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Investigations on fine fraction of aged municipal solid waste recovered


through landfill mining: Case study of three dumpsites from India

Article  in  Waste Management & Research · June 2018


DOI: 10.1177/0734242X18782393

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WMR0010.1177/0734242X18782393Waste Management & ResearchSomani et al.

Original Article

Waste Management & Research

Investigations on fine fraction of aged


1­–12
© The Author(s) 2018
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DOI: 10.1177/0734242X18782393
https://doi.org/10.1177/0734242X18782393

landfill mining: Case study of three journals.sagepub.com/home/wmr

dumpsites from India

Mohit Somani1, Manoj Datta1, GV Ramana1 and TR Sreekrishnan2

Abstract
Reclamation of the dumps/landfills having huge quantities of decades-old garbage (aged waste or legacy waste) in an environmentally
sound manner is one of the major challenges faced by the developing nations in general and in particular by urban local bodies in
India. The article presents the feasibility of landfill mining operation specifically to recover soil-like material at old dumpsites of India
for re-use in geotechnical applications. Aged municipal solid waste was collected from three dumpsites of India and initial tests were
conducted on the soil-like material of the municipal solid waste. Initial tests results of grain size distribution, compositional analysis,
organic content, total dissolved solids, elemental analysis, heavy metal analysis and colour of the leached water from finer fraction
of aged municipal solid waste are presented. From the preliminary investigation, it was found that organic content in 15–20-year-old
dumpsites varies between 5%–12%. The total dissolved solids ranges between 1.2%–1.5%. The dark coloured water leaching out from
aged waste, with reference to local soil, is one of the objectionable parameters and depends on the organic content. The concentration
of heavy metals of the finer fraction were compared with the standards. It was found that copper, chromium and cadmium are present
at elevated levels in all the three dumpsites. The study concluded that the bulk of the soil-like material from aged municipal solid
waste landfills can be used as cover material for landfills at the same site. However, some treatment in terms of washing, thermal
treatment, blending with local soil, biological treatment, etc., is required before it can be re-used in other geotechnical applications.

Keywords
Aged municipal solid waste, critical parameters, fine fraction, landfill mining, open dumps, reuse

Received 22nd March 2018, accepted 15th May 2018 by Associate Editor Mario Grosso.

Introduction
The basic principle of sustainable solid waste management is to out of 50 biggest dumpsites directly threaten marine and coastal
maximise the utility of material to the greatest possible extent areas. The 50 biggest dumpsites directly affect daily lives of 64
with disposal as the least preferred option (Directive, 2008; million people. More than 750 people died in the first half of
Wagner and Raymond, 2015). In contrast to this, waste per capita 2016 because of improper management of waste at dumpsites
is rising as economies develop. Globally, around 2 billion tonnes (ISWA, 2017). There are thousands of unscientific and ill-
per year of municipal solid waste (MSW) is generated annually managed open dumpsites in India today, which are being noticed
(Wilson et al., 2015). In 2008, India produced 48 million tonnes owing to the various short and long-term issues and impacts they
of solid waste as per one estimate. By 2016, this had risen to 52 can potentially cause (Kumar et al., 2017). Until 2011, about 59
million tonnes (Kumar et al., 2017). landfills (basically open dumps) exist in the country, 376 landfills
Open dumps pose numerous health, safety and environmental were under planning and 1305 landfill sites were identified for
threats. Some of these threats are: fire, contamination of streams, future use (Central Pollution Control Board, 2012).
rivers and lakes, soil and groundwater, drinking water owing to
the migration of leachate into subsoil, inhalation of toxic gases,
1Department of Civil Engineering, IIT Delhi, New Delhi, India
disease carried by mosquitoes, flies and rodents, damage to plant 2Department of Biochemical Engineering and Biotechnology, IIT
and wildlife habitats, decrease in the quality of life of nearby resi- Delhi, New Delhi, India
dents and the local community. In developing countries open
Corresponding author:
dumpsites are common owing to the low budget for waste dis-
Mohit Somani, Department of Civil Engineering, Block IV/116, IIT
posal and non-availability of skilled manpower (Ali et al., 2014). Delhi, Hauz Khas, New Delhi 110016, India.
A total of 40% of the world’s waste directly goes to dumpsites; 38 Email: msomani02@gmail.com
2 Waste Management & Research 00(0)

Table 1.  ‘Fine fraction’ as adopted in literature.

