09-12-19 - JR - IIT-N-CHAINA - Jee-Adv - 2015-P2 - CAT-19 - Key & Sols

Sec: Jr.
IIT-N-CHAINA JEE-ADV Date: 09-12-19

Time: 03:00 Hrs 2015-P2 Max.Marks:240
KEY SHEET
PHYSICS
1 7 2 7 3 4 4 7 5 5
6 8 7 2 8 3 9 AD 10 AB
11 AD 12 CD 13 ABC 14 ACD 15 AB
16 AB 17 B 18 A 19 B 20 C
CHEMISTRY
21 7 22 9 23 3 24 5 25 4
26 2 27 5 28 2 29 BC 30 ABD
31 ACD 32 ABCD 33 ABC 34 ABC 35 AB
36 CD 37 D 38 C 39 B 40 C
MATHS
41 1 42 6 43 1 44 4 45 9
46 2 47 1 48 8 49 ABCD 50 ABCD
51 ABC 52 BCD 53 ABD 54 BC 55 CD
56 AD 57 ABCD 58 CD 59 AB 60 AC
NARAYANA IIT ACADEMY 09-12-19_Jr.IIT-N-CHAINA_Jee-Adv_2015-P2_CAT-19_Key & Sols
SOLUTIONS
PHYSICS
01. Suppose that the plank is displaced from its equilibrium position by x at time t, the centre of the
cylinder is, therefore, displaced by x/2.
Therefore, the mechanical energy of the system is gives by
E = KE (Plank) + PE (spring) + KE system given by
1 1 1
 mv 2  kx 2  Ir 2 (i)
2 2 2
1
I P  IG   2m  R 2   2m  R 2   2m  R 2
2
2
 3mR
As cylinder is rolling velocity of centre of cylinder will be half of the velocity of the plank (top most
point of the cylinder)
v v
v cylinder   R   
2 2R
Substituting the value of  is eq.(i), we get
2
1 1 2 1 2  v 
E  mv  kx   3mR  
2

2 2 2  2R 
1 1 3
 mv 2  kx 2  mv2
2 2 8
7 1
 mv 2  kx 2 (ii)
8 2
Differentiating Eq.(ii) w.r.t., time
dE 7  dv  1 dx
 0  m 3v    k.2x.
dt 8  dt  2 dt
7
0  mv.a  kx.v
4
7 4k
Here ma  kx  0 or a   x
4 7m
a  2 x
Comparing with 7m 7m
T  2 
4k k
02. Let the mass be divided into x grams (for ice) and (1000 – x) grams (for vapour)
Heat released by x grams of water  x  1  5  x  80
Heat absorbed by (1000 – x) grams of water
 1000  x   1  95  1000  x   540
Assuming that the conversion of the other part takes place at 1000C
Sec: Jr.IIT-N-CHAINA Page 2

Modest doubt is called the beacon of the wise.
85x  95 1000  x   540 1000  x  or x  882g

Mass of water vapourised is = 112g
Thus the masses to be divided into 882 g for conversion into ice and 118 g for conversion into vapour.
03. Before and after changing the temperature,
12 2 1 2
    2 1   2 t    1 1  1t  
2
2
4 4
and 1   2
04. Let equilibrium temperature be 1000C, heat required to convert 1 kg ice at -200C to 1 kg water at
1000C is equal to
1
H1  1000   20  1000  80  1  1  1000  190kcal
2
Heat released steam to convert 1 kg steam at 2000C to 1 kg water at 1000C is equal to
1
H 2  1000   100  1000  540  590kcal
2
1 kg ice at -200C = H1 + 1 kg water at 1000C (i)
1 kg ice at -2000C = H2 + 1 kg water at 1000C (ii)
By adding Eq. (i) and (ii)
1 kg ice at -200C + 1 kg steam at 2000C = H1 + H2 + 2kg water at 1000C
Here heat required to ice is less than heat supplied by steam, so mixture equilibrium temperature is
1000C. Then steam is not completely converted into water.
So mixture has water and steam, which is possible only at 1000C. Mass of steam which converted into
water Is equal to
1
190  1  100 7
m 2  kg
540 27
So mixture content
7 20
Mass of steam  1   kg
27 27
7 34
Mass of water  1   kg
27 27
05. As 15.2 cm3 of Hg overflows at 1000C
(final volume of Hg) – (final volume of glass flask= 15.2 cm3
 1000 1       1000 1   g    15.2
Where   rise in temperature = 100 – 0 = 1000C
15.2
 g     0.000182  0.000152
1000

  g  3  105 / 0 C    g  1  105 / 0 C
3
06. When m1 is displaced relative to m 2 by a distance x, each spring will be deformed by same amount.
Hence, the springs are connected in parallel. The equivalent spring constant is
If the spring is cut, the force constant of spring

