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Experimental Investigation On A Thermoelectric Cooler For
Experimental Investigation On A Thermoelectric Cooler For
Research Article
Experimental Investigation on a Thermoelectric Cooler for
Thermal Management of a Lithium-Ion Battery Module
Xinxi Li , Zhaoda Zhong , Jinghai Luo , Ziyuan Wang, Weizhong Yuan, Guoqing Zhang,
Chengzhao Yang , and Chuxiong Yang
School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China
Copyright © 2019 Xinxi Li et al. This is an open access article distributed under the Creative Commons Attribution License, which
permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Electric vehicles (EVs) powered by lithium batteries, which are a promising type of green transportation, have attracted much
attention in recent years. In this study, a thermoelectric generator (TEG) coupled with forced convection (F-C) was designed as
an effective and feasible cooling system for a battery thermal management system. A comparison of natural convection cooling,
F-C cooling, and TEG cooling reveals that the TEG is the best cooling system. Specifically, this system can decrease the
temperature by 16.44% at the discharge rate of 3C. The coupled TEG and F-C cooling system can significantly control
temperature at a relatively high discharge rate. This system not only can decrease the temperature of the battery module
promptly but also can reduce the energy consumption compared with the two other TEG-based cooling systems. These results
are expected to supply an effective basis of the design and optimization of battery thermal management systems to improve the
reliability and safety performance of EVs.
battery cabinet. The flow field and temperature distribution In this study, a new thermal management model of a
of two- and six-layer configurations containing 24 batteries temperature control battery based on semiconductor refrig-
were analyzed in detail by experiments and numerical eration is proposed. This model is characterized by the
simulations. The results showed that the passive air cooling real-time feedback of the temperature of the battery module
system utilizing natural convection (N-C) can maintain bat- through the rapid cooling/heating of the semiconductor
tery temperature at optimal values between 20°C and 30°C. and the effect of the fan. The temperature control module is
Situ et al. [25] designed a coupled battery thermal manage- reflected in the temperature control heat management model
ment (BTM) system based on a novel quaternary phase by the temperature control module of the battery protection
change material plate for balancing the temperature in rect- board. The design and specific operation of the experiment
angular LiFePO4 battery modules; meanwhile, the paraffin, are as follows. First, adiabatic cotton is used to wrap the
expanded graphite, low-density polyethylene, and copper experiment box to create an adiabatic environment. Then,
mesh were combined into a quaternary PCMP to strengthen the parameters of the temperature control module are fully
the heat transfer. The results revealed that the double out- tested. Finally, the discharge experiments of the battery mod-
stretched copper mesh through the phase change material ule at different rates and conditions are tested.
plate could disturb the air flow tempestuously and give rise
to a decrease in thermal resistance; thus, the temperature dis- 2. Materials
tribution inside the battery and temperature uniformity
within the battery module were both better optimized. How- 2.1. Working Principles. Lithium-ion batteries produce a
ever, the battery module cannot be applied during the oper- large amount of heat with the electrochemical reaction
ating status because the batteries have to continue working during charging and discharging. Specifically, the battery
at a hot environment. The stability, reliability, and simplifica- module causes the sharp increase in temperature at a high
tion of the system need to be improved for fixed investment discharge rate. The heat production of a lithium-ion battery
and power consumption. Long-term safety preservation of during charging and discharging is mainly composed of four
battery temperature is also important. parts, which can be found in
In recent years, the thermoelectric effect in a semicon-
ductor has been widely investigated because it can produce Q = Qr + Qj +Qp + Qs , 1
temperature gradient when an electric current is launched.
And thermoelectric generator (TEG) cooling can promptly where Q is the actual generated heat of the battery, Qr is the
create a relatively lower temperature than the surrounding reaction heat, Qj is the Joule heat, Qp is the reaction heat in
temperature, which could not need extra moving parts for the electrode, and Qs is the secondary reaction heat.
converting electrical capacity into refrigerating capacity. The principles of the TEG are the Seebeck and Peltier
The degree of cooling can easily be adjusted depending on effects. The Seebeck effect, which was discovered in 1821, is
the current size. The refrigeration effect can also be main- a phenomenon due to the difference in temperature between
tained for a long time without extra maintenance. This char- two substances or semiconductors. This difference causes the
acteristic not only can improve the system reliability but also voltage difference between the two substances. The afore-
can simplify the system structure for thermal management. mentioned effect can be expressed as
Therefore, thermoelectric generator (TEG) cooling is an
effective approach for thermal management of a battery
ΔV
module [26, 27]. α= , 2
To overcome the negative effects of heat dissipation, con- ΔT
siderable efforts have been invested to investigate an effective
cooling system for a battery module, according to the heat where α is the Seebeck coefficient, △V is the voltage differ-
transfer medium, which should include the air-based thermal ence, and △T is the temperature difference.