S.No. Reference Sieve size (mm) S.No. Reference Sieve size (mm)
1 Prechthai et al., 2008 50 6 Kurian et al., 2003 10
2 Jain et al., 2005 0.475 7 Hull et al., 2005 25
3 Monkare et al., 2016 20 8 Quaghebeur et al., 2013 10
4 Wolfsberger et al., 2014 40 9 Hogland 2002 50
5 Masi et al., 2014 4 10 Zhao et al., 2007 40

Landfill mining is the process of recovering valuable In the present study, aged MSW was collected from three
materials from landfilled MSW. The process involves excava- dumpsites located at Kadapa, Hyderabad and Delhi. Aged
tion, pre-processing, trommeling/screening, post-treatment waste may be defined as the MSW that has been disposed of in
and reuse of landfilled materials with the objectives of con- an unlined dumpsite (with nominal or no soil cover) more than
servation of landfill space; reuse of materials; reduction of 10 years ago. The present study is aimed at assessing the feasi-
landfill footprint; and elimination of potential contamination bility of using fine fraction of mined material as earthfill. In
source and rehabilitation of dumpsite (Rosendal et al., 2009). this article, attention is focused on fraction finer than 4 mm.
Landfill mining can be defined as a process for extracting The composition of aged MSW was examined through on-site
minerals or other solid natural resources from waste materials grain size distribution (GSD) with a set of sieves. The objec-
that previously have been disposed of by burying them in the tives of the present study are to: (a) review landfill mining
ground (Krook et al., 2012). The recoverable fractions from studies/projects and compile the properties of soil-like material
landfill mining primarily includes metals, combustibles and mined from aged waste on the basis of available literature; (b)
possibly soil-like material, which requires extensive study, report the results of some initial tests on finer fraction (<4 mm)
not only about the overall composition, but also about the obtained from aged waste of three Indian dumpsites; (c) iden-
pretreatment before use (Kaartinen et al., 2013). Previous tify critical aspects that need to be monitored for re-use of aged
studies/projects have shown that different landfill sites have MSW.
different potential for mining depending upon the age of
landfill, type of waste, location of the landfill, hydrological
Literature review
and meteorological conditions, etc. The characterisation of
mined waste from landfill has been done by screening the Savage (1993) reported that the initial efforts for landfill mining
waste into different particle size fractions and subsequent was attempted in Tel Aviv, Israel as long back as 1953 for obtain-
analysis on screened fractions (Hogland, 2002; Hull ing fertilisers for orchards. Landfill mining is still an evolving
et al.,2005; Kurian et al., 2003; Prechthai et al., 2008; subject and is being improved in terms of utility of mined materi-
Quaghebeur et al., 2013). One of the most critical aspects of als (Gaintanarou et al., 2014).
landfill mining is the end term utility of the mined product Table 2 presents the summary of several landfill mining pro-
(Masi et al., 2014). One of the major hurdles in the success of jects carried out in several parts of world. It can concluded that at
landfill mining operations is the difference between resource almost all the landfill sites the material after reclamation was
potential and technical potential, that is for technical, eco- used as cover at the site itself. A total of 60%–70% reclaimed
nomical and ecological reasons, it is not possible to convert material has been reported as soil-like material. However, only at
the complete deposited resources into marketable recyclables Edinburg landfill the reuse has been mentioned as construction
(Frandegard et al., 2013). material, but details about its geochemical and geotechnical
The high soil-like content in the aged MSW is likely the result properties are not given.
of daily covering soil, street sweepings, drain silt and construc- The reviewed articles contain conceptual discussion about the
tion and demolition (C&D) waste along with the humification of properties of aged MSW, simulating it as a soil material. They
organic matter in the fresh MSW (Parrodi et al., 2017). Several include discussion on how the material recovered from the land-
definitions for ‘finer fractions’ are available in the literature fill can be blended with the local soil to be used for different
depending upon the sieve size adopted. Fine fractions (often purposes to increase the strength and reduce the compressibility.
defined as size <10 mm to <60 mm) have been identified as 40%– Table 3 presents the comparison of the investigations done on the
80% of the mined materials in previous studies (Hogland, 2002; suitability of MSW soils as an earthfill material.
Hull et al., 2005; Kaartinen et al., 2013; Kurian et al, 2003;
Monkare et al., 2016). The sieve size used in various studies are
shown in Table 1.
Recent landfill mining initiatives in India
In the present study, fine fraction reclaimed from waste has Kurian et al. (2003) reported the reuse of decomposed waste
been defined as the fraction of aged MSW finer than 4.75 mm in from the solid waste dumpsite in Deonar, near Mumbai, India.
size. Material finer than 4.75 mm comprises of clay, silt and sand However, as the topic of landfill mining has been raised in India
as per geotechnical application (IS 2720-4 (1985)). recently, limited data about the real onsite composition and
Somani et al. 3

Table 2.  Summary of landfill mining projects reported in literature.

