This document contains a test paper with 18 questions related to electrochemistry and chemical kinetics. The questions cover topics such as:
1. Molar conductivity and how dilution affects it.
2. Kohlrausch law and how it can be used to determine molar conductivity of a weak electrolyte.
3. Calculating EMF of a cell using standard reduction potentials.
4. Differences between metallic and electrolytic conductivity.
5. Calculating molar conductivity from resistivity and cell constant.
6. Explaining the Nernst equation.
7. Factors that affect the rate of a chemical reaction.
This document contains a test paper with 18 questions related to electrochemistry and chemical kinetics. The questions cover topics such as:
1. Molar conductivity and how dilution affects it.
2. Kohlrausch law and how it can be used to determine molar conductivity of a weak electrolyte.
3. Calculating EMF of a cell using standard reduction potentials.
4. Differences between metallic and electrolytic conductivity.
5. Calculating molar conductivity from resistivity and cell constant.
6. Explaining the Nernst equation.
7. Factors that affect the rate of a chemical reaction.
This document contains a test paper with 18 questions related to electrochemistry and chemical kinetics. The questions cover topics such as:
1. Molar conductivity and how dilution affects it.
2. Kohlrausch law and how it can be used to determine molar conductivity of a weak electrolyte.
3. Calculating EMF of a cell using standard reduction potentials.
4. Differences between metallic and electrolytic conductivity.
5. Calculating molar conductivity from resistivity and cell constant.
6. Explaining the Nernst equation.
7. Factors that affect the rate of a chemical reaction.
This document contains a test paper with 18 questions related to electrochemistry and chemical kinetics. The questions cover topics such as:
1. Molar conductivity and how dilution affects it.
2. Kohlrausch law and how it can be used to determine molar conductivity of a weak electrolyte.
3. Calculating EMF of a cell using standard reduction potentials.
4. Differences between metallic and electrolytic conductivity.
5. Calculating molar conductivity from resistivity and cell constant.
6. Explaining the Nernst equation.
7. Factors that affect the rate of a chemical reaction.
TEST-PAPER A. CLASS -12 9. Calculate the mole fraction of ethyl alcohol and Chapter – SOLUTION AND SOLID STATE water in the solution of 92 g ethyl alcohol and 72 g water. 1. What is Raoult’s law? Derive its mathematical 10. 8 gm NaOH is dissolved in 500 g water. expression. Calculate the molality of the solution. 2. What are ideal and Non ideal solutions? Give 11. The number of atoms in the face centred cubic examples. structure are 3. Write three differences between positive (a) 4 (b) 6 (c) 3 (d) 2 deviation and negative deviation of Non ideal 12. In NaCl crystal each sodium ion is surrounded solutions. by 4. What is molal boiling elevation constant? Derive a relationship between molecular mass (a) 3 Cl- (b) 8 Cl- of solute and boiling point elevation (c) 4 Cl- (d) 6 Cl- 5. What is molal freezing depression constant? 