snitgi22, 1137 AM CHEM 115 - Fall 2022 - Helen Amadis - Gravimetric Analysis/Data Colleton -LabArchves, Your Electronic Lab Notebook (. @ CHEM 115 - Fall 2022 - Helen Ahmad/8 - Gravimetric WA Analysis/Data Collection Kein alley - Jl 17,2018, 1:18 PM EDT Exp 8 - Gravimetric Analysis - Data Collection hitpssimynotebook labarchives.comientesipin|_ pagelMTExMTUxMC4OMDAWMDAWMDAxDg NTAWOCE4NTUWMDGvTmBOZW.E2evNDAYMze2.... 1‘nin6i22, 1997 AM CHEM 115-- Fall 2022 - Helen Amadis - Gravimetric Analysis/Data Colleton -LabArchves, Your Electronic Lab Notebook (. Lab Partner: Sarah Date of Experiment: 11/08/2022 Data Collection Synthesis of salicylic ac 4) mass of methyl salicylate and graduated cylinder (9) ») mass of graduated cylinder after pouring the meth! salicylate (Q) c) mass of methy! salicylate (g) 4d) Description of salicylic acid crystals: crystals. (from woek!, part 2, step 4) €) Mass of salicylic acid and container after drying (q) (week 2) £) Mass of empty container (g) (week 1) 4g) Mass of salicylic acid (g) hh) Melting point of recrystallized salicylic acid (°C) ’) Literature value of pure salicylic acid (°C) ‘Synthesis of acetylsalicylic acid (aspirin) i) Mass of salicylic acid crystals used in this synthesis (a) k) Mass of acetylsalicylic acid (aspirin) + 50-mL beaker |) Mass of empty 50-mL beaker m) Mass of aspirin crystals Error Analysis: Helen Atmad - Nov 16, 2022, 11:97 AM EST 11.202, 6.442, 4.76. __sreating tiny white needle-like 85.863, 52.544, 3.319, hitpsimynotebook labarchives.comientesipin|_ pagelMTExMTUxMC4OMDAWMDAWMDAxIDg NTAWOCE4NTUWMDgvTmB0ZW.E2evNDAYMze2.... 2hsnitgi22, 1137 AM CHEM 115 - Fall 2022 - Helen Amadis - Gravimetric Analysis/Data Colleton -LabArchves, Your Electronic Lab Notebook (. Make notes in your lab notebook concerning changes made to the original instructions, mistakes, and potentialireal errors. These need not be in complete sentences, but should be neat and make sense to anyone who reads them. No errors or changes were made during this experiment. Data Analysis/Calculations: ‘To "show all calculations", do your work on regular paper then take a picture of it and insert it under the appropriate sections below. See the General Chemistry Laboratory Handbookfor instructions on how to calculate theoretical and percent yield in problems #1 and #3. 4.2). What is the actual (or experimental) yield of salicylic acid? _3.319, b). Use the compound determined to be the limiting reactant in the pre-lab exercise to calculate the theoretical yield in grams, (Use the actual mass from line “c" instead of the volume and density used in the pre-lab,) Show calculations. (4.76g methy| salicylate) (1mole methyl salicylate/ 152.15g methy! salicylate) = 0.031mole methyl salicylate {0.031mole methy| salicylate) (1mole salicylic acid/ 1mole methyl! salicylate) (138.12g salicylic acid) = 4,282g salicylic acid c). What is the percent yield? Show calculations. (3.319g/ 4.2829) x100% 75% 2, Write the overall reaction between methy! salicylate and water, as shown on page 1 of this document, showing all atoms and bonds. (You may leave the benzene ring as a hexagon as it will not change. Ignore the NaOH.) Circle the reactant bonds that are broken on the reactant side and the bonds that are formed on the products product side. Salicylic acid can be created by hydrolyzing methyl salicylate, an ester. In this lab, we make use of the two distinct functional groups on the aromatic ring. First, the hydrolysis of the methyl salicylate will result in the production of the free carboxylic acid group. The alcohol that hydrolysis releases is methanol. hitpssimynotebook labarchives.comientesipin|_ pagelMTExMTUxMC4OMDAWMDAWMDAxDg NTAWOCESNTUWMDgvTmB0ZW.VE2evNDAYMze2.... 3ksningi22, 1997 AM CHEM 115 - Fall 2022 - Helen Amadis - Gravimetric Analysis/Data Colleton -LabArchves, Your Electronic Lab Notebook (. 3a) Assume that the salicylic acid was the limiting reactant in the second synthesis in which aspirin was formed, What was the actual yield? b) Calculate the theoretical yield in grams. Show calculations. (3.3199 salicylic acid) (mole salicylic acid/ 138g salicylic acid) = 0.024g salicylic acid (0.024g salicylic acid) (1mole aspirin’ 1 mole salicylic acid) (180.16g aspirin) = 4.33g aspirin c) Calculate the percent yield. Show calculations. Discussion Questions: LResiate the overall premise of this experiment, (What was the most important objective?) The overall goal of this experiment is to calculate the mass of an ion in a natural compound in order to determine the ‘mass percent of an ion in an impure compound of a certain amount. The ion must be completely isolated before you ‘an determine the mass. Precipitation assists in the completion of this ion isolation. At the end of this experiment, we ‘were meant to determine the yield of aspirin. 2.2) Summarize the results of each part of the experiment. Explain which of your two syntheses resulted in the largest percent yield and provide a brief explanation for this. (Recall what was used as your reactant in step two and how this could have affected your yield.) hitpsimynotebook labarchives.comientesipin|_ pagelMTExMTUxMC4OMDAWMDAWMDAxDgINTAWOCESNTUWMDGyTmBOZWIVE2evNDAYMze?.... 4/5snit6i22, 1137 AM (CHEM 115 - Fall 2022 - Helen Amadis - Gravimetric Analysis/Data Colleton -LabArchves, Your Electronic Lab Notebook (. Salicylate acid has to be synthesized for this experiment. We achieved that by first determining the mass of the container and the methyl salicylate, and then weighing the container after the methyl salicylate had been poured. The results show that 4.769 of methyl salicylate is detected. Now we had to calculate the weights of the crystal and container together, then weigh just the container to determine the mass. These numbers can be subtracted to get the salicylic acid concentration, which came out to be 3.319. The initial syntheses yielded a high % yield. _b) Compare the melting point of your recrystallized salicylic acid to that of the literature value. What can you say about the purity of your product? 3.a) Summarize any discrepancies that occurred in the experiment, This would include changes to the procedure and known errors or mistakes that occurred. If there were no discrepancies, then state this. Never state that there were “no errors,” but rather that “no errors were observed” or something similar. ‘There were no errors which occurred during this experiment. ).During the vacuum filtration step after the synthesis of salicylic acid, a student got confused and used warm water to wash the product (instead of the cold water the procedure calls for). What will happen to the overall yield that the student calculates? ‘The yield would be lower ifthe student made the error of using warm water rather than cold. This is so because the hot filtration would remove the undissolved product. Conclusion: Provide the percent yield for each of your products and the meting point range for your first product. Itis crucial that reactions are as cost efficient as possible, and one factor for determining effectiveness is figuring out the percent yield of the reaction's product. The yield for synthesis #1 was 77.5% (the salicylic acid melting point range was not reached in the lab). hitpssimynotebook labarchives.comientesipin|_ pagelMTExMTUxMC4OMDAWMDAWMDAxDg INTAWOCESNTUWMDGvTmB0ZW.E2evNDAYMze2.... 5