S.No. Name of landfill Reference Main objectives Particle Soil-like Suggested use of
site size (mm) material (%) reclaimed soil
1 Naples landfill, Kurian et al., Groundwater protection, 75 40–60 Cover material
USA 2003 recovery of landfill volume
2 Filbornia landfill, Hogland et al., Technical feasibility study 18 55–70 Covering material
Sweden 1997
3 Frey farm Kurian et al., Recovery of waste fuel to 25 41 Cover material
landfill, Canada 2003 fully exploit the capacity of
a waste incineration plant
4 Maung Pathum Joseph et al., Potential rehabilitation and 2 69–75 Landfill cover
Dumpsite, 2004 material recovery material, compost
Thailand after supplying P & K
5 Burghof landfill, Joseph et al., Environmental remediation N.A. 70.5 Fine material was
Germany 2004 and construction of new reused at landfill site
landfill
6 Perdido landfill, Dhar, 2015 Increased capacity, 25 70.4 Daily cover, reuse
USA reduced footprint and outside the landfill is
addressing groundwater also possible
problems
7 Edinburg landfill, Dhar, 2015 Technical and economic 25 75 Cover and off-site
UK feasibility study beneficial use
8 Clovis landfill, Dhar, 2015 groundwater contamination 50 60 Not reported
USA mitigation, airspace
recovery, and soil recovery
9 Kuopio landfill, Monkare et al., Feasibility study to analyse 20 45–50 Not reported
Finland 2016 the content of fine fraction
10 Lohja landfill, Monkare et al., Feasibility study to analyse 20 60–70 Not reported
Finland 2016 the content of fine fraction
11 REMO landfill, Quaghebeur Assessment of volarisation 10 40–60 Not reported
Belgium et al., 2013 potential of material stored
in landfill

P & K: Phosphorous and Potassium; N.A.: Not available.

condition of Indian landfill sites (e.g. Singh et al., 2017) are developed before current regulations (MoEF (2000) and MoEF
available. (2016)) were in place. Table 5 presents the general information
As presented in Table 4, the recent studies on landfill mining about all three dump sites.
shows that around 50%–60% of the total material looks as soil- The samples were collected between December 2016 and
like material from geotechnical point of view. However, from the February 2017 from the location as shown in Figure 1. Samples
limited test data, it was observed that a high amount of organic were taken from a depth of 4–5 m from Delhi and Hyderabad
content, chloride, sulphate and salts are the critical issues to be dump sites as presented in Figure 2. However, at Kadapa dump-
consider before using it in earthworks. Detailed characterisation site capping was underway. So, samples were collected from
on aged waste has not been reported in the above mentioned stockpiles of mined waste. All the collected samples were sealed
studies. in separated pre-cleaned polythene bags and stored in cooling
cabinets.

Materials and methods


On-site GSD and compositional analysis
In the course of this work, the recovery potential of soil-like
material from three selected open dump sites in India was inves- At the Delhi landfill site, after excavating the samples and partial
tigated. The scope of this investigation contained the steps of air drying for 7–8 days, on-site studies about GSD and composi-
excavation, sampling procedure and some preliminary field and tional analysis were carried out as shown in Figure 3. The age of
laboratory analysis. waste was confirmed through newspaper clippings, food packets,
etc., as shown in Figure 4. The water content at the time of per-
forming GSD and compositional analysis was 10%–12% and the
Site description and sampling details lumps present in the samples were broken up using a wooden
The material used in the current research originates from the old hammer. GSD was performed as per the availability of sieve
dumpsites located at Okhla, Jawaharnagar and Ukkayyapalli in sizes at the site. At the Kadapa landfill, 30 mm, 8 mm and 4 mm
Delhi, Hyderabad and Kadapa, respectively. All these sites were trommel was available. Hence, GSD was performed accordingly.
4 Waste Management & Research 00(0)

Table 3.  Some characteristics of material recovered from landfill mining from literature.