1
k   k11  k 2 2  k

Substituting 1   / 5 and  2  4 / 5, we have
5
k1  5k and k 2  k
4
25
Then k eq  k
4
Now we have two particles of masses m1 and m 2 and one spring of stiffness
25
k eq  k
4
m1m 2
The reduced mass is  
m1  m 2
Where m1  m and m 2  3m
This gives   3/ 4m
Substituting   3/ 4m and k eq  25/ 4k in the formula
25
k eq k
  4  25k  5 k
 3 3m 3m
m
4
07. Let us consider two systems
System 1: ‘Rod + insect’
System 2: counter weight
Both the systems have equal masses and equal net external fore. Also, both the system are initially at
rest. It means the displacement of system – 1 and system 2 should be same

As system 2 constant of only one object, it means that the displacement of the object should be equal
to displacement of centre of mass of system 1. Say the displacement of centre of mass of system 2 is
‘y’ downward
For the displacement of centre of mass of system 1
m y     M  m y
 ycm 1   y
m  M  m
 m  My   My
 2My  m
m m
y or  upward 
2M 2M
m
Hence, the rod will displace by distance upward when the insect reaches the other end of the rod
2M
08. When the block B is released, it moves under gravity. After moving a distance h, it pull the string in
downward direction. At this time tension developed in string is impulsive to nature. This impulse the
block A in upward direction both the blocks starts moving with common velocity
The velocity of block B just before the string becomes taut

u  2gh (i)
Now using impulse momentum equation
 
Pinitial  J  Pfinal
For A : 0 + J = 2mv
or J = mv (ii)
For block B: - mu + J = -mv (iii)
u 2gh
From Eqs. (i), (ii) and (iii); v  
3 3
2gh
Hence, the block A starts moving up with velocity
3
09. From the given data for rod A, we have
L   A LT
L 0.05
or  A    2  103 / 0 C
LT 25  100

From rod B, we have L   B LT
L 0.04
or  B    10 5 / 0 C
LT 40  100
If and C is made of segments of A and B of lengths 1 and  2 respectively, then we have at 0 C .
0
1   2  50cm …(i)
At T  50 C     50.03cm
0 ' '
1 2
Then  A 1T   B 2 T  0.03cm
or 2  10   1  50  10   2  60  0.03cm
5 5
0.03
21   2   105  60cm (ii)
50
Solving eqs. (i) and (ii), we get I1  10 cm and I 2  40 cm
10. Given that f = 600 oscillations / min, m = 0.2 kg
1
A = Amplitude = ½ x length of path = 0.1 m  m
10
1 600
As,     10Hz    2  20  rad / s
T 60
2 2
The magnitude of velocity of a particle performing SHM is given as v   A  x
1
At x = A/2 = m , the velocity at this position
20
2 2
1  1 
v x A / 2  20       3 m / s
 10   20 
Hence, kinetic energy at this position
1 1 32
2
k x A / 2  mv x2 A / 2   0.2 
2 2
 
3 
10
J
We can write potential energy at any position x as
1 1
U  kx 2   m2  x 2
2 2
2
1 2 1 2  1  2
Hence, U  kx   m     J
2 2  20  10
11. Given equations are
y1  10sin   / 4 12t  1 (i)

y 2  5 sin 3t  3 cos3t  (ii)
We recast these in the form of standard equation of SHM which is
y  Asin  t    (iii)