management systems such as natural or air-forced cooling The Peltier effect, which was discovered in 1834, is a
[28, 29], liquid-based thermal management systems such as phenomenon when the current passes through the different
heat pipe or fluid liquid cooling [30, 31], and phase change substances, which results in decalescence and exothermic
material-based thermal management system [32, 33]. How- reaction at the joint of the different substances with the direc-
ever, air-based thermal management systems would hinder tion of the current in addition to the irreversible Joule heat.
the heat dissipation among the batteries due to their rela- TEG materials are evaluated by the merit ZT, which is
tively low thermal conductivity and heat transferring effi- defined on the basis of N- and P-type material properties
ciency. Meanwhile, the liquid-based thermal management and is determined by three physical properties, namely, See-
systems with complex structures have to increase the extra beck coefficient, electrical conductivity, and thermal conduc-
cost, which also easily causes short circuit if leakage of the liq- tivity. These properties can be found in
uid occurs in the system and leads to serious thermal run-
away problem for the battery module. In addition, a phase α2
ZT = σT, 3
change material-based thermal management system has to κ
affect the weight of battery module increment and its cost is
extremely high [34]. The instant performance of heat dissipa- where κ is the thermal conductivity, σ is the electrical con-
tion is also challenging. ductivity, and T is the temperature.
International Journal of Photoenergy 3
The conversion efficiency between electrical power and Table 1: Performance parameters of commercial TEG.
refrigeration is measured using the coefficient of perfor-
mance (COP) in the TEG, which can be expressed as I max U max △T max Qcmax L×W ×H
Type
(A) (V) (°C) (W) (mm)
TEC1-12703 3.0 15.4 67 31.1 40 × 40 × 4 5
Qc
COP = , 4 TEC1-12704 4.0 15.4 67 39.3 30 × 30 × 4 2
Pinput
TEC1-12705 5.0 15.4 67 49.4 40 × 40 × 3 9
TEC1-12706 6.0 15.4 67 55.0 40 × 40 × 3 8
where Qc is the refrigerating capacity and Pinput is the electric
power input. Obviously, the better the ZT, the higher the TEC1-12707 7.0 15.4 67 66.3 40 × 40 × 3 7
COP. The optimum refrigeration effectiveness for ideal TEC1-12708 8.0 15.4 67 75.8 40 × 40 × 3 6
assembly equipment is presented as follows [35]:
Nut
Fixed plate
Fixed bolt
Battery
4 5
(a) (b)
Figure 1: 3D diagram of the battery module and the temperature measurement points of the battery module: (a) 3D diagram of the battery
module and (b) the position of temperature measurement points.
(a) (b)
(c) (d)
Figure 2: Physical and local diagrams of the experiment: (a) the whole experiment equipment, (b) the battery module, (c) the thermoelectric
generators, and (d) the semiconductor chip between the upper and lower sections.
5 min on both sides of the TEG. In the refrigeration section, 3.2. Experimental Results of the TEG, N-C, and F-C Cooling at
the temperature drops rapidly from 28.82°C to 9.56°C. On Different Rates of a Battery Module. Figure 6 shows the tem-
the contrary, the temperature increases quickly from perature of nine batteries in the module accompanied with
29.01°C to 41.03°C on the exothermic section. different cooling models such as TEG, F-C, and N-C at vari-
After 5 min, the temperature changes slowly in the TEG. ous discharge rates. The temperature of the middle battery in
The ultimate temperature is 4.71°C on the refrigeration the module is slightly higher than those of other batteries.
section and is 41.22°C on the exothermic section. This phe- The main reason is ascribed to the superposition of other
nomenon is due to two main reasons. On the one hand, nearby batteries. As shown in Figures 6(a) and 6(b), the tem-
the current flows through the P semiconductor and N peratures of the battery module with F-C increase slower
semiconductor, thereby causing temperature difference in than those of the module with N-C. The main reason is that
accordance with the Peltier effect. On the other hand, F-C accelerates the air flow velocity and thus improves the
the temperature transfers through the ceramic material, thus capacity of dissipating heat. As shown in Figure 6(c), the
increasing the temperature on both sides of the TEG to temperature of the module with TEG not only presents
achieve new balance. decreasing tendency but also shows lower values than those
International Journal of Photoenergy 5
Temperature controller
Thermal insulation cotton Battery charge\discharge ark
h
itc e
Heat preservation Sw arg
disch
e\
arg
Ch
Data collection
Experiment box Batteries
Refrigeration T-type
thermocouples
Temperature
acquisition
Figure 3: Schematic of the thermal response measurement platform used for batteries.