Location Southern Seoul city, Korea Deonar landfill, Kodungaiyur Perungudi


California, USA India landfill, India landfill, India
Age of waste 60 years 25 years 4–12 year 15 years 15 years
Grain size Passing 75 µ sieve Not reported % passing 8 mm Fine soil less than Fine soil less than
distribution (35.5–28.9)% (soil-like sieve − 63.5% 2 mm − 56%–68% 2 mm − 33%–41%
material) % greater than
25 mm sieve −
31.5%
Specific gravity Not reported 2.58–2.44 Not reported Not reported Not reported
Liquid limit 48%–62% Not reported Not reported Not reported Not reported
Plastic limit 24%–32% Not reported Not reported Not reported Not reported
Maximum dry 16.5–15.2 15.5–6.77 9.41 8.8–11.77 9.4–9.7
density (kN m-3)
Optimum 10.9%–18.8% 7.4%–13.9% 14% 30%–40% 23%–30%
moisture content
Organic content 6.3%–12.4% 6.06%–12.45% 14.5% 8.9%–20.7% 8.9%–15.8%
Remarks From stability and If organic content Fine material Fine fraction can be  
compressibility is more than 8%, blended with applied as compost
criteria, waste can it can not be used dolomite, to non-edible crops
be blended with as sub-grade gypsum, neem or as cover material
soil and can be material cake and was after determining
used in fill sold as fertiliser the geotechnical
suitability
References Oettle et al., 2010 Song et al., 2003 Kurian et al., 2003  

Table 4.  Recent initiatives on landfill mining in India.

Location Pirana landfill, Ghazipur landfill, New Delhi


Ahmedabad
Age of waste N.A. 5 years 10 years 15 years
Grain size 0–4 mm 15–20 29 27 34
distribution 4–16 mm 16–17 18 17 14
analysis (%) >16 mm 44–55 53 56 52
Moisture content (%) 17–19 1.3 0.8 1.1
Organic content (%) 9.79–10.21 5.17 2.93 3.3
Carbon (%) 1.66–4.83 N.A. N.A. N.A.
Hydrogen (%) 0–0.62 N.A. N.A. N.A.
Nitrogen (%) 0–0.46 N.A. N.A. N.A.
Sulphur (%) 0–0.12 N.A. N.A. N.A.
Plasticity N.A. Non-plastic
Maximum dry density (kN m-3) N.A. 16.7 16 15.5
pH 7.8–9.2 7.4 7.6 7.6
Sulphate (mg kg-1) N.A. 15430 9003.7 10485
Chloride (mg kg-1) N.A. 2563 1590 1843
Reference Singh et al., 2017 Vasant, 2017

Table 5.  General information about the landfill sites.

S.No. Landfill Started in Total area (acre) Height (m) Total quantity of waste (MT) Present condition
1 Okhla landfill, Delhi 1994 40 65–70 6 millions Open dumping
2 Jawaharagr landfill, Hyderabad 1999 350 N.A. N.A. Engineered landfill
3 Ukkayyapalli landfill, Kadapa 1965 10 10–12 0.2 millions Closed

MT: Metric ton; N.A.: Not available.


Somani et al. 5

Figure 1.  Site location and sampling points from the dumps.

At the Hyderabad landfill, only 20 mm and 4 mm trommels were Composition analysis of MSW in this study was carried out as
available and GSD was performed without air drying. At the per the procedure outlined by Zekkos et al. (2010a). As the col-
Delhi landfill, GSD was performed manually by using sieve of lected MSW samples were wet, the composition of all the sam-
200 mm, 80 mm, 35 mm, 16 mm and 4 mm. ples was determined after air drying them in an open space under
6 Waste Management & Research 00(0)

Figure 2.  Excavation of aged MSW.

