Ci 15

Safety Data Sheet according to Directive 91/155/EC and
National Notification on Safety Data Sheet Preparation

Procedures and Principles (26.12.2008 - No: 27092)
NIPACIDE CI 15 Page 1(11)
Substance key: 000000054995 Revision Date: 12.05.2011

Version : 2 - 2 / TR Date of printing : 09.06.2011
SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier
Trade name
NIPACIDE CI 15
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Industry sector : Techno-chemical industry.
Type of use : Biocidal product
1.3. Details of the supplier of the safety data sheet

Identification of the company
Clariant Production UK Ltd
Unit 2, Rawdon Park

LS19 7BA Yeadon, LEEDS
Telephone no. : +44 113 239 7920
Information about the substance/mixture
Division Functional Chemicals
tel.: +44 113 2397956
e-mail: uksafetyinfo@clariant.com
1.4. Emergency telephone number

00800-5121 5121 (24 h)
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according EC Directive (67/548/EEC or 1999/45/EC, as amended)
Category of Hazard symbol R - phrases
danger/Category
corrosive corrosive Causes burns.
sensitizing Irritant May cause sensitization by skin contact.
dangerous for the Harmful to aquatic organisms, may cause
environment long-term adverse effects in the aquatic
environment.
2.2. Label elements

Labelling in accordance with EC-Directives (67/548/EEC or 1999/45/EC, as amended)
hazard warning labelling compulsory
EU Annex I Directive 67/548/EEC

Symbols/Indications of danger
Corrosive
R phrases
34 Causes burns.
43 May cause sensitization by skin contact.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S phrases
28.2 After contact with skin, wash immediately with water and soap.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
61 Avoid release to the environment. Refer to special instructions/Safety data
sheets.
2.3. Other hazards

Causes burns.
May cause sensitization by skin contact.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical characterization
Aqueous preparation of isothiazolinones
Hazardous ingredients
5-Chloro-2-methyl-2,3-dihydroisothiazol-3-one and 2-Methyl-2,3-dihydroisothiazol-3-
one (3:1)
Concentration : >= 0,6 - < 2,5 %
CAS number : 55965-84-9
Index Number 613-167-00-5
Classification hazard substance EC
T Toxic R 23/24/25
C Corrosive R 34
R 43
N Dangerous for the environment R 50
R 53
GHS classification EC

Acute toxicity Category 3 H331

Skin corrosion Category 1B H314
Skin sensitization Category 1 H317
Acute aquatic toxicity Category 1 H400
Chronic aquatic toxicity Category 1 H410
The text of the R-phrases is shown in section 16.
The text of the H-phrases is shown in section 16.
SECTION 4: First aid measures

4.1. Description of first aid measures
After inhalation
When inhaled remove to fresh air and seek medical aid.
After contact with skin
If skin problems persist, seek medical advice.
In case of contact with skin wash off immediately with soap and water
After contact with eyes
Rinse immediately with gently running water for 15 minutes, maintaining eyelids open.
Consult an ophthalmologist or a physician.
After ingestion
Rinse mouth thoroughly with water.
Do not induce vomiting.
Get medical treatment
4.2. Most important symptoms and effects, both acute and delayed
Symptoms
treat symptomatically
Hazards
No additional risks are known.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment
Treat symptomatically.
SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

water spray jet
alcohol-resistant foam
carbon dioxide
dry powder
5.2. Special hazards arising from the substance or mixture

In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Nitrous gases (NOx)
Carbon dioxide (CO2)
5.3. Advice for firefighters

Special protective equipment for firefighting
Use self-contained breathing apparatus
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective clothing.
Ensure adequate ventilation.
6.2. Environmental precautions

Do not allow spilt product to enter soil or waterways
If the product gets into drains, inform the relevant authorities immediately.
6.3. Methods and material for containment and cleaning up

Take up with absorbent material (eg sand, kieselguhr, universal binder)
Place in suitable containers and send for recovery or disposal.
6.4. Reference to other sections

