Based on

CF + OYM
AIATS-04

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CSS-04
CHEMISTRY
AIATS-04 (CF + OYM)-Q.56 (3) CH2ClCH2CH2COOH
Topic: Acidic Strength of Carboxylic Acids (4) CH3CH2CH2COOH
The correct order of acidic strength of the given 4. Acidic strength is maximum for.
carboxylic acids is
(1) CHC–COOH
CF3COOH H–COOH C6H5COOH
(2) C6H5–COOH
I II III (3) CH2=CH–COOH
(1) I > II > III (2) III > I > II (4) CH3COOH
(3) III > II > I (4) I > III > II AIATS-04 (CF + OYM)-Q.60
Topic: Reaction of Ammonia Derivatives with
Carbonyl Compounds
Statement I: Addition of ammonia and its
derivatives to carbonyl group of aldehyde is a
nucleophilic addition.
Statement II: Addition of hydrazine to
acetaldehyde is catalysed by base.
In the light of the above statements, choose the
Practice Questions: correct answer from the options given below.
1. The correct order of acidic strength of the given (1) Statement I is incorrect but statement II is
carboxylic acids is correct.
HCOOH CH3COOH C6H5COOH (2) Both statement I and statement II are
correct.
I II III
(3) Both statement I and statement II are
(1) I > II > III (2) I > III > II
incorrect.
(3) III > II > I (4) II > III > I
(4) Statement I is correct but statement II is
2. Minimum pKa among the following is of incorrect.

(1) (2)

(3) (4)
Practice Questions:
1. Which of the following on reaction with carbonyl
group of aldehydes and ketones give
3. Most acidic among the following is semicarbazone?
(1) CH3CH2CHClCOOH (1) H2N–NH–C6H5 (2) H2N–NHCONH2
(2) CH3CHClCH2COOH (3) H2N–NH2 (4) H2N–OH

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CSS-04 Chemistry

2.

Product B in above reaction is (2)

(1) Oxime (2) Imine
(3) Hydrazone (4) Amide
3. Which of the following reaction is not a
nucleophilic addition reaction? (3)
(1) CH3CHO + HCN 
(2) CH3CHO + CH3OH 
dry HCl
 (4) All of these
(3) CH3CHO + CH3MgBr  dry ether
AIATS-04 (CF + OYM)-Q.68
(4) CH3CHO + I2 
 NaOH Topic: Reduction of Nitrobenzene
AIATS-04 (CF + OYM)-Q.61 The electrolytic reduction of nitrobenzene in
strongly acidic medium produces
Topic: Preparations of Aldehydes/Ketones
(1) Azobenzene
(i) NaNH2 HgSO4 , H2SO4
CH3 – C  CH 
(ii) CH3 Br
A B (2) Azoxybenzene
In the above reaction, product B is (3) p-Aminophenol
(1) CH3COCH3 (4) Aniline
(2) CH3COCH2CH3
(3)

(4) CH3CH2CH2CHO

Practice Questions:
1. Nitrobenzene on reaction with Zn dust in
aq NaOH gives
(1) Azobenzene
(2) Azoxybenzene
Practice Questions: (3) Hydrazobenzene
H O (4) p-aminophenol
 B 
CH CN
1. CH3CH2Br 
Mg
dry ether
A 
3 3
C
2. Nitrobenzene on reaction with Zn/NaOH in
Product C in the above reaction is CH3OH gives
(1) Azobenzene
(1) CH3CH2CH2COOH
(2) Azoxybenzene
(2) CH3CH2CH2CHO
(3) Hydrazobenzene
(3) CH3CH2COCH3
(4) p-aminophenol
(4) CH3CH2CHO
3. Nitrobenzene on reaction with Na 3AsO3/NaOH
(i) O
2. CH3–CH2–CH2Cl 
alc KOH

 A  3
(ii) Zn/H O
 B + HCHO in alkaline glucose solution gives
2
(1) Azobenzene
Product B in the above reaction is
(2) Azoxybenzene
(1) CH3COCH3 (2) CH3CH2CHO
(3) Hydrazobenzene
(3) CH3CHO (4) CH3CH2COOH (4) p-aminophenol
3. Which of the following reaction(s) involves 4. Nitrobenzene on electrolytic reduction in weakly
preparation of benzaldehyde? acidic medium gives
(1) Azobenzene
(2) Azoxybenzene
(1)
(3) p-aminophenol
(4) Aniline

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CSS-04 Chemistry

AIATS-04 (CF + OYM)-Q.94

Topic: Structure of Glucose
Number of asymmetric carbon atoms present in
–D–glucose is
(1) 3 (2) 5
(3) 6 (4) 4

Practice Questions:
1. Consider the following reaction sequence

(i)
Major product C is
(1)
Practice Questions: (2)
1. –D–glucose and –D–glucose are (3)
(1) Anomers
(2) Epimers (4)
(3) Homomers 2. Benzal chloride on reaction with water at 373 K
gives
(4) Enantiomers
(1) Acetophenone
2. Glucose will not react with
(2) Benzyl alcohol
(1) Tollens' reagent (3) Benzaldehyde
(2) Br2/H2O (4) Phenylacetaldehyde
3. Major product of the given reaction is
(3) NaHSO3
 C2H5 2 Cd
(4) HCN CH3CH2COCl  
(1) CH3CH2CH2CH2CHO
3. Glucose on reaction with concentrated HNO 3
gives
(2)
(1) Gluconic acid
(2) Saccharic acid (3)
(3) Fructose (4)

(4) Lactic acid

4. Which compound on reductive ozonolysis will
AIATS-04 (CF + OYM)-Q.87 give acetone as one of the products?
Topic: Preparation of Aldehydes and Ketones
(1)
SnCl  HCl H O
R  CN 
2
 (A) 
3
R – CHO
The intermediate compound (A) is a/an
(2)
(1) Primary amine
(2) Secondary amine
(3)
(3) Acid amide
(4) Imine
(4) 

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CSS-04 Chemistry

Based on
AIATS-04 (CF + OYM)

Corporate Office: Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.011-47623456

CONCEPT STRENGTHENING SHEET

CSS-04 CHEMISTRY
Answer Key

AIATS-04 (CF + OYM)-Q.56 AIATS-04 (CF + OYM)-Q.68

Topic: Acidic Strength of Carboxylic Acids Topic: Reduction of Nitrobenzene
1. (2) 1. (3)
2. (1) 2. (1)
3. (1) 3. (2)
4. (1) 4. (4)
AIATS-04 (CF + OYM)-Q.60 AIATS-04 (CF + OYM)-Q.94
Topic: Reaction of Ammonia Derivatives with Topic: Structure of Glucose
Carbonyl Compounds 1. (1)
1. (2) 2. (3)
2. (3) 3. (2)
3. (4) AIATS-04 (CF + OYM)-Q.87
AIATS-04 (CF + OYM)-Q.61 Topic: Preparation of Aldehydes and Ketones
Topic: Preparations of Aldehydes/Ketones 1. (3)
1. (3) 2. (3)
2. (3) 3. (2)
3. (4) 4. (3)

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