Name: Class: See. Index No. CORAL SECONDARY SCHOOL (CSS END-OF-YEAR EXAMINATION 2016 CHEMISTRY Paper 1 5073/01 14 October 2016 SECONDARY 3 EXPRESS Duration: 45 minutes Additional Material: OTAS Sheet READ THESE INSTRUCTIONS FIRST ‘Wiite in soft pencil Do not use staples, paper clips, glue or correction fuid answers A, B, Gand D. Choose the one you consider correct and record your choice in soft pencit on the separate Answer Sheet. Read the instructions on the OTAS sheet very carefully. Each correct answer will score one mark. A mark wil not be deducted fora wrong answer. ‘Any rough working should be done In this booklet, copy of the Periodic Table is printed on page 13. ‘The use of an approved scientific calculator is expected, where appropriate. ‘This question paper consists of 13 printed pages, including this page. ‘There are thirty questions on this paper. Answer all questions. For each question there are four possible (58 End OF Yea Eraminaion 216 hemi (731°2 11 The diagram shows the level in the burette filed with dilute hydrochloric acid at the start and end of titration. ‘What volume of acid was added from the burette? start end 25.8 om* 26.6 cm? 273.0? oo wo > 27.4 om? 2 The apparatus below is used to obtain a dry sample of gas X from a mixture of gases, water concentrated sulfuric acid What is the gas collect at X? A. ammonia B argon © helium D hydrogen chloride CS Tid Yea Beaman 016 Sheri SII3 3 The boiling point of water is 100 °C. The melting point of sodium chloride is 801 °C. Which of the following is most likely to be the boiling point of seawater? A % B 104°C c 796°C D 805°C. 4 Iwas suspected that an unknown substance X was one of the three substances P, Q or R. Spots of each substance were put on the starting ines of two pieces of chromatography Paper. One paper was developed with water and the other with ethanol. ‘The diagram shows the final chromatograms. developed with water developed with ethanol solvent front TTY |,— starting line x LP @ Rx Ba CR D Pora CSS era OF Year Branston 2S 3 ~ Chri (807301) x [Turn Ove4 5 Zines purified by fractional distillation in a fractionating column made of silicon carbide. Zine boils at 908 °C. Which ofthe following statements is true? ‘A. The boiling point of silicon carbide is slightly higher than zinc. B__ The boiling point of silicon carbide is slightly lower than zinc. © Silicon carbide has a structure similar to diamond, o Silicon carbide has a structure similar to carbon dioxide, 6 The table below shows the melting and boiling points of four metals. metal point/*C | boiling point /=C | cacsium 2 685 potassium 63 768 rubicium 39 701 sodium 98 890 How many metals wil be in the molten state when heated to 35 °C? Ad B 2 c3 D4 7. Which statement expiains why a solid is denser than a liquid? ‘A. The partcies ina solid have more energy than those ina liquid. B_ The particles in a solid are heavier than those ina liquid. © Tho pattices in a solid are closer together than those in a liquid. D “The particles in a solid are held together by stronger forces of attraction. CS Ear Yea rain 05 8 Anew substance was discovered and a series of experiments were conducted on it, Which observation suggests that the substance cannot be an element? ‘A. Itis broken down into two products when heated. B__Iteissolves in water to give a colourless solution. When exposed to air, it changes colour gradually. When heated in air, it could form two oxides. 9 Which of the following diagram shows the particles in hydrogen chloride? “lO ce "Toe 8 Co Oo Ce . e89 °| oe g S88 oo a 40. Anelement, R, has p protons and n neutrons in its nucleus. Which row gives a possible correct numberof protons, neutrons and electrons ina positive ion of an isotope of R? protons neutrons alecrons | A ? net poi B P ant ptt c ptt a pet D pet 0 po TESTI Dern - — Cherish (307901) 34 [Turn Over6 11. Thvee elements X, Y and Z have consecutive, increasing proton numbers. 