50
(a)
Air flow 40
41.03°C
Temperature (°C)
30
Heat rejection
20
P
N 9.56°C
Current flow, I
Heat flow, Q
10
0 297 s
0 1000 2000 3000 4000 5000 6000
Time (s)
Active cooling
TC
TH
Battery module Figure 5: Temperature and time diagram of the cold and hot ends
of TEG refrigeration.
Figure 4: Schematic of the battery module with coupled TEG In Figure 7(a), it shows that the temperature of the bat-
and F-C. tery module increases rapidly as the discharge rate increases.
After analyzing the results of three duplicate experiments,
of other cooling models as time progresses during dischar- Figure 7(b) shows the average value of the maximum temper-
ging at 1 C. This finding may be because the TEG is accompa- atures of the battery module with the N-C, F-C, and TEG
nied by refrigerating capacity adjacent to the battery module cooling models at different discharge rates and the standard
in the equipment. The interchange with the heat produced by deviation is indicated by error bars. Table 2 shows the exact
the battery decreases the temperature to protect the safety of value of the temperatures.
the battery module. What is more, at high discharging rate Notably, the TEG cooling model considerably reduces
conditions, the average temperature of the TEG cooling model the temperature regardless of the discharge rate. The temper-
is still lower than those of the F-C and N-C cooling models. ature differences among the batteries in the module are also
6 International Journal of Photoenergy
90 75
75 3C 3C 60 3C
60
60
45 45
45
30 30 30
75 2.5C 2.5C 2.5C
60 50
60
45 45 40
Temperature (°C)
Temperature (°C)
Temperature (°C)
30 30 30
50
60 2C 60 2C 2C
50 50 40
40 40
30 30
30
50 1.5C 45 1.5C 35 1.5C
40
40 35 30
30 30 25
50 25 30
1C 40 1C
45 25
40 35
35 1C 20
30 30
25 25 15
0 2000 4000 0 2000 4000 0 2000 4000
Time (s) Time (s) Time (s)
(a) (b) (c)
Figure 6: Temperature and time diagram of N-C, F-C, and TEG cooling thermal management at different discharge rates of batteries: (a) N-C
cooling, (b) N-C cooling, and (c) TEG cooling.
90
70 80
The max temperature (°C)
The max temperature (°C)
70
60
60
50 50
40
40 30
20
30
10
20 0
0 1000 2000 3000 1C 1.5C 2C 2.5C 3C
Time (s) Discharge rate
1C 2.5C N-C
1.5C 3C F-C
2C TEC
(a) (b)
Figure 7: Diagram of the highest channel at different rates: (a) temperature variations as time changes and (b) the column graphs with the
maximum temperature of N-C, F-C, and TEG.
Table 2: Exact value of the temperatures of N-C, F-C, and TEG promptly decrease the temperature’s increasing speed but
cooling models. also can remarkably reduce the temperature value.
40
Temperature (°C)
Temperature (°C)
Temperature (°C)
35
25 35
30 30
20
25
0 1000 2000 3000 4000 0 1000 2000 3000 4000 0 1000 2000 3000 4000
Time (s) Time (s) Time (s)
(a2) (b2) 50 (c2) 50
1.5C discharge 1.5C discharge 1.5C discharge
35 45 45
Temperature (°C)
Temperature (°C)
Temperature (°C)
40 40
30 35
35
30
30
25
25
0 1000 2000 3000 0 1000 2000 3000 0 1000 2000 3000
Time (s) Time (s) Time (s)
(a3) 50 (b3) 55 (c3) 55
2C discharge 2C discharge 2C discharge
45 50 50
Temperature (°C)
Temperature (°C)
Temperature (°C) 45
45
40
40 40
35
35
35
30 30
30
25 25
0 1000 2000 0 1000 2000 0 500 1000 1500 2000 2500
Time (s) Time (s) Time (s)
(a4) 60 (b4) 65 (c4)
2.5C discharge 60 2.5C discharge 60 2.5C discharge
55
Temperature (°C)
Temperature (°C)
Temperature (°C)
50
50 50
40 45
40 40
30 35
30
30
0 500 1000 1500 0 500 1000 1500 2000 0 500 1000 1500 2000
Time (s) Time (s) Time (s)
T1 T6 T1 T6 T1 T6
T2 T7 T2 T7 T2 T7
T3 T8 T3 T8 T3 T8
T4 T9 T4 T9 T4 T9
T5 T5 T5
(a) (b) (c)
Figure 8: Thermal management model of TEG temperature control in different modes: (a) single TEG, (b) FC+TEG-40°C, and (c)
FC-40°C+TEG-40°C.
