OUT GOING SR(MPC) Date: 09-06-2022

Time: 3 Hrs Max. Marks: 300

Name of the Student: ___________________ H.T. NO:

09-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-7 _QP FINAL

PHYSICS : TOTAL SYLLABUS

CHEMISTRY : TOTAL SYLLABUS
MATHEMATICS : TOTAL SYLLABUS
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PHYSICS MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

1. When the planet Jupiter is at a distance of 824.7 million kilometers from the earth, its
angular diameter is measured to be 35.72''. The diameter of the Jupiter is.
1) 1.43 109 m 2) 1.43 105 km 3) 2.94 108 m 4) 2.94 105 km
2. A heavy body of mass 25 kg is to be dragged along a horizontal plane (   1 / 3 ). The
least force required is (g = 10 m/s2)
250
1) 25 N 2) 250 N 3) 125 N 4) N
3

3. The object in figure weighs 100 kg and hangs at rest. Then T1 / T2 is

4 3 9 5
1) 2) 3) 4)
3 4 5 9

10
4. A stone of mass 1 kg tied to a light inextensible string of length L = m is whirling in
3
a circular path of radius ‘L in a vertical plane. If the ratio of the maximum tension in the
string to the minimum tension in the string is 4 and if ‘g’ is taken to be 10 m/sec2 the
speed of the stone at the highest point of the circle is
1) 20 m/s 2) 10 3 m/s 3) 5 2 m/s 4) 10 m/s

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5. From a uniform circular disc of radius a, an isosceles right angled triangle with the
hypotenuse as the diameter of the disc is removed. The distance of the centre of mass of
the remaining portion from the centre of the circle is

1) 3   1 a 2)
  1 a 3)
a
4)
a
6 3   1 3   1

6. Radius of gyration of a body depends upon

1) Shape of the body 2) Axis of rotation
3) Both (1) & (2) 4) We can’t say
7. An adiabatic cylinder has 8 gram of helium in it at 400 K and its piston of area 1 cm2
(which has mass 1 kg) is movable. If a block of mass 62 kg is placed on the piston then
the final temperature of the gas will be (Take atmospheric pressure to be 105 Nm–2 and
g = 10 m/s2)

1) 500 K 2) 800 K 3) 1200 K 4) 1600 K

8. To establish an instantaneous displacement current of a 2A in the space between two
parallel plates of 1F capacitor, the potential difference across the capacitor plates will
have to be changed at the rate of
1) 4 104 V / s 2) 4 106 V / s 3) 2 104 V / s 4) 2 106 V / s

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9. Which of the following figures best represents the variation of particle momentum and
associated de Broglie wavelength?

1) 2)


3) 4)
10. A 7Li target is bombarded with a proton beam current of 10–4A for 1 hour to
produce 7Be of activity 1.8 × 108 disintegrations per second. Assuming that one
7
Be radioactive nucleus is produced by bombarding 1000 protons. Half-life of
7
Be is ______ (approx.)
1) 6.63 × 106 sec 2) 7.63 × 106 sec 3) 8.66 × 106 sec 4) 9.63 × 106 sec
7
11. If the ratio of the concentration of electrons to that of holes in a semiconductor is and
5
7
the ratio of currents is then, the ratio of their drift velocities respectively is
4
4 5 4 5
1) 2) 3) 4)
7 8 5 4
12. For an amplitude modulated wave, the maximum and minimum amplitudes are found to
be 15V and 5V respectively. The modulation index,  is
1) 2.0 2) 3.0 3) 0.3 4) 0.5

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13. Initially the conducting spherical shells A and B are at potential VA and VB respectively.
Now sphere B is earthed by closing the switch. The potential of A will now become

B
A

1) 0 2) VA 3) VA  VB 4) VB

14. Two batteries of emfs  1 and  2   2  1  and internal resistance r1 and r2 ,

respectively are connected in parallel as shown in figure.

1) The equivalent emf  eq of the two cells is between  1 and  2 , i.e., 1   eq   2 .

2) The equivalent emf  eq is smaller than  1

3) The  eq is given by  eq  1   2 always

4)  eq is independent of internal resistances r1 and r2 .

15. A proton beam is going from north to south and an electron beam is going from south to
north. Neglecting the earth’s magnetic field, the electron beam will be deflected
1) Towards the proton beam 2) Away from the proton beam
3) Upwards 4) Downwards

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16. A conducting rod PQ is rotated in about an axis passing through O and perpendicular to
the plane of rotation of the rod with constant angular speed  . A magnetic field of
induction B is applied perpendicular to the plane of rotation. The one end of the rod is
at a distance a and other end is at a distance b from O. Find induced emf across the
ends of the rod.