Equation (1) may be written as
y1  10sin 12t / 4     / 4  
 10sin  3t   / 4   (iv)
Comparing Eq.(iv) with Eq.(iii), we have
Amplitude of first SHM = A1 = 10 cm and 1  3
Time period of first motion
T1  2 / 1  2 / 3   2/ 3  s
Equation (ii) may also be written as y 2  5sin3t  5 3 cos3t
Let us put 5  A 2 cos  (v)
And 5 3  A 2 sin  (vi)
Then y 2  A 2 cos  sin 3t  A 2 sin  co3t
 A 2in  3t    (vii)
Squaring (5) and (6) and adding,w e have
2
A 2   5   5 3   10cm
 
2
 
i.e., amplitude of second SHM is 10 cm and time period of second SHM is T2
2  / 2  2 / 3  2 / 3s
Thus, the ratio of amplitude
A1 : A 2  1and
Periodic times are T1  T2   2/ 3  s
12. Let t0C = increase in the temperature.
Increase in length of first rod   11t
Increase in length of second rod   2 2 t
Total extension in length due to rise in temp.,
 11t   2 2 t   11   2 2  t (i)
Since the walls are rigid, this increase in length will not happen. This will be compensated by equal
and opposite force F, F producing decrease in the lengths of the rods due to elasticity
F  1
Decrease in length of first rod 
Y1  A
F 2
And decrease in length of second rod 
Y2  A
F  1  2 
Total decrease in length due to elastic force     (ii)
A  Y1 Y2 
From equation (i) and (ii), we have

F  1  2 
      11   2 2  t
A  Y1 Y2 
ii) Length of the first rod = original length + increase in length due to temperature = decrease in length
 F 1 
due to force   1   11t  
 A Y1 
F2
and length of second rod   2   2 2 t 
AY2
 The total length is same  1   2 at all temperatures.
13. Consider an element of length dx at a distance x from the rotation axis. Centripetal force required for
2
this element is  Adx   x
Tension at a point P, at a distance r from the axis is equal to sum of centripetal force on a ll elements
lying between P and B.
L
A2 2 2
Tension at P,Tr  A
2
 xdx  2
L  r 
r
Now assume that dl is extension in an element of length dr located at a distance r from the axis.
dl
Strain 
dr
T 1 2 2 2
Stress  1    L  r 
A 2
1 2 2 2
 dl  L  r  dr
2 Y 
Change in length of the entire rod
L
2 2  2 L2  1 2 L
   d 
2Y 0
 L  r  dr  2Y L  3   3 Y
2 2
 
14. The velocity with which the liquid comes out is given by the expression
2 v 2
P0  1g  30cm   2g  10cm  p 0 
2
v  2.24m / s
Due to transfer of liquid, change is momentum takes place and hence a force has been exerted on the
2
liquid in backward direction, this force is given by F  2 av , where a is the cross-sectional area of
4
hole  1200  5  10  5  3N
Normal contact fore between the vessel and the surface is
N = mg
N   1A  0.3 g    2 A  0.2  g  420 N
Where A is the cross sectional area of the vessel

Limiting friction force, f L  N  0.04  420  16.8 N
As f1  F, therefore the minimum force necessary to maintain the static equilibrium is 0. For the
maximum value of the applied force
Fmax  f 2  F  16.8  3  19.8N
15. m1g sin   T  N1  m1a

 m1g sin   T  m1g cos   m1a (1)
T  m 2g sin   N 2  m 2
 T  m 2g sin   m 2g cos   m 2 (2)
Adding 1 and 2 we get
  m1  m 2  sin     m1  m 2  cos  

a   g
  m1  m 2  
For m1 downward along the incline
So, the m2 acceleration is directed up the incline i.e., a 2  a
16. Let u m be the velocity at C, the midpoint of A and B


Passage 17 and 18
Initially in equilibrium let the elongation in spring be y  then mg  ky 0
As the bullet strikes the block with velocity v0 and gets embedded into it, the velocity of the combined
mass can be computed by using the principle of moment conservation.
m 4m v
v0  vv 0
3 3 4
Let new mean position is at distance y from the origin, then
4m 4m
ky  gy
3 3k
Now. me block executes SHM about mean position defined by y = 4mg / 3k with time period,
T  2 4m / 3k . At t = 0, the combined mass is at a displacement of  y  y0  from mean position
2 2
and is moving with velocity v. Then by using v   A  x we can find the amplitude of motion
.
To compute the time taken by the combined mass from y = mg/k to y = 0, we can either go for equation
method or circular motion projection method