13. Body centred cubic lattice has a coordination Derive a relation between molecular mass of a no. solute and molal freezing point depression constant. (a) 8 (b)12 6. At 298 K, the vapour pressure of water is 23.75 (c) 6 (d) 4 mm Hg. Calculate the vapour pressure at the same temperature of 5% aqueous solution of 14. Give answer in one word urea. 1. Define Unit cell 7. In a solution 0.52 g glucose (C6H12O6) is 2. What is a crystal lattice dissolved in 80.2 gm water. Calculate the boiling point of solution. (Kb for water=0.52 Km -1) 3. Write the formula for determining 8. For benzene depression in freezing point density of a crystal constant kf=4.90 and boiling point is 5.51°C. on 4. What do you understand by coordination dissolving 0.816 g of a compound A in 7.5 g of number in a crystal. benzene, freezing point of solution becomes 5.What do you understand by radius ratio? SAINT S.R.S SCHOOL 10. 8xzke NaOH dks 500 xzke ty esa foys; TEST-PAPER fd;k x;kA foy;u dh eksyyrk Kkr dhft, A CLASS -12 11. Qyd dsfUnzr ?kuh; voLFkk esa izfr ,dd dksf’kdk CHAPTER – foy;u vkSj Bksl voLFkk ijek.kq dh la[;k gksrh gS (a)4 (b) 6 (c) 3 (d) 2 1. jkmYV dk fu;e D;k gSA blds xf.krh; #i dh 12. lksfM;e DyksjkbM fdzLVy esa izR;sd lksM;e O;qRifRRk dhft,A vk;u f?kjk gqvk gS 2. vknZ’k vkSj vukn’kZ foy;u D;k gSA mnkgj.k nhft,A (a) 3 Cl- (b) 8 Cl- 3. /kukRed rFkk _.kkRed fopyuksa esa dksbZ rhu varj crkb;s A (c) 4 Cl- (d) 6 Cl- 4. Eksyy DoFkukad mU;;u fLFkjkad D;k gS? fdlh fosys; ds vk.kfod nzO;eku vkSj DoFkukad esa lac/k 13. dk; dsfUnzr ?ku tkyd dh leUo;u la[;k gksrh n’kkZus ds fy;s O;atd mRiUu dhft,A gS & 5. Ekksyy fgekad voueu fLFkjkad D;k gS? eksyy (a) 8 (b)12 fgekad voueu fLFkjkad rFkk foys; ds vk.kfod nzO;eku esa lac/k n’kkZus okys lw+= dh LFkkiuk (c) 6 (d) 4 dhft,A 14. ,d okD; esa mRrj nhft, 6. 298 k ij ty dk ok"i nkc 23.75 mm Hg gSA 1- ;wfuV lSy dh ifjHkk"kk nhft,A blh rki ij ;wfj;k ds 5% foy;u dk ok"i nkc Kkr dhft,A 2- fdzLVy tkyd fdls dgrs gSAa 7. ,d foy;u esa 0.520 Xywdksl (C6H12O6) 3- ;wfuV lSy ds ?kuRo Kkr djus dk lw+ ¥ 80.2 ty esa foys; gSA ml foy;u dk DoFkukad crkb;sA Kkr djksA ty ds fy;s Kb=0.52 Km -1 4-fdzLVy esa leUo;u la[;k ls vki D;k le>rs 8. csathu ds fy, fgekad voueu fLFkjkad kf=4.90 gksA rFkk DoFkukad 5.51°C gSA ;kSfxd A ds 0.816 5- vk;fud f¥T;k vuqikr ls D;k le>rs g csathu 7-5 g ds esa foys; djus ij foy;u gks A dk fgekad 1.59°C gks tkrk gSA ;kSfxd A dk vk.kfod nzO;eku Kkr djks A 9. 92 xzke ,fFky ,YdksgkWy rFkk 72 xzke ty ds foy;u esa ,fFky ,sYdksgkWy vkSj ty dk eksy izHkkt Kkr dhft,A SAINT S.R.S SCHOOL 8. The rate of chemical change is directly proportional TEST-PAPER to……………………….. 9. The hydrolysis is ethyl acetate in …………… is a ………. CLASS -12 Order reaction. Chapter – ELECTROCHEMISTRY AND CHEMICAL KINETICS 10. The rate constant of a first order reaction has the Instruction M.M 50 unit ………… 1. Q.no. 1 to 7 are 5 Marks 11. The inversion of cane sugar is an example of 2. Q.no. 8 to 16 are 1 Marks ………..reaction. 