ORGANIC Class 11th Level 3

Q.1 An sp3 hybrid orbital contains

(a) 1/4th s character (b) ½ s character (c) 1/3rd s character (d) 2/3rd s character

Q.2 The number of σ and π bonds in but -1-en-3-yen are

(a) 5σ and 5π (b) 7σ and 3π (c) 8σ and 2π (d) 6σ and 4π

Q.3 Toluene contains

(a) 15 σ and 3π bonds (b) 6 σ and 3π bonds (c) 9σ and 3π bonds (d) 9σ and 6π bonds

Q.4 The Cl –C-Cl angle in 1,1,2,2,-tetrachloroethene and tetra chloromethane respectively are about

(a) 1200 and 109.50 (b) 900 and 109.50 (c) 109.50 and 900 (d) 109.50 and 1200

Q.5 The strongest of the four acids listed below is

(a) HCOOH (b) CH3 COOH (c) CICH2 COOH (d) FCH2 COOH

Q.6 Strongest acid among following is

(a) CF3COOH (b) CBr3 COOH (c) CH3COOH (d) CCl3COOH

Q.7 Resonance in most of the organic molecules

(a) increases reactivity (b) decreases stability (c) increases stability (d) none

Q.8 All bonds in benzene are equal due to

(a) tautomerism (b) I –effect (c) sp2 –hybridisation (d) isomerism

Q.9 Homolytic fission of C –C bond in ethane gives an intermediate in which carbon is

(a) sp3 hybridised (b) sp2 hybridised (c) sp hybridized (d) sp2 d hybridized

Q.10 Heterolysis of carbon chlorine bond produces

(a) Two free radicals (b) Two carbonium ions (c) Two carbanions (d) One cation and one anion

Q.11 The central C-atom of free radical possesses

(a) 6 electrons (b) 8 electrons (c) 7 electrons (d) None of the above

Q.12 Which of the following species is paramagnetic in nature?

(a) Primary (b) methyl (c) secondary (d) tertiary

Q.13 Consider the following carbonation

1. C6H5CH2 2. C6H5 CH2CH2 3. C6H5CHCH3 4. C6H5C(CH3)2

The correct sequence for the stability of these is

(a) II < I < III < IV (b) II < III < I < IV (c) III < I < II < IV (d) IV < III < I < II

Q.14 The false statements among the following are

1. a primary carbocation is less stable than a tertiary carbocation

2. secondary propyl corbocation is more stable than allyl carbocation

3. a tertiary free radical is more stable than a primary free radical

4. isopropyl carbanion is more stable than ethyl carbanion

(a) 1 and 2 (b) 2 and 3 (c) 1 and 4 (d) 2 and 4

Q.15 The reaction (CH3)3 C –Br →(CH3)3 C –OH is

(a) elimination reaction (b) substitution reaction (c) free radical (d) addition reaction

Q.16 Which of the following is an example of elimination reaction ?

(a) Chlorination of methane (b) Dehydration of ethanol (c) Nitration of benzene (d) Hydroxylation of ethylene

Q.17 The reaction CH2 = CH –CH3 + HBr →CH3. CH (Br) CH3 is

(a) nucleophilic addition (b) electrophilic addition (c) electrophilic substitution (d) free radical addition

Q.18 The reaction C2H5I + KOH → C2H5OH + KI is called

(a) hydroxylation substitution (b) selectrophilic substitution (c) nucleophilic substitution (d) dehydroiodination

Q.19 The isomers have the same

(a) structural formula (b) chemical properties (c) molecular formula (d) physical properties

Q.20 An alkane can show structural isomerism if it has number of minimum carbon atoms.

(a) 1 (b) 2 (c) 3 (d) 4

Q.21 An isomer of ethanol is

(a) methanol (b) dimethyl ether (c) diethyl ether (d) ethylene glycol

Q.22 Which are isomers ?

(a) methanol and methoxymethane (b) ethanol and ethoxyethane

(c) propionic acid and ethyl acetate (d) propionaldehyde and acetone

Q.23 How many cyclic isomers of C5H10 are possible?

(a) 4(b) 3 (c) 2 (d) 5

Q.24 CH3CHCl2 and CH2Cl. CH2Cl show which type of isomerism?

(a) functional (b) Chain (c) Position (d) metamerism

Q.25 Which of the following will show metamerism?

(a) CH3 COC3 H7 (b) CH3 SC2 H5 (c) CH3OCH3 (d) CH3OC2H5

Q.26 How many structural formula are possible for C5H11 Cl ?

(a) 6(b) 8 (c) 10 (d) 12

Q.27 How many chain isomers can be obtained from the alkane C 6H14 ?

(a) 4(b) 5(c) 6 (d)7

Q.28 But -2- ene exhibits geometrical isomerism due to

(a) rotation around C2 – C3 double bond (b) rotation around C3 – C4 sigma bond

(c) restricted rotation around C = C bond (d) rotation around C 1 – C2 bond

Q.29 Which of the following will show geometrical isomerism ?

(a) 1 –butene (b) 1.2-Dibromobutene (c) Propene (d) Isopropylene

Q.30 Which of the following has the lowest exhibit cis trans ( geometrical ) isomerism?

(a) 2- Butene (b) 2- Butyne (c) 2- Butanol (d) 1 –Butene