412 13 If element X is a noble gas, what will be the symbol for the ion of element Z in its ‘compounds? A B é D In which compound does one of the atorns not achieve the electroni A B c D 2 ~ z z configuration 2,87 CFs con MgO PFs ‘Aluminium melts at 660 °C while sodium melts at 98 *C. Which statement best.explains why aluminium has a higher melting point than sodium? A B iS D Aluminium has a smaller atomic radius than sodium. Aluminium has a stronger metallic bond than sodium, Group | metals have low densities. Group I metals are soft.7 14 Four substances have the following properties — oy — ~—M ‘conducts electricity only in aqueous state N conducts electricity in both sold and molten states o conducts electcty in both molten and aqueous states. P does not conduct electity in any state ‘What could these four substances be? M __N ° = A NaOH co Mg H:S0, B co H:S0, NaOH Mg c 1:80, Mg NaOH co D Mg NaOH He804 co 15 Which particles are responsible for the conduction of electricity in calcium chloride? A electrons only B_ electrons and positive ions negative ions D__ negative and positive ions 46 Which of the following shows the correct structure for hydrogen peroxide? A HO-H-O B H-O-O-H © O-H-O-H D O-H-H-O 47 Antimony oxide has the formula Sb:03 while potassium dichromate has the formula KzCr.Or, What is the formula of antimony dichromate? A SbCnOr B Sb:CKOr C Sb{CHOr)s D Sb(CrOr)e ‘CSS End OF You Eran 76 a Charis (60720 3% !Torn Over8 18 What is the ionic equation for the reaction of barium carbonate with sulfuric acid? A COs+ 2H? —» CO2+ H,O B Ba +S0¢-+ BaSO. © H'+OH HO D ‘There is no ionic equation for the reaction. 419. One mole of sodium sulfate, NaxSOs, is dissolved in water. How many moles of ions does the solution contain? At B2 c 3 D7 20 The reaction when steam is passed over hot coke is shown in the reaction below. H.0 +C-+CO+H: What i the total volume of gases formed from 9 g of steam? A 12d? B 244m? © 36am? D 48m? 24 Milk of magnesia is @ suspension of magnesium oxide in water and is used as a medicine. ‘Whats it most likely used for? ‘A curing headaches B_ asanantiseptic © neutralizing stomach acids D soathing insect bites “CS Ea a GBBT9 22 Armetal forms an oxide which dissolves in water. ‘What is the colour observed when a few drops of Universal indicator are added to the solution? A red soo g 23 What does the term strong acid mean in relation to nitric acid? ‘A Each molecule of acid produces two hydrogen ions in water. B tis fully ionised in an aqueous solution. CC _tforms.a solution of pH 1. D__Itforms a solution of pH 5. 24 The following graph shows the change in pH as substance R is added to hydrochloric acid. 14 pH 7 | nat amount of R added Which statement best explains the shape of the graph? ‘A Rrneutralises the acid to form a neutral salt. B_ Risaninsolubie salt, © Risasoluble base. D Ris an insoluble carbonate. Ed OF Ya Eraniaton 2078 Chemisty (507308) 36 ITorn Over25 Which of the following gives the highest concentration of hydrogen ions? A 8 c D dissolving 1 mole of ethanoic acid in 100 om of water dissolving 1 mole of carbon dioxide gas in 100 om? of water dissolving 1 mole of hydrogen chloride in 100 om? of water dissolving 1 mole of sulfuric acid in 400 cm? of water 10 26. Five siudents each dissolved an antacid tablet in 100 can? of water. They thon titrated 25.0 em* oftheir tablet solutions with dilute hydrochloric acid, using the same indicator. The results are shown in the table below. student 1 2 3 4 final reading/ em? | 24.5 285 24.4 246 21.4 Which statement could explain the result obtained by student 5? A oo ° CSS End Cor Evasion ‘The conical flask was rinsed with the tablet solution. ‘The conical flask was rinsed with hydrochloric acid ‘The burette was washed out with hydrochloric acid. ‘The pipette was washed out with the tablet solution. Choma 50730"n 27. The table below indicates which anions will