  
Required t  
 
 4mg 4mg 

y  y 0  3k k   mg
cos    
A  A  3kA
 
y 4mg
cos   
A 3kA
 mg  1  4mg 
cos 1    cos  
 3kA   3kA 
So, t 

4m  1  mg  1  4mg  
  cos    cos  
3k   3kA   3kA  
Passage II
R y  mg
Torque about the CM
 F  R x  R  I
MR 2  a t 
 F  Rx R   
2 R
F  2F 
 F  Rx    a t  
3  3M 
F 2F
 F   Rx  RX 
3 3

CHEMISTRY
21. Conceptual
22. Monosubstituted = 1, disubstituted = 2, trisubstituted = 2
Tetrasubstotuted = 2, pentasubstituted = 1, hexasubstited = 1
Total = 9
CH 3OH  CH 3 MgI  CH 4  Mg  OH  I
23. 32 g 1mole
96 g 3mole
24. Ease of dehydration α stability of carbonation
25. Hoff mann product is major

26. One ring + one π bond
27. 1, 5, 6, 7 and 8 are exothermic
28. N is 6 and M is 4
CX3
29. Shows reverse hyper conjugation.
30. The presence of e – donating groups by inductive and mesomeric effects decreases acidic nature of
phenol.

31. Absence of d – orbitals in CF3
32. All the given redueing agents are suitable.
33. aldehydes, ketones and carboxylic acids are reduced by red phosphorous in HI.
34. Kolbe’s electrolysis. CO2 contains Pπ – Pπ bonds.
35. As 30 carbon free radical is more stable, hydrogen present on it is more reactive.
36. More the number of carbon atoms, more is the heat of conbustion.
37. Resonance decreases bond length
38. In compound X, C – N bond is a single bond. In compound Z, C – N will get double bond character
due to resonance.
39. Resonance and active methylene group
40. Transitoid form is stable can’t for intermolecular its bond.
MATHEMATICS
  
41. a.b  b .c  c .a  cos 
  
a.d  b .d  c.d  cos 
  
Since a , b , c have to be non-coplanar.
       
If d   a   b   c , by symmetry       k 
d  k a  b  c 
  

d .a  k 1  b.a  c.a 
cos   k 1  2cos   ........... 1
 
d .d  3K cos   K cos   1..........  2 
2
From (1) and (2) 3cos   1  2cos
 1  cos 2 
 3   1  2cos 
 2 
 3  3 cos 2  2  4 cos 
 4 cos 2  2  4 cos 
 4 cos   3 cos 2  1
  
42. Let c  xa  yb where x,y are scalars

  
 c  x iˆ  ˆj  2kˆ  y 2iˆ  ˆj  kˆ 

 c  iˆ  x  2 y   ˆj   x  y   kˆ  2 x  y 

But c .a  0
6 x
6x  5 y  0  y 
5
 7 x ˆ x ˆ 4 x ˆ
So, c  i  j k
5 5 5
49 x  x  16 x 2
2 2
25
We have  1  x2 
25 66
 5  7 ˆ 1 ˆ 4 ˆ 
c    i  j k
66  5 5 5 
 11
p  c .b 
6
11
So  6
p
  
43. Let c inclined at angles  with b and 2 with a
            
a  b  c  a.a  a.b  a.c and b .a  b .b  b .c
 6  4 cos 3  c cos 
6 cos 3  4  c cos 2 Eliminating c,
 6  4cos3  cos 2   6cos3  4 cos
 4  4cos3 cos 2  cos 2   6  cos3  cos 2 
2  cos3 cos 2  cos  3  2  
 3  cos3 cos  cos  cos  3  2  
3
 2sin 2  3sin   cos  
4
6  4cos3 8
i   c    3  2 cos3 
cos  3
8

3
3  2  4 cos3   3cos   
8  21 9  
 3  2      5
3  16 4  
   
44. V is coplanar with V1 and V2 and perpendicular to V3
   

Let V   V1  V2 V3 
  
  V3  V1  V2  
 
     
  V3 .V2  V1  V3 .V1  V2 
 

   5  i  j  2 k    2  iˆ  2 ˆj  kˆ 
 

ˆ
V   3iˆ  9 ˆj  12k  …………….(1)
 

