonal Planar (B) square pyramidal (C) Angular (D) Trigonal bipyramidal
23.The central atom in a molecule is in sp2 hybrid state. The shape of
molecule will be
(A) Pyramidal (B) Tetrahedral (C) Octahedral (D) Trigonal planar
3
24.sp d hybridization is considered to be a combination of two hybridization. They are
(A) p3 + sd (B) sp2 + pd (C) spd + p2 (D) none of these
25.If the equatorial plane is x–y plane in sp3d hybridisation then the orbital used in pd
hybridisation are -
(A) pz and 𝑑$ ! (B) px and dxy (C) py and dyz (D) none of these
26.Match List-Ι (Hybridisation) with List-ΙΙ (shapes) and select the correct answer using the
codes given below the lists -
List-I List-II
(A) dsp2 (A) Square planar
3
(B) sp (B) Tetrahedral
(C) d2sp3 (C) Octahedral
3
(D) sp d (D) Trigonal bipyramidal
(A) a → 1; b → 2; c → 3; d → 4 (B) a → 4; b → 2; c → 3; d → 1
(C) a → 1; b → 3; c → 2; d → 4 (D) a → 1; b → 4; c → 3; d → 3
27.Which of the following hybridisation results in non-planar orbitals
(A) sp3 (B) dsp2 (C) sp2 (D) sp
28.Octahedral molecular shape exists in .......... hybridisation
(A) sp3d (B) sp3d2 (C) sp3d3 (D) None of these
3
29. sp hybridization leads to which shape of the molecule
(A) Tetrahedron (B) Octahedron (C) Linear (D) Plane triangle
3 2
30.The geometry of the molecule with sp d hybridised central atom is
(A) Square planar (B) Trigonal bipyramidal
(C) Octahedral (D) Square pyramidal

1 2 3 4 5 6 7 8 9 10
C B C D A C C C B A
11 12 13 14 15 16 17 18 19 20
C B D C D B A D B A
21 22 23 24 25 26 27 28 29 30
D B D B A A D B A C