form precipitates with the three metal cations given, metal cations anions present, carbonate chloride sulfide key _ barium y x x forms precipitate cadmium v x V__| = does not form silver Y v v precipitate ‘A student has a solution containing dissolved salts of all three metals, namely barium, cadmium and silver. He wishes to separate solid compounds of each metal from the solution by filtration, In what order must he add the anions in order to filter out a compound of each metal at each step? carbonate, chloride, sulfide A B carbonate, sulfide, chloride C chloride, carbonate, sulfide D chloride, sulfide, carbonate 28 The most suitable method to prepare lead) chloride crystals is to react hydrochloric acid with A. lead metal. B_ lead{t) oxide. lead) carbonate, D lead(t) nitrate. 29° Which of the following shows a correct use of a noble gas? A. Neon is used in advertising ights. B__ Helium is used in the extraction of iron. © Argon is used in combustion reactions. D_ Krypton is used to fill lightbulbs. “DSS ERO eat Seaabon I (Chenisty 0730¢) 34 (Tern Over2 30. Which row shows the correct order of the relative size of the following ions and atoms? increasing size i Es al our Nat Na K Bi out Na Nat K c] K Nat Na ut o| «Kk Na | Nat ut ~ END OF PAPER ~13 ‘aunssaud pue esnyesaewle} 00! Ye ,LUP ¥2 81 S26 Aue jo ej0Us BLD JO OwUIOA oF] cos zor] oor |uneusbn) wna [rseupuen| unin, wry | ungnt | a | wna a set_| ext | ot | uo prounoy col-06! joueynuey 12-26. | 28 i to |e | a ge | ze | ie ocr | nse] stan | wnwied | man” | 208 aN ve} 4 aja | sia r sotentl 4 i TAL iA TAT AT TT Tay TroIG ‘Squsulayg Ou} JO age 91poued oUL e TSS End Or Yea Ein DIS Chis (07381),Glass: Sec___| Index No.: Gre _s,, CORAL SECONDARY SCHOOL 9) ae 3E (C&S END-OF-YEAR EXAMINATION 2016 CHEMISTRY Paper 2 | 5073/02 7 October 2018 | SECONDARY 3 EXPRESS) = Duration: 1 hour 30 minutes Candidates must answer ALL questions in the space provided in the Question Paper. READ THESE INSTRUCTIONS FIRST ‘Write your name, class and index number on all the work you hand in. ‘Wie n dark blue or black pen. ‘You may use an HB pencil for any diagrams or graphs. Do not use staples, paper clips, highlighters, glue or correction fluid. Section A [50 marks} ‘Answer all questions in the spaces provided. Section B [20 marks] ‘Ansmer all questions in he spaces provided. “The number of marks is given in brackets { Jat the end of each question or part question. ‘A copy of Periodic Table is printed on page 14. “The use of an approved scientific calculator is expected, where appropriate. | “This question paper consists of 14 printed pages, includ rsa af (68S End OF Year Examination 20162 SECTION A Answer all questions in this section in the spaces provided. ‘The total mark for this section is 50. 4 The diagram shows a laboratory preparation of ammonia gas. (@) 3) () TREE Ver oan 6 ss mixture of ammonium chloride and siaked lime dry ammonia gas jar to dry ammonia gas ‘Suggest the name of the chemical present in slaked lime, a A student tied to dry the ammonia gas obtained using concentrated sulfuric acid, i) Explain why his atlempt was unsuccessful 0 (i) Suggest another chemical to dry the ammonia gas. 0 The industial manufacturing of ammonia is carried out using the Haber process. In this reaction, nitrogen and hydrogen gas are mixed together to form ammonia gas. (State the arrangement and movement of particles in the gases. 2 Cerise (07302)3 (i) Complete the table to show the formula and M, of the three gases. gas formula | M, ammonia hydrogen nitrogen 1) (ii) Hence, arrange the three gases in increasing rate of diffusion, (iv) 36 moles of ammonia gas were produced in the process. Calculate the volume occupied by the gas at room temperature and pressure. m “CSSENE OF Year Gearon 2018 (Chenisty 607302) 4o [Torn Over2 Silicon is an element in Group IV of the Periodic Tabie. fa) licon has three naturally occurring isotopes. The abundance of each isotope is given below. isotope ‘relative abundance! % Si 922 Si AT *3i Ey () Explain what is meant by the term ‘isotopes’. i} (ii) Using the Periodic Table and **Si as reference, complete the following table. umber of protons. number of electrons number of neutrons (1) Gil) Using the information on the relative abundance of isotopes, find the average mass of silicon, correct to 1 decimal place. ‘Show your working clearly. 