Chemical Equilibrium JEE Main 2021 (August) Chapter-wise Questions

 
Questions with Answer Keys MathonGo

Q1 2021 (27 Aug Shift 2)

When 5.1 g of solid NH 4 HS is introduced into a two litre evacuated flask at 27 ∘

,
C 20% of the solid

decomposes into gaseous ammonia and hydrogen sulphide. The K for the reaction at 27 p
∘
C is x × 10 . The
−2

value of x is ____.

(Integer answer)

[ Given R = 0.082 L atm K
−1
 mol
−1
]

Q2 2021 (27 Aug Shift 1)

The number of moles of NH , that must be added to 2 L of 0.80 M AgNO in order to reduce the
3 3

+
concentration of Ag ions to 5.0 × 10
+ −8
M (Kformation  for [Ag(NH3 ) ]
2
= 1.0 × 10 )
8
is ____.

(Nearest integer)

[Assume no volume change on adding NH ] 3

Q3 2021 (26 Aug Shift 2)

The reaction rate for the reaction

[PtCl4 ]
2−
+ H2 O ⇌ [Pt (H2 O) Cl3 ]
−
+ Cl
−

was measured as a function of concentrations of different species. It was observed that

2−
−d[[PtCl4 ] ]

−5 2−
= 4.8 × 10 [[PtCl4 ] ] − 2.4×
dt

10
−3
[[Pt (H2 O) Cl3 ]
−
] [Cl
−
] .

where square brackets are used to denote molar concentrations. The equilibrium constant K c
= ____.(Nearest
integer)

Q4 2021 (26 Aug Shift 2)

The equilibrium constant K at 298 K for the reaction A + B ⇌ C + D

is 100 . Starting with an equimolar solution with concentrations of A, B, C and D all equal to 1M, the
equilibrium concentration of D is ____×10 −2
M. (Nearest integer)

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Chemical Equilibrium JEE Main 2021 (August) Chapter-wise Questions
 
Questions with Answer Keys MathonGo

Q5 2021 (26 Aug Shift 1)

The OH concentration in a mixture of 5.0 mL of 0.0504 M NH

−
4 Cl and 2 mL of 0.0210 M NH solution is
3

x × 10
−6
M . The value of x is ____. (Nearest integer)

[ Given K w = 1 × 10
−14
and Kb = 1.8 × 10
−5
]

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Chemical Equilibrium JEE Main 2021 (August) Chapter-wise Questions
 
Questions with Answer Keys MathonGo

Answer Key

Q1 (6) Q2 (4) Q3 (50) Q4 (182)

Q5 (3)

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Chemical Equilibrium JEE Main 2021 (August) Chapter-wise Questions
 
Hints and Solutions MathonGo

Q1 (6)
5.1 g
moles of NH 4 HS initially taken = 51 g/mol

= 0.1 mol

volume of vessel = 2ℓ

NH4 HS(s) ⇌ NH3( g) + H2  S(g)

t = 0      0.1 mol

t = ∞ 0.1(1 − 0.2) 0.1 × 0.2 0.1 × 0.2

⇒ partial pressure of each component

P =
nRT

V
=
0.1×0.2×0.082×300

= 0.246 atm

⇒ kP = PNH3 × PH2  S = (0.246)

2
= 0.060516

= 6.05 × 10
−2

⇒ 6

Q2 (4)

Let moles added = a

Ag
+

(aq..)
+ 2NH3(aq.) ⇌ Ag(NH3 )
+

2(aq.)

a
t = 0 0.8 ( )
2

−8 a
t = ∞ 5 × 10 ( − 1.6) 0.8
2

0.8 8
= 10
2
−8 a
(5×10 )( −1.6)
2

a
⇒ − 1.6 = 0.4 ⇒ a = 4
2

Q3 (50)
−2 −

−
[PtCl4 ] + H2 O ⇌ [Pt (H2 O) Cl3 ] + Cl

−2
−d[PtCl4 ]

dt
= 4.8 × 10
−5
[PtCl
−2

4
] − 2.4 × 10
3

0
[Pt (H2 O) Cl3 ] [u]

−5
kf 4.8×10
⇒ Keq = = −3
= 0.02
kb
2.4×10

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Chemical Equilibrium JEE Main 2021 (August) Chapter-wise Questions
 
Hints and Solutions MathonGo

Q4 (182)

A + B ⇌ C + D : Keq = 100

1M 1M 1M 1M

First check direction of reversible reaction.

[C][D]
Since Q c
=
[A][B]
= 1 < Keq. ⇒ reaction will

move in forward direction to attain equilibrium state.

⇒ A + B ⇌ C + D : Keq = 100

 to 1 1 1 1

teq.  1 − x 1 − x 1 + x 1 + x

(1+x)(1+x)
Now : K eq = 100 =
(1−x)(1−x)

2
1+x
⇒ 100 = (
1−x
)

1+x
(i) 10 = ( 1−x
)

⇒ 10 − 10x = 1 + x

⇒ 11x = 9

⇒ x =
11
9

1+x
(ii) −10 = 1−x

⇒ −10 + 10x = 1 + x

⇒ −9x = −11

⇒ x =
11

→ ' x ' cannot be more than one, therefore not valid. therefore equation concretion of (D) = 1 + x

9 20
= 1 + =
11 11

= 1.8181 = 181.81 × 10
−2

−2
≃ 182 × 10

Q5 (3)

[NH
+

4
] = 0.0504& [NH3 ] = 0.0210

+ −
[NH ][HO ]
So K b
=
4

[NH3 ]

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Chemical Equilibrium JEE Main 2021 (August) Chapter-wise Questions
 
Hints and Solutions MathonGo

Kb ×[NH3 ]
[HO
−
] = +
= 1.8 × 10
−5
×
2

5
×
210

504

[NH ]
4

−6
= 3 × 10

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