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Lecture 11
Lecture 11
To carry out this conversion, devices called solar cells are used, constituted by semiconductor materials in which
a constant electric field has been created artificially (by means of a p-n junction).
The semiconductor material Silicon is vey important for Solar PV system and 60% of the earth’s crust is
composed of silica that has a high content of Si. In addition to this it has interesting electronic properties. 90%
of the current solar cells are made of silicon, and the others are governed by the same physics.
Gallium Arsenide (AsGa) has better qualities than Silicon for the production of electrical energy, but its scarcity
in nature makes it very expensive. It has very high efficiency.
Those four electrons of its outer layer (of valence) are available to associate with other atoms.
Silicon crystallizes in a network similar to that of a diamond. Through covalent bonds, very stable and strong,
each silicon atom shares one of its four valence electrons with four other atoms.
Since electrons tend to occupy the lowest energy levels, most of them are linked, and at absolute zero
temperature, all of them.
At room temperature, some acquire enough energy to escape the bond and can then move through the material
(conduction). However, this behavior is NOT PECULIAR WITH SILICON ONLY but with all materials.
NCER by Dr. Shantanu Srivastava, Assistant Professor MED,
MNNIT Allahabad
Solar Photo-Voltaic System
What is peculiar is the amount of energy needed to release an electron from the link.
The quantum theory describes the differences between conductors (metals) and semiconductors using energy band
diagrams.
The electrons present in an isolated atom can occupy only allowed energy levels; there are other levels that cannot be
occupied and that are called forbidden levels.
When an isolated atom becomes part of a determined crystalline structure, it interacts with other nearby atoms of the
crystal and the energy levels are affected producing a splitting of the same that gives rise to bands of energy.
Electrons have energies that lie in bands. In the same way that the electrons in an atom cannot have any energy, the
electrons in a crystal cannot take any energy either. And just as the last energy levels in an atom define the chemical
properties of the atom, the last bands of energy define the electronic properties of a crystal
In metals, this band is partially full, but for semiconductors at absolute zero temperature, it is completely empty.
At room temperature, only one in 1010 electrons is in the conduction band.
The electrons of the outermost layers that intervene in the chemical bonds, called valence electrons, occupy an
energy band (valence band, the one before conduction in terms of energy levels) that can overlap with the
conduction band or remain separated.
The energy that an electron must acquire to jump that forbidden band is called gap
energy.
Depending on the width (energy) of the bandgap (gap width), the materials exhibit
different electrical behavior, resulting in Conductive materials (the permitted band
overlaps the conduction band), Insulating materials (the forbidden band is wide, of
the order of 10eV), and semiconductor materials (the bandgap is of the order of
1eV).
The amount of energy needed, in the case of semiconductors (1.12eV for silicon to
25°C), allows an effective control of the flow of charges.
NCER by Dr. Shantanu Srivastava, Assistant Professor MED,
MNNIT Allahabad