Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.C-120 WTA-14 Date: 06-11-22
Time: 10:00AM to 01:00PM JEE-ADV_(2021-P1) Max. Marks: 180

KEY SHEET
PHYSICS
1 D 2 C 3 B 4 B 5 0.18
6 0.16 7 3 8 3 9 1 10 2
11 ABC 12 AC 13 BC 14 BD 15 BCD
16 AD 17 3 18 60 19 2

CHEMISTRY
20 A 21 C 22 A 23 D 24 127.5
25 426.75 26 65 27 22.5 28 99 29 1
30 AD 31 ABCD 32 ABCD 33 ABC 34 ABD
35 ACD 36 3 37 9 38 4

MATHEMATICS
39 A 40 A 41 D 42 C 43 4
44 7.50 45 2 46 392 47 14 48 17
49 AD 50 ABCD 51 ABC 52 AC 53 ABCD
54 A 55 7 56 4 57 40
 Sri Chaitanya IIT Academy 06-11-22_Jr.C-120_Jee-Adv(2021-P1)_WTA-14_Key & Sol’s

SOLUTIONS
PHYSICS
1. Given, Length of cylinder, 1=80cm
Radius of the cylinder, r=20cm Moment of inertia of the cylinder I=2.7 k g m 2
2
I  ICM  M d
3 2
Mr  L 
From the parallel axis theorem  I   M    d  L / 2
2  2 
2
 0 .2 
2
 0 .8   2 16 
 2 .7  M  M    M 
100 100 
2  2   
 M  15kg
M c y lin d e r M 15
    
2 2
V c y lin d e r r L   0 .2   0 .8
3 3
 0 .1 4 9 2  1 0 k g / m

2. 1 2 2 1 1 2 1 2 2  v 7v
2 2

For sphere, mv  I  m gh or mv   m R  2  m gh or h 
2 2 2 2 5  R 10 g

1  mR 
2 2
1 2 3v
mv     m gh or h'
2 2 2  4g
For cylinder
2
h 7v / 10 g 14
  
2
h' 3v / 4g 15
3. M(1) M(2)
R R
2R
R
R 900
2
M(3) M(4) Mv
Centripetal Force Fnet 
R
G M 1M
Gravitational force between two masses  2
2
d
2
GM
So, F1 2  F1 3   M 1  M 2  M  Resultant of these two forces
 
2
2R
2
GM
 2 Combining all forces and equating with centripetal force we get
2
2R
2
GMM GMM Mv GM  1 1  2
 2        v
 
2 2
2R 2R  R R  2 4 

GM  4  2  2
GM 4  2 
    v  v 
R  4 2  R4 2

1 GM 2 2 1 
 v 
2 R

4. KE of ball in position B = mg (R – r) Science, it rolls without slipping the ratio

of rotational to translational kinetic energy will be

Sec: Jr.C-120 Page 2

 Sri Chaitanya IIT Academy 06-11-22_Jr.C-120_Jee-Adv(2021-P1)_WTA-14_Key & Sol’s
2 2
K 2 Kr K 2 5
     KT  mg (R  r)
2 5 KT 2 5 7
r r

1 2 5 10 g (R  r ) v 10 g
 mv  m g (R  r)  v     
2 7 7 R  r 7(R  r
5. Angular momentum L  Pr  PH

 1m 0.9 m
0.9m P=0.2

0.1 kg 2
 L  0 .2  0 .9  0 .1 8 k g m / s
P Or,
 J  0 .1 8
6. There will be no velocity along the string just after string becomes taut.
P cos 0 .2  0 .9
 V    1 .8 m / s
m 1  0 .1
1 1 2
 0 .1   1 .8   0 .1 6 2 J
2
Kinetic energy, K  mv  
2 2
I  I1  I 2  I 3  I 4
7.
2
 1 
 
2
 0 m  2 m 2l
 2 
2 2
 ml  2ml
2
 3m l

8. L  I
2
 3m l 

9. mv
2
K

3
R R
1
V
R
10. 2 R
T 
V
2
 T R
11. The rod is released from rest so that it falls by rotating about its contant point
with the floor without slipping.