Projection of V on iˆ  ˆj  kˆ
 3  9  12
  6 3    1
3

  
V   3iˆ  9 ˆj  12kˆ    iˆ  3 ˆj  4kˆ


   
45. Let the angle between a and b is  and a  b and c is 
 
  abc   6  sin  cos   1
So  sin   1, cos   1    90 0 ,   0 0
  
 a , b , c are mutually perpendicular
4 0 1
  
Again b c d   0  0 9 c .d  0

1 c .d 1
 3 3 
 c .d   we have a.d  0
2
2
  2     3 3 27
   
a  c .d  a.d c  c .d a 
2
a 
4
  2    2 36
So a  c .d   a  c   d  9
4
       
46.  
a  b   r  c    a b c  r   a b r  c
   
 a r c  b  b r c  a
       
 a b c  r  a b r  c  b c r  a   c a r  b
Now

               
     
 a  b   r  c   b  c   r  a    c  a   r  b   a b c  r   a b r  c   b c a  r
             
 b c r  a  c a b  r  c a r  b  3  a b c  r   a b c  r  2  a b c  r
So   2
  2
47.  a b c   0  a b c   0
   
  
a.a a.b a.c 1 cos  cos 
  
b .a b .b b .c  cos  1 cos   0
      cos  cos  1
c .a c .b c .c
cos 2   cos 2   cos 2   2 cos  cos  cos   1
  
48. Give b  a  12, c  6
 
Equation of CD is r  tc and equation of AB is
 
    
 b ac
a 

r  a s b a S .D      8
b a c
8  6 12 1
V  48 v8
6 2 6
49.
We have,
 2 2 2 
a  b  a  b  2 a .b  
 2 2 2  
 a  b  a  b  2 a b cos 2
 2  
 a  b  2  2cos 2  a  b 1  
 2  
 a  b  4 sin 2   a  b  2 sin 
Now,
 
a  b  1  2 sin   1
1    5 
 sin       0,     , 
2  6  or  6 
   
50. We know that  b  c  0, then
a
     
ab  b c  c a
   
Given a  2b  3c  0
     
 2a  b  6b  c  3c  a
Hence,
         
 
a  b  b  c  c  a  2 a  b or 3  c  a 
51. Conceptual
52. Conceptual
53. Conceptual
54. Conceptual
55. Conceptual
56. Conceptual
57. Conceptual
58. Conceptual
59. Draw the graph of y  x 2 e  x
1
60. Draw the graph of y  3x 
ln x
*****
PAPER SETTERS
SUBJECT FACULTY NUMBER
PHYSICS Mr. SUDHAKAR K 8919377488
CHEMISTRY Mr. Y SRINIVASA RAO 9440537915
MATHEMATICS Mr. N RAVI SHEKAR REDDY 9885599004


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Sec: Jr.

IIT-N-CHAINA JEE-ADV Date: 09-12-19

31 ACD 32 ABCD 33 ABC 34 ABC 35 AB

51 ABC 52 BCD 53 ABD 54 BC 55 CD

Sec: Jr.IIT-N-CHAINA Page 2

85x  95 1000  x   540 1000  x  or x  882g

If the spring is cut, the force constant of spring

Sec: Jr.IIT-N-CHAINA Page 4

The velocity of block B just before the string becomes taut

Sec: Jr.IIT-N-CHAINA Page 5

Sec: Jr.IIT-N-CHAINA Page 6

Sec: Jr.IIT-N-CHAINA Page 7

Sec: Jr.IIT-N-CHAINA Page 8

15. m1g sin   T  N1  m1a

Adding 1 and 2 we get

  m1  m 2  sin     m1  m 2  cos  

Sec: Jr.IIT-N-CHAINA Page 9

Sec: Jr.IIT-N-CHAINA Page 10

Sec: Jr.IIT-N-CHAINA Page 11

Sec: Jr.IIT-N-CHAINA Page 12

25. Hoff mann product is major

Sec: Jr.IIT-N-CHAINA Page 15

Sec: Jr.IIT-N-CHAINA Page 17

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