Additional information
Information regarding personal protective measures see, chapter 8.
Information regarding Waste Disposal, see chapter 13.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
No special measures necessary if stored and handled as prescribed.
7.2. Conditions for safe storage, including any incompatibilities

Advice on storage compatibility
Do not store with strong oxidizing agents

Further information on storage conditions

Store at a temperature between 5 to 40 °C
Storage stability
Shelf life: 12 Months
7.3. Specific end use(s)

No further recommendations.
SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Exposure limit values
Exposure limit values are not available.
DNEL/DMEL values
DNEL/DMEL values are not available.
PNEC values
PNEC values are not available.
8.2. Exposure controls

General protective measures
Avoid contact with eyes and skin
Hygiene measures
Work in an adequately ventilated room.
Hand protection : PVC gloves
These types of protective gloves are offered by various
manufacturers. Please note the manufacturers´ detailed
statements, especially about the minimum thickness and the
minimum breakthrough time. Consider also the particular
working conditions under which the gloves are being used.
Eye protection : Safety goggles
Body protection : protective clothing
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Form : Liquid
Colour : yellow
Odour : odourless
pH value : 2 - 4 (20 °C)
Melting point : approx. 0 °C

Boiling point : approx. 100 °C

Flash point : Not applicable
Solubility in water : (20 °C)
soluble
Thermal decomposition : 200 °C (Heating rate : 3 K/min)
Method : DSC
No decomposition if used as prescribed.
Viscosity (dynamic) : 20 mPa.s (20 °C)
Method : Brookfield-Visc.
9.2. Other information

Density : approx. 1,02 g/cm3 (20 °C)
SECTION 10: Stability and reactivity

10.1. Reactivity
See section 10.3. "Possibility of hazardous reactions"
10.2. Chemical stability

Stable.
10.3. Possibility of hazardous reactions

Reactions with oxidising agents.
Reactions with reducing agents.
Reactions with amines.
10.4. Conditions to avoid

strong heat
10.5. Incompatible materials

Strong oxidizers
10.6. Hazardous decomposition products

When used and handled as intended, none.
SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute oral toxicity : LD50 > 2.000 mg/kg (rat)
Method : calculated
Acute dermal toxicity : not available

Acute inhalation toxicity : not available

Irritant effect on skin : corrosive (rabbit)
Irritant effect on eyes : corrosive (rabbit)
Sensitization : sensitizing (Guinea pig)
Repeated dose toxicity: not tested.
Assesment of mutagenicity : not tested.
Assessment of not tested.
carcinogenicity :
Assessment of toxicity to not tested.
reproduction :
Remarks
The classification was made by the conventional (calculation) method of the Dangerous
Preparations Directive (1999/45/EC)
SECTION 12: Ecological information

12.1. Toxicity
Fish toxicity : LC50 13 mg/l
Method : calculated
Daphnia toxicity : not tested.
Algae toxicity : not tested.
12.2. Persistence and degradability

Biodegradability : Method : OECD 301 D
The product is readily biodegradable according to OECD
criteria.
12.3. Bioaccumulative potential

Bioaccumulation: not tested.
12.4. Mobility in soil

Transport and distribution not tested.
between environmental
compartments :
Behaviour in environmental compartments
not tested.
12.5. Results of PBT and vPvB assessment

No data available.

12.6. Other adverse effects

Additional ecotoxicological remarks
Do not allow to enter soil, waterways or waste water
The classification was made by the conventional (calculation) method of the Dangerous
Preparations Directive (1999/45/EC)
SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product
In accordance with regulations for hazardous waste, must be taken to a hazardous
waste disposal site
Uncleaned packaging
Regulations concerning reuse or disposal of used packaging materials must be
observed.
SECTION 14: Transport information

Section 14.1. to 14.5.