1)

B b2  a 2  2)

B b 2  a 2  3)

B b2  a 2  4)

B b 2  a 2 
2 2 3 4
17. A resistance of 20  is connected to a source of an alternating voltage V  220sin 100 t  .
The minimum time taken by the current to change from the peak value to rms value is
1) 2.0 s 2) 0.25 s 3) 2.5  103 s 4) 2.5  10 3 s
18. Ratio of width of central bright to that of first bright in single slit diffraction pattern is
1) 4 2) 3 3) 2 4) 1
19. A table is revolving about its own axis at 5 revolutions per second. A sound source of
frequency 1000 Hz is fixed on the table at 70 cm from the axis. The minimum frequency
heard by a listener standing at a large distance from the table will be
(speed of sound = 352 m/s)
1) 1000 Hz 2) 1066 Hz 3) 941 Hz 4) 352 Hz
20. Which of the following functions of time represent simple harmonic.
1) x = sin ωt – cos ωt 2) x = sin3 ωt 3) x = 1 + ωt + ω2 t 4) All of these

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SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
21. A motor car is at a speed 60 m/s on a circular road of radius 1200m, which speeds up at
a constant rate 4 m / s 2 . At this instant the net acceleration of the car is (in m / s 2 )
22. The radii of circular orbits of two satellites A and B of earth are 4R and R, respectively.
If the speed of the satellite A is 3V, then the speed of satellite B will be _ __times that of
V.
23. The power radiated by a black body is ‘P’, and it radiates maximum energy around the
wavelength λ 0 . If the temperature of the black body is now changed so that it radiates
maximum energy around a wavelength λ 0 / 2 , the power radiated by it will increase by a
factor of
24. A capacitor stores 50C charge when connected across a battery. When the gap between
the plates is filled with a dielectric, a charge of 100 C flows through the battery. The
dielectric constant of the material is
25. ABC is an equilateral triangle of side 2m. There is a uniform electric field of intensity
100V/m in the plane of the triangle and parallel to BC as shown. If the electric potential
at A is 200V, then the electric potentials at B (in Volt) is

26. The ionization potential of H-atom is 13.6V. When it is excited from ground state by
0
monochromatic radiations of 970.6 A , the number of emission lines will be (according to
Bohr’s theory)
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27. The apparent dip measured using a dip circle in two mutually perpendicular planes (the
planes lie on either side of magnetic meridian) are found to be 370 and 450 respectively.

1  x 
The real dip is calculated as cot   , where x and y are least possible integers, then
 y
value of x  y is
28. A large cylindrical tank has a hole of cross-section 1cm2 at its bottom. If the water is
allowed to flow into the tank from a tube above it at the rate of 70 cm3/sec, then the
maximum height up to which water can rise in the tank is P  10 2 cm , find the value of
‘P’
29. A circular coil of 100 turns and effective diameter 20 cm carries a current of 0.5 Amp.
It is to be turned in a magnetic field of B = 2.0 T from a position in which the normal to
the plane of the coil makes an angle   0 to one in which  1800 . The work required in
this process is n J . Find n.
30. An object is kept at a distance of 16 cm from a thin lens and the image formed is real. If
the object is kept at a distance of 6 cm from the same lens the image formed is virtual. If
the size of the image formed are equal, then find the magnitude of focal length of the
lens (in cm)?

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CHEMISTRY MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
31. NO2 gas is obtained by heating
1) NH4NO2 2) NH4NO3 3) LiNO3 4) NaNO3
32. Last line of the Lyman series of H-atom has frequency v1 , last line of Lyman series of