at 440 °C/750 °C to a constant mass. However, drying at 105 °C


may volatilise some portion of the organic material in the MSW. To
compensate for the potential for volatilisation of organic matter,
many investigators recommend measuring the initial moisture con-
tent and dry weight of MSW at a temperature below 105 °C.
However, there is no agreement upon the standardised temperature
at which to do this. In the present study, moisture content was
determined by drying waste at 60 °C to a constant mass and organic
content is determined by heating the dried waste at 550 (±50 °C),
which is in accordance with Monkare et al. (2016) and Zekkos
et al. (2010b). TDS was determined as per IS 2720-21 (1997).
Heavy metals analysis was also carried out. One gram of the oven
dried sample (dried at 60 °C till constant weight and passed through
1 mm sieve) was digested with HNO3 and HCl in a 1:3 ratio as
mentioned by Wagland et al. (2017). After digestion, all the sam-
ples were set aside to cool and were diluted with 1 N nitric acid.
Figure 3.  Screening of aged MSW.
The mixture was filtered through an acid-washed Whattman No.42
filter paper into a 50 ml volumetric flask and diluted to the required
sunlight until a constant dry weight was obtained. The air dried volume. All the digested samples were aspirated into a double
MSW samples were first sieved through a large size sieve having beam atomic absorption spectrophotometer (ECIL 4141, India) for
20 mm square openings for separating the sample into the <20 mm the analysis of selected heavy metals. Elemental analysis was per-
(soil-like or soil-sized) and the >20 mm (fibrous) fractions. formed using a Vario EL cube CHNS analyser.
Fraction >20 mm was then manually sorted into different con- Concerns about the colour of the water leached through from
stituents, such as gravel, textile, plastic, paper, wood and wood- soil-like aged waste used in earthfill has not been reported in the
like, glass and miscellaneous items. The quantity of dry MSW literature. However, if the soil used in the road subgrade leaches
sample used for the compositional analysis varied between 120 out coloured water may contaminate the surrounding water bodies
and 140 kg. This is in conformation to the minimum quantity and also may have some aesthetic issues. A colour test was per-
(91–136 kg) recommended in ASTM D5231-92 (2016) for the formed in the present study to address the same concern. Soil-like
determination of the composition of unprocessed MSW. material from the aged waste was mixed with ultrapure water in a
1:3 ratio and was shaken for 30 min at 200 r min-1 in a rotary
Preliminary laboratory analysis shaker. Then, it was allowed to settle down for 12–15 h. After 24 h,
it was decanted through a Whattman filter paper No. 42, the inten-
The lab tests carried out includes determination of moisture con- sity of colour was measured through the Lovibond Tintometer.
tent, organic content, Total dissolved solid (TDS) heavy metal
analysis, elemental analysis (CHNS) and release of colour leached
through the soil-like material from aged MSW. TDS in the present Results and discussions
study represent total soluble solids in the soil matrix of the aged
MSW. The standard procedure used in geotechnical practice to
Grain size distribution
evaluate moisture content and organic content of organic soils At Hyderabad landfill GSD analysis was carried out without air
ASTM D2974-14 involves drying the material at 105 °C and then drying. Therefore, the fraction of soil-like material was found to
Somani et al. 7

be less. The results of GSD reveals that the significant fraction of washing it becomes 35%. The complete GSD analysis including
soil-like material was observed in aged MSW at all the landfills, hydrometer analysis for all the three landfills is presented in
which can be further considered for its geotechnical suitability. Figure 5.
Laboratory grain size analysis of MSW samples (<4 mm) was
carried out after drying at 60 °C as presented in Table 6. Both dry
Compositional analysis
and wet sieve analyses were carried out on MSW sample from all
the landfills. The fine fraction was found higher in wet sieve Table 7 presents the results of compositional analysis carried out
analysis in comparison with dry sieve analysis. The higher finer at the landfill sites. It can be observed that the maximum amount
fraction from wet sieve analysis is owing to better break down of of soil-like material was found in Kadapa landfill site. This site is
lumps of waste particles. This is consistent with the observations the oldest among these three landfill sites and dumping has
of Monkare et al. (2016), Kaartinen et al. (2013), Quaghebeur stopped. The concentration of inert waste (significantly construc-
et al. (2013) and Ramaiah et al. (2017). Hence, the wet sieving tion and demolition waste) was found to be maximum in the
method was adopted for all the three MSW samples and obtained Delhi landfill waste, while it was found the least in the Hyderabad
grain size distribution curves of MSW samples from this study. landfill. The percentage of paper was found to be almost negligi-
GSD analysis of aged MSW (<4 mm) from the Delhi landfill ble in all the landfills, as the waste considered for compositional
shows that the fraction below 0.0075 mm was 8% on a dry basis, analysis was very old and paper-like material would have decom-
while after washing (i.e. wet basis) it becomes 43%. Similarly, posed owing to environmental factors.
GSD analysis of aged MSW (<4 mm) from the Hyderabad land-
fill shows that the fraction below 0.075 mm in the dry sample was
2%, while after washing it becomes 25%. GSD analysis of aged
Moisture content and organic content
MSW from the Kadapa landfill also revealed that the fraction Significant moisture and organic matter contents are normally to
below 0.0075 mm in the dry sample was 12%, while after be expected in the fine fractions. These interrelated parameters
are of critical relevance, since processing routes and possible end
uses for these fractions will depend on their quantities (Parrodi
et al., 2017). The moisture content and organic content in finer
fraction of MSW were found to be least at the Kadapa site, while
at the Hyderabad landfill these were found to be higher. Organic
content at the Delhi landfill ranges between 6.8%–7.4%. From
Table 8 it can been observed that the inert waste is present in
maximum concentration at the Delhi landfill of around 25%.
Therefore, organic content was also found less in aged waste
from the Delhi landfill.
Table 9 shows the results obtained for moisture content and
organic content from various landfill mining studies. The mois-
ture content and organic content obtained in the present study are
observed to be less than that reported in the literature. The waste
was dried for 7–8 days before performing the sieve analysis and
the values reported are determined after performing the sieving
except in the case of Hyderabad landfill where the waste as trom-
Figure 4.  Newspaper clipping confirming age of waste. meled without air drying.