ADR
UN no. UN 3265
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s., solution
Hazard inducer(s): Chloromethylisothiazolinone
Methylisothiazolinone
Class: 8
Primary risk: 8
Packing group: III
Hazard no. : 80
Remarks Shipment permitted
ADNR
UN no. UN 3265
Class: 8
Primary risk: 8
Packing group: III
RID
UN no. UN 3265
Class: 8
Primary risk: 8
Packing group: III
Hazard no. : 80

IATA
UN no. UN 3265
Class: 8
Primary risk: 8
Packing group: III
IMDG
UN no. UN 3265
Class: 8
Primary risk: 8
Packing group: III
EmS : F-A S-B
14.6. Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
No transport as bulk according IBC - Code.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
15.2. Chemical safety assessment

No Chemical Safety Assessment (CSA) is yet available for the substance, or for the
component substances, contained in this product.

SECTION 16: Other information

Text of the R-phrases assigned to the ingredients/components mentioned in section
3:
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
34 Causes burns.
43 May cause sensitization by skin contact.
50 Very toxic to aquatic organisms.
53 May cause long-term adverse effects in the aquatic environment.
List of the text of the hazard statements mentioned section 3 (H-phrases) :
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H331 Toxic if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
This information corresponds to the present state of our knowledge and is intended as a
general description of our products and their possible applications. Clariant makes no
warranties, express or implied, as to the information's accuracy, adequacy, sufficiency or
freedom from defect and assumes no liability in connection with any use of this information.
Any user of this product is responsible for determining the suitability of Clariant's products
for its particular application. Nothing included in this information waives any of Clariant's
General Terms and Conditions of Sale, which control unless it agrees otherwise in writing.
Any existing intellectual/industrial property rights must be observed. Due to possible
changes in our products and applicable national and international regulations and laws, the
status of our products could change. Material Safety Data Sheets providing safety
precautions, that should be observed when handling or storing Clariant products, are
available upon request and are provided in compliance with applicable law. You should
obtain and review the applicable Material Safety Data Sheet information before handling
any of these products. For additional information, please contact Clariant.

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Safety Data Sheet according to Directive 91/155/EC and

National Notification on Safety Data Sheet Preparation

Substance key: 000000054995 Revision Date: 12.05.2011

SECTION 1: Identification of the substance/mixture and of the

1.3. Details of the supplier of the safety data sheet

Unit 2, Rawdon Park

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.2. Label elements

Substance key: 000000054995 Revision Date: 12.05.2011

2.3. Other hazards

SECTION 3: Composition/information on ingredients

Substance key: 000000054995 Revision Date: 12.05.2011

Acute toxicity Category 3 H331

SECTION 4: First aid measures

SECTION 5: Firefighting measures

Substance key: 000000054995 Revision Date: 12.05.2011

Suitable extinguishing media

5.2. Special hazards arising from the substance or mixture

5.3. Advice for firefighters

SECTION 6: Accidental release measures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: Handling and storage

7.2. Conditions for safe storage, including any incompatibilities

Substance key: 000000054995 Revision Date: 12.05.2011

Further information on storage conditions

7.3. Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.2. Exposure controls

SECTION 9: Physical and chemical properties

Substance key: 000000054995 Revision Date: 12.05.2011

Boiling point : approx. 100 °C

9.2. Other information

SECTION 10: Stability and reactivity

10.2. Chemical stability

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

10.5. Incompatible materials

10.6. Hazardous decomposition products

SECTION 11: Toxicological information

Substance key: 000000054995 Revision Date: 12.05.2011

Acute inhalation toxicity : not available

SECTION 12: Ecological information

12.2. Persistence and degradability

12.3. Bioaccumulative potential

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

Substance key: 000000054995 Revision Date: 12.05.2011

12.6. Other adverse effects

SECTION 13: Disposal considerations

SECTION 14: Transport information

Substance key: 000000054995 Revision Date: 12.05.2011

Substance key: 000000054995 Revision Date: 12.05.2011

14.6. Special precautions for user

SECTION 15: Regulatory information

15.2. Chemical safety assessment

Substance key: 000000054995 Revision Date: 12.05.2011

SECTION 16: Other information

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