He ion has frequency v2 and 1st line of Lyman series of He ion has frequency v3 , then
1) 4v1  v2  v3 2) v1  4v2  v3 3) v2  v3  v1 4) v2  v1  v3
33. 25ml solution containing mixture of Na2CO3 and NaOH required 20 ml of 1N HCl for
the end point using phenolphthalein. In a separate titration, 25 ml of the same mixture
required 25ml of same HCl for methyl orange end point. Ratio of moles of Na2CO3 and
NaOH taken in initial mixture
1) 1 : 1 2) 1 : 2 3) 2 : 1 4) 1 : 3
34. Which one of the following species is planar and non-polar with two lone pairs of
electrons on the central atom?
1) ClF3 2) XeF5 3) PCl5 4) BrF5
35. Match the following
List – I List – II
P) Ni (CO)4 1) Octahedral, paramagnetic
Q) [Ni(CN)4]2- 2) Square planar, diamagnetic
R) [Ni(NH3)6]2+ 3) Tetrahedral, diamagnetic
S) [NiCl4]2- 4) Tetrahedral, paramagnetic
P Q R S P Q R S
(1) 2 1 3 4 (2) 3 2 1 4
(3) 4 3 1 2 (4) 1 3 4 2

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36. Relatively strongest oxidizing agent among the following is
1) VO2 2) MnO4 3) Cr2O72 4) VO2
37. The standard electrode potential for the following reaction is +1.33 V. What is potential
at pH=2.0?
Cr2O72 (aq,1M )  14 H  (aq)  6e   2Cr 3 (aq,1M )  7 H 2O(l )
1) +1.82V 2) +1.99 V 3) +1.61 V 4) +1.05V
38. During the preparation of acetanilide from aniline, the addition of excess acetic
anhydride and prolonged heating should be avoided because
1) it is oxidized 2) it is reduced
3) diacetyl derivate is formed 4) triacetyl derivative is formed
39. When a 20 mL of 0.08 M weak base BOH is titrated with 0.08M HCl, the pH of the
solution at the end point is 5. What will be the pOH if 10 mL of 0.04 M NaOH is added
to the resulting solution?
1) 5.40 2) 5.88 3) 4.92 4) 6.88
40. In the process of extraction of gold, O
Roasted gold ore CN   H2O   X   OH  2

 X   Zn 
 Y   Au ;
 2
1) X   Au  CN  2  , Y   Zn  CN  4 
 4
3) X   Au  CN  2  , Y   Zn  CN  6 
Identify the complexes  X  and Y  .
3 2
2) X   Au  CN  4  , Y   Zn  CN  4 
 2
4) X   Au  CN  4  , Y   Zn  CN  4 

41. Which of the following statement is incorrect?

1) Ionization energy of an element is equal in magnitude but opposite in sign to the
electron gain enthalpy of the cation of that element.
2) ‘F’ has the highest Electronegativity out of all the elements in the long form of
periodic table.
3) In any period, the atomic radius of the noble gas is lowest.
4) The second ionization energy of sulphur is greater than that of chlorine.

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42. Match List-1 with List-II and select the correct answer using the codes given below the
lists:
List-I List-II
P) Benzene + Toluene 1) formation of azeotropic mixture
Chloroform + non-ideal solution with positive
Q) 2)
acetone(propanone) deviation from Raoult’s law
R) Ethanol + Acetone 3) ideal solution
S) HCl + water 4) Hmix  0

1) P  3, 4; Q 1; R 1; S 1, 2 2) P  3, 4; Q 1; R 1, 2; S 1

3) P 1; Q  3, 4; R 1; S 1,2 4) P 1; Q  3, 4; R 1,2; S 1
43. True statements for Tyndal effect
1) It is observed when diameter of dispersed particles is not much smaller than wave
length of light used
2) The refractive indices of dispersed phase and dispersion medium differ greatly in
magnitude, it is observed
3) Tyndal effect is more for lyophobic sols generally than lyophillic sols
4) All of these
44. The incorrect statement related to thin layer chromatography is
1) The relative adsorption and separation of each component of the mixture is expressed
in terms of its retardation factor.
2) A type of liquid –liquid chromatography
3) The spots of amino acids are identified by spraying with ninhydrin solution
4) The spots of some colourless compounds are identified by using with Iodine.

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45. The correct order of acidic strength of the following is
COOH COOH COOH COOH

NO2
P) Q) R) S)
NO2

NO2

1) P>Q>R>S 2) Q>S>R>P 3) S>Q>R>P 4) Q>R>S>P

Zn / HCl
46. Given that C2 H 5  X  C2 H 6  HX , Here ‘X’ can not be
1) F 2) Cl 3) Br 4) I
47.
OH
OH

OH

This conversion can be carried out by

1) H 2 SO4 / , NaBH 4 2) NaIO4 , H  /  3) HIO4 , NaBH 4 4) H  / , Zn  Hg  .HCl
48. Which of the following products will be formed on addition of water to but-1-yne in
acidic medium, in the presence of Hg 2 ions as a catalyst