2] TSS Ed Oe ExarinarOn TS Chemisty 5073021s {b) Silicon reacts with chlorine on heating to form siicon(IV) chloride, SiCl4, which has a simple molecular structure. (Suggest two physical properties of sticon(IV) chloride. (li) Drawa ‘dot-and-cross’ diagram for silicon( IV) chloride. ‘You only need to show the outer shell electrons for each atom. 1) (c) _Silicon(iV) chloride reacts with water to form silicon(V) oxide. Part of the structure of silicon(V) oxide is shown below. key @ silicon atom © oxygen atom Predict one property of silicon(|V) dioxide and explain your answer, in terms of structure and bonding 2) SS FTO Year Braninaaa Goris (507302) ma {Tara Over6 3 Since 1850, most books have been printed on acidic paper which becomes brittle and disintegrates over time. Paper tends to be acidic from chemicals added to the paper to reduce absorbency and minimize bleeding of inks. These chemicals, in the presence of moisture, generates sulfuric acid. ‘Acids also form in paper by the absorption of air pollutants- mainly sulfur dioxide. The fact that books are usually more brown and britle along the edges than in the centre clearly illustrates this absorption of pollutants from the air. By treating books with diethyl zinc vapour, the acids in the paper are neutralized and books can be preserved. Diethyl zinc contains 52.8 % of zinc, 99.0 % of carbon and 8.20 % of hydrogen by mass. ‘When diethyl zinc passes through the closed books, it reacts with the small amount ‘of water in the paper to form zine oxide and ethane gas, Cate. The zinc oxide then neutralizes the acid in the paper. (@) Use the data to show that the empirical formula of diethyl zina is ZnC4Hvo fea) (b) Explain why potfutants like sulfur dioxide can contribute to acids forming in the paper. tu) (c) The molecular formula of diethyl zinc is the same as the empirical formula. Write a balanced chemical equation, with state symbols, for the reaction of diethyl zinc with water. “CSS Ene Vea Earn TE (Chem 807302)7 (a) The total moisture content of the book was found to be 1.2.9. Calculate the mass of diethyl zine vapour required to react with this quantity of water. 2 4 Sea salt, sodium chloride is easily obtained by evaporation of seawater. This salt can be made in the laboratory by titration of the reagents. (a) Name the reagents that can be used to prepare sodium chloride, (b) Brictly explain the processes required to oblain the salt solution. In your answer, specify the apparatus required to measure the reagents. 4) (c)_A student suggested using the reaction of sodium and acid fo prepare the salt a titration of the reagents will not be required. () Name the gas evolved in his reaction and describe a test for the gas. 2) (i) Explain why the student says that titration of the reagents is not required if sodium is used iva nanan ae heist (507902)(ii) Give one reason why this reaction is not used to prepare sodium chloride. 5 In an experiment to study the relative reactivity of halogens, chlorine is passed through the tube containing potassium bromide and potassium iodide. potassium bromide potassium iodide QR (black solid) tt gentle heat After a short while, coloured vapours are seen at P and Q. (a) Identify the black solid R. 0 (©) (State the colours observed at P and Q. P. a 2 (ii) Explain why these coloured vapours are observed at P and Q. a TSS End Yew Bann 0 (Cheniy 0702)‘CSS EOF Year an 016 9 Elements in Group Il of the Periodic Table are known as the alkaline earth metals. They behave very similarly o these in Group |. (a) Explain the trend of reactivity down Group Il. a) (b) Barium, an alkaline earth metal is stored in the same way as sodium. (Hows barium stored? : (1) (i) What can you infer about the reactivity of barium? 