Table 6.  Grain size distributions at the three sites on partially air-dried/wet samples.

Sieve size (mm) Kadapa landfill Hyderabad landfill Delhi landfill


0–4 26.5 14.9 33.2
4–8 12.7 Not available Not available
8–30 15.6 Not available Not available
>30 26.7 Not available Not available
4–16 Not available Not available 20.4
4–20 Not available 15.5 Not available
>20 Not available 74.2 Not available
16–35 Not available Not available 14
35–80 Not available Not available 10
80–200 Not available Not available 11
>200 Not available Not available 3
8 Waste Management & Research 00(0)

The organic content observed in mined soil-like material var- 0.3%–0.4%, chloride was 0.1%–0.15%, while sulphate was
ies between 5%–15%, whereas the organic content in local soil 0.08%–0.09%.
(Delhi silt) was found to vary between 0.6% and 0.9%. Table 10
depicts the tolerance limit for organic content of the soil to be
Heavy metal analysis
used in earthfill/subgrade given by various regulatory authorities.
The permissible limit is 5% or less. The results of heavy metal analysis for all the three landfills in
comparison with the local soil (Delhi silt) and global standards
(Canadian, Dutch and Continental crust) are presented in Table 12.
TDS On comparing the concentration of heavy metal in the present
TDS were determined as per IS 2720-21 (1997) (1:10 dilution). study with the various standards. It was found that copper, chro-
The sample for TDS was prepared as per IS 2720-21 (1997); 20 g mium and cadmium were found to be high in almost all the
of soil-like material was mixed with 200 ml water (1:10 dilution) landfills.
and then it was shaken for 15 h at 200 r min-1. After that, it was Table 13 shows the comparison of metal concentrations in the
allowed to settle down for 24 h and then it was decanted through finer fraction of solid waste collected from all the three landfills
a Whatman filter paper 42. The filtrate was further centrifuged with results of similar studies reported in literature. Table 13
for 15 min at 10,000 r min-1, then 100 ml of filtrate was kept at shows that the copper concentration appear to be considerably
105 °C in a thermostatically controlled oven and hence TDS was higher than those reported from the other contaminated waste
determined by gravimetrical analysis. dump sites. Heavy metal concentrations reported by Karim et al.
Sulphate and chloride were also determined on the water ali- (2017) in Bangladesh landfills are much lower than what has
quot (1:10 dilution) of aged waste from all the landfills as per been observed in this study. Kurian et al. (2003) reported that in
APHA (American Public Health Association, 1995). A high con- soil-like material from MSW, mercury, chromium and lead
tent of dissolved solids, including sulphate and chloride, were exceeded the permissible limit for compost as per Indian stand-
observed in the present study as shown in Table 11. For the ards. However as per United States Environmental Protection
Kadapa landfill, TDS was found lower in comparison with the Agency (USEPA) standards, all are within the standard limits.
Delhi and Hyderabad landfills.
In comparison with local soil (Delhi silt) these results are
significantly higher. The TDS in the Delhi silt was found to be Elemental analysis
Elemental analysis of compost samples was also carried out as
shown in Table 14.
It can be observed that the soil-like material falls in between
the range for local soil and compost. However, it can neither be
classified as compost nor as soil.

