ea ee ee (a) Define the following terms : (i) Molarity (ii) Molal elevation constant (K, ») (b) A solution containing 15 g urea (molar mass = 60 g mol-) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 190 g mol!) in water. Calculate the mass of glucose present in one litre of its solution. OR (a) What type of deviation is shown by a mixture of ethanol and acetone? Give reason. (b) A solution of glucose (molar mass = 180 g mol-) in water is labeled as 10% (by mass). What would be the molality and molarity of the solution? (Density of solution = 1.2 g mL") [DELHI 2015] (a) A10% solution (by mass) of sucrose in water has a freezing point of 269.15 K. Calculate the freezing point of 10% glucose in water if the freezing point of pure water is 273.15 K. Given: (Molar mass of sucrose = 342 g mol") (Molar mass of glucose = 180 g mol-!) (b) Define the following terms: (i) Molality (m) (ii) Abnormal molar mass [ALL INDIA 2017]8. (a) State Raoult’s law for a solution containing volatile components. How does Raoult’s law become a special case of Henry’s law? (b) 1.00 g of a non-electrolyte solute dissolved in 50 g of benzene lowered the freezing point of benzene by 0.40 K. Find the molar mass of the solute. (K, for benzene = 5.12 K kg mol")9. 3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62 K. Calculate the Van’t Hoff factor and predict the nature of solute (associated or dissociated). (Given: Molar mass of benzoic acid = 122 g mol, K, for benzene =4.9 K kg mol”)6. Calculate the emf of the following cell at 25°C Ag(s)| Ag’ (10M) || Cu** (10M) | Cu(s) Given E®., = +0.46 V and log10" =n [ALL INDIA 2013] 7. (a) Calculate ArG® for the reaction Mg(s) + Cu** (aq) Mg** (aq) + Cu(s) Given: E°,, = +2.71V,1F = 96500mol"! (b) Name the type of cell which was used in Apollo space programme for providing electrical power. [ALL INDIA 2014](a) Define molar conductivity of a solution and explain how molar conductivity changes with change in concentration of solution for a weak and a strong electrolyte. (b) The resistance of a conductivity cell containing 0.001 M KC] solution at 298 K is 1500 ©. What is the cell constant if the conductivity of 0.001 M KCI solution at 298 Kis 0.146 x10°S cm™!? (a) Define the following terms: (i) Limiting molar conductivity (ii) Fuel cell (b) Resistance of a conductivity cell filled with 0.1 mol L- KCl solution is 100 Q. If resistance of the same cell when filled with 0.02 mol L-! KCl solution is 540 Q, calculate the conductivity and molar conductivity of 0.02mol L KCl solution. The conductivity of 0.1 mol L~ KCI solution is 1.29 x 10° Q"1 em-!1.29 x 107.07 em,3. 5. What do you understand by the rate law and rate constant of a reaction? Identify the order of a reaction if the units ofits rate constant are: @ L mols} (ii) Lmol s [ALL INDIA 2011] What do you understand by the ‘order of a reaction’? Identify the reaction order from each of the following units of reaction rate constant: (i) L mol s1 (ii) Lmol s [ALL INDIA 2012] For a reaction: H, + Cl, ——2HCl Rate =k (i) Write the order and molecularity of this reaction. (it) Write the unit of ‘R’, [ALL INDIA 2016] For the reaction 2N,0;(g)——> 4N0, (g)+0, (8), the rate of formation of NO, (g) is 2.8 x 10° Ms“. Calculate the rate of disappearance of N,0, (g). [ALL INDIA 2018]7. A first order reaction takes 20 minutes for 25% decomposition. Calculate the time taken when 75% of the reaction will be completed? (Given: Jog2 = 0.8010, log3 = 0.4771, log4 = 0.6021) [ALL INDIA 2017] 8. A first order decomposition reaction takes 40 minutes for 30% decomposition. Calculate its ty value. [DELHI 2016]2. Determine the values of equilibrium constant (Ke) and AG® and for the following reaction: Ni(s)+2Ag* (aq) > Ni** (aq) + 2Ag(s) E® =1,05V(1F = 96500C mol *)