6 ooameenen m (©) Alkaline earth metals obtained the term ‘earth’ in their namo because their oxides melt at very high temperature that they remain as solids earths") in fires. (Explain, using its structure and bonding, why oxides of Group i! elements have a high melting point. (i) Using barium as an example, suggest how alkaline earth metals acquired the term ‘atkaline’. 2 ‘Chernistry (8073002) 43, {Turn Over10 SECTION B Answer all questions in this section in the spaces provided. ‘The total mark for this section is 20. 7 _onisation energy is defined as the energy required to remove the most loosely held ‘electron from one mole of gaseous atoms to produce 1 mole of gaseous ions each with a charge of 1+. X(g)—> X* (g) +e Graph 7.1 shows the trend of ionisation energy. Graph 7.4 He VM, . . A mae 0 5 10 15 20 25 30 35 25 20 ionisation energy 15 7MS 1.0 05 atomic number Table 7.1 shows the atomic radius of elements in Period 2. Table 7.4 elemont atomic radius! nm lithium 182 berylium 1 boron " 88 - carbon 77 nitrogen 70 oxygen 66 _ fuorine - a neon 51 a (@) Identify the element with the highest ionisation energy and suggest a reason for its high ionisation energy. (2) CSS E RTO You aan ohon TT Cheri 07902}uw {b) What trends are shown in Graph 7.1 and Table 7.1? fa (c) How is the ionisation energy of an atom affected by its atomic radius in general? Use evidence from the information to explain your reasoning. (a) In a chemical reaction, ionisation energy is important in order to predict “whether various atoms make covalent or ionic bonds with each other Use evidence from Graph 7.1 to help explain how ionisation energy can help predict whether atoms make covalent or ionic bonds with each other. 4) CS EnT Oe Baimabon 0 Chernin (507202) he [Turn Over2 ‘The use of invisible ink is one of the ways to hide secret messages. ‘The idea behind the design of invisible inks is a fairly simple one. All itrequires is 2 colourless substance that produces a coloured product when a ‘revealer” is applied, fa) Phenolphthalein, an acid-base indicator, which is colourless in solutions with pH less than 10 and pink in solutions with pH above 10 is a suitable candidate for making an invisible ink. (Suggest a suitable revealer for the invisible ink made of Phenolphthalein. "i (ii) The revealed message was left in the open to dry. After a few days, it was noticed tha the ink started to fade. Explain what could have happened. a {b) Asstudent has been tasked to design a new invisible ink and its reveater. He found the following chemicals in the laboratory: iiute sufrio acid calcium carbonate | copper) oxide ‘Sodium hydroxide | biue Imus solution | chromiurn(if) carbonate lead(})niate | _ potassium iodide barium nitrate (i) Compete tne folewing table to show two paits of chemicals that could act as the Invisble Ink and the reveater. Explain why these pairs of chemicals are chosen. nul, | invisibieink | revealer | reason for choice hydrochloric | jron(tt) iron({i) chloride which is ‘om acid hyroxide | green in colour is formed, 1 2 = 4 TSS 0a an TE Chomsky (07302)1B Wile a balanced chemical equation for the reaction between one of the invisible ink and revealer selected in (bY). ~ END OF PAPER ~ CS End OF Year Examination 2016 a0 a us Ceri (507302) (Turn Over4 s0u08 prouroy eol-o6t sayes poveujuer 31-65, a ee) eu | 2] 38 vat | mami we |W | soul?) ene exe | et ser] a aS vate’ | ste | a w_| oo wea zt) ned w | 19 ow | eN or _| ose | ee o a veel Ta ung | am on | “3 | on oz | ot ei? z T tame tat eH 4 » : t oA aA TAAL a aHOIS, } ‘Syuawely 043 Jo 91421 SPoHOd OyL SSE Oa Exaraion (Chemisty (207302)‘Answer Scheme for End of Year Examinations 2016 ‘Sec 3 Express Pure’ Chemistry (5073) Paper 1 (30 marks) 7 18 Bl2ai[c 2 c D {22 D fa [8 B (23 |B [a |B c f24 | 3 5 c D_ 125 D 6 A B |26 B 7 c c |27 D 8 A D [28 D 9 A | ¢ [29 A 40 A B_ 130 A a Paper 2: Section A(S0marks) — ~| No Answer I Mark da Calcium hydroxideloxide. | 1 4b (i) | Ammonia is a basle gasialkaline gas and wil be 4 neutralised by sulfuric acid. 4b (i) | Calcium oxide/Calcium chloride 1 4e (i) | They are arranged randomly and far apart and 1 move rapidly in all directions. 