Sec: Jr.C-120 Page 3

 Sri Chaitanya IIT Academy 06-11-22_Jr.C-120_Jee-Adv(2021-P1)_WTA-14_Key & Sol’s

12. ^ ^  ^ ^
Given F   t i  j or F  t i j
1
(   IN S and   IN )

13. dv d  kr 
2

r 
2
Given: potential energy, V Kr /2 Applying, | F |     kr
dr dr  2 
2
mv
Also F  ( particle is moving in circular orbit)
R
2
mv k
Or,  kR  v   R And angular momentum,
R m

Sec: Jr.C-120 Page 4

 Sri Chaitanya IIT Academy 06-11-22_Jr.C-120_Jee-Adv(2021-P1)_WTA-14_Key & Sol’s
 k  2
L  m vR  m  RR  km R
 m 
14. For solid cylinder,


R
F

3 3  a  2F
F  R  mR    a  For hollow cylinder,
2  R  m
 a 
   R  
2 F
F  R  2mR a  For solid cylinder
  2m
2F F
f  F  m    m g  F  3 m g
3m 3
a m ax  2  g

15. 4
2
 r A  rP 
3

2
3
 rA  By Law of conservation of
2 2
T     T   rP
GM  2  2G M
m V A r A  m V P rP
angular momentum
 V A r A  V P rP
16. The force of attraction between any two-point masses is responsible for
providing the necessary centripetal force to a mass to revolve in a circle of
radius r. Using trigonometry, we get

l l
O
r

l /2 l
cos 30   l

r 2r

2
l l Gmm l 2 Gm 3G m

2
 r   r   m r   m 
2
  
2 3
2 cos 30 3 l 3 l l
17. 3v 3v
v cm v v cm 2v 2 v cm 3v v cm rw ,
2 2R
18. 1 1 3
2
60%
K 1 43 5
1 2
R
19. M  mass of complete sphere =
4
R
3
 Mass of the removed part =
3
4 GMm GMm
R
3
 /8 F2  2
 2
3 9R 50 R
GMm
F1  2
9R

Sec: Jr.C-120 Page 5

 Sri Chaitanya IIT Academy 06-11-22_Jr.C-120_Jee-Adv(2021-P1)_WTA-14_Key & Sol’s

CHEMISTRY
20. C H  F2  C H 3 F  F   H    302 kJ / m ol
3

C H 3
 C l2  C H 3C l  C l   H    109 kJ / m ol

C H 3  B r2  C H 3 B r  B r   H    100 kJ / m ol

C H 3  I2  CH 3I  I   H    89 kJ / m ol

21.

22. CH4 is least reactive

23. v  4 0 0  4 0 0  8 0 0 m l Total heat produced = Heat taken by solution
 v S ,  T  +heat taken by calorimeter  m s ,  T  2 2

 H    8 0 0  1  4 .4    1 2  4 .4    3 5 7 2 .8 c a l

1000
H n e u tr a lis ta io n
   3 5 7 2 .8   8 .9 k c a l
400
24. enthalpy change for reaction
25. Average enthalpy
26. H r    H f  p    H f R
 90   25 

27. 12 g  90
3  ?