8 International Journal of Photoenergy
50
20
40 15.95
Q (J)
30 12.38
20 10
10
0 0
1C 1.5C 2C 2.5C TEG FC-40°C+TEG-40°C FC+TEG-40°C
Discharge rate
TEG
FC-40°C+TEG-40°C
FC+TEG-40°C
(a) (b)
Figure 9: The maximum temperature and energy consumption among pure TEG, FC+TEG-40 C, and FC-40°C+TEG-40°C: (a) column
°
graphs with the maximum temperature TEG, FC+TEG-40°C, and FC-40°C+TEG-40°C and (b) the diagram of energy consumption.
at all periods and the TEG for thermoelectric refrigeration Table 3: Corresponding temperature value of the pure TEG,
FC+TEG-40°C, and FC-40°C+TEG-40°C.
was launched at the average temperature of the battery
module of 40°C. Rate 1C 1.5C 2C 2.5C
In the FC-40°C+TEG-40°C cooling system, the TEG
TEG 27.40 35.56 47.24 56.52
for thermoelectric refrigeration and the fans for F-C were
FC+TEG-40°C 41.56 46.63 51.59 57.02
launched at the average temperature of the battery module
of 40°C. The temperature of the three cooling systems was FC-40°C+TEG-40°C 40.81 44.05 49.63 56.43
measured at the discharge rates of 1.0, 1.5, 2.0, and 2.5 C
as time progressed. The results show that the pure TEG
cooling system presents excellent cooling performance.
Specifically, the corresponding temperatures of this system 4. Conclusions
are lower than those of the two other cooling systems. The
reason is that the TEG for thermoelectric refrigeration can In this study, the thermal management system for a cylin-
effectively provide a cooling resource to exchange the heat drical lithium-ion battery module constructed by nine
produced by the battery module. FC-40°C+TEG-40°C dis- 18650-type batteries was designed and compared with tra-
plays a relatively high temperature, but it still can satisfy ditional air cooling systems, which was based on semicon-
the requirements of the temperature of the battery module ductor thermoelectric cooling, natural forced cooling, and
in application at the discharge rate of 2.5 C. forced convection cooling. The maximum temperature rise
After analyzing the results of the three duplicate and distribution within the different battery modules at
experiments, the average value of the maximum temper- different discharge rates were investigated by experiment.
atures among the pure TEG, FC+TEG-40°C, and The maximum temperature of thermal management based
FC-40°C+TEG-40°C is shown in Figure 9(a) and the on the TEG cooling system was optimized. And three
standard deviation is indicated by error bars. Meanwhile, cooling systems which were pure TEG, F-C coupled with
Table 3 shows the corresponding average value of the maxi- TEG at 40°C (FC+TEG-40°C), and TEG coupled with
mum temperatures. F-C both at 40°C (FC-40°C+TEG-40°C) were compared
Figure 9(b) shows the energy consumption for compar- to further analyze the cooling performance. The main con-
ing the economic cost, and the error bars indicate one clusions are summarized as follows:
standard deviation of the energy consumption, which is
calculated by multiplying the current, voltage, and time (1) The temperature of the battery module with a TEG
during the three duplicate experiment processes. Using the presented a decreasing tendency and lower values
formula Q = U · I · t, the pure TEG is found to exhibit the than F-C and N-C cooling models as time progresses
highest energy waste during refrigeration compared with during discharging at 1 C. The main reason was that
the two other systems. On the contrary, FC+TEG-40°C the TEG accompanied by refrigerating capacity adja-
consumes the least energy. Thus, FC+TEG-40°C is the cent to the battery module in the equipment can
best choice as the thermal management model of TEG interchange the heat produced by the battery for
temperature control. decreasing the temperature of the batteries
International Journal of Photoenergy 9
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