Chemistry World

WORKSHEET
Class 12 - Chemistry
Time Allowed: 30 minutes
Maximum Marks: 15

1. Assertion (A): The Daniell cell becomes dead after some time.
[1]
Reason (R): Oxidation potential of zinc anode decreases and that of copper increases.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

2. Assertion (A): Zinc displaces copper from copper sulphate solution.
[1]
Reason (R): The E 0
298
of Zn is -0.76 volts and that of Cu is +0.34 volts.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

3. Assertion (A): Copper sulphate can be stored in a zinc vessel.
[1]
Reason (R): Zinc is more reactive than copper.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

4. Assertion (A): Current stops flowing when ECell = 0.
[1]
Reason (R): Equilibrium of the cell reaction is attained.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

5. Assertion: Copper liberates hydrogen from a solution of dilute hydrochloric acid.
[1]
Reason: Hydrogen is below copper in the electrochemical series.

a) If both Assertion & Reason are true and the b) If both Assertion & Reason are true but the
reason is the correct explanation of the reason is not the correct explanation of the
assertion. assertion.

c) If Assertion is true statement but Reason is d) If both Assertion and Reason are false
false. statements.
6. Assertion (A): The resistivity for a substance is its resistance when it is one meter long and its area of cross- [1]
section is one square meter.

Reason (R): The SI units of resistivity is ohm metre (m).

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 a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

7. Assertion (A): EAg+/Ag increases with increase in concentration of Ag+ ions.

[1]

Reason (R): EAg+/Ag has a positive value.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

8. Assertion (A): Conductivity of an electrolyte decreases with decrease in concentration.
[1]
Reason (R): Number of ions per unit volume increases on dilution.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

9. Assertion (A): Equivalent conductance of all electrolytes decreases with increasing concentration.
[1]
Reason (R): Lesser number of ions is available per g equivalent at higher concentration.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

10. Assertion (A): Λ m for weak electrolytes shows a sharp increase when the electrolytic solution is diluted.
[1]
Reason (R): For weak electrolytes degree of dissociation increases with dilution of solution.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

11. Assertion: For the Daniel cell, Zn ∣∣Z n 2+
∣
∣∣
2+
∣ C u ∣
∣ Cu with Ecell = 1.1 V, the application of opposite potential [1]
greater than 1.1 V results into the flow of electron from cathode to anode.

Reason: Zn is deposited at anode and Cu is dissolved at the cathode.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of

c) A is true but R is false. d) A is false but R is true.

12. Assertion (A): In electrolysis, the quantity of electricity needed for depositing. 1 mole of silver is different from [1]
that required for 1 mole of copper.

Reason (R): The molecular weights of silver and copper are different.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

13. Assertion (A): Gold chloride (AuCl3) solution cannot be stored in a vessel made of copper, iron, nickel- [1]
chromium, zinc or tin.

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 Reason (R): Gold is a very precious metal.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

14. Assertion: Identification of cathode and anode is done by the use of a thermometer.
[1]
Reason: Higher is the value of reduction potential, greater would be its reducing power.

a) If both Assertion & Reason are true and the b) If both Assertion & Reason are true but the
reason is the correct explanation of the reason is not the correct explanation of the
assertion. assertion.

c) If Assertion is true statement but Reason is d) If both Assertion and Reason are false
false. statements.
15. Assertion (A): Cu is less reactive than hydrogen.
[1]
Reason (R): E Cu
Θ
2+
/Cu
is negative.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

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