3  90 270
4    2 2 .5
12 12
28. 1600
 1 0 0  9 9 .4 4  9 9
1609
29. 9
 1 0 0  0 .5 5  1
1609
30. Conceptual
31.
C-H - bound cleavage

CH 3CH 2  CH 2  NO2 CH 3  CH  CH 3

NO2

Sec: Jr.C-120 Page 6

 Sri Chaitanya IIT Academy 06-11-22_Jr.C-120_Jee-Adv(2021-P1)_WTA-14_Key & Sol’s
C-C- bound cleavage

CH 3CH 2  NO2 .CH 3 NO2

32. Conceptual
33. Conceptual
34. DC–C + 6 DC – H = 620 kJ 2DC–C + 8 DC – H = 880 kJ
 2DC–C + 12 DC – H = 1240 2DC–C + 8 DC – H = 880
 4 DC – H = 360 DC – H = 90 kJ/mol  DC – C = 620 – 6 × 90 = 620 – 540 = 80
kJ/mol
35. equilibrium constant
36.
+ H2  ,  H = –119 KJ/mol

+ 3H2  ,  H = –3 × 119 KJ/mol

H°f benzene = –156 + 357

theoretical = 201 KJ/mol.
but Resonance energy =  H  f ( actual ) –  H  f ( theoretica l)

 H°f(actual) = –152 + 201 = 49 KJ/mol

37. Amount of O2 taken per day = 500 × 5
× 20 × 60 × 24 ml
100

PV
= 720 litre No. of moles of O2 taken/day =
RT

1  720
= = 29.27 C12H22O11 (s) + 12 O2 (g)  12 CO2(g) + 11H2O ( l )
0 . 082  300

1 mole 12 mole  H = –3690 J/mole By 12 moles of O2, heat liberated

= –3690 J  By 29.27 moles of O2, heat liberated
29 . 27
= × (–3690) J = 9000 J = 9 KJ
12

38. The reaction involved is: Fe2O3(s) + 2Al  Al2O3 (s) + 2Fe(s)
 H =  f H (Al2O3, s) –  f H (Fe2O3, s)
= (–1669 + 833) kJ/mol = –836 kJ/mol
Total mass of the reactants = Molar mass of Fe2O3 + 2 × (molar mass of Al)
836
= 160 + 2 × 27 = 214 gm. Fuel value per gm of mixture = = 3.906 kJ/gm
214

 3 .9 0 6 k j
= 3906 J/gm
 4

Sec: Jr.C-120 Page 7

 Sri Chaitanya IIT Academy 06-11-22_Jr.C-120_Jee-Adv(2021-P1)_WTA-14_Key & Sol’s

MATHEMATICS
39. b  c  a
2 2 2

From  A B C , cos A  .............  i 

2bc
AC b 2b
From  C A D , cos C    .............  ii 
CD a / 2 a
BD AB
From ABD , 
s in  A  9 0  s in  A D B
0

b B D C
cos A   [ fr o m E q .( ii )]. From (i) and (ii)
c
2c  a 
2 2

b  c  a  2 b o r c  a   3b
2 2 2 2 2 2 2
Now, cos A cos C 
3ca
40. Let A  9 0    r s  r   s  a   a 
0

 A 
r  s  a Tan  2 R s in A  r  r  2 R 
 
 2 
41. A b c
C ot : C ot : C ot  l : m : n th e n
2 2 2
a : b : c   m  n  : 1  n  : 1  m 
42. N
150

600

XBA  BAM  30 , N BX  120

0 0 C x
B100m
450 300
 N BA  150
0
A
M
h
F r o m  M N A , S in 4 5 
0

AN
 AN  2h

AN AB
F rom  N B A, 0
 0
s in 1 5 0 s in 1 5 0

h  50  3  1 m ts
43. a 
Radius of the circumscribed circle  R  cos ec
2 n
1  
And, radius of the inscribed circle  r  a cot  
2  n 
a a cos  / n 
R  r  
2 s in   / n  2 s in   / n 

a 1  c o s  / n  1   
  a cot  
2  2 s in   / 2 n  c o s   / 2 n  2  2n 

Sec: Jr.C-120 Page 8

 Sri Chaitanya IIT Academy 06-11-22_Jr.C-120_Jee-Adv(2021-P1)_WTA-14_Key & Sol’s
44. 360
0
1 1
In  O A B , O A  OB  r and AOB   72
0
 Area of  A O B  r  r s in 7 2 
0 2
r cos18 
0