1 te (ii) gas | formula uf ‘ammonia NH 7 41 mark for correct 1 2 formula ae J > 4 mark for correct ritrogen Ne 28 Me 4c (ii)_| Nitrogen, ammonia, hydrogen 1 id 864 dm? 1 (no marks if nohwrong units) Total 9 marks | 2a) | Atoms ofthe same clement withthe a ‘same number of protons but different number of 1 neutrons, 2a(ii) | p=14,n=14,e=14 1 2a (ity | (0.922%28)+(0.04729)¥(0.031%30)= 28.4 4 mark for working 1 mark for correct answer 2b{i) | Low melting and boiling point/Does not conduct 1 electricity in any state/Insoluble in water 1 yb2biii) 1+ correct bonding 1+ correct number of electrons shared 2c Hard/High melting and boiling point. Because it has a 7 giant molecular structure and a lot of energy is needed to overcome the strong covalent bonds holding the 4 atoms together. OR OR Does not conduct electricity in any states. All 1 valenci il bonding, 1 ‘There is no free electrons to carry the charge. Total 44 marks 3a yn iS i % 52.8 39.0 8.2 Ar 65 12 4 No.ofmel [oat2 [3.25 32 1 ‘Simplest ratio [4 4 10 1 Empirical formula: ZnC4Hy0 a» ‘Sulfur dioxide is a non-metal oxide. Hence it is acidic. 1 36 | ZnCaHre (9) + HzO ()—+ ZnO (s) + 2CaHe(9) Ao alenoed 4+ state symbols, gq__ | Number of mol of water = "2/4 5 =0.06667 4 No. of mol of diethyl zinc = 0.0667 Mass = 0.0667*(65+48+10)= 8.209 1 Ja | Sodium hydroxide/Sodium carbonate - Hydrochloric acid 4b | Fill up the burette with sodium carbonate/sodium 1 hydroxide OR hydrochloric acid Pipette 25 om? of dilute hydrochloric acid OR sodium —_ | 1 ccarbonatelsodium hydroxide into a conical flask. ‘Add a suitable ingicator and titrate tl the indicator 1 changes colour. Repeat the experiment without the indicator. 1 4ci | Hydrogen gas. 1 The gas should extinguish a ighted splint wth a pop 1 sound, acti | Sodium is 2 solid reagent, it wil remain undissolved 1 when added in excess. dium is a highly reactive metal and the reaction _Gelli | would be too vigourous/explosive. 7 | - Total 10 marks Ba | lodine 7 sbi | Areddish brown vapour is observed at P. 1 ‘Apusple vapour is observed at Q. Since chlorine is more reactive than bromine, it wil displace bromine from potassium bromide, resulting in bromine produced at P. Bromine then displaces jodine from potessium iodide to form iodine, resulting ina purple vapour at Q. 1 1+ state reactivity 41- explaining products are as a result of displacement. Total 5 marks 6bi bil Goi Reactivity Increases down Group I. ‘Since atomic radius increases down Group 1, it becomes easier to lose their valence electrons, hence reactivity increases. ‘They are stored under oil. Barium is very reactive. Group It oxides are tonic compounds and they have a Giant ionic latice structure, Moling involves overcoming the strong electrostatic force of ‘attraction between oppositely charged ions. Hence a ot of heat eneray is required. Barium reacts with water to form barium hydroxide and hydrogen ass, ‘Since barium hydroxide is a soluble base, an alkaline solution is formed. i, 1 a Total 8 marks.Paper 2: Section B (20marks) No Answer Mark Ta Tb Te 7d Helium Itis a noble gas/has a stable electronic CuSO.+ HO. oR 2KI + PL(NOs)2 > Phils + 2KNOs oR BH:SOu +Cro{COs)a > Cra(SOu)a + 3H:O + 3CO2 HB invisible ink. ‘1 mark for correct exotanation. Colour of products is required for litmus ONLY. No marks if revealer and ink are incorrect. Total for qns: 4 1+ correct formula 1+ balanced Total 9 marks