Release of colour
Concerns about the colour of the water that leached out through
soil-like material mined from dumps has not been reported in the
literature. However, if the soil is used in filling low lying areas or
in embankment/subgrade, the leaching of coloured water may
Figure 5.  Wet GSD on <4 mm portion of aged MSW. cause contamination of the surrounding water bodies and may

Table 7.  Compositional analysis of aged MSW.

Components Percentage

  Delhi landfill Hyderabad landfill Kadapa landfill


Soil like material 71.9 73.1 75.2
C&D waste 23.4 15.4 16.2
Plastics 3.3 2.7 3.7
Textiles 0.8 1.4 1.01
Glass 0.2 2.6 1.73
Wood 0.2 1.5 1.30
Others 0.5 0.5 1.5
Total 100 100 100

C&D: construction and demolition.


Somani et al. 9

Table 8.  Moisture content and organic content after partial also have aesthetic issues. The colour of the leached water was
air-drying and screening. observed to be dark brown in the case of the Hyderabad landfill,
Landfill site MC (%) OC (%) while for the Delhi landfill it was comparatively lighter, as shown
in Figure 6. The colour of the water leached out from local soil
Kadapa 6–8 6.5–6.7 appears to be clean and transparent, while the mined materials a
Hyderabad 16–18 11–12
have darker and objectionable colour.
Delhi 10–11 6.8–7.4
The intensity of colour is presented in Table 15. It can be
MC: moisture content; OC: organic content. observed that the intensity of colour coming out from the

Table 9.  Moisture content and organic content reported in literature from landfill mining projects.

S.No. Landfill site Reference Particle size MC (%) OC (%)


1 Perungudi, India Kurian et al., 2003 <20 mm 21.4–52 8.9–15.8
2 Kodungaiyur, India Kurian et al., 2003 <20 mm 15.5–46 8.9–20.7
3 Hogbytorp, Sweden Jani et al., 2016 <10 mm 23.5 16.6
4 Deonar, India Kurian et al., <8 mm 14 14.50
2003
5 4 landfill sites, UK Gutierrez et al., <19 mm 25-41 58–79
2015

MC: moisture content; OC: organic content.

Table 10.  Permissible organic content in soil to be used in subgrade/earthfill.

S.No. Name of country Maximum limit for organic content Regulatory organisation
1 USA Indiana 3% for road subgrade Indiana Department of Transportation (INDOT)
(El Howayek et al., 2012)
Louisiana 5% Louisiana Standard Specification for Road and
Bridges (2016)
Texas 1% Texas Department of Transportation (2005)
California If organic content is up to 1% Department of Transportation, California (Jones D
then soil can be used without any and Jones D (2010))
treatment. Maximum limit is 5%
2 Australia 1% Department of Transport and Main Roads
3 India 3% Ministry of Road Transport and Highway (2002)
4 UK 2% UK Department of Transportation (1991)

Table 11.  Total dissolved solids from all the landfills.

S.No. Landfill TDS (%) Chloride (%) Sulphate (%)


1 Delhi landfill 1.4–1.5 0.7–0.75 0.4–0.45
2 Hyderabad landfill 1.80–1.85 0.5–0.55 0.8–0.85
3 Kadapa landfill 0.50–0.55 0.36–0.38 0.09–0.10

TDS: total dissolved solids.

Table 12.  Metal concentrations in finer fraction from all the landfills.

Landfill sites Heavy metals concentration (mg kg-1 dry weight)

Co Ni Cr Fe Mn Pb Zn Cu Cd
Kadapa 6.16 25.15 68.59 6660 253.5 85.58 115.05 148.34 7.66
Hyderabad 5.09 20.48 88.75 5750 134.8 81.46 129.95 329.28 8.53
Delhi 14.96 66.06 135 9282 319.8 81.01 63.98 271.31 1.89
Local soil (Delhi silt) 10.8 28 11.2 3800 105 30.85 55.32 233.35 1.7
Canadian standards (Canadian 40 50 64 — — 70 200 63 1.4
Council of Ministers of the
Environment, 1999)
Dutch standards, (VROM, 2001) 190 100 — — — 530 720 190 13
Continental crust (Wedephol, 1995) 19 5.59 25.4 45,000 105 15.1 30.5 14.5 0.1
10

