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考試用筆記 5
考試用筆記 5
δ ( t) →
ACq ) →
ICE )
=
ACq ) 1ε
A
Define :
Invariant Q
Overal )
=
SI (5) ds =
@
2 ☆ SICε) dq
scattring power
of sample
δ ()
< >
A ( 5) ∵ ds =
d ) < sd θ )
$ ( ssin θ dd )
"
。% [ Ics
"
∴ Q =
) s ' sinod4 dods
9 。
"
dp
=
.
。
v
占)
( . 、 [ ( 5)
∵ I( 5) fEteizasrdr
=
Q ) eizasidids :
SI ) ds ffE (f [feizasids] dr i
= =
(s
=
[ ∴ ( t ) 8 () dr = B
(0 ) = V
<☆
2
>
1 6 due the
sample whole
scattering
to as
.
I (5 ) =
fP eizasidr
) . I(
q
)
=J ∴( t ) eiqtdr δ (a )
'
ou z e + =
'
P 0( r 1
-Solb ( u) du r
Gc
④
lets () =
→
() +☆ ' C)
☆ []
」
δ> u
n -
∞ ”
歲爽
*
*
fluceuation H ( ω =☆ ( ]
) -
☆> ,
⼼ …
∴ …
u )
: E (t ) =
SoCDCtr ) duu time time
=
sdcd r >
Spta) da =☆>√
sfniaidufpcuis
s da 了 :fptasden
s sfdie= ssxV - >^ V : 0
8
same as
Sntutz) du
{~
ICq 3
J 是 C] EiE. rdi
SnlHCU- ) du +☆ fdu
IE
]
=
E ( )=
3
∴ →
=[ ( ) ←∞>√
ET f 8 ([)
0
= (
ICq) =
J. ( ) ei
ε
irdr = [
1 }(r ) eigidi+ <
0→ Vfeiε idr f 3 -
q
fPp r )eiqidr +☆ U δ☆
mallscuelering
(
Hullscattering
dueto tlucenatininstp blodkced a beam
stopper
due to the sample vol .
as a whole Coecurs at q =
0
]
by
𠃍
Diffraction
1 7
.
by crystals
expomential @ 800 m
temp ,
— decay
I(
q
)
MU decay 4
@
high temp .
T 4 S 9 54
I[I θ )
,
, , ,
~~
temprature effeat
∵存 thermal wibration
for 2 鼠 =
在位置上市 ,
獲得修正項
realspae
δ (r = E( t
) ) * z( r )
tlattice factor
誰入撓射強度⼤
0?
AC 5 )
@
F (5 ) E(
⑤☆
110
reciprocal
= x
space
structare factor
2 .
1 Model Structure studied by SAS
球 Iα q 00
是 → sdimensiom
:
omunsseering
lgIN
、
Ixexpl rcd q
I α → 1 dimensiom
aviniereginiRgpurtidksize df
disk Ixq^→
“
dimensiom
IXE
1 2
外墨 qmin
partideshape fractal
唱 002 -
dimension →
=
0
Intermediate
.
region
:
,
啊ih述影喲喲orihilbyhh
Ogaiz
t
鋭
1
-
0
40
競
.
Porod (
…
)
:
d 看形貌
σ
Ix 总
笔 min
岁
>
lag q
"
=
0
. 002
qmax0 . 4 A
' 3 θ= 50
Grange放⼤倍率
20
= 50
→
取決於想要看到的東 )
q( A
I( =
C0" n V Pq SCE onc fluctuation
i n
)
)
.
)
.
q
the A of partides
☆= contrastte In SLD P ( q ) form factor :
形狀 ⼤⼩分佈
Rg radius of
,
qyration
:
Pp ☆s intra
scarteringide
=
pa
-
interaction
:
Scq
n ' of control
density
:
, conc
by
A
partick
ter _
( 份⼦間 )
sexponential intensiey
decayxexpE
^
IcE) ( p
ε
)
←
—
tpowerlar
smea
/ polydicperce… …
… …
decay (
fringes ( humps )
晶
nodispersesizedistribantion
書乐多 ,
q
_
1 .
dilute particulate sys .
( phase separation)
X :
Flory Huggins
-
interaceion
2 .
a
nonparticalate 2 -
phase sys .
( )=
.
X φ 兩者相作
totthhigtionntatiti
.
At 号
BrcusIioG
A
x 上兩者相吸
lamella 鋒⼀定
A3 O
periodicsys
4
3 .
. 1 : 2 : 3 : =
oH - ^
a
B
→
asdlubleblend
se
。
4 -
滨 = - < S +
片
↓ 。
—
x A
T emp
Low critical saturation
flucruaeion
Icqdensiey
个 —
separatios
phuse
LcsT
whan
> [σ } -
☆☆ heating
3 Compositiomfluctuation —
—
← 「4 ☆ [ S
3 E 3 [ 1
> if [ 3
T 23 Ts >
54 ex . 出志晶 saltsugar
q
q
: 0 LCST : phase sEparation
nall
when
coaling
(oppez critical satu ration Temp )
.
2 .
2 Dilute particulate sys .
Define : D
Rg
'
drCldr
SoCt
iSrotridt
=
)
partide is continuoos medium
⑤
蓔
:
分離 , 不連續⼩
bjbiir rjtbndsinekbeuds
;
enters
底
Rg ==^
it
② particde is diserete
scattering
=
÷
centers are ofthe same kind of atom
Rg
= =
、
3R
ideal exluded
魂排公)
vdume chain Soodi 告R3 351
R
assumption
: 1 no
Cphantom
Rg R sphere
=
bond
angle limitation →
2
,
no
立体障礙
3 .
no hindrance
) beads
end to end distance
tncurelatia
-
(Nt (
-
tctiiljorrelation
N (
= 前
liil
< 7 =
' tiili>
④
bondjbondJuncorrelation
i
喲 lt
⑨
=
0
γ >
逊
之 βj
∵ itj ∴ 0 =
④
Ntsroots
mean
square
'
NEO
"
-
< r >= Nl
-
( )
r
:
<
end -
to -
end distance ,
Rg ' E γ
5 以推導來的 不⽤證 ,
A( ) f eiq rdr
.
=
σ ( t)
q
17
Spherical particdes :
'
' =
t) =
' sin θ drdodo
esolidsphere
%
δ ()= %
↑,
真空 {
品
。 ( r ) r = [ "eiqrcossin θ d θ了 dr
及 .
→
2π
。—
⼝
。↓ ☆
S
V =π R → 4 π: 發
3 令 U -
- iErcos θ dU =
iErsindde sinod θ= iqrdu
'
iqi
"
.⑤ ( sinEr RSsinErdr
= 4%
.
- 2
→ A( ) = 2π r ) r dr =
4π rsin ( fr ) dr
q
令 u =
r du
dr =
dr =
sin ( qr ) dr → ⼼ =
感 cos ( qr)
dr 是
-
=
cos sin )
=
是 cos ( ER)
sinCE+ 2
sin ( ER
(
RcosCER ) πP(
)
4
→ A(
q
) =
- E
+
E
>
)
=
E sin ( qR )- ERcos ( ER )
R
>。 sin
②③π
— ]
[
( qR )- ERCOsCER
3 v
4 π=
l
sinx
xcs
-
here
Alq ) 3 Vf x ER
= =
w
3