O O

1) CH 2  CH 2  CH 2  C  H 2) CH 3  CH 2  C  CH 3
O O O

3) CH 3  CH 2  C  OH  CO2 4) CH 3  C  OH  H  C  H

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49. The major product of the following reaction is :

1) 2) 3) 4)

50. Among the following which one takes more than 3 minutes time to give red precipitate
on boiling with the mixture CH3COOH   CH3COO 2 Cu ?
1) D-Glucose 2) Sucrose 3) Maltose 4) D-Fructose
SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
51. Number of chiral centres in chloramphenicol is/are
52. The sum of the number of  bonds and lone pairs in the final product of the following
reaction is

53. An organic molecule has 5C = C bonds (heat of hydrogenation for one C = C bond is
28.8k J / mol) and the experimental value for heat of hydrogenation is 99 k J /mol of
compound. The magnitude of resonance energy in k J /mol of compound is

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54. Chlorine water on cooling to 00 C deposits greenish yellow crystals of Cl2 . XH 2O .
What is the value of X?
55. How many moles of dilute HNO3 can be reduced by 4 moles of zinc?
56. Under the same reaction conditions initial concentration of 1.386 mol dm 3 of a
substance becomes half in 40 sec and 20 sec through first order and zero order kinetics
k 
respectively. Ratio  0  of the rate constants for first order k1  and zero order k0  of
 k1 

the reaction is
57. Density of vapours of a substance of molar mass 18 gm/mole at 1atm pressure and 500K
100
is 0.36 kgm-3. Compressibility factor for the vapour is Z, then the value of is
Z

Take R  0.082 L atm mole1K 1 

58. The volume (in ml) of 10 volume H2O2 solution that decolourises 200 ml of 1N KMnO4
solution in acidic medium is
59. An element crystalises in FCC lattice having edge length 400 pm. The maximum
diameter in pm which can be placed in interstitial sites without disturbing the structure is
60. Assuming H 0 and S 0 do not change with temperature the boiling point of liquid A (in
K) as per the thermodynamics data given below is
Thermodynamics A (liq) A (gas)
H 0  kJ / mol  -130 -100

S 0 JK 1 mol 1
  100 200

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MATHEMATICS MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

61. If a  0 then the real roots of the equation x 2  2 a x  a  3a 2  0 , (‘ a ’ being a parameter) are

1) a 1  2  , a  1  6  2) a 1  2  , a  1  6 

3) a  1  2  , a  1  6  4) a 1  2  , a 1  2 

62. Let z1 and z2 be the complex numbers on the Argand plane such that z1  2 and

1  i  z2  1  i  z 2  8 2 , then the minimum value of z1  z2 is equal to

1) 1 2) 2 3) 3 4) 4

63. Let X denotes the determinant of matrix X and tr  X  denotes trace of matrix X. If ‘A’
2
 
is a square matrix of order 2, then tr A2   tr  A  is equal to

A
1) 2) 2 A 3) 3 A 4) 4 A
2

P 39
64. The sum of last 20 coefficients in the expansion of 1  x  is 2 where P is divisible by

1) 19 2) 17 3) 15 4) 13

65. If ‘a’ and ‘b’ are chosen randomly from the set consisting of numbers 1, 2, 3, 4, 5, 6 with
2/ x
 ax  bx 
replacement. Then the probability that xLt    6 is
0
 2 

1 1 1 2
1) 2) 3) 4)
3 4 9 9
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66. Four terms are in G.P in which the third term is greater than the first term by 9 and the
second term is greater than the fourth term by 18. Then the first term is

1) 5 2) 3 3) 4 4) 2

67. If the Boolean expression  p  q  *  p  q  is a tautology then *and  are respectively

given by

1) ,  2)  ,  3)  ,  4)  , 

68. If x1 , y1 are the roots of x 2  8x  20  0, x 2 , y 2 are the roots of

4x 2  32x  57  0 and x 3 , y 3 are 2

the roots of 9x  72x  112  0, then the points

 x1, y1  ,  x 2 , y2  and  x 3 , y3  :

1) are collinear 2) form an equilateral triangle

3) form a right angled isosceles triangle 4) are concyclic

69. Let the tangents to the parabola y 2  4ax drawn from the point ‘P’ have slope m1 and
m2 . If m1m2  2 , then the locus of point P is

a
1) x  a 2) x  3) x  a  0 4) x  2a
2

x2 y2
70. The minimum length of intercept on any tangent to the ellipse   1 cut by the
4 9
2 2
circle x  y  25

