Assume that:

MNaOH = MKHP = 0.05M

VNaOH = 500mL or 0.5L
VKHP = 100mL or 0.1L
With estimated moleculare weights:
MWNaOH = 39.997 g/mol
MWKHP = 204.22 g/mol

NaOH Standardization:
moles of solute
Molarity=
Litreof Solution
0.999927 g NaOH 1 g NaOH
( )
mol 39.997 g /mol NaOH
0. 05 NaOH =
L 0.5 L NaOH
Take the assumption that MKHP is 0.05M:
moles of solute
Molarity=
Litreof Solution
1.0211 g KHP 1 g KHP
( )
mol 204.22 g/mol KHP
0. 05 KHP=
L 0.5 L KHP
KHP Solution
- 1g KHP
- 105ml
Distilled Initial burette Final burette mL, NaOH
water reading (ml) reading (ml) consumed
- 10 drops of
phenolphthal
ein
1st Trial (25mL) 0 9.2 6.8 Light Pink
2nd Trial (45mL) 9.2 16.5 7.3 Light Pink
3rd Trial (35mL) 16.5 22.3 5.8 Light Pink

NaOH + KHP → NaKP + H 2 O(1 :1)

1 mol KHP 1mol NaOH mol NaOH
weigℎed KHP ( g ) × × =
204.22 g KHP 1 mol KHP L NaOH (dispensed)

1 mol KHP 1 mol NaOH 2.8 ×10− 5 mol NaOH

1 g KHP × × =
204.22 g KHP 1 mol KHP 0.005 8 L NaOH (dispensed )
DATA
Titration

Methyl Orange Phenolphthalein indicator

No. No. of
Initial Final of Initial Final drops of
Sample
buret buret mL, drop buret buret mL, Phenolphth
Details
te te NaOH s of te te NaOH alein
Source/Vol
readi readi consu Meth readi readi consu
ume
ng ng med yl ng ng med
(ml) (ml) Oran (ml) (ml)
ge
Surface 0 0.1 0.1 10 0 0.1 0.1 10
Water
(100ml)
Tap Water 0.1 0.2 0.1 10 0.1 0.2 0.1 10
(100ml)
Mineral 0.2 0.3 0.1 10 0.2 0.3 0.1 10
Water
(100ml)

Sample Details Methyl Orange Phenolphthalein

Total Acidity
Source/Volume Acidity Acidity
Surface Water (100ml) 2.8 ×10
−8
2.8 ×10
−8
2.8 ×10
−8

Tap Water (100ml) 2.8 ×10

−8
2.8 ×10
−8
2.8 ×10
−8

Mineral Water (100ml) 2.8 ×10

−8
2.8 ×10
−8
2.8 ×10
−8

Sample computation
For Phenolphthalein:

Phenolphthalein
Initial Final No. of drops of
mL,
Sample Details burette burette Phenolphthalein
NaOH
Source/Volume reading reading
consumed
(ml) (ml)
Surface Water 0 0.1 0.1 10
(100ml)
Tap Water 0.1 0.2 0.1 10
(100ml)
Mineral Water 0.2 0.3 0.1 10
(100ml)

C sample V sample =C NaOH V NaOH

C NaOH V NaOH
C sample =
V sample
For Surface Water:
−6
C NaOH =9.51× 10 mol NaOH=computed ¿ standardization
V NaOH =0. 1 mL=.000 1 L=NaOH consumed

V sample =100 mL=0.1 L

( 2.8 ×10− 5 mol NaOH ) (0.000 1 L NaOH )

C surface water=
0.1 L SurfaceWater
−8
C surface water=2.8 ×10
For Tap Water:
−6
C NaOH =9.51× 10 mol NaOH=computed ¿ standardization
V NaOH =0. 1 mL=.000 1 L=NaOH consumed

V sample =100 mL=0.1 L

( 2.8 ×10−5 mol NaOH ) ( 0.0001 L NaOH )

C tapwater =
0.1 L Tap Water
−8
C tapwater =2.8 ×10
For Mineral Water:

C NaOH =9.51× 10−6 mol NaOH=computed ¿ standardization

V NaOH =0. 1 mL=.000 1 L=NaOH consumed

V sample =100 mL=0.1 L

( 2.8 × 10−5 mol NaOH ) (0.000 1 L NaOH )

C mineral water =
0.1 L MineralW ater
−8
C mineral water =2.8× 10

For Methyl Orange:

Methyl Orange
Initial Final No. of drops of
mL,
Sample Details burette burette Methyl Orange
NaOH
Source/Volume reading reading
consumed
(ml) (ml)
Surface Water 0 0.1 0.1 10
(100ml)
Tap Water 0.1 0.2 0.1 10
(100ml)
Mineral Water 0.2 0.3 0.1 10
(100ml)
 C sample V sample =C NaOH V NaOH

C NaOH V NaOH
C sample =
V sample
For Surface Water:

C NaOH =9.51× 10−6 mol NaOH=computed ¿ standardization

V NaOH =0. 1 mL=.000 1 L=NaOH consumed

V sample =100 mL=0.1 L

( 2.8 ×10− 5 mol NaOH ) (0.000 1 L NaOH )

C surface water=
0.1 L SurfaceWater
−8
C surface water=2.8 ×10
For Tap Water:
−6
C NaOH =9.51× 10 mol NaOH=computed ¿ standardization
V NaOH =0. 1 mL=.000 1 L=NaOH consumed

V sample =100 mL=0.1 L

( 2.8 ×10−5 mol NaOH ) ( 0.0001 L NaOH )

C tapwater =
0.1 L Tap Water

C tapwater =2.8 ×10− 8

For Mineral Water:

C NaOH =9.51× 10−6 mol NaOH=computed ¿ standardization

V NaOH =0. 1 mL=.000 1 L=NaOH consumed

V sample =100 mL=0.1 L

( 2.8 × 10−5 mol NaOH ) (0.000 1 L NaOH )

C mineral water =
0.1 L MineralW ater
−8
C mineral water =2.8× 10