Table 13.  Comparison of metal concentrations in fine fraction of solid waste of present study with similar studies.
Landfill location Conc. (mg kg-1 on dry basis)

Hg As Cd Ni Pb Cu Cr Zn Mn Co Fe

Perungudi, India (Joseph et al., 2004) 0.29 0.57 1.29 ±0.31 32 ±8 86 ±16 113 ±42 140 ±40 284 ±111 — — —
Shanghai, China (Zhang et al., 2008) — — 1.5–2.8 30–51 98–173 78–221 143–229 228–323 — — —
Matuali, Bangladesh (Karim et al., 2017) — — N.D. 0.84–9.89 5.66–87.89 14.41–137.70 10.10–81.19 19.41–163.80 9.66–82.89 —
Khulna, Bangladesh (Karim et al., 2017) — — N.D. 0.42–0.90 11.18–69.6 4.72–14.66 1.72–2.96 12.46–29.4 16.28–24.26 —
Kano, Nigeria (Anake et al., 2009) — — 22.3 ±19.3 6.0 ±8.72 2917 ±538 — 81.2 ±61.3 — — — —
Kaduna, Nigeria (Anake et al., 2009) — — 1.17 ±0.71 0.67 ±0.3 84.3 ±41.3 — 10.8 ±1.15 — — — —
Gboko dump site, Nigeria (Benjamin et al., 2012) — 0.145 0.499 0.445 1.063 — 0.278 —  
Fiborna landfill, Sweden (Joseph et al., 2004) 1.6 12 88 53 0.39 500  
Shanghai landfill, China (Xiaoli et al., 2007) 1–3 44–61 280–440 300–540 110–160 970–1360  
Madurai dump site (Anjanapriya and Lalitha, 2015) 2.55–4.28 32.1–41.2 19.9–22.3 53–85.3 290–300 298–310 98–206 303–380  
Kudjape landfill, Estonia (Kaczala et al., 2017) 4–6.4 1.12–1.21 29–44 128–477 191–362 54–123 1300–2000 313–383 5.6–8.1 29,600–53,900
Kuopio landfill, Finland (Kaartinen et al., 2013) <100 100 100–200 75–217 100–200 600–1100 700–1300 — 37,000–41,000
Hogbytorp landfill, Sweden (Jani et al., 2016) 0.7 (0.2) 5.1 (1.7) 2.1 (0.6) 111.4 (33.7) 240 (65.3) 1460 (684) 254 (54) 1848 (488) — 23.3 (5.8) 28,724 (8108)
Present Kadapa — — 7.66 25.15 85.58 148.34 68.59 115.05 253.45 6.16 6660.0
study Hyderabad — — 8.53 20.48 81.46 329.28 88.75 129.61 134.88 5.09 5750.0
Delhi — — 1.89 66.06 81.01 271.31 135.95 63.81 319.75 14.96 9282.5
Waste Management & Research 00(0)
Somani et al. 11

Table 14.  Elemental analysis of finer fraction of aged MSW. Table 15.  Colour of water released from soil reclaimed in
comparison with local soil.
Sample N (%) C (%) H (%) S (%) O (%)
Landfill site Colour (Pt-Co unit)
Delhi landfill 0.2 3.7 0.3 0.3 2.2
Hyderabad landfill 0.7 8.5 0.7 0.3 3.7 Kadapa 440–480
Kadapa landfill 0.3 4.1 0.4 0.1 1.5 Hyderabad 1500–1800
Local soil (Delhi silt) 0.01 0.97 0.23 0.05 0.08 Delhi 320–340
Compost (Bawana plant, 0.53 8.42 0.85 0.40 6.19 Local soil 25–35
Delhi)

Declaration of conflicting interests


The authors declared no potential conflicts of interest with respect to
the research, authorship, and/or publication of this article.

Funding
The authors disclosed receipt of the following financial support for
the research, authorship, and/or publication of this article: Financial
support provided by IIT Delhi (under Faculty Interdisciplinary
Research Project scheme) and logistic support provided by Ramky
Enviro Engineers Ltd (REEL) and South Delhi Municipal
Figure 6.  Colour of the leached through aged MSW. Corporation (SDMC) is greatly acknowledged.
Left to Right: Kadapa landfill, Hyderabad landfill, Delhi landfill and
local soil sample.
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