1) 8 2) 9 3) 2 4) 11

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71. The distance of the origin from the point of intersection of the line

  
r  2i  j  2k   3i  4 j  2k and the plane r. i  j  k  5 is 
1) 2 2) 4 3) 3 4) 5

cos  sin x   cos x

72. lim 
x 0 x4

1 1 1 1
1) 2) 3) 4)
6 5 4 2


  1  x s i n x    c o s x  5
 ; x  0
 x2
73. Let f  x    3 ; x  0 (  ,  ,  &   )

 1
   x   x3   x
1   2  ; x  0
   x 

If f  x  is continuous at x  0 , then the value of     2   2  e 2  is

1) 8 2) 10 3) 12 4) 26

74. An apache helicopter of enemy is flying along the curve given by y  x 2  7 . A soldier,
placed at  3, 7  wants to shoot down the helicopter when it is nearest to him. Then the

nearest distance is _______ (in units)

1) 3 2) 5 3) 0 4) 5

75. The equation of the tangent at the point on the curve 9y 2  x3 , where the normal to the
curve makes equal intercepts with the positive coordinate axes, is

1) 3 x  3 y  4  0 2) 3 x  3 y  5  0 3) 3 x  3 y  4  0 4) 3 x  3 y  10  0

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Narayana IIT Academy 09-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-7 _QP FINAL
2x x
e  2e
76.  e2x  1
dx is equal to (where ‘c’ is the constant of integration)

1
1) n  e 2x  1  tan 1  e x   c 2) n  e2x  1  tan 1  ex   c
2

1 1
3) n  e2x  1  2 tan 1  ex   c 4) n  e2x  1  2 tan 1  ex   c
2 2

1
xdx
77. The value of the definite integral  1  x  3  x  is
0

 2   3  3  3
1)   1 2) 1   3) 1   4) 1  
4 3  8 2  8 6  4 2 

 1 y2   x 2 1 
78. Solution of the differential equation   2
dx   2
  dy  0 (where ‘c’ is
 x  x  y     x  y  y 

the parameter)

x xy xy xy 2 xy
1) ln   C 2)  Ce x / y 3) ln xy  C  4) ln xy  C 
y xy x y x y x y

79. The ratio of the greatest value of f  x   2  cos x  sin 2 x , x  R to its least value is

13 7 11 9
1) 2) 3) 4)
4 4 4 4

1 x2  x
80. Let f: R     R be a function such that f  x   , a  0 , a R .
a  1  ax

The set of values of ‘a’ so that ‘f’ is onto is

1)  0,   2) 1,   3)  1,1 4) 0,1

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Narayana IIT Academy 09-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-7 _QP FINAL
SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

 1   1  1  1 
81. Let M be a 2  2 matrix such that M      and M 2      . If x1 and
1  2   1 0
x2  x1  x2  are the two values of x for which det  M  xI   0, where I is identity

matrix of order 2, then the value of  5 x1  2 x2  is (det (A) denotes the determinant of

matrix A)

82. The number of permutations of the digits 1, 2, 3, ....., 9 (taken all at a time ) in which
none of the blocks 34,45,678 appears is 9! – (8!+8!+7!)+7!+6!+6!-k! then ‘k’ must be
equal to

83. Let A  1, 2,3, 4,5 . Then the total number of reflexive relations on A is 2 , then  equals

84. Mean & variance of the numbers “12”& “14” is same as the mean & variance of the four

numbers 12, 14, &  and      . Then     __

2 2 2
85. If a, b, c are unit vectors then the value of a  2b  b  2c  c  2a does not exceed to

86. The value of ‘x’ such that the four points A = (3, 2, 1), B = (4, x, 5), C = (4, 2, -2) and

D = (6, 5, -1) are coplanar is

3
3
87. 0
cos x dx is ----------------

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Narayana IIT Academy 09-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-7 _QP FINAL

The area of the region bounded by the curves 4 y  4  x and y  7  x in sq. units is
2
88.

20

20
1
x i
89. If  sin xi  10 then
i 1
i 1

10
is equal to (sinx is invertible in the principle interval )

90. Let S1  x2 + y2 – 4x – 8y + 4 = 0 and S2 its image in the line y = x. The radius of the
3
circle touching y = x at (1, 1) and orthogonal to S2 is , then 2  2 


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