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ΔG
ΔG
E o
= - G / (n F) - ( 0.05911 V / n ) log [ a Fe2+ / a Fe3+ ]
To further develop this equation requires making a choice about the activities of Fe3+ and Fe2+.
The usual choice is to take the activities of dissolved species as 10-6, although other choices can
be made.
The regions within the stability field for water where Fe3+ and Fe2+ are
stable can be determined by considering the reduction of iron (III) to
iron (II):
o
= - G / (n F) - ( 0.05911 V / n ) log [ a Fe2+ / a Fe3+ ]
Standard Free Energy of
Formation (Gf)
The standard Gibbs free energy of
formation (Δ𝐺𝑓° ) is defined as the
free energy change for the formation
of one mole of a given compound
from its constituent elements in their
standard states. Pressure (1 atm) or
Molarity (1 M)
= 0 for elements)Gf(
در شرایط استاندارد
An example is given below.
(Gf )