3. Q.no. 17 to 18 are 6 Marks 12. The participation of total number of molecules in the reaction is called …………. 1. What is molar conductance? What is the effect of 13. Define rate of reaction dilution on molar conductance ? 14. What is specific rate constant ? 2. What is Kohlrausch law? How can molar 15. Define temperature coefficient? conductance of any weak electrolyte at infinite 16. Write Arrhenius equation. dilution be determined by the help of this law 17. Reaction of reactant A is of first order and its half 3. Calculate the EMF of following cell at 25°C life is 2 minutes. Calculate the time in which Cu (s) |Cu 2+ (aq) (0.1M) ǁ Ag + (0.1M) |Ag concentration of A is left 25 % of initial Given E°(Cu 2+/Cu) =0.34V, E° Ag (Ag+/Ag)=0.80 V concentration. 4. Give five differences between metallic and 18. The Half life of a first order reaction is 100 electrolytic conductance. seconds . Calculate the rate constant. 5. The resistivity of a 0.8 M solution of an electrolyte is 5x10 -3 ohm cm. Calculate the molar conductivity of the solution. (cell constant= 1) Prepared By- Dr. Amar Singh Thakur 6. The specific conductivity of a 0.02 mol per litre solution at 298 K is 2.48x 10 -2 ohm -1 cm -1. Find out its molar conductivity. 7. Explain Nernst equation . 7. uZULkV lehsdj.k fyf[k,A SAINT S.R.S SCHOOL TEST-PAPER 8. jklk;fud ifjorZu dh nj ---------- ds CLASS -12 lekuqikrh gSA Chapter – fo/kqr jlk;u vkSj jklk;fud cyxfrdh 9. ,fFky ,slhVsV dk ------ ek/;e esa ty vi?kVu Instruction M.M 50 ------------ dksfV dh vfHkfdz;k gSA 1. Q.no. 1 to 7 are 5 Marks 2. Q.no. 8 to 16 are 1 Marks 10.izFke dksfV dh vfHkfdz;k ds fy;s nj fLFkjkad 3. Q.no. 17 to 18 are 3 Marks dh bdkbZ------gSA 1. eksyj pkydrk fdls dgrs gSaA eksyj pkydrk 11.xUus dh 'kDdj dk izrhiu -------- vfHkfdz;k dk ij ruqrk dk D;k izHkko iM+rk gSA mnkgj.k gSA 2. dkyjkW’k dk fu;e D;k gSA bl fu;e }kjk 12.vfHkfdz;k esa Hkkx ysus okys dqy v.kqvksa dh fdlh nqcZy fo?kqr vi?kV~; ds fy, vuUr ruqrk la[;k ------- dgykrh gSA ij vk.kfod pkydrk fdl izdkj Kkr dj 13.vfHkfdz;k nj ls vki D;k le>rs gSaA ldrs gSaA 14.fof’k"V nj fLFkjkad fdls dgrs gSaA 3. fuEufyf[kr lsy dk 25°C ij EMF Kkr djks % 15.rki xq.kkad ls D;k le>rs gks A Cu (s) |Cu 2+ (aq) (0.1M) ǁ Ag + (0.1M) |Ag 16.vkjghfu;l lehdj.k fyf[k,A Given E°(Cu 2+/Cu) =0.34V, E° Ag (Ag+/Ag)=0.80 17.vfHkdkjd AV dh vfHkfdz;k izFke dksfV dh gS 4. /kkfRod pkydrk rFkk fo?kqr vi?kVuh pkydrk rFkk mldk v}Z vk;q dky 2 feuV gSA og esa 5 varj fyf[k,A le; Kkr djks tc A dk lkUnz.k izkajfHkd 5. fdlh fo?kqr&vi?kV~; ds 0.8M foy;u dh lkanz.k dk 25% jg tk;sxk A izfrjks?kdrk 5x10 -3 vkse lseh gS rks foy;u 18.izFke dksfV dh ,d vfHkfdz;k dk v}Zvk;q dky dh eksyj pkydrk Kkr dhft,A ¼lsy fLFkjkad 100 lsd.M gSA vfHkfdz;k ds osx fLFkjkad dh ¾1) x.kuk djks A 6. 0.02 eksy izfr yhVj KCl foy;u dh 298 k Prepared By- Dr. Amar Singh Thakur ij fof’k"V pkydrk 2.48x 10 -2 ohm -1 cm -1 gks rks eksyj pkydrk dk eku Kkr dhft,A