A Chemistry Point

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STD-12 Exam Type : Ch :2 known question test Total Marks : 60 Hours : 2 Hrs

Answer following question as asked (Each of three marks)

(1) State and explain Henry's law. What is the importance of Henry's law constant.
(2) (i)Explain painful condition known as bends with the help of Henry's law.
(ii)At higher altitudes, people suffer from a disease called anoxia. Explain why?
(3) Derive Raoult's law for a solution containing volatile liquids.Give graph and conclusion drawn from it
(4) State Raoult's law .Derive an equation to express that relative lowering of vapour pressure for a
solution is equal to the mole - fraction of the solute in it when the solvent alone is volatile.
(5) Why positive deviation in Raoult’s law take place for solution.Give characteristics and two example
(6) Why the boiling point of a liquid gets raised on dissolution of non - volatile solute into it? Illustrate
elevation in boiling point with the help of vapour pressure - temperature curve of a solution.
(7) What are isotonic, hypertonic and hypotonic solutions? Explain with the help of examples.
(8) Why do we get abnormal molecular masses from colligative properties?What is van't Hoff factor?

Solve the following :

(9) A solution contains 90 g of H2O, 6.4 g of methanol and 18.4 g of glycerol. What is the mole - fraction
of glycerol? (Glycerol = CH2CH - CHOH - CH2CH)
(10) If N2 gas is bubbled through water at 293 K, how many milli moles of N2 gas would dissolved in 1
litre of water? Assume that N2 exerts a partial pressure of 0.987 bar. Given that Henry's law
constant for N2 at 293 K is 76.48 k bar.
(11) Vapour pressure of chloroform (CHCl3) and dichloromethane (CH2Cl2) at 298 K are 200 mm Hg and
415 mm Hg respectively. Calculate (i) the vapour pressure of the solution prepared by mixing 25.5g
of CHCl3 and 40 g of CH2Cl2 at 298 K and (i) Mole fraction of each component in vapour phase.
(12) The vapour pressure of pure benzene at a certain temperature is 0.85 bar. A non - volatile, non -
electrolyte solid weighing 0.5 g when added to 39 g of benzene (molar mass 78 g mol -1), Vapour
pressure of the solution, them is 0.845 bar. What is the molar mass of the solid substance?
(13) 2 gm of benzoic acid (C6H5COOH) dissolved in 25 gm of benzene shows a depression in freezing
point equal to 1.62 K. Molal depression constant for benzene is 4.9 K kg mol-1.
(a) What is the percentage of association of benzoic acid if it forms dimmer in benzene?
(b) Calculate the van't Hoff factor and predict the nature of the solute.
(14) 0.6 mL of acetic acid (CH3COOH), having density 1.06 g mL-1 is dissolved in 1 litre of water. The
depression in freezing point observed for this strength of acid was 0.0205 K. Calculate the van't Hoff
factor and the dissociation constant of acid. (Given Kf = 1.86 K kg mol-1)
(15) A solution containing 0.8960 g of K2SO4 in 500 mL solution. Its osmotic pressure is found to be 0.690
atm at 27oC. Calculate the value of Van't Hoff factor. (At. mass K = 39, S = 32, O = 16), R = 0.082 atm
mol-1K-1
(16) Vapour pressure of pure water at 298 K is 23.8 m m Hg. 50 g of urea (NH2CONH2) is dissolved in 850 g of water.
Calculate the vapour pressure of water for this solution and its relative lowering.
(17) How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na 2C03 and
NaHCO3 containing equimolar amounts of both?
(18) Calculate the mass of a non-volatile solute (molecular mass 40 g mol-1) that should be dissolved in 114 g of
octane to reduce its pressure to 80%. (C.B.S.E. Outside Delhi 2008)
(19) A solution containing 30g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at
298 K. Further, 18g of water is then added to the solution and the new of vapour pressure becomes 2.9 kPa
at 298 K. Calculate (i) molar mass of the solute. (ii) vapour pressure of water at 298 K.
(20) Two elements A and B form compounds having formula AB2 and AB4. When dissolved in 20g of benzene (C6H6),
1 g of AB2 lowers the freezing point by 2.3 K whereas 1.0 g of AB4 lowers it by 1.3 K. The molar depression
constant for benzene is 5.1 K kg mol-1. Calculate atomic masses of A and B.
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