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  • A Deep Insight in S - N1 Mechanism

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    nirmla
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    This document contains information about chemical reactions and reaction mechanisms including: 1. Lists of species in order of relative acidity, basicity, and reactivity. 2. Diagrams showing step-wise reaction mechanisms involving molecular additions, eliminations, and substitutions. 3. Structural representations of reactants, products, intermediates, and transition states in organic reactions.

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    A Deep Insight in S_N1 Mechanism

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    This document contains information about chemical reactions and reaction mechanisms including: 1. Lists of species in order of relative acidity, basicity, and reactivity. 2. Diagrams showing step-wise reaction mechanisms involving molecular additions, eliminations, and substitutions. 3. Structural representations of reactants, products, intermediates, and transition states in organic reactions.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    6 views60 pages

    A Deep Insight in S - N1 Mechanism

    Uploaded by

    nirmla
    This document contains information about chemical reactions and reaction mechanisms including: 1. Lists of species in order of relative acidity, basicity, and reactivity. 2. Diagrams showing step-wise reaction mechanisms involving molecular additions, eliminations, and substitutions. 3. Structural representations of reactants, products, intermediates, and transition states in organic reactions.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 60

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    2H2O H3O+ Br
    _
    Br
    +
    +
    −
    −

    −
    HS -

    BF3

    (CH3)3N

    CH2
    I > II > III > IV

    II > I > III > IV


    NH3

    H2O

    CH3COOH
    NO2ˉ

    CNˉ

    NaHSO3

    Clˉ
    CF3SO3ˉ > CCl3SO3ˉ
    CNˉ > Iˉ

    NH2ˉ > OHˉ


    (CH3)3CLi

    NaNH2

    CH3ONa

    NaOH
    CH3Oˉ > CH3ˉ

    CH3Sˉ > CH3SH

    NH3 > H2O

    (CH3CH2)3N > (CH3CH2)3P


    ∝

    ⇌ Br
    _
    Narrow
    opening
    (RDS)

    Large
    openings
    Narrow opening
    (RDS)

    Largest
    opening

    Large
    opening
    Narrow opening
    (RDS)

    Large
    opening

    Largest
    opening
    Large
    opening

    Narrow
    opening
    (RDS)

    Large
    opening
    Br Nu-
    Nu
    R2
    C C
    C R1 R3
    R3 R1 R3 R1
    R2 R2
    Br R2
    R2
    R3 R1
    C C R1 C
    R3
    R3 R1
    Nu
    R2 Nu-
    Nu R2

    C R3 R1
    R3 C
    R1
    R2
    Nu
    CH3 CH3

    H3C C CH2 Br H3C C OCH3

    H CH3
    CH3 CH3 CH3

    H2 O
    H C Cl H C OH + HO C H
    AgNO3

    C2H5 C2H5 C2H5


    −

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