5 2 2
pentagon
 A2   5  A r e a of AO B 
1 2  Also, Area of the circle  A1    r 2 ................( ii ) Hence,
 5  r c o s 1 8 ''  ..........( i )
 2 
r 2   
2
A1
  sec  
A2 5 2 0 5  10 
r cos18
2
a  b  c  14
45. a  b  c   a  b  c   2  ab  bc  ca 
2 2 2 2
abc
 
4R
abc  84
 196  124  72
r  r1  r2  r3   a b  b c  c a  s
2

ab  bc  ca  13  49  62,

46. a  b  c  3abc   a  b  c   a  b  c  ab  bc  ca 
3 3 3 2 2 2

 3 84   14 72  62 

 392
47. A H  2 R cos A B H  2 R cos B C H  2 R cos C H D  2 R cos B cos C H E  2 R cos A cos C H F  2
Now AH. BH. CH=3
 BH  CH  7
2 2 2
AH
3
 cos A .cos B.cos C   4R  cos A  7
2 2
3
Now
8R
7
  cos A 
2
2
4R
48. Now HD. HE. HF
  2 R cos B cos C   2 R cos A cos C   2 R cos A cos B   8 R co s
3 2 2 2
A cos B cos C

9 9
 8R  
3
6 3
64 R 8R
49. The angles of the tringle are in A.P Now one angle is greter that 6 0 0 and other is less
Then 6 0 0 . Let A  6 0 0 . Thus, larger angles are A and B  a  1 0 A N D B  9;  B  60
0

100  c  81
2

60  c  10C  19  0  C  5 
0 2
Using the cosine formula cos 6
2  10  c
Given that a  1 0 , b  9 a r e th e lo n g e r s id e s .  c  5  6
50. In  A F E , A D is angle bisector of  A ,and AD  EF  D is m id p o in t of EF AEF is isoscel
Therefore,  A F E is isosceles triangle Now, To fond AD, Area
Area   A B C   A r e a   A B C   A r e a   A D C 
A
4 b c s in
1 1 A 1 A 2bc 2
 b c s in A  c A D s in  b A D s in AE   H .M o f b a n d c ; E F 
2 2 2 2 2 b  c b  c

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 Sri Chaitanya IIT Academy 06-11-22_Jr.C-120_Jee-Adv(2021-P1)_WTA-14_Key & Sol’s
51. 3 3  3 1 3 1
TanATanBTanC   3   TanA  3 ,T anB  ,T anC  1
3 1  3 1 3 1

 A  60 , B  75 , C  45
0 0 0

52. b  c ss  a
  b  bc  2s  s  a  a  b  c  C   / 2
2 2 2 2

2c bc
53. For a right-angled triangle inscribed in a circle of radius
R the length of the hypotenuse is 2R.
Then area is maximum when its is isosceles triangle with each side  2R

2

2   
1 R
 S  2  2 R    R
2
 r    r  2 1 R
2 S  2 1 R 
1 1 1 1 2 1
   
r1 r2 r3 r R

54. 10 40
A Q B  B Q C    T a n  , ta n 2    d  10 2 m ts
d d
55.  a  2b    a  c   0  a  c & a  2b 
2 2
triangle is isosceles
a  c b
2 2 2 2
7b 7
Now cos B   2
  8 cos B  7
2ac 8b 8
56. s in C 
1  cos A cos B
.............( i ) We know that  1  s in C  1  cos  A  B   1  A  B
s in A a in B
1 1
fr o m (1) s in C  1  C  9 0 & A  B  4 5  a , b , c  :1  k 
0 0
: 2
2 2
 10k
4 2
k
N ow  4
6

B
57. 3h/4
C

3 AC h
h/4 
Given ta n   . In  A O C , ta n    A O

5 OA 160
AB
In  A O B , ta n       h  40
OA

Sec: Jr.C-120 Page 10