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Atomic Structure
Atomic Structure
• Electronics
Electron Mechanics
Atomic structure
of elements.
• atoms are made up of three particles:
protons, neutrons and electrons
Atomic structure
of elements
• Protons and neutrons have approximately the same
mass.
• Atoms always have an equal number of protons and
electrons.
• number of protons or electrons in an atom is called
Atomic structure atomic number
of elements. • atomic number = number of protons or electrons in
an atom
• Atomic weight = no: of protons + no: of neutrons
Atomic structure
of elements
Atomic structure
of elements
• An electron moving around the nucleus
possesses two types of energies .
Copper
Atom
• Insulators have a high resistance so
current does not flow in them.
• Good insulators include:
• Glass, ceramic, plastics, & wood
• Most insulators are compounds of
several elements.
Insulators • The atoms are tightly bound to one
another so electrons are difficult to strip
away for current flow.
• Semiconductors are at the heart of almost every
electronic system in use today, from your washing
machine to the space shuttle.
for solids
There important energy band are
• Valance band (VB)
• Conduction band (CB)
• Valence band. The range of energies
(i.e. band) possessed by valence
Energy level electrons is known as valence band.
and diagram
for solids
Energy level
and diagram
for solids
• Insulators: Insulators (e.g. wood, glass etc.) are
those substances which do not allow the passage
of electric current through them.
• In terms of energy band, the valence band is full
while the conduction band is empty.
• The energy gap between valence and conduction
bands is very large (~ 15 eV) as shown in Fig.
• Therefore, a very high electric field is required to
Classification push the valence electrons to the conduction
band.
of Solids and • At room temperature, the valence electrons of
the insulators do not have enough energy to cross
over to the conduction band.
Energy Bands • An insulator has negative temperature coefficient
of resistance.
• Conductors. Conductors (e.g. copper, aluminium) are those
substances which easily allow the passage of electric current
through them.
• It is because there are a large number of free electrons
available in a conductor.
• In terms of energy band, the valence and conduction bands
Classification overlap each other as shown in Fig. Due to this overlapping, a
slight potential difference across a conductor causes the free
Energy Bands
• Semicondutors. Semiconductors (e.g. germanium, silicon etc.) are those
substances whose electrical conductivity lies in between conductors and
insulators.
• In terms of energy band, the valence band is almost filled and conduction
band is almost empty.
• Further, the energy gap between valence and conduction bands is very
small as shown in Fig.
• Therefore, comparatively smaller electric field (smaller than insulators
but much greater than conductors) is required to push the electrons from
Classification •
the valence band to the conduction band.
A semiconductor has:
of Solids and •
•
(a) almost full valence band
(b) almost empty conduction band
Energy Bands • (c) small energy gap(:::'. 1 eV) between valence and conduction
bands.
.
Classification
of Solids and
Energy Bands
• The unique capability of semiconductor atoms is their ability
to combine together to form a physical structure called a
crystal structure.
Semiconductors
Bonds in
Semiconductors
• The semiconductor is divided into two types.
• The pure form of the semiconductor is known as
the intrinsic semiconductor.
• The semiconductor in which intentionally
impurities is added for making it conductive is
known as the extrinsic semiconductor.
• Doping
• To make the semiconductor conduct electricity, other atoms
called impurities must be added. This process is called doping.
• An impurity, or element like arsenic, has 5 valence electrons.
• Adding arsenic (doping) will allow four of the arsenic valence
N-type electrons to bond with the neighboring silicon atoms.
• The one electron left over for each arsenic atom becomes
Semiconductor available to conduct current flow.
• Impurities, such as arsenic, that free up electrons (negative
charges) to move through a semiconductor are called donor
dopants
• You can also dope a semiconductor material with an
atom such as boron that has only 3 valence electrons.
• The 3 electrons in the outer orbit do form covalent
bonds with its neighboring semiconductor atoms as
before. But one electron is missing from the bond.
• This place where a fourth electron should be is
referred to as a hole.
• The hole assumes a positive charge so it can attract
electrons from some other source.
• Impurities, such as boron, that free up holes (positive
charges) to move through a semiconductor are called
acceptor .
• If you use lots of arsenic atoms for
doping, there will be lots of extra
electrons so the resistance of the
material will be low and current will
flow freely.
Resistance • If you use only a few arsenic atoms,
Effects of there will be fewer free electrons so
the resistance will be high and less
Doping current will flow.
• By controlling the doping amount,
virtually any resistance can be
achieved.
Based on the impurities present in extrinsic
semiconductors they are classified in to two categories
• N-